专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US06409986B1 Zeolite ITQ-5 失效
标题翻译：沸石ITQ-5
公开(公告)号：US06409986B1
公开(公告)日：2002-06-25
申请号：US09581877
申请日：2000-06-19
申请人： Miguel-Angel Camblor Fernandez , Avelino Corma Canos , Susana Valencia Valencia
发明人： Miguel-Angel Camblor Fernandez , Avelino Corma Canos , Susana Valencia Valencia
IPC分类号： C01B3948
CPC分类号： B01J29/70 , B01J29/04 , B01J29/7007 , C01B37/005 , C01B39/06 , C01B39/08 , C01B39/48 , Y10S423/27
摘要： The present invention relates to zeolithic materials having a characteristic X ray diffraction pattern, and its preparation method, characterized by the relatively low pH of the synthesis medium and the use of F− anions as mineralizing agent. The invention also claims the use of the obtained material in catalytic processes for the transformation of hydrocarbons and in oxidation process. The method comprises heating at 363-473° K a reaction mixture which contains a source of at least one tetravalent element T(IV), optionally a source of an element T(III), optionally H2O2, a structure director organic cation, a source of anions F− and water, the presence of alkaline cations is not necessary.
摘要翻译：本发明涉及具有特征X射线衍射图的沸石材料及其制备方法，其特征在于合成介质的pH值相对较低，并且使用F-阴离子作为矿化剂。本发明还要求所获得的材料在烃转化和氧化过程的催化过程中的用途。该方法包括在363-473°K加热反应混合物，该反应混合物含有至少一种四价元素T（IV）的源，任选的元素T（III）的源，任选的H 2 O 2，结构导向剂有机阳离子，源的阴离子F-和水，碱性阳离子的存在是不必要的。

2. 发明授权

US6077498A Zeolite ITQ-1 失效
标题翻译：沸石ITQ-1
公开(公告)号：US6077498A
公开(公告)日：2000-06-20
申请号：US875302
申请日：1997-10-07
申请人： Maria Jose Diaz Cabanas , Miguel Angel Camblor Fernandez , Catalina Corell Martires , Avelino Corma Canos
发明人： Maria Jose Diaz Cabanas , Miguel Angel Camblor Fernandez , Catalina Corell Martires , Avelino Corma Canos
IPC分类号： B01J29/035 , B01J29/04 , B01J29/70 , C01B37/00 , C01B37/02 , C01B39/48 , C07C4/06 , C07C5/27 , C07C7/13 , C10G11/05 , C10G45/64 , C10G47/16 , C01B39/46
CPC分类号： C10G47/16 , B01J29/035 , B01J29/04 , B01J29/70 , C01B37/005 , C01B37/02 , C01B39/48 , C07C4/06 , C07C5/2775 , C07C7/13 , C10G11/05 , C10G45/64 , C07C2529/70
摘要： The present invention relates to a microporous crystalline material of zeolitic nature, called ITQ-1A, to the process for its preparation and its use in processes of separation and transformation of organic compounds. In the roasted and anhydrous stage, the chemical composition of the material corresponds to the empirical formula: x(M.sub.1/n XO.sub.2):yYO.sub.2 :SiO.sub.2, wherein x has a value smaller than 0.02 and may equal 0: y has a value smaller than 0.04 and may equal 0: m is H.sup.+ or an inorganic cation with the charge +n: X is a chemical element with an oxidation status +3 (Al, Ga, B, Cr) and Y is a chemical element with an oxidation status +4 (Ti, Ge, V). When x=0 and y=0, the material may be described as a new polymorphe form of microporous silica. The material of this invention is characterized also by its X ray diffraction pattern. The process for the preparation of said zeolite is characterized by the use of one or a plurality of organic additives in a reaction mixture which is crystallized through heating.
摘要翻译： PCT No.PCT / ES96 / 00218 Sec。 371日期1997年10月7日第 102（e）日期1997年10月7日PCT 1996年11月19日PCT公布。第WO97 / 19021号公报日期1997年5月29日本发明涉及沸石性质的微孔结晶材料，称为ITQ-1A，用于其制备及其在有机化合物的分离和转化过程中的应用。在焙炒和无水阶段，材料的化学成分对应于经验公式：x（M1 / nXO2）：yYO2：SiO2，其中x的值小于0.02，并且可以等于0：y具有小于0.04的值并且可以等于0：m是H +或具有电荷+ n的无机阳离子：X是氧化态为+3（Al，Ga，B，Cr）的化学元素，Y是氧化态为+4的化学元素（Ti，Ge，V）。当x = 0和y = 0时，材料可以被描述为新的多孔形式的微孔二氧化硅。本发明的材料的特征在于其X射线衍射图。制备所述沸石的方法的特征在于在通过加热结晶的反应混合物中使用一种或多种有机添加剂。

