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    • 3. 发明授权
    • Process for producing 1,2,4-triazolin-5-one derivatives, and
intermediates therefor
    • 制备1,2,4-三唑啉-5-酮衍生物的方法及其中间体
    • US4845232A
    • 1989-07-04
    • US923935
    • 1986-10-24
    • Hisanori MatsuiKeiji SutohMoriharu YamamotoKazuhiro TakagiKunihiro YabutaniKuniaki TaninakaMitsuru Kajioka
    • Hisanori MatsuiKeiji SutohMoriharu YamamotoKazuhiro TakagiKunihiro YabutaniKuniaki TaninakaMitsuru Kajioka
    • C07D249/12
    • C07D249/12
    • A process for producing 1,2,4-triazolin-5-one derivatives represented by the general formula (I) ##STR1## wherein R is a haloalkyl group of 1 to 5 carbon atoms and R.sup.1 is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an alkyl group of 1 to 6 carbon atoms having halogen atom substituents, a cycloalkyl group of 3 to 6 carbon atoms, a cycloalkyl group of 3 to 6 carbon atoms having halogen atom substituents, a cyanoalkyl group of 2 to 4 carbon atoms, an alkenyl group of w to 6 carbon atoms, an alkynyl group of 2 to 6 carbon atoms, a lower alkoxyalkyl group of 2 to 6 carbon atoms, a lower alkylthioalkyl group of 2 to 8 carbon atoms, a lower alkylsufinylalkyl group of 2 to 6 carbon atoms, a lower alkylsufonylalkyl group of 2 to 6 carbon atoms, a lower alkoxyalkoxyalkyl group of 3 to 8 carbon atoms, a hydroxycarbonylalkyl group of 2 to 3 carbon atoms, a lower alkoxycarbonylalkyl group of 3 to 6 carbon atoms, a benzylgroup, a benzyl group having 1 to 2 substituents (selected from a halogen atom, a lower alkyl group of 1 to 3 carbon atoms, a lower alkoxy group of 1 to 3 carbon atoms, a nitro group, a lower alkoxycarbonyl group of 2 to 4 carbon atoms, a hydroxycarbonyl group and a phenoxy group), an alpha-methylbenzyl group or a phenethyl group.
    • 一种由通式(I)表示的1,2,4-三唑啉-5-酮衍生物的方法,其中R是1至5个碳原子的卤代烷基,R 1是氢原子, 具有1至6个碳原子的烷基,具有卤素原子取代基的1至6个碳原子的烷基,3至6个碳原子的环烷基,具有卤素原子取代基的3至6个碳原子的环烷基,氰基烷基 2至4个碳原子的链烯基,2至6个碳原子的炔基,2至6个碳原子的低级烷氧基烷基,2至8个碳原子的低级烷硫基烷基, 2至6个碳原子的低级烷基磺酰基烷基,2至6个碳原子的低级烷基磺酰基烷基,3至8个碳原子的低级烷氧基烷氧基烷基,2至3个碳原子的羟基羰基烷基,3至6个低级烷氧基羰基烷基 碳原子,苄基,具有1〜2个取代基的苄基(选自a 卤素原子,1〜3个碳原子的低级烷基,1〜3个碳原子的低级烷氧基,硝基,2〜4个碳原子的低级烷氧基羰基,羟基羰基和苯氧基), α-甲基苄基或苯乙基。
    • 6. 发明授权
    • .DELTA..sup.2 -1,2,4-triazolin-5-one derivatives, and uses thereof
    • DELTA 2-1,2,4-三唑啉-5-酮衍生物及其用途
    • US4909833A
    • 1990-03-20
    • US106599
    • 1987-10-13
    • Mitsuru KajiokaAtsushi TsushimaYoichi HachitaniKenichi Ikeda
    • Mitsuru KajiokaAtsushi TsushimaYoichi HachitaniKenichi Ikeda
    • A01N43/653C07D249/12
    • C07D249/12A01N43/653
    • A .DELTA..sup.2 -1,2,4-triazolin-5-one derivative represented by the following general formula (I), a process for manufacturing thereof, a herbicidal composition comprising it as an active ingredient, and a use of it as a herbicide: ##STR1## wherein R is a hydrogen atom, a univalent alkali metal atom, an unsubstituted quaternary ammonium salt, a substituted quaternary ammonium salt having at least one C.sub.1 -C.sub.4 alkyl group as a substituent, an unsubstituted-alkyl group having 1 to 6 carbon atoms, a C.sub.1 -C.sub.6 substituted-alkyl group having at least one halogen atom as a substituent, a cycloalkyl group having 3 to 6 carbon atoms, a C.sub.1 -C.sub.3 substituted-alkyl group having a cyano group as a substituent, an alkenyl group having 2 to 6 carbon atoms, an alkynyl group having to 2 to 6 carbon atoms, an alkoxyalkyl group having 2 to 6 carbon atoms, an alkylthioalkyl group having to 2 to 8 carbon atoms, an alkylsulfinylalkyl group having 2 to 6 carbon atoms, an alkylsulfonylalkyl group having 2 to 6 carbon atoms, an alkoxyalkoxyalkyl group having 3 to 8 carbon atoms, a hydroxycarbonylalkyl group having 2 to 3 carbon atoms, an alkoxycarbonylalkyl group having 3 to 6 carbon atoms, an unsubstituted-benzyl group, a substituted-benzyl group having at least one substituent selected from the group consisting of halogen atoms and alkyl groups having 1 to 3 carbon atoms, or a phenethyl group; R.sup.1 is a haloalkyl group having 2 to 5 carbon atoms; and X is a halogen atom.
    • 由以下通式(I)表示的DELTA 2-1,2,4-三唑啉-5-酮衍生物,其制备方法,包含其作为活性成分的除草组合物及其作为除草剂的用途 :其中R是氢原子,一价碱金属原子,未取代的季铵盐,具有至少一个C1-C4烷基作为取代基的取代的季铵盐,未取代的烷基, 1至6个碳原子,具有至少一个卤素原子作为取代基的C1-C6取代的烷基,具有3至6个碳原子的环烷基,具有氰基作为取代基的C1-C3取代的 - 烷基, 碳原子数2〜6的烯基,碳原子数2〜6的炔基,碳原子数2〜6的烷氧基烷基,碳原子数2〜8的烷硫基烷基,碳原子数2〜6的烷基亚磺酰基烷基 原子,具有2〜6个碳原子的烷基磺酰基烷基 ms,具有3至8个碳原子的烷氧基烷氧基烷基,具有2至3个碳原子的羟基羰基烷基,具有3至6个碳原子的烷氧基羰基烷基,未取代的苄基,具有至少一个取代基的取代苄基, 由卤素原子和碳原子数1〜3的烷基构成的基团,或苯乙基; R1是碳原子数2〜5的卤代烷基; X为卤素原子。