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    • 1. 发明授权
    • Laminate having improved dimensional stability and heat resistance
    • 层压板具有改善的尺寸稳定性和耐热性
    • US5780147A
    • 1998-07-14
    • US614548
    • 1996-03-13
    • Mikio SugaharaMitsutoshi YoshinobuYoshiyuki Tanaka
    • Mikio SugaharaMitsutoshi YoshinobuYoshiyuki Tanaka
    • A47B13/08A47B96/18B32B7/12B32B27/04B32B15/04B32B15/06B32B15/08
    • A47B13/086A47B96/18B32B27/04B32B7/12Y10T428/26Y10T428/2804Y10T428/31678Y10T428/31692Y10T442/3382Y10T442/658
    • Disclosed is a laminate comprising a thermosetting resin-impregnated prepreg layer (A) constituting a surface layer, a rubber or thermoplastic resin layer (B) having a flexibility and a hot melt resin adhesive layer (C), the thermosetting resin-impregnated prepreg layer and rubber or thermoplastic resin layer being heat bonded through the hot melt resin adhesive layer. The layer (A) is a prepreg impregnated with a thermosetting resin selected from a diallyl phthalate resin, an unsaturated polyester, a phenol resin, an aminoalkyd resin, an epoxy resin, an acrylurethane resin and a melamine resin. The rubber or resin of the layer (B) is a rubber or a thermoplastic resin selected from chlorinated polyethylene, polybutene, ethylene-vinyl acetate copolymer, an ethylene-propylene-diene copolymer, a chloroprene polymer, chlorosulfonated polyethylene, a styrene-butadiene copolymer and polyvinyl chloride. In addition, the hot melt resin of the layer (C) is a hot melt resin having a melting point of 60.degree. to 165.degree. C. and a solubility parameter (SP value) of 7.4 to 10.9, selected from an ethylene-vinyl acetate copolymer an ethylene-acrylic acid copolymer, carboxylated polyethylene, polyurethane, polybutylene terephthalate and a modified ethylene-vinyl acetate copolymer.
    • 公开了包含热固性树脂浸渍的预浸料层(A),构成表层的层压体,具有柔软性的橡胶或热塑性树脂层(B)和热熔树脂粘合剂层(C)的热固性树脂浸渍预浸料层 并且通过热熔树脂粘合剂层热粘合橡胶或热塑性树脂层。 层(A)是浸渍有选自邻苯二甲酸二烯丙酯树脂,不饱和聚酯,酚醛树脂,氨基醇酸树脂,环氧树脂,丙烯酸聚氨酯树脂和三聚氰胺树脂的热固性树脂的预浸料。 层(B)的橡胶或树脂是选自氯化聚乙烯,聚丁烯,乙烯 - 乙酸乙烯酯共聚物,乙烯 - 丙烯 - 二烯共聚物,氯丁二烯聚合物,氯磺化聚乙烯,苯乙烯 - 丁二烯共聚物中的橡胶或热塑性树脂 和聚氯乙烯。 此外,层(C)的热熔树脂是熔点为60〜165℃的热熔树脂,溶解度参数(SP值)为7.4〜10.9,选自乙烯 - 醋酸乙烯酯 共聚物,乙烯 - 丙烯酸共聚物,羧化聚乙烯,聚氨酯,聚对苯二甲酸丁二醇酯和改性的乙烯 - 乙酸乙烯酯共聚物。