3. 发明授权

US06500404B1 Zeolite ITQ-3 有权
标题翻译：沸石ITQ-3
公开(公告)号：US06500404B1
公开(公告)日：2002-12-31
申请号：US09424897
申请日：2000-02-28
申请人： Miguel-Angel Camblor Fernandez , Avelino Corma Canos , Luis-Angel Villaescusa Alonso
发明人： Miguel-Angel Camblor Fernandez , Avelino Corma Canos , Luis-Angel Villaescusa Alonso
IPC分类号： C01B3948
CPC分类号： C10G45/64 , B01J20/18 , B01J29/04 , B01J29/70 , C01B37/005 , C01B37/02 , C01B39/06 , C01B39/48 , C07C1/20 , C07C4/04 , C07C4/06 , C07C7/13 , C07C2529/70 , C10G3/49 , C10G25/03 , C10G35/095 , C10G2400/20 , Y02P30/42 , Y02P30/464 , C07C11/02
摘要： The present invention refers to a crystalline material of zeolitic nature named ITQ-3 characterized by its characteristic X-ray diffraction pattern and its microporous properties, to the process of preparation thereof characterized by the use of one or several organic additives in a reaction mixture that is made to crystallize by heating and to the use thereof in processes of separation and transformation of organic compounds, which material has the empirical formula x(M1/nXO2):yYO2:SiO2 where x has a value lower than 0.15 and may be equal to zero; and y has a value lower than 0.1 and may be equal to zero; M is H+ or an inorganic cation of charge +n, X is a chemical element with oxidation state (Al, Ge, B and Cr), Y is a chemical element with oxidation state (Ti, Ge and V), and when x=0 and y=0 can be described as a new polymorphous of silica of microporous nature.
摘要翻译：本发明涉及其特征在于其特征X射线衍射图及其微孔性质的沸石性质的结晶材料，其制备方法的特征在于在反应混合物中使用一种或几种有机添加剂，通过加热结晶并在有机化合物的分离和转化过程中使用，该材料具有经验式x（M1 / nXO2）：yYO2：SiO2，其中x具有低于0.15的值，并且可以等于零; 并且y具有小于0.1的值并且可以等于零; M是H +或无机阳离子+ n，X是具有氧化态（Al，Ge，B和Cr）的化学元素，Y是具有氧化态（Ti，Ge和V）的化学元素，当x = 0和y = 0可以被描述为微孔性质的二氧化硅的新的多形态。

4. 发明授权

US5972204A Phosphorous-containing zeolite with structural type CON, its preparation and its use for catalytic cracking 失效
标题翻译：具有结构型CON的含磷沸石，其制备及其用于催化裂化
公开(公告)号：US5972204A
公开(公告)日：1999-10-26
申请号：US014424
申请日：1998-01-27
申请人： Avelino Corma Canos , Eric Benazzi , Herve Caufriez , Maria Jose Diaz Cabanas , Maria Sol Grande Casas , Miguel Angel Camblor Fernandez , Gil Mabilon
发明人： Avelino Corma Canos , Eric Benazzi , Herve Caufriez , Maria Jose Diaz Cabanas , Maria Sol Grande Casas , Miguel Angel Camblor Fernandez , Gil Mabilon
IPC分类号： B01J29/85 , B01J29/86 , B01J35/00 , C01B39/12 , C01B39/48 , C10G11/05 , B01J29/70
CPC分类号： C01B39/12 , B01J29/85 , B01J29/86 , B01J35/0006 , C01B39/48 , C10G11/05
摘要： A phosphorous-containing zeolite with structural type CON in its aluminosilicate or borosilicate form contains at most 10% by weight of phosphorous. A process for its preparation is described, starting from existing zeolites (SSZ-26, SSZ-33 or CIT-1) or from beta zeolites and an organic structuring agent or template which is 1-N,N,N-trimethyl adamantammonium hydroxide or 2-N,N,N-trimethyl adamantammonium hydroxide. The zeolite is used for catalytic cracking of hydrocarbon feeds.
摘要翻译：具有硅铝酸盐或硼硅酸盐形式的结构型CON的含磷沸石含有至多10重量％的磷。描述了其制备方法，从现有的沸石（SSZ-26，SSZ-33或CIT-1）或β沸石和作为1-N，N，N-三甲基金刚烷基氢氧化铵的有机结构剂或模板开始， 2-N，N，N-三甲基金刚烷基氢氧化铵。沸石用于烃进料的催化裂化。

