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    • 6. 发明授权
    • Hair processing additives
    • 头发加工助剂
    • US4957731A
    • 1990-09-18
    • US340194
    • 1989-04-19
    • Michael W. HelioffCarmen D. BiresRobert B. Login
    • Michael W. HelioffCarmen D. BiresRobert B. Login
    • A61K8/49A61Q5/04A61Q5/08A61Q5/10A61Q5/12C07D207/26C07D207/27D06M16/00
    • D06M16/00A61K8/4913A61Q5/04A61Q5/08A61Q5/10A61Q5/12C07D207/27
    • A composition comprising an aqueous hair coloring, bleaching, reducing, oxidizing or permanent structure altering formulation and a conditioning amount of a quaternized compound having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is linear alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group of alkyl, alkyleneoxyalkyl, alkyleneoxyalkenyl, alkoxy, hydroxyalkyl, aryl, aralkyl, alkaryl, alkyleneamidoalkyl, alkylenecarbamoylalkyl, aryleneamidoalkyl and arylenecarbamoylalkyl radicals, and R.sub.2 and R.sub.3, together with the quaternized nitrogen atom can form a heterocyclic radical containing from 1 to 2 heteroatoms selected from the group of nitrogen, sulfur and oxygen, in which case R.sub.1 can represent a double bond in the heterocyclic structure or can be any of the aforementioned groups for R.sub.1, R.sub.2 and R.sub.3 ; said groups R.sub.1, R.sub.2 and R.sub.3 each having up to 30 carbon atoms and at least one of R.sub.1, R.sub.2 and R.sub.3 being a radical having from 8 to 30 carbon atoms when R.sub.2 and R.sub.3 are not part of a heterocyclic moiety; and A.sup.-- is an anion derived from an oxylated sulfur compound, having the formula:R'SO.sub.3.sup.--wherein R' is alkyl, alkoxy, phenyl, phenoxy, alkylenephenyl, alkylenephenoxy, phenylenealkyl or phenyleneoxyalkyl and wherein the alkyl moieties of said R' groups contain from 1 to 20 carbon atoms and said R' groups are optionally alkoxylated with from 1 to 20 units of ethyleneoxide and/or propylene oxide.
    • 一种组合物,其包含水性染发剂,漂白剂,还原剂,氧化剂或永久性结构改变制剂和调理量的具有下式的季铵化化合物:其中m是1至4的整数; R是具有3至8个碳原子的直链亚烷基,并且任选地被C 1至C 4烷基取代; R 1,R 2和R 3各自独立地选自烷基,烷氧基烷基,亚烷氧基烯基,烷氧基,羟基烷基,芳基,芳烷基,烷芳基,亚烷基酰氨基烷基,亚烷基氨基甲酰基烷基,亚芳基酰氨基烷基和芳基甲酰氨基烷基,R2和R3与季铵化氮原子 形成含有1至2个选自氮,硫和氧的杂原子的杂环基,其中R1可以表示杂环结构中的双键或可以是R 1,R 2和R 3中的任何上述基团; 所述R 1,R 2和R 3各自具有至多30个碳原子,当R 2和R 3不是杂环部分时,R 1,R 2和R 3中的至少一个是具有8至30个碳原子的基团; 并且A-是衍生自氧化硫化合物的阴离子,其具有下式:R'SO 3 - ,其中R'是烷基,烷氧基,苯基,苯氧基,亚烷基苯基,亚烷基苯氧基,亚苯基烷基或苯基氧基烷基,并且其中所述R'基团的烷基部分 含有1至20个碳原子,并且所述R'基团任选地被1至20个单元的环氧乙烷和/或环氧丙烷烷氧基化。
    • 7. 发明授权
    • Compositions used in permanent alteration of hair color
    • 用于永久改变头发颜色的组合物
    • US4834767A
    • 1989-05-30
    • US60284
    • 1987-06-10
    • Michael W. HelioffCarmen D. BiresRobert B. Login
    • Michael W. HelioffCarmen D. BiresRobert B. Login
    • A61K8/49A61Q5/08A61Q5/10
    • A61K8/4913A61Q5/08A61Q5/10
    • A permanent hair color altering composition comprising an aqueous preparation on the basis of melanin dissolution and/or oxidation of a hair colorant dye intermediate, which contains as a swelling and penetration agent, a quaternized amino lactam having the formula: ##STR1## wherein m is an integer having a value of from 1 to 4; R is alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group of alkyl, alkyleneoxy alkyl, alkylhydroxy, alkoxy, aryl, aralkyl, alkaryl, and alkylene amidoalkyl radicals, said groups each having from 1 to 30 carbon atoms and at least one of R.sub.1, R.sub.2 and R.sub.3 is a radical having from 8 to 30 carbon atoms; and X.sup.- is a chloride, bromide or iodide anion. The invention also relates to the use of said quaternized compounds.
    • 一种永久性头发变色组合物,其包含基于黑色素溶解和/或氧化毛发着色剂染料中间体的水性制剂,其含有作为溶胀和渗透剂的季铵化氨基内酰胺,其具有下式:其中m为 值为1〜4的整数; R是具有3至8个碳原子的亚烷基,并且任选地被C 1至C 4烷基取代; R 1,R 2和R 3各自独立地选自烷基,亚烷氧基烷基,烷基羟基,烷氧基,芳基,芳烷基,烷芳基和亚烷基酰胺基烷基,所述基团各自具有1至30个碳原子, R2和R3是具有8至30个碳原子的基团; X-是氯,溴或碘阴离子。 本发明还涉及所述季铵化合物的用途。