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1. 发明授权

US07854508B2 Plastic lens and manufacturing method of plastic lens 有权
标题翻译：塑胶透镜及塑料透镜的制造方法
公开(公告)号：US07854508B2
公开(公告)日：2010-12-21
申请号：US12089519
申请日：2006-09-15
申请人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
发明人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
IPC分类号： G02C7/02 , B29D11/00 , C03C17/00
CPC分类号： G02B1/111 , C09D183/04
摘要： A plastic lens includes: a plastic lens base material; a hard coat layer formed on the plastic lens base material; an organic antireflection film formed on the hard coat layer; and a primer layer between the plastic lens base material and the hard coat layer. The plastic lens base material contains at least a sulfur atom. The hard coat layer contains at least: fine metal oxide particles containing a titanium oxide having a rutile-type crystalline structure; and an organosilicon compound represented by a general formula of R1SiX13. The antireflection film contains a coating composition containing at least: an organosilicon compound represented by a general formula of XmR23−mSi—Y—SiR23−mXm; an epoxy group-containing organic compound containing one or more epoxy group in a molecule; and fine silica particles with average particle size of 1 to 150 nm, the antireflection film having a refractive index lower than that of the hard coat layer by 0.10 or more.
摘要翻译：塑料透镜包括：塑料透镜基材; 塑料透镜基材上形成的硬涂层; 形成在硬涂层上的有机抗反射膜; 以及塑料透镜基材和硬涂层之间的底漆层。塑料透镜基材至少含有硫原子。硬涂层至少含有：含有金红石型结晶结构的氧化钛的金属氧化物微粒; 和由通式R1SiX13表示的有机硅化合物。防反射膜含有至少含有由通式XmR23-mSi-Y-SiR23-mXm表示的有机硅化合物的涂料组合物，分子中含有一个或多个环氧基的含环氧基的有机化合物; 平均粒径为1〜150nm的二氧化硅微粒，折射率比硬涂层的折射率低0.10以上的防反射膜。

2. 发明申请

US20090040457A1 PLASTIC LENS AND MANUFACTURING METHOD OF PLASTIC LENS 有权
标题翻译：塑料镜片塑料镜片及其制造方法
公开(公告)号：US20090040457A1
公开(公告)日：2009-02-12
申请号：US12089519
申请日：2006-09-15
申请人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
发明人： Mikito Nakajima , Katsuyoshi Takeshita , Yusuke Kutsukake , Jun Kinoshita , Shuji Naito , Koichi Takahama , Hiroshi Yokogawa , Takeyuki Yamaki , Akira Tsujimoto , Ryozo Fukuzaki
IPC分类号： G02B1/04 , B05D5/06 , G02B1/11 , G02C7/02
CPC分类号： G02B1/111 , C09D183/04
摘要： A plastic lens includes: a plastic lens base material; a hard coat layer formed on the plastic lens base material; an organic antireflection film formed on the hard coat layer; and a primer layer between the plastic lens base material and the hard coat layer. The plastic lens base material contains at least a sulfur atom. The hard coat layer contains at least: fine metal oxide particles containing a titanium oxide having a rutile-type crystalline structure; and an organosilicon compound represented by a general formula of R1SiX13. The antireflection film contains a coating composition containing at least: an organosilicon compound represented by a general formula of XmR23-mSi—Y—SiR23-mXm; an epoxy group-containing organic compound containing one or more epoxy group in a molecule; and fine silica particles with average particle size of 1 to 150 nm, the antireflection film having a refractive index lower than that of the hard coat layer by 0.10 or more.
摘要翻译：塑料透镜包括：塑料透镜基材; 塑料透镜基材上形成的硬涂层; 形成在硬涂层上的有机抗反射膜; 以及塑料透镜基材和硬涂层之间的底漆层。塑料透镜基材至少含有硫原子。硬涂层至少含有：含有金红石型结晶结构的氧化钛的金属氧化物微粒; 和由通式R1SiX13表示的有机硅化合物。防反射膜含有至少含有由通式XmR23-mSi-Y-SiR23-mXm表示的有机硅化合物的涂料组合物，分子中含有一个或多个环氧基的含环氧基的有机化合物; 平均粒径为1〜150nm的二氧化硅微粒，折射率比硬涂层的折射率低0.10以上的防反射膜。