5. 发明授权

US06191323B1 Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta 有权
标题翻译：使用锡取代沸石β将酮和醛还原成醇的方法
公开(公告)号：US06191323B1
公开(公告)日：2001-02-20
申请号：US09557300
申请日：2000-04-25
申请人： Laszlo T. Nemeth , Avelino Corma Canos , Susana Valencia Valencia , Jaime G. Moscoso , Marcelo Eduardo Domine
发明人： Laszlo T. Nemeth , Avelino Corma Canos , Susana Valencia Valencia , Jaime G. Moscoso , Marcelo Eduardo Domine
IPC分类号： C07C2914
CPC分类号： C07C29/14 , B01J29/04 , B01J29/89 , C07C29/143 , C07C2601/14 , Y10S423/27 , C07C35/12 , C07C35/08
摘要： A process for the reduction of ketones or aldehydes to alcohols has been developed. The process involves contacting the ketone or aldehyde with a primary or secondary alcohol and a catalyst at reduction conditions. The catalyst is a molecular sieve having the empirical formula: (MwSnxTiySi1-x-y-zGez)O2 where M is a trivalent metal such as aluminum or boron. These molecular sieves have a microporous three dimensional framework structure of at least SiO2 and SnO2 tetrahedral units, a crystallographically regular pore system and the characteristic x-ray diffraction pattern of zeolite beta.
摘要翻译：已经开发了将酮或醛还原成醇的方法。该方法包括在还原条件下使酮或醛与伯醇或仲醇和催化剂接触。催化剂是具有以下经验式的分子筛：其中M是三价金属如铝或硼。这些分子筛具有至少SiO 2和SnO 2四面体单元的微孔三维骨架结构，晶体学规则孔系统和β沸石的特征X射线衍射图。

6. 发明授权

US09856145B2 Material ITQ-55, method for preparation and use 有权
公开(公告)号：US09856145B2
公开(公告)日：2018-01-02
申请号：US14744169
申请日：2015-06-19
申请人： Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantin Sanz , Jose Luis Jordá Moret
发明人： Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantin Sanz , Jose Luis Jordá Moret
IPC分类号： C01B39/48 , C01B37/02 , B01J20/18 , B01J29/70 , B01D71/02 , B01D53/04 , B01D53/047 , C01B3/50 , B01D53/02 , B01D53/22 , C01B17/16 , C01B21/04 , C01C1/12 , B01J20/30 , C07C1/20 , C07C1/32 , C07C2/76 , C07C29/00 , C07C41/01 , C01B39/06 , C01B39/08 , C01B37/00 , C01B39/12 , B01J29/89 , B01J29/86
CPC分类号： C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
摘要： This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1-g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, a method for its preparation and its use.

