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1. 发明授权

US07211128B2 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US07211128B2
公开(公告)日：2007-05-01
申请号：US10973294
申请日：2004-10-27
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Géraldine Laborie , Chantal Rigaill
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Géraldine Laborie , Chantal Rigaill
IPC分类号： B01D53/04
CPC分类号： C10L3/10 , B01D53/04 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/80 , B01D2258/06 , B01D2259/40086 , C10G5/02 , Y02C10/08
摘要： The raw natural gas is pretreated in treating unit 30. The treated gas is then purified by adsorption of the mercaptans in first enclosure 31. The various cuts that make up the purified gas are separated in fractionating unit 34. Part of the methane making up the purified gas is saturated with a C5+ hydrocarbon in contactor 33, then it is fed into second enclosure 32 so as to regenerate the adsorbent material contained in this second enclosure. The gas from the second enclosure is washed in unit 35, then recycled.
摘要翻译：原料天然气在处理单元30中预处理。然后经处理的气体通过吸附第一外壳31中的硫醇进行纯化。构成净化气体的各种切割在分馏单元34中分离。构成净化气体在接触器33中用C5 +烃饱和，然后将其进料到第二外壳32中，以便再生包含在该第二外壳中的吸附材料。来自第二壳体的气体在单元35中洗涤，然后再循环。

2. 发明授权

US07311758B2 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US07311758B2
公开(公告)日：2007-12-25
申请号：US11106504
申请日：2005-04-15
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Géraldine Laborie , Chantal Rigaill
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Géraldine Laborie , Chantal Rigaill
IPC分类号： B01D53/04 , C07C7/13
CPC分类号： C10L3/102 , B01D53/04 , B01D53/261 , B01D2253/104 , B01D2253/108 , B01D2257/306 , C10L3/10
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A water-laden purge gas is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the water. The gas from the third enclosure is washed in unit L, then recycled.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。将含水的吹扫气体进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇被解吸并用水代替。来自第三个外壳的气体以单元L洗涤，然后再循环。

3. 发明申请

US20050229784A1 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US20050229784A1
公开(公告)日：2005-10-20
申请号：US11106504
申请日：2005-04-15
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Geraldine Laborie , Chantal Rigaill
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Geraldine Laborie , Chantal Rigaill
IPC分类号： B01D8/00 , B01D47/00 , B01D53/04 , B01D53/14 , B01D53/26 , B01D53/72 , C10L3/10
CPC分类号： C10L3/102 , B01D53/04 , B01D53/261 , B01D2253/104 , B01D2253/108 , B01D2257/306 , C10L3/10
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A water-laden purge gas is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the water. The gas from the third enclosure is washed in unit L, then recycled.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。将含水的吹扫气体进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇被解吸并用水代替。来自第三个外壳的气体以单元L洗涤，然后再循环。

4. 发明申请

US20050109206A1 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US20050109206A1
公开(公告)日：2005-05-26
申请号：US10973294
申请日：2004-10-27
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Geraldine Laborie , Chantal Rigaill
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Geraldine Laborie , Chantal Rigaill
IPC分类号： B01D53/04 , C10G5/02 , C10L3/10 , B01D53/02
CPC分类号： C10L3/10 , B01D53/04 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/80 , B01D2258/06 , B01D2259/40086 , C10G5/02 , Y02C10/08
摘要： The raw natural gas is pretreated in treating unit 30. The treated gas is then purified by adsorption of the mercaptans in first enclosure 31. The various cuts that make up the purified gas are separated in fractionating unit 34. Part of the methane making up the purified gas is saturated with a C5+ hydrocarbon in contactor 33, then it is fed into second enclosure 32 so as to regenerate the adsorbent material contained in this second enclosure. The gas from the second enclosure is washed in unit 35, then recycled.
摘要翻译：原料天然气在处理单元30中预处理。然后经处理的气体通过吸附第一外壳31中的硫醇进行纯化。构成净化气体的各种切割在分馏单元34中分离。构成净化气体在接触器33中用C5 +烃饱和，然后将其进料到第二外壳32中，以便再生包含在该第二外壳中的吸附材料。来自第二壳体的气体在单元35中洗涤，然后再循环。