3. 发明授权

US07582351B2 Composite thin film holding substrate, transparent conductive film holding substrate, and panel light emitting body 有权
标题翻译：复合薄膜保持基板，透明导电膜保持基板和面板发光体
公开(公告)号：US07582351B2
公开(公告)日：2009-09-01
申请号：US10492534
申请日：2002-10-24
申请人： Hiroshi Yokogawa , Masaru Yokoyama , Kenji Kawano , Norihiro Itou , Koichi Takahama , Takeyuki Yamaki , Akira Tsujimoto , Yasuhisa Kishigami , Nobuhiro Ide
发明人： Hiroshi Yokogawa , Masaru Yokoyama , Kenji Kawano , Norihiro Itou , Koichi Takahama , Takeyuki Yamaki , Akira Tsujimoto , Yasuhisa Kishigami , Nobuhiro Ide
IPC分类号： B32B7/02 , B32B5/16 , H05B33/12
CPC分类号： G02B1/10 , C08K3/36 , C08K7/22 , C08L2205/20 , C09D7/70 , G02B1/11 , G02B5/0236 , G02B5/0242 , G02B5/0247 , G02B5/0278 , H01J5/16 , H01J2211/44 , H01L51/0096 , H01L51/5268 , Y02E10/549 , Y10T428/24942 , Y10T428/25 , Y10T428/259 , Y10T428/265 , Y10T428/31663
摘要： There is provided a composite thin film-holding substrate in which a composite thin film (4) comprising a filler (2) having a refractive index lower than that of a substrate (1) and a binder (3) having a refractive index higher than that of the filler (2) is formed on a surface of the substrate (1). Light is efficiently scattered when passing through the composite thin film (3) which comprises the filler (2) and the binder (3) having different refractive indexes from each other. In addition, the refractive index of a composite thin film (4) comprising a filler (2) having a low refractive index is low. As a result, the discharge efficiency of light which passes through the composite thin film (4) from the substrate (1) to the external is improved.
摘要翻译：提供一种复合薄膜保持基板，其中复合薄膜（4）包括折射率低于基板（1）的折射率的填料（2）和折射率高于填料（2）的表面形成在基材（1）的表面上。当通过包含彼此具有不同折射率的填料（2）和粘合剂（3）的复合薄膜（3）时，光被有效地分散。此外，包含低折射率的填料（2）的复合薄膜（4）的折射率低。结果，提高了通过复合薄膜（4）从基板（1）到外部的光的放电效率。

4. 发明申请

US20070190305A1 Coating material composition and article having coating film formed therewith 审中-公开
标题翻译：涂料组合物和具有与其形成的涂膜的制品
公开(公告)号：US20070190305A1
公开(公告)日：2007-08-16
申请号：US11730269
申请日：2007-03-30
申请人： Takeyuki Yamaki , Hiroshi Yokogawa , Koichi Takahama , Masaru Yokoyama , Akira Tsujimoto , Norihiro Itou , Kenji Kawano , Yasuhisa Kishigami , Nobuhiro Ide
发明人： Takeyuki Yamaki , Hiroshi Yokogawa , Koichi Takahama , Masaru Yokoyama , Akira Tsujimoto , Norihiro Itou , Kenji Kawano , Yasuhisa Kishigami , Nobuhiro Ide
IPC分类号： B32B3/26 , B32B3/00 , B32B9/00
CPC分类号： B32B27/20 , B32B7/02 , B32B27/06 , B32B2305/72 , B32B2327/18 , C09D183/02 , C09D183/04 , G02B1/113 , H01J5/16 , H01J2211/44 , Y10T428/249953 , Y10T428/249974 , Y10T428/249981 , Y10T428/249987
摘要： The present invention provide a coating material composition comprising at least fine hollow particles and a matrix-forming material, wherein when the coating material composition is applied and dried to form a coating film having a low refractive index, the matrix-forming material forms a porous matrix.
摘要翻译：本发明提供一种包含至少细小的中空颗粒和基体形成材料的涂料组合物，其中当涂覆和干燥涂料组合物以形成具有低折射率的涂膜时，基质形成材料形成多孔矩阵。