7. 发明申请

US20060286029A1 Microporous crystalline zeolite material, zeolite ITQ-28, production method thereof and use of same 失效
标题翻译：微孔结晶沸石材料，沸石ITQ-28，其制备方法及用途
公开(公告)号：US20060286029A1
公开(公告)日：2006-12-21
申请号：US11392473
申请日：2006-03-29
申请人： Avelino Corma Canos , Maria Sabater Picot , Susana Valencia Valencia
发明人： Avelino Corma Canos , Maria Sabater Picot , Susana Valencia Valencia
IPC分类号： C01B39/48
CPC分类号： C01B37/005 , B01J29/035 , B01J29/70 , B01J29/87 , B01J29/89 , C01B37/02 , C01B39/065 , C01B39/48
摘要： The invention relates to a microporous crystalline zeolite material, zeolite ITQ-28, the production method thereof and the use of same. More specifically, the invention relates to a microporous crystalline zeolite material, ITQ-28, which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, is characterised by having empirical formula x (M1/nXO2): y YO2: SiO2, wherein: M is selected from H+, at least one inorganic cation with charge +n, preferably alkalines or alkaline earths, and a mixture of both; X is at least one chemical element in oxidation state +3, preferably Al, Ga, B, Fe, Cr or mixtures thereof; Y is at least a chemical element in oxidation state +4, which is different from Si, preferably Ge, Ti, Sn, V or mixtures of same; x has a value of between 0 and 0.2 inclusive; and y has a value of between 0 and 0.1 inclusive. The invention is further characterised in that the material as it is synthesised has an x-ray diffraction pattern with at least values of angle 2θ (degrees) and the relative intensities given in table 1. The invention also relates to the method of preparing said material and to the use thereof in the conversion of organic compounds.
摘要翻译：本发明涉及微孔结晶沸石材料，沸石ITQ-28，其制备方法及其用途。更具体地说，本发明涉及一种微孔结晶沸石材料ITQ-28，其在煅烧状态中并且在其不存在其晶格缺陷的情况下，通过硅烷醇的存在而表现出来，其特征在于具有经验式x（ M 1 / n 2 XO 2）：y Y 2 O 2 SiO 2其中：M选自H 至少一种带电荷的无机阳离子，优选碱金属或碱土金属，以及二者的混合物; X是氧化态+3，优选Al，Ga，B，Fe，Cr或其混合物中的至少一种化学元素; Y至少是氧化态+4的化学元素，其不同于Si，优选Ge，Ti，Sn，V或其混合物; x的值在0和0.2之间; y的值在0和0.1之间。本发明的特征还在于其合成的材料具有x射线衍射图，其至少具有角度2θ（度）和表1中给出的相对强度。本发明还涉及制备所述材料的方法以及其在有机化合物的转化中的用途。

8. 发明申请

US20160008753A1 Separation and Storage of Fluids Using ITQ-55 有权
标题翻译：使用ITQ-55分离和储存液体
公开(公告)号：US20160008753A1
公开(公告)日：2016-01-14
申请号：US14744485
申请日：2015-06-19
申请人： Edward W. Corcoran, JR. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Jade Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantín Sanz , Miguel Palomino Roca
发明人： Edward W. Corcoran, JR. , Pavel Kortunov , Charanjit S. Paur , Peter I. Ravikovitch , Jade Yu Wang , Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia , Angel Cantín Sanz , Miguel Palomino Roca
IPC分类号： B01D53/04 , B01D53/047 , B01J20/18
CPC分类号： C01B39/48 , B01D53/02 , B01D53/04 , B01D53/0407 , B01D53/0462 , B01D53/047 , B01D53/228 , B01D53/229 , B01D71/028 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/20 , B01D2256/22 , B01D2256/24 , B01D2256/245 , B01D2256/26 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/404 , B01D2257/406 , B01D2257/50 , B01D2257/504 , B01D2257/70 , B01D2257/702 , B01D2257/7022 , B01D2257/80 , B01J20/18 , B01J20/3078 , B01J29/70 , B01J29/86 , B01J29/89 , C01B3/508 , C01B17/167 , C01B21/0466 , C01B37/002 , C01B37/007 , C01B37/02 , C01B39/06 , C01B39/08 , C01B39/12 , C01B2203/0405 , C01B2210/0018 , C01C1/12 , C07C1/20 , C07C1/322 , C07C2/76 , C07C29/00 , C07C41/01 , C07C2529/70 , C07C2529/76 , C07C2529/78 , Y02C10/08
摘要： This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1−g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
摘要翻译：本发明涉及沸石性质的微孔结晶材料，其经煅烧状态并且在不存在硅烷醇存在下的结晶基质缺陷的情况下，经验式x（M1 / nXO2）：yYO2：gGeO2 :( 1-g）SiO 2，其中M选自H +，至少一种电荷无机阳离子+ n和两者的混合物，X是至少一种氧化态的化学元素+3，Y是至少一种具有氧化态+4不同于Si，x取值在0和0.2之间，均包括在内，y取0到0.1之间的值，均包括在内，g取0至0.5之间的值，这两者都包含在ITQ-55中，以及其制备方法。本发明还涉及沸石性质的结晶材料用于吸附流体组分，流体组分的膜分离，储存流体组分以及催化各种转化反应的用途。

