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1. 发明授权

US08388777B2 Alkali metal perchlorate-containing gas generants 有权
标题翻译：碱金属高氯酸盐气体发生剂
公开(公告)号：US08388777B2
公开(公告)日：2013-03-05
申请号：US13355665
申请日：2012-01-23
申请人： Michael W. Barnes , Ivan V. Mendenhall , Robert D. Taylor
发明人： Michael W. Barnes , Ivan V. Mendenhall , Robert D. Taylor
IPC分类号： C06B29/00 , C06B29/02 , D03D23/00 , D03D43/00
CPC分类号： C06D5/06
摘要： Alkali metal perchlorate-containing gas generant compositions which, upon combustion, produce or result in an improved effluent and related methods for generating an inflation gas for use in an inflatable restraint system are provided. Such alkali metal perchlorate-containing gas generant compositions include at least one alkali metal perchlorate present with a mean particle size in excess of 100 microns. Such alkali metal perchlorate-containing gas generant compositions also include or contain a suitable non-azide, organic, nitrogen-containing fuel and at least one copper-containing compound selected from the group consisting of basic copper nitrate, cupric oxide, copper diammine dinitrate-ammonium nitrate mixture wherein ammonium nitrate is present in the mixture in a range of about 3 to about 90 weight percent, copper diammine bitetrazole, a copper-nitrate complex resulting from reaction of 5-aminotetrazole with basic copper nitrate and combinations thereof.
摘要翻译：提供了在燃烧时产生或导致改进的流出物的碱金属高氯酸盐气体发生剂组合物，以及用于产生用于可充气约束系统的充气气体的相关方法。这种含高氯酸高氯酸的气体发生剂组合物包括至少一种平均粒度超过100微米的碱金属高氯酸盐。这种含碱金属高氯酸盐气体发生剂组合物还包括或含有合适的非叠氮化物，有机，含氮燃料和至少一种选自碱式硝酸铜，氧化铜，二硝酸铜二氧化钛 - 硝酸铵混合物，其中硝酸铵在约3至约90重量％的范围内存在于混合物中，铜二氨基四唑，由5-氨基四唑与碱式硝酸铜的反应产生的硝酸铜络合物及其组合。

2. 发明授权

US6132538A High gas yield generant compositions 失效
标题翻译：高产气量组合物
公开(公告)号：US6132538A
公开(公告)日：2000-10-17
申请号：US124944
申请日：1998-07-30
申请人： Ivan V. Mendenhall , Robert D. Taylor , Michael W. Barnes
发明人： Ivan V. Mendenhall , Robert D. Taylor , Michael W. Barnes
IPC分类号： C06D5/06 , C06B31/28 , C06B31/56
CPC分类号： C06D5/06
摘要： Gas generant compositions, such as may be suited for use in inflating automotive inflatable restraint airbag cushions, are provided. Such gas generant compositions generally contain a mixture of guanidine nitrate, ammonium nitrate, and a transition metal ammine nitrate, such as copper diammine dinitrate and preferably also contain one or more ballistic additives.
摘要翻译：提供了气体发生剂组合物，例如可适用于充气汽车充气约束气囊垫。这种气体发生剂组合物通常含有硝酸胍，硝酸铵和硝酸过渡金属氨合物的混合物，例如硝酸二氧化钛，优选还含有一种或多种弹道添加剂。

3. 发明授权

US5629494A Hydrogen-less, non-azide gas generants 失效
标题翻译：无氢非叠氮化物气体发生剂
公开(公告)号：US5629494A
公开(公告)日：1997-05-13
申请号：US609270
申请日：1996-02-29
申请人： Michael W. Barnes , Robert D. Taylor
发明人： Michael W. Barnes , Robert D. Taylor
IPC分类号： C06B31/02 , C06B31/08 , C06B43/00 , C06D5/00 , C06D5/06 , C06B47/08
CPC分类号： C06D5/06
摘要： A gas generant composition contains no hydrogen, using as the major fuel component cupric and/or zinc bitetrazole and as a major oxidizer component CuO and/or Fe.sub.2 O.sub.3. A minor fuel component may be a salt of dicyanamide which reduces processing sensitivity of the composition. A minor oxidizer component may be a nitrate, chlorate, or perchlorate salt.
摘要翻译：气体发生剂组合物不含氢，用作主要燃料组分铜和/或锌四唑并且作为主要的氧化剂组分CuO和/或Fe 2 O 3。次要燃料组分可以是二氰胺的盐，这降低了组合物的加工敏感性。次要氧化剂组分可以是硝酸盐，氯酸盐或高氯酸盐。