5. 发明申请

US20050109238A1 Coating material composition and article having coating film formed therewith 审中-公开
标题翻译：涂料组合物和具有与其形成的涂膜的制品
公开(公告)号：US20050109238A1
公开(公告)日：2005-05-26
申请号：US10492532
申请日：2002-10-23
申请人： Takeyuki Yamaki , Hiroshi Yokogawa , Koichi Takahama , Masaru Yokoyama , Akira Tsujimoto , Norihiro Itou , Kenji Kawano , Yasuhisa Kishigami , Nobuhiro Ide
发明人： Takeyuki Yamaki , Hiroshi Yokogawa , Koichi Takahama , Masaru Yokoyama , Akira Tsujimoto , Norihiro Itou , Kenji Kawano , Yasuhisa Kishigami , Nobuhiro Ide
IPC分类号： B32B7/02 , B32B27/20 , C08K7/24 , C09D183/02 , C09D183/04 , G02B1/10 , G02B5/02 , G02B5/20 , H01J5/16 , C07G1/00
CPC分类号： B32B27/20 , B32B7/02 , B32B27/06 , B32B2305/72 , B32B2327/18 , C09D183/02 , C09D183/04 , G02B1/113 , H01J5/16 , H01J2211/44 , Y10T428/249953 , Y10T428/249974 , Y10T428/249981 , Y10T428/249987
摘要： The present invention provide a coating material composition comprising at least fine hollow particles and a matrix-forming material, wherein when the coating material composition is applied and dried to form a coating film having a low refractive index, the matrix-forming material forms a porous matrix.
摘要翻译：本发明提供一种包含至少细小的中空颗粒和基体形成材料的涂料组合物，其中当涂覆和干燥涂料组合物以形成具有低折射率的涂膜时，基质形成材料形成多孔矩阵。

6. 再颁专利

USRE38850E1 Functional coated product and process for producing the same and the use thereof 失效
标题翻译：功能性涂层产品及其制备方法及其用途
公开(公告)号：USRE38850E1
公开(公告)日：2005-10-25
申请号：US10336919
申请日：1997-12-11
申请人： Junko Ikenaga , Takeyuki Yamaki , Koichi Takahama , Toshiharu Sako , Hirotsugu Kishimoto
发明人： Junko Ikenaga , Takeyuki Yamaki , Koichi Takahama , Toshiharu Sako , Hirotsugu Kishimoto
IPC分类号： B05D7/24 , B32B15/08
摘要： The present invention provides a functional coated product having excellent adhesion properties of a coating to a substrate, hardly causing the deterioration of the substrate and the coating due to a photocatalyst, hardly having dirt because the smoothness of the surface coating is high, and having high photocatalytic action; a method for producing the same and the use thereof.The coated product of the present invention has the first coating layer comprising a cured coating made of an acryl-modified silicone resin coating material, which is formed on the surface of the substrate, and the second coating layer comprising a cured coating made of a functional coating material containing the photocatalyst, which is formed con the surface of the first coating layer. When producing such a coated product, the acryl-modified silicone resin coating material is applied to the surface of the substrate as the first coating layer and it is semi-cured. After that, a photocatalyst-containing functional coating material is applied to the surface of this first coating layer in a semi-cured condition and then both of the coating layers are cured. Thereby, a coated product having a higher effect can be obtained.
摘要翻译：本发明提供了一种功能性涂层产品，其具有优异的涂层对基材的粘合性能，由于表面涂层的光滑度高而几乎不会由于光催化剂而导致基板和涂层的劣化，几乎不具有污垢，并且具有高的光催化作用; 其制造方法及其用途。本发明的涂布产品具有包含由丙烯酸改性的有机硅树脂涂层材料制成的固化涂层的第一涂层，其形成在基材的表面上，第二涂层包括由功能性的包含与第一涂层的表面形成的光催化剂的涂料。当制造这种涂布产品时，将丙烯酸改性的有机硅树脂涂料作为第一涂层施加到基材的表面并将其半固化。之后，在半固化状态下将含光催化剂的功能性涂料涂布到该第一涂层的表面，然后使两层涂层固化。由此，可以获得具有更高效果的涂布产品。