9. 发明申请

US20090202416A1 Separation of Fluids Using Zeolite Itq-32 失效
标题翻译：使用沸石Itq-32分离液体
公开(公告)号：US20090202416A1
公开(公告)日：2009-08-13
申请号：US11989330
申请日：2006-07-24
申请人： Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia
发明人： Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia
IPC分类号： B01D15/04 , C07C7/12 , B01D53/02 , C07C7/144 , C01B21/04
CPC分类号： C07C7/13 , B01D15/00 , B01D53/02 , B01D53/04 , B01D53/047 , B01D2253/108 , B01D2253/308 , B01D2256/10 , B01D2256/24 , B01D2257/702 , B01J20/18 , C01B39/48 , C10G25/03 , C10G53/08 , C10G2300/1081 , C10G2300/1092 , C10G2300/805 , C10G2400/20 , C10L3/10 , C10L3/102 , C10L3/12
摘要： The invention relates to a method of separating fluids from mixtures using a zeolite known as ITQ-32 consisting of a two-dimensional pore system comprising channels with openings formed by 8 tetrahedra which are interconnected by channels with openings formed by 12 tetrahedra. The inventive method comprises at least the following steps: a) the zeolite ITQ-32 material is brought into contact with the mixture of fluids, b) one or more of the components are adsorbed in the zeolite ITQ-32 material, c) the non-adsorbed components are extracted, and d) one or more of the components adsorbed in the zeolite ITQ-32 material are recovered.
摘要翻译：本发明涉及一种使用称为ITQ-32的沸石从混合物中分离流体的方法，所述沸石由二维孔隙系统组成，该二维孔隙系统包括由8面四面体形成的开口的通道，该通道由通过由12面四面体形成的开口的通道相互连接。本发明的方法至少包括以下步骤：a）使沸石ITQ-32材料与流体混合物接触，b）一种或多种组分被吸附在沸石ITQ-32材料中，c） - 吸附的组分被提取，并且d）吸收在沸石ITQ-32材料中的一种或多种组分被回收。

10. 发明申请

US20090068092A1 Microporous Crystalline Zeolite Material, Zeolite ITQ-32, Preparation Method Thereof and Use of Same 失效
标题翻译：微孔结晶沸石材料，沸石ITQ-32，其制备方法及其用途
公开(公告)号：US20090068092A1
公开(公告)日：2009-03-12
申请号：US11883354
申请日：2006-01-26
申请人： Avelino Corma Canos , Angel Cantin Sanz , Fernando Rey Garcia , Susana Valencia Valencia , Sandra Leiva Herrero
发明人： Avelino Corma Canos , Angel Cantin Sanz , Fernando Rey Garcia , Susana Valencia Valencia , Sandra Leiva Herrero
IPC分类号： C01B39/02 , C01B39/04
CPC分类号： C01B37/02 , B01J20/18 , B01J29/70 , C01B39/06 , C01B39/065 , C01B39/082 , C01B39/12 , C01B39/48
摘要： The invention relates to a microporous crystalline zeolite material which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, has empirical formula x(M1/nXO2):y YO2:SiO2, in which M is selected from among H+, at least one inorganic cation with charge +n and a mixture of both; X is at least one chemical element in oxidation state +3; Y is at least one chemical element in oxidation state +4, which is different from Si, x has a value of between 0 and 0.2 inclusive, and y has a value of between 0 and 0.1 inclusive. In addition, as it is synthesised, and in the calcined state, the material has a characteristic X-ray diffraction pattern known as ITQ-32. The invention also relates to the method of preparing said material and to the use thereof.
摘要翻译：本发明涉及一种微孔结晶沸石材料，其在煅烧状态下并且不存在其晶格缺陷的缺陷，通过硅烷醇的存在表现出具有经验式x（M1 / nXO2）：y YO2：SiO2，其中M选自H +，至少一种带电荷的无机阳离子和两者的混合物; X是至少一种氧化态的化学元素+3; Y是氧化态+4中的至少一种化学元素，其与Si不同，x具有在0和0.2之间的值，包括0和0.2之间，y的值在0和0.1之间。此外，如合成，并且在煅烧状态下，该材料具有称为ITQ-32的特征X射线衍射图。本发明还涉及制备所述材料的方法及其用途。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式