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    • 2. 发明授权
    • Polyorganosiloxane containing methacryloxy group or acryloxy group and method for producing the same
    • 含有甲基丙烯酰氧基或丙烯酰氧基的聚有机硅氧烷及其制造方法
    • US09018332B2
    • 2015-04-28
    • US12863165
    • 2009-01-14
    • Tadashi OkawaEiji Ando
    • Tadashi OkawaEiji Ando
    • C08G77/20C08G77/38C08G77/12C08G77/46
    • C08G77/38C08G77/12C08G77/46
    • A methacryloxy group- or acryloxy group-containing polyorganosiloxane in which a methacryloxy group or acryloxy group is bonded to a silicon atom in the polyorganosiloxane across a long-chain alkylene group or poly(alkyleneoxy)-long chain-alkylene group having 11 to 20 carbon atoms. A method of producing this methacryloxy group- or acryloxy group-containing polyorganosiloxane, in which a silicon-bonded hydrogen atom-containing polyorganosiloxane is addition reacted in the presence of a hydrosilylation reaction catalyst with a 1-alkenyl methacrylate or a 1-alkenyl acrylate or a 1-alkenyloxypolyalkylene glycol methacrylate or a 1-alkenyloxypolyalkylene glycol acrylate.
    • 含有甲基丙烯酰氧基或丙烯酰氧基的聚有机硅氧烷,其中甲基丙烯酰氧基或丙烯酰氧基通过长链亚烷基或聚(亚烷氧基) - 长链亚烷基键合到聚有机硅氧烷中的硅原子上,其具有11至20个碳 原子 在含硅键合的含氢原子的聚有机硅氧烷的加成反应催化剂的存在下,在氢化硅烷化反应催化剂与1-链烯基甲基丙烯酸酯或1-烯基丙烯酸酯的情况下生产该含甲基丙烯酰氧基或含丙烯酰氧基的聚有机硅氧烷的方法,或 1-链烯氧基聚亚烷基二醇甲基丙烯酸酯或1-链烯氧基聚亚烷基二醇丙烯酸酯。
    • 10. 发明授权
    • Method for purifying 3-methacryloxypropyldimethylhalosilanes or 3-methacryloxypropyl methyldihalosilanes
    • 3-甲基丙烯酰氧基丙基二甲基卤硅烷或3-甲基丙烯酰氧基丙基甲基二卤代硅烷的纯化方法
    • US06197988B1
    • 2001-03-06
    • US08984482
    • 1997-12-01
    • Tadashi OkawaRyuzo Mikami
    • Tadashi OkawaRyuzo Mikami
    • C07F704
    • C07F7/20
    • A method for purifying 3-methacryloxypropyldimethylhalosilanes or 3-methacryloxypropylmethyldihalosilanes which is characterized by the fact that 1-methyl-2-methacryloxyethyldimethylhalosilanes or 1-methyl-2-methacryloxyethylmethyldihalosilanes contained in products or fractions consisting of 3-methacryloxypropyldimethylhalosilanes or 3-methacryloxypropylmethyldihalosilanes produced by a hydrosilation reaction of allyl methacrylate with dimethylhalosilanes or methyldihalosilanes are decomposed by means of a metal halide which shows the properties of a Lewis acid, after which these compounds are subjected to fractional distillation.
    • 一种纯化3-甲基丙烯酰氧基丙基二甲基硅烷或3-甲基丙烯酰氧基丙基甲基二卤代硅烷的方法,其特征在于1-甲基-2-甲基丙烯酰氧基乙基二甲基二硅烷硅烷或1-甲基-2-甲基丙烯酰氧基乙基甲基二卤代硅烷包含在由3-甲基丙烯酰氧基丙基二甲基卤硅烷或3-甲基丙烯酰氧基丙基甲基二卤代硅烷 甲基丙烯酸烯丙酯与二甲基卤硅烷或甲基二卤硅烷的氢化硅烷化反应通过显示路易斯酸性质的金属卤化物分解,之后将这些化合物进行分馏。