7. 发明授权

US06221498B1 Antifouling silicone emulsion coating-composition, process for producing the same and antifouling article coated therewith 失效
标题翻译：防污硅氧烷乳液涂料组合物，其制造方法和涂覆有防污涂料的制品
公开(公告)号：US06221498B1
公开(公告)日：2001-04-24
申请号：US09180763
申请日：1999-01-11
申请人： Koichi Takahama , Takeyuki Yamaki , Minoru Inoue , Akiharu Goto , Junko Ikenaga , Hirotsugu Kishimoto
发明人： Koichi Takahama , Takeyuki Yamaki , Minoru Inoue , Akiharu Goto , Junko Ikenaga , Hirotsugu Kishimoto
IPC分类号： B32B904
CPC分类号： C08K3/22 , C09D183/04 , Y10S525/902 , Y10T428/31663 , Y10T428/31667 , C08L83/04 , C08L2666/54
摘要： An antifouling silicone emulsion coating-composition comprising following components (A), (B), (C) and (D), an amount of the component (C) incorporated being in the range of 5 to 80% by weight relative to the total solid contents in the composition: (A) partially hydrolyzed organosiloxane with a weight-average molecular weight of 600 to 5,000 (determined using a polystyrene calibration curve), represented by the average formula (I): R2aSiOb(OR1)c(OH)d wherein R1 and R2 represent a monovalent hydrocarbon group; a, b, c and d are numerals satisfying the following relationships: a+2b+c+d=4, 0≦a
摘要翻译：包含以下组分（A），（B），（C）和（D））的防污硅氧烷乳液涂料组合物，组合物（C）的含量相对于总量为5-80重量％组合物中的固体成分：（A）由平均分子式（I）表示的重均分子量为600〜5000的部分水解的有机硅氧烷（使用聚苯乙烯校准曲线测定）：R2aSiOb（OR1）c（OH）d 其中R1和R2表示一价烃基; a，b，c和d是满足以下关系的数字：a + 2b + c + d = 4,0 <= a <3,0

8. 发明授权

US6165619A Functional coated product and process for producing the same and the use thereof 有权
标题翻译：功能性涂层产品及其制备方法及其用途
公开(公告)号：US6165619A
公开(公告)日：2000-12-26
申请号：US117738
申请日：1998-08-05
申请人： Junko Ikenaga , Takeyuki Yamaki , Koichi Takahama , Toshiharu Sako , Hirotsugu Kishimoto
发明人： Junko Ikenaga , Takeyuki Yamaki , Koichi Takahama , Toshiharu Sako , Hirotsugu Kishimoto
IPC分类号： B62D63/02 , B01J35/02 , B05D1/36 , B05D5/00 , B05D7/00 , B05D7/24 , B32B27/00 , C09D5/00 , C09D7/12 , C09D183/04 , F21V7/22 , B32B15/08
CPC分类号： B05D7/546 , Y10T428/31663 , Y10T428/31667
摘要： The present invention provides a functional coated product having excellent adhesion properties of a coating to a substrate, hardly causing the deterioration of the substrate and the coating due to a photocatalyst, hardly having dirt because the smoothness of the surface coating is high, and having high photocatalytic action; a method for producing the same and the use thereof.The coated product of the present invention has the first coating layer comprising a cured coating made of an acryl-modified silicone resin coating material, which is formed on the surface of the substrate, and the second coating layer comprising a cured coating made of a functional coating material containing the photocatalyst, which is formed con the surface of the first coating layer. When producing such a coated product, the acryl-modified silicone resin coating material is applied to the surface of the substrate as the first coating layer and it is semi-cured. After that, a photocatalyst-containing functional coating material is applied to the surface of this first coating layer in a semi-cured condition and then both of the coating layers are cured. Thereby, a coated product having a higher effect can be obtained.
摘要翻译： PCT No.PCT / JP97 / 04559 Sec。 371日期：1998年8月5日 102（e）日期1998年8月5日PCT 1997年12月11日PCT公布。公开号WO98 / 25711 日期1998年6月18日本发明提供了一种功能性涂层产品，其具有优异的涂层对基材的粘合性能，由于表面涂层的光滑度是几乎不会由于光催化剂而导致基材和涂层的劣化，几乎不具有污垢高，具有高光催化作用; 其制造方法及其用途。本发明的涂布产品具有包含由丙烯酸改性的有机硅树脂涂层材料制成的固化涂层的第一涂层，其形成在基材的表面上，第二涂层包括由功能性的包含与第一涂层的表面形成的光催化剂的涂料。当制造这种涂布产品时，将丙烯酸改性的有机硅树脂涂料作为第一涂层施加到基材的表面并将其半固化。之后，在半固化状态下将含光催化剂的功能性涂料涂布到该第一涂层的表面，然后使两层涂层固化。由此，可以获得具有更高效果的涂布产品。

