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1. 发明授权

US5744653A Method for preparing 1,3-dihydroxy-4,6-bis(.alpha.-methyl-.alpha.(4'-hydroxyphenyl)ethyl)benz ene 失效
标题翻译：制备1,3-二羟基-4,6-双（α-甲基-α（4'-羟基苯基）乙基）苯的方法
公开(公告)号：US5744653A
公开(公告)日：1998-04-28
申请号：US699190
申请日：1996-08-19
申请人： Mizuo Ito , Shigeru Iimuro
发明人： Mizuo Ito , Shigeru Iimuro
IPC分类号： B01J27/08 , B01J27/10 , B01J27/24 , C07B61/00 , C07C37/14 , C07C39/15 , C08G59/32 , C08G59/62 , C08G63/133 , C08G63/20 , C08G64/14 , C07C39/12
CPC分类号： C08G63/133 , C07C37/14 , C08G59/3218 , C08G59/621 , C08G63/20 , C08G64/14
摘要： A method for preparing 1,3-dihydroxy-4,6-bis�.alpha.-methyl-.alpha.-.alpha.(4'-hydroxyphenyl)ethyl!benzene represented by the following formula (1): ##STR1## comprising the step of initiating a reaction of resorcin with 4-isopropenylphenol in a mixed solvent which comprises a non-polar solvent and a polar solvent in the presence of an acidic catalyst. The method can easily be handled, ensures a high yield, permits the reduction of impurity content and can provide highly pure 1,3-dihydroxy-4,6-bis�.alpha.-methyl-.alpha.-(4'-hydroxyphenyl)ethyl!benzene. The resulting phenolic compound is useful as, for instance, a branching agent for polycarbonates, polyesters or the like; a raw material for radiant ray-sensitive components for use as resist materials; a raw material for epoxy resins; and a hardening agent for epoxy resins.
摘要翻译：由下式（1）表示的1,3-二羟基-4,6-双[α-甲基-α-α（4'-羟基苯基）乙基]苯的制备方法：间苯二酚与4-异丙烯基苯酚的反应在酸性催化剂存在下包含非极性溶剂和极性溶剂的混合溶剂。该方法可以容易地处理，确保高产率，允许杂质含量的降低，并且可以提供高纯度的1,3-二羟基-4,6-双[α-甲基-α-（4'-羟基苯基）乙基]苯。所得的酚类化合物可用作例如聚碳酸酯，聚酯等的支化剂; 用作抗蚀材料的辐射敏感元件的原料; 环氧树脂原料; 和环氧树脂用硬化剂。

2. 发明授权

US5157165A Method for preparing highly pure 1,1,2,2-tetrakis(4-hydroxy-3,5-dimethylphenyl)ethane 失效
标题翻译：制备高纯度1,1,2,2-四氯乙烯（4-羟基-3,5-二甲基苯基）乙烯的方法
公开(公告)号：US5157165A
公开(公告)日：1992-10-20
申请号：US796440
申请日：1991-11-22
申请人： Naru Koike , Shigeru Iimuro , Mizuo Ito
发明人： Naru Koike , Shigeru Iimuro , Mizuo Ito
IPC分类号： B01J27/10 , C07B61/00 , C07C37/11 , C07C39/15 , C07D301/28 , C07D303/24 , C08G59/06 , C08G59/32 , C08G59/62
CPC分类号： C08G59/621 , C07C37/11 , C08G59/3218
摘要： Herein provided are a method for preparing 1,1,2,2-tetrakis(4-hydroxy-3,5-dimethylphenyl)ethane (TKXE) comprising subjecting two molecules of bis(3,5-dimethyl-4-hydroxyphenyl) methane to dehydration-condensation under oxidizing conditions, an epoxy resin prepared by epoxidating TKXE obtained by the method and an epoxy resin composition comprising TKXE obtained by the method as a hardener and an epoxy resin as well as methods for preparing the resin and composition. The method makes it possible to prepare highly pure TKXE in the form of crystals. Moreover, the epoxy resin and the epoxy resin composition can provide hardened products excellent in physical properties such as heat resistance and mechanical strength.