5. 发明申请

US20060204419A1 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US20060204419A1
公开(公告)日：2006-09-14
申请号：US11366581
申请日：2006-03-03
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
IPC分类号： B01D53/46
CPC分类号： C10L3/10 , B01D53/0462 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2256/245 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40045 , B01D2259/40052 , B01D2259/40056 , B01D2259/40064 , B01D2259/4009 , B01D2259/403 , Y02C10/08
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A steam-rich stream is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the steam.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。富含蒸汽的料流进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇解吸并用蒸汽代替。

6. 发明授权

US07449049B2 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US07449049B2
公开(公告)日：2008-11-11
申请号：US11366581
申请日：2006-03-03
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
IPC分类号： B01D53/04 , B01D53/48 , C07C7/13
CPC分类号： C10L3/10 , B01D53/0462 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2256/245 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40045 , B01D2259/40052 , B01D2259/40056 , B01D2259/40064 , B01D2259/4009 , B01D2259/403 , Y02C10/08
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A steam-rich stream is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the steam.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。富含蒸汽的料流进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇解吸并用蒸汽代替。

7. 发明授权

US08790617B2 Process for producing hydrogen with complete capture of CO2 and recycling unconverted methane 有权
标题翻译：完全捕获二氧化碳并回收未转化甲烷生产氢气的方法
公开(公告)号：US08790617B2
公开(公告)日：2014-07-29
申请号：US12568317
申请日：2009-09-28
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/26
CPC分类号： C01B3/56 , B01D53/04 , B01D2253/102 , B01D2253/304 , B01D2253/308 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2259/4009 , C01B3/48 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/0822 , C01B2203/0827 , C01B2203/1241 , C01B2203/148 , Y02C10/04 , Y02C10/08 , Y02E60/324 , Y02P20/128 , Y02P20/152 , Y02P30/30
摘要： The present invention concerns a process for producing hydrogen from a hydrocarbon feed and steam, comprising: a step for producing a synthesis gas in a unit for steam reforming the hydrocarbon feed in the presence of steam, with a fuel providing the heat necessary for the reaction; a step for steam converting synthesis gas obtained in the preceding step, producing a stream of hydrogen containing methane and carbon dioxide; a step for capturing carbon dioxide present in the stream obtained from the steam conversion step in order to separate the carbon dioxide from the stream of hydrogen; a step for capturing and recycling the methane and other impurities (CO, CO2) present in the stream of hydrogen to the steam reforming step.
摘要翻译：本发明涉及一种从烃类进料和蒸汽中生产氢气的方法，包括：在蒸汽存在下用于在烃类进料中蒸汽重整的单元中生产合成气的步骤，提供反应所需的热量 ; 在前述步骤中获得的蒸汽转化合成气的步骤，产生含有甲烷和二氧化碳的氢气流; 用于捕获从蒸汽转化步骤获得的物流中存在的二氧化碳以从二氧化碳流中分离二氧化碳的步骤; 将存在于氢气流中的甲烷和其它杂质（CO，CO 2）捕获并再循环到蒸汽重整步骤的步骤。

8. 发明授权

US08216324B2 Process for the production of hydrogen with a thermally-integrated desulfurization unit 有权
标题翻译：用热一体化脱硫装置生产氢气的方法
公开(公告)号：US08216324B2
公开(公告)日：2012-07-10
申请号：US12057576
申请日：2008-03-28
申请人： Alexandre Nicolaos , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
发明人： Alexandre Nicolaos , Michel Thomas , Fabrice Giroudiere , Jijun Xu , Kishore Doshi
IPC分类号： B01J7/00 , B01J8/00 , C01B3/36 , C01B6/24 , C01B3/24 , C01B3/26
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0883 , C01B2203/0888 , C01B2203/0894 , C01B2203/1064 , C01B2203/107 , C01B2203/1229 , C01B2203/1247 , C01B2203/1258 , C01B2203/127 , C01B2203/1294 , Y02P20/129
摘要： The invention relates to a process for the production of thermally-integrated hydrogen from a liquid hydrocarbon feedstock that contains sulfur-containing compounds that comprise at least one stage for heating the liquid hydrocarbon feedstock by indirect heat exchange with a hot stream, a stage for desulfurizing the heated hydrocarbon feedstock, a stage for evaporating the desulfurized hydrocarbon feedstock by indirect heat exchange with the hot stream that exits from the autothermal reformer, a stage for autothermal reforming of the hydrocarbon feedstock, and a stage wherein the carbon monoxide content in the hydrogen-rich gas that is produced is reduced in a reactor for converting carbon monoxide with water. The invention also relates to the hydrogen production installation that corresponds to this process.
摘要翻译：本发明涉及从含有含硫化合物的液体烃原料生产热一体化氢的方法，所述含硫化合物包含至少一个阶段，用于通过与热流的间接热交换来加热液体烃原料，脱硫阶段加热的烃原料，用于通过与从自热重整器出口的热流间接热交换来蒸发脱硫烃原料的阶段，烃原料的自热重整阶段，以及其中氢 - 生成的富氧气体在用于将一氧化碳与水一起转化的反应器中减少。本发明还涉及对应于该方法的氢生产设备。