9. 发明授权

US5830387A Process of forming a hydrophobic aerogel 失效
标题翻译：形成疏水性气凝胶的方法
公开(公告)号：US5830387A
公开(公告)日：1998-11-03
申请号：US916973
申请日：1992-08-12
申请人： Hiroshi Yokogawa , Masaru Yokoyama , Koichi Takahama , Yuriko Uegaki
发明人： Hiroshi Yokogawa , Masaru Yokoyama , Koichi Takahama , Yuriko Uegaki
IPC分类号： C01B33/158 , B01J13/00
CPC分类号： C01B33/1585 , Y10T428/24273 , Y10T428/2993
摘要： A hydrophobic aerogel is fabricated by reacting a polymer having a skeleton structure of (SiO.sub.2).sub.n with a hydrophobic agent having hydrophobic groups as well as functional groups reactive to silanol groups to obtain a denatured polymer, forming a gel consisting of two phase of a dispersing medium and the denatured polymer which was performed a hydrophobic treatment, and then, supercritically drying the gel at temperature and pressure above a critical point of the dispersing medium. The hydrophobic aerogel has improved characteristics free from deterioration in light transmissivity as well as lowered thermal resistance and also free from a dimensional variation such as shrinkage which would otherwise occur by contact with moisture, so that it can maintain the excellent characteristics for long time periods. Particularly, the aerogel is useful as a material having excellent light transmissivity and thermal resistance.
摘要翻译：通过使具有（SiO 2）n的骨架结构的聚合物与具有疏水基团的疏水剂以及与硅烷醇基反应的官能团反应来制备疏水性气凝胶，以获得变性聚合物，形成由两相分散体介质和进行疏水处理的变性聚合物，然后在高于分散介质的临界点的温度和压力下超临界干燥凝胶。疏水性气凝胶具有改善的光透过性劣化特性以及耐热性降低的特征，并且也不受诸如通过与水分接触而产生的收缩等尺寸变化的影响，从而能够长期保持优异的特性。特别地，气凝胶作为具有优异的透光性和耐热性的材料是有用的。

10. 发明授权

US5496527A Process of forming a hydrophobic aerogel 失效
标题翻译：形成疏水性气凝胶的方法
公开(公告)号：US5496527A
公开(公告)日：1996-03-05
申请号：US234965
申请日：1994-04-28
申请人： Hiroshi Yokogawa , Masaru Yokoyama , Koichi Takahama , Yuriko Uegaki
发明人： Hiroshi Yokogawa , Masaru Yokoyama , Koichi Takahama , Yuriko Uegaki
IPC分类号： C08J3/00 , C01B33/158 , C08G77/02 , C08G77/06 , C08G77/08 , C08G77/32 , C01B33/12
CPC分类号： C08G77/06 , C01B33/1585 , C08G77/02
摘要： A hydrophobic aerogel having excellent transparency is formed by the following process of the present invention. That is, a first gel having a SiO.sub.2 skeleton structure is prepared by hydrolysis and condensation of an alkoxysilane compound in the presence of a solvent. The solvent contained in the first gel is replaced at least partially with a medium to form a second gel. The second gel is reacted with a hydrophobic agent having hydrophobic groups as well as functional groups reactive with silanol groups under a supercritical condition of the medium to form a hydrophobic gel. The medium contained in the hydrophobic aerogel is removed by a supercritical drying method, so that the hydrophobic aerogel having improved transparency and an extremely fine porous structure is obtained.
摘要翻译：通过本发明的以下方法形成具有优异透明性的疏水性气凝胶。也就是说，通过在溶剂存在下水解和缩合烷氧基硅烷化合物来制备具有SiO 2骨架结构的第一凝胶。至少部分地用介质置换第一凝胶中所含的溶剂以形成第二凝胶。第二凝胶与具有疏水基团的疏水剂以及在介质的超临界条件下与硅烷醇基团反应以形成疏水性凝胶的官能团反应。通过超临界干燥法除去疏水性气凝胶中所含的介质，得到具有提高的透明性和极细微孔结构的疏水性气凝胶。

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