3. 发明授权

US5399783A Preparation of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane 失效
标题翻译： 6,6'-二羟基-3,3,3'，3'-四甲基-1,1'-螺二茚满的制备
公开(公告)号：US5399783A
公开(公告)日：1995-03-21
申请号：US225559
申请日：1994-04-11
申请人： Mizuo Ito , Shigeru Iimuro
发明人： Mizuo Ito , Shigeru Iimuro
IPC分类号： C07C37/84 , C07C39/12
CPC分类号： C07C37/84 , C07C2103/84
摘要： Crystals of 6,6'-dihydroxy-3,3,3',3'-tetramethyl -1,1'-spirobiindane (hereinafter referred to as SPI) are obtained by cooling a phenol solution containing 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane when crystallization is started at a temperature higher than a transition temperature between SPI and an adduct of SPI with phenol. The crystals are washed with an organic solvent or contacted with water and further washed with an organic solvent. When crystallization is started at a temperature less than the transition temperature, adduct crystals of SPI with phenol are obtained from the phenol solution. Phenol is removed from the adduct crystals and the adduct crystals are contacted with water to obtain a hydrate and further the hydrate is washed with an organic solvent.
摘要翻译：通过将含有6,6'-二羟基-3,3,3'，3'-四甲基-1,1'-螺二茚满的酚溶液（以下称为SPI），3,3'，3'-四甲基-1,1'-螺二茚满当结晶在高于SPI与SPI与苯酚的加合物之间的转变温度的温度下开始时。晶体用有机溶剂洗涤或与水接触，并进一步用有机溶剂洗涤。当在低于转变温度的温度下开始结晶时，从苯酚溶液中获得SPI与苯酚的加合物晶体。从加合物晶体中除去苯酚，并将加合物晶体与水接触，得到水合物，再用有机溶剂洗涤水合物。

4. 发明授权

US5304624A Epoxy resin derived from the highly pure compound and method for preparing the resin and composition 失效
标题翻译：衍生自高纯度化合物的环氧树脂和制备树脂和组合物的方法
公开(公告)号：US5304624A
公开(公告)日：1994-04-19
申请号：US910209
申请日：1992-07-09
申请人： Naru Koike , Shigeru Iimuro , Mizuo Ito
发明人： Naru Koike , Shigeru Iimuro , Mizuo Ito
IPC分类号： B01J27/10 , C07B61/00 , C07C37/11 , C07C39/15 , C07D301/28 , C07D303/24 , C08G59/06 , C08G59/32 , C08G59/62 , C08G59/00
CPC分类号： C08G59/621 , C07C37/11 , C08G59/3218
摘要： A method for preparing 1,1,2,2-tetrakis(4-hydroxy-3,5-dimethylphenyl)ethane (TKXE) comprising subjecting two molecules of bis(3,5-dimethyl-4-hydroxyphenyl) methane to dehydration-condensation under oxidizing conditions, an epoxy resin prepared by epoxidating TKXE obtained by the method and an epoxy resin composition comprising TKXE obtained by the method as a hardener and an epoxy resin as well as methods for preparing the resin and composition. The method makes it possible to prepare highly pure TKXE in the form of crystals. Moreover, the epoxy resin and the epoxy resin composition can provide hardened products excellent in physical properties such as heat resistance and mechanical strength.
摘要翻译：制备1,1,2,2-四（4-羟基-3,5-二甲基苯基）乙烷（TKXE）的方法，包括使双分子的双（3,5-二甲基-4-羟基苯基）甲烷经脱水缩合在氧化条件下，通过环氧化通过该方法获得的TKXE制备的环氧树脂和包含通过该方法获得的TKXE作为硬化剂和环氧树脂的环氧树脂组合物以及制备该树脂和组合物的方法。该方法可以制备晶体形式的高纯度TKXE。此外，环氧树脂和环氧树脂组合物可以提供耐热性和机械强度等物理性能优异的硬化物。

