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    • 10. 发明授权
    • Isoxazoline derivatives as insecticidal compounds
    • 异恶唑啉衍生物作为杀虫剂
    • US09247740B2
    • 2016-02-02
    • US14240428
    • 2012-08-24
    • Jerome Yves CassayrePeter RenoldThomas PitternaMyriem El Qacemi
    • Jerome Yves CassayrePeter RenoldThomas PitternaMyriem El Qacemi
    • C07D413/12C07D331/04A01N43/20A01N43/80A01N43/40A01N43/54
    • A01N43/20A01N43/40A01N43/54A01N43/80C07D331/04C07D413/12
    • The present invention provides compounds of formula (I), wherein G1 is oxygen; R1 is hydrogen; R2 is group P (P) L is a bond, methylene or ethylene; one of A1 and A2 is S, SO or SO2 and the other is —C(R4)R4—R3 is hydrogen or methyl; each R4 is independently hydrogen or methyl; Y1 is C—R6, CH or nitrogen; Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R5 is hydrogen, halogen, cyano, nitro, NH2, C1-C2alkyl, C1-C2haloalkyl, C3-C5cycloalkyl, C3-C5halocycloalkyl, C1-C2alkoxy, C1-C2haloalkoxy; R6 together with R5 forms a —CH═CH—CH═CH— bridge; X2 is C—X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X1, X3 and X6 are not hydrogen; X4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. The invention also provides intermediates useful for the preparation of compounds of formula (I), as well as methods of controlling insects, acarines, nematodes or molluscs using the compounds of formula (I).
    • 本发明提供式(I)化合物,其中G1是氧; R1是氢; R2是基团P(P)L是键,亚甲基或亚乙基; A1和A2之一是S,SO或SO2,另一个是-C(R4)R4-R3是氢或甲基; 每个R 4独立地是氢或甲基; Y1是C-R6,CH或氮; Y2和Y3独立地是CH或氮; 其中Y1,Y2和Y3中不超过两个是氮,并且其中Y 2和Y 3不都是氮; R5是氢,卤素,氰基,硝基,NH2,C1-C2烷基,C1-C2卤代烷基,C3-C5环烷基,C3-C5卤代环烷基,C1-C2烷氧基,C1-C2卤代烷氧基; R6与R5一起形成-CH = CH-CH = CH-桥; X2是C-X6或氮; X1,X3和X6独立地为氢,卤素或三卤代甲基,其中X 1,X 3和X 6中的至少两个不是氢; X4是三氟甲基,二氟甲基或氯二氟甲基。 本发明还提供了可用于制备式(I)化合物的中间体,以及使用式(I)化合物控制昆虫,螨虫,线虫或软体动物的方法。