9. 发明授权

US08137562B2 Use of a colloidal suspension of a cationic polymer to treat a support for medical use 有权
标题翻译：使用阳离子聚合物的胶体悬浮液来治疗用于医疗用途的支持物
公开(公告)号：US08137562B2
公开(公告)日：2012-03-20
申请号：US12305362
申请日：2006-09-06
申请人： Michel Thomas
发明人： Michel Thomas
IPC分类号： B01D11/00 , B01D39/00 , B01D63/06 , B01D63/00 , B01D67/00
CPC分类号： B01D67/0093 , A61L33/06 , B01D69/02 , B01D71/82 , B01D2323/38 , B01D2325/12 , B01D2325/14 , Y10T29/49826
摘要： The invention concerns a composite support comprising a base support for the treatment of a biological fluid, in which: “the base support is essentially-constituted by a first polymer carrying anionic or anionizable groups;” at least a part of the surface of the base support is coated with a second polymer ionically bonded to the first polymer, the second polymer carrying the cationic or cationizable groups which are capable of forming an ionic bond with the anionic or anionizable groups of the first polymer; in which the second polymer is in the colloidal form and in mixture with a polyacid during application to the support, allowing the composite membrane to adsorb at least one entity containing anionic or anionizable groups by bonding with cationic or cationizable groups of the second polymer.
摘要翻译：本发明涉及一种复合载体，其包括用于处理生物流体的基础载体，其中：“基础载体基本上由携带阴离子或阴离子基团的第一聚合物构成”;基底表面的至少一部分支撑体涂覆有离子键合到第一聚合物的第二聚合物，第二聚合物携带能够与第一聚合物的阴离子或阴离子基团形成离子键的阳离子或阳离子基团; 其中所述第二聚合物为胶体形式，并且在施加到所述载体中时与多元酸混合，允许所述复合膜通过与所述第二聚合物的阳离子或阳离子基团结合而吸附至少一个含有阴离子或阴离子基团的实体。

10. 发明授权

US06454998B1 Blood circulation apparatus coupling device which improves biocompatibility of inner surfaces with treated blood 失效
标题翻译：血液循环装置联合装置，其改善内表面与处理过的血液的生物相容性
公开(公告)号：US06454998B1
公开(公告)日：2002-09-24
申请号：US09364052
申请日：1999-07-30
申请人： Michel Thomas , Pierre Valette
发明人： Michel Thomas , Pierre Valette
IPC分类号： A61M3700
CPC分类号： A61M1/16 , A61L33/068 , A61M1/3672 , A61M1/3673 , B01D61/28 , B01D63/021 , B01D65/022 , B01D67/0088 , B01D67/0093 , B01D71/42 , B01D2313/13 , B01D2321/34 , B01D2321/346 , C08L79/02
摘要： A coupling is connectable to an access of a blood compartment. The compartment has at least one inner surface intended to be coated with at least one molecular layer of a substance soluble in an aqueous solution and capable of increasing biocompatibility. A determined quantity of the substance is deposited inside the coupling in a form such that the substance is capable of undergoing, substantially without deterioration, an irradiation capable of sterilizing the coupling.
摘要翻译：联接器可连接到血液隔室的通路。隔室具有至少一个内表面，其旨在涂覆有至少一种可溶于水溶液的物质的分子层并且能够增加生物相容性。确定量的物质以耦合器内部的形式沉积，使得物质能够基本上不损坏能够消除联接器的照射。

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