5. 发明授权

US5395915A Method for simultaneous preparation of bisphenol F and novolak phenol resins 失效
标题翻译：同时制备双酚F和酚醛清漆酚树脂的方法
公开(公告)号：US5395915A
公开(公告)日：1995-03-07
申请号：US104920
申请日：1993-08-12
申请人： Shigeru Iimuro , Satoru Ito , Tomoko Takashima , Takashi Kitamura
发明人： Shigeru Iimuro , Satoru Ito , Tomoko Takashima , Takashi Kitamura
IPC分类号： C07C37/74 , C07C39/16 , C08G8/10 , C08G8/20 , C08G14/02 , C08G8/04
CPC分类号： C07C39/16 , C07C37/20 , C07C37/74 , C08G8/10 , C08G8/20 , Y02P20/582
摘要： Herein disclosed is a method for simultaneously preparing a highly pure bisphenol F and/or a bisphenol F for general use and a novolak phenol resin and/or a high molecular weight novolak phenol resin comprising the steps of:(1) a preparation step comprising reacting phenol with formaldehyde in the presence of an acid catalyst and removing the acid catalyst, water and the unreacted phenol from the resulting reaction product to give a crude bisphenol F;(2) a distillation step comprising distilling a part of the crude bisphenol F to give a highly pure bisphenol F, as a distillate, having a binuclear moiety-content of not less than 95% by weight and a novolak phenol resin, as a still-bottom product, having a binuclear moiety-content of not more than 15% by area;(3) a step for mixing the highly pure bisphenol F with the remaining crude bisphenol F to give a bisphenol F for general use; and(4) a step for polymerizing the novolak phenol resin with formaldehyde in the presence of an acid catalyst to give a high molecular weight novolak phenol resin.
摘要翻译：本文公开了一种用于同时制备用于一般用途的高纯度双酚F和/或双酚F和酚醛清漆酚醛树脂和/或高分子量酚醛清漆酚树脂的方法，包括以下步骤：（1）制备步骤，包括使苯酚与甲酸在酸催化剂存在下，从所得反应产物中除去酸催化剂，水和未反应的苯酚，得到粗双酚F; （2）蒸馏步骤，包括蒸馏粗双酚F的一部分，得到作为蒸馏物的高纯度双酚F，双核部分含量不小于95重量％，酚醛清漆酚树脂作为静止物双产物，双核部分含量不超过面积的15％; （3）将高纯度双酚F与剩余的粗双酚F混合以得到通常使用的双酚F的步骤; 和（4）在酸催化剂存在下使酚醛清漆酚醛树脂与甲醛聚合的步骤，得到高分子量酚醛清漆酚醛树脂。

6. 发明授权

US5247013A Biocompatible polyester and production thereof 失效
标题翻译：生物相容性聚酯及其生产
公开(公告)号：US5247013A
公开(公告)日：1993-09-21
申请号：US902794
申请日：1992-06-26
申请人： Hosei Shinoda , Masami Ohtaguro , Shigeru Iimuro
发明人： Hosei Shinoda , Masami Ohtaguro , Shigeru Iimuro
IPC分类号： C08G63/06 , C08G63/664
CPC分类号： C08G63/664 , C08G63/06
摘要： A biocompatible polyester which has improved hydrolyzability obtained by bonding saccharide to the structure of a polymer consisting of a glycolic acid unit and/or a lactic acid unit, and a process for Preparing the biocompatible polyester are disclosed.
摘要翻译：公开了具有改善的水解性的生物相容性聚酯，其通过将糖键合到由乙醇酸单元和/或乳酸单元组成的聚合物的结构上而获得，并且制备生物相容性聚酯的方法。

7. 发明授权

US4950804A Process for preparing bisphenol A 失效
标题翻译：制备双酚A的方法
公开(公告)号：US4950804A
公开(公告)日：1990-08-21
申请号：US310350
申请日：1989-02-14
申请人： Shigeru Iimuro , Yoshio Morimoto , Takashi Kitamura
发明人： Shigeru Iimuro , Yoshio Morimoto , Takashi Kitamura
IPC分类号： B01J27/10 , C07B61/00 , C07C27/00 , C07C37/20 , C07C37/84 , C07C39/16 , C07C67/00
CPC分类号： C07C37/84 , C07C37/20
摘要： A process for producing high-purity bisphenol A comprises reacting phenol with acetone in the presence of hydrochloric acid as the catalyst to obtain a product mixture, removing the hydrochloric acid from the product mixture, thereby yielding a liquid mixture, adding water to the liquid mixture, evaporating a water-phenol mixture from the liquid mixture under reduced pressure, thereby cooling the liquid mixture and crystallizing out the adduct of bisphenol A with phenol, and finally recovering bisphenol A from the adduct, wherein an improvement comprises treating the water-phenol mixture with a weakly basic ion-exchange resin and recycling and reusing the treated mixture as the water to be added to the liquid mixture. This process does not causes any troubles such as the corrosion of equipment and the decomposition and discoloration of bisphenol A during distillation.

8. 发明授权

US5618984A Phenol aralkyl resins, preparation process thereof and epoxy resin compositions 失效
标题翻译：苯酚芳烷基树脂，其制备方法和环氧树脂组合物
公开(公告)号：US5618984A
公开(公告)日：1997-04-08
申请号：US490507
申请日：1995-06-14
申请人： Tomoyuki Kawabata , Teruo Yuasa , Shigeru Iimuro
发明人： Tomoyuki Kawabata , Teruo Yuasa , Shigeru Iimuro
IPC分类号： C08G61/02 , C08L63/00 , C07C39/21 , C07C37/055
CPC分类号： C08G61/02 , C08L63/00
摘要： An allyletherificated phenol aralkyl resin is obtained through the reaction of a phenol aralkyl resin with an allyl halide in the presence of a base in an organic solvent at room temperature to 100.degree. C. and changed into an allylated phenol aralkyl resin at 160.degree.-250.degree. C. through Claisen rearrangement. The two resins are low in melt viscosity. Epoxy resin compositions containing the allylated phenol aralkyl resin as the curing agent give cured products being excellent in heat and moisture resistances.
摘要翻译：在碱存在下，在有机溶剂中，在室温至100℃下，通过苯酚芳烷基树脂与烯丙基卤反应获得烯丙醚化的酚芳烷基树脂，并在160-250℃下变成烯丙基化苯酚芳烷基树脂 DEGC通过Claisen重排。两种树脂的熔融粘度低。含有烯丙基化酚芳烷基树脂作为固化剂的环氧树脂组合物得到耐热和耐湿性优异的固化产物。

9. 发明授权

US5437918A Degradable non-woven fabric and preparation process thereof 失效
标题翻译：可降解无纺布及其制备方法
公开(公告)号：US5437918A
公开(公告)日：1995-08-01
申请号：US145621
申请日：1993-11-04
申请人： Keiko Taniguchi , Masahiro Washino , Shinobu Moriya , Hosei Shinoda , Masami Ohtaguro , Akihiro Funae , Shigeru Iimuro
发明人： Keiko Taniguchi , Masahiro Washino , Shinobu Moriya , Hosei Shinoda , Masami Ohtaguro , Akihiro Funae , Shigeru Iimuro
IPC分类号： C08G63/08 , D04H1/42 , D04H3/02 , D04H3/14 , B32B1/02 , B32B1/08 , B32B1/10 , B32B27/02
CPC分类号： D04H3/02 , C08G63/08 , D04H1/435 , D04H1/4382 , D04H3/14 , Y10T428/31786 , Y10T442/697
摘要： A degradable non-woven fabric obtained from an web formed of lactic acid-based polymer filaments comprising of one or more lactic acid-based polymers selected from a poly (DL-lactic acid) having more than 80 mol % of L-lactic acid units, poly (DL-lactic acid) having more than 80 mol % of D-lactic acid units, L-lactic acid/hydroxycarboxylic acid copolymer having 70 mol % or more of L-lactic acid units, and D-lactic acid/hydroxycarboxylic acid copolymer having 70 mol % or more of D-lactic acid units, and a preparation process of the degradable non-woven fabric which has good dimensional stability and can be degraded and disappeared under natural environment when abandoned.
摘要翻译：从由乳酸类聚合物长丝形成的纤维网得到的可降解无纺布，其包含一种或多种乳酸基聚合物，所述乳酸基聚合物选自具有大于80mol％的L-乳酸单元的聚（DL-乳酸），D-乳酸单元多于80摩尔％的聚（DL-乳酸），L-乳酸单元70摩尔％以上的L-乳酸/羟基羧酸共聚物，D-乳酸/羟基羧酸具有70摩尔％以上的D-乳酸单元的共聚物和可降解无纺布的制备方法，其具有良好的尺寸稳定性，并且在废弃时可以在自然环境下降解和消失。

10. 发明授权

US5216112A Phenolic resin and method for preparing same 失效
标题翻译：酚醛树脂及其制备方法
公开(公告)号：US5216112A
公开(公告)日：1993-06-01
申请号：US745422
申请日：1991-08-15
申请人： Shinji Ando , Yukio Fukui , Shigeru Iimuro
发明人： Shinji Ando , Yukio Fukui , Shigeru Iimuro
IPC分类号： C08G14/09 , C08G61/02
CPC分类号： C08G61/02
摘要： A phenolic resin can be obtained by a condensation reaction between a specific trifunctional aromatic compound and a phenolic compound. This resin can be reacted with a curing agent such as a hexamine to give cured articles having excellent heat resistance, electrical properties, wear resistance and chemical resistance, and the phenolic resin is also much more excellent in curing reactivity as compared with conventional techniques.

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