4. 发明授权

US07147733B2 Ammonium perchlorate-containing gas generants 有权
标题翻译：含高氯酸铵的气体发生剂
公开(公告)号：US07147733B2
公开(公告)日：2006-12-12
申请号：US10899451
申请日：2004-07-26
申请人： Michael W. Barnes , Ivan V. Mendenhall , Robert D. Taylor
发明人： Michael W. Barnes , Ivan V. Mendenhall , Robert D. Taylor
IPC分类号： C06B31/00 , C06B29/22
CPC分类号： C06B23/02 , C06B29/22
摘要： Ammonium perchlorate-containing gas generant compositions which, upon combustion, produce or result in an improved effluent and related methods for generating an inflation gas for use in an inflatable restraint system are provided. Such ammonium perchlorate-containing gas generant compositions include ammonium perchlorate present with a mean particle size in excess of 100 microns. Such ammonium perchlorate-containing gas generant compositions also include or contain a chlorine scavenger present in an amount effective to result in a gaseous effluent that is substantially free of hydrogen chloride when the gas generant is combusted, wherein at least about 98 weight percent of the chlorine scavenger is a copper-containing compound. Suitable copper-containing chlorine scavenger compounds include basic copper nitrate, cupric oxide, copper diammine dinitrate-ammonium nitrate mixture wherein ammonium nitrate is present in the mixture in a range of about 3 to about 90 weight percent, copper diammine bitetrazole, a copper-nitrate complex resulting from reaction of 5-aminotetrazole with basic copper nitrate and combinations thereof.
摘要翻译：提供了含有高氯酸铵的气体发生剂组合物，其在燃烧时产生或导致改进的流出物以及用于产生用于可充气约束系统的膨胀气体的相关方法。这种含高氯酸铵的气体发生剂组合物包括平均粒径超过100微米的高氯酸铵。这种含高氯酸铵的气体发生剂组合物还包含或含有氯清除剂，其量有效地导致当气体发生剂燃烧时基本上不含氯化氢的气态流出物，其中至少约98重量％的氯清除剂是含铜化合物。合适的含铜氯清除剂包括碱式硝酸铜，氧化铜，二硝酸铜二硝酸铵 - 硝酸铵混合物，其中硝酸铵在约3至约90重量％的范围内存在于混合物中，铜二氨基四唑，硝酸铜由5-氨基四唑与碱式硝酸铜反应产生的络合物及其组合。

5. 发明授权

US5670740A Heterogeneous gas generant charges 失效
标题翻译：异质气体发生器费用
公开(公告)号：US5670740A
公开(公告)日：1997-09-23
申请号：US540379
申请日：1995-10-06
申请人： Michael W. Barnes , Robert D. Taylor , Christopher Hock , Michael P. Jordan , Matthew A. Cox , Alan J. Ward
发明人： Michael W. Barnes , Robert D. Taylor , Christopher Hock , Michael P. Jordan , Matthew A. Cox , Alan J. Ward
IPC分类号： C06B45/00 , C06D5/06 , C06B31/12
CPC分类号： C06D5/06 , C06B45/00
摘要： A gas generant charge comprises a heterogeneous mixture of between about 80 and about 95 wt % of a first gas generant composition 1) and between about 5 and about 20 wt % of a second gas generant composition 2), based on the total weight of 1) plus 2). The first gas generant composition 1) comprises between about 20 and about 40 wt % fuel A) and between about 20 and about 60 wt % oxidizer B). Between about 50 and about 85 wt % of the fuel A) is a triazole or tetrazole compound A.sup.1), and between about 15 and about 50 wt % of the fuel is, a water-soluble fuel A.sup.2). At least about 20 wt % of the oxidizer B), up to 100%, a transition metal oxide B.sup.1); balance of the oxidizer is selected from the group B.sup.2) consisting of alkali and/or alkaline earth metal nitrates, chlorates or perchlorates. The second gas generant composition 2) comprises between about 30 and about 65 wt % of a fuel C) which is an organic compound containing only the elements carbon, hydrogen, and oxygen, the oxygen content being between about 35 and about 65 wt % of the organic compound, and an between about 35 and about 70 wt % of an oxidizer D) which is selected from the group consisting of alkali metal chlorates, alkali metal perchlorates, and mixtures thereof. The mixed generant charge produces less undesirable gases than the first gas generant composition alone and less particulate matter than the second gas generant composition alone.
摘要翻译：气体发生剂装料包含基于总重量1的第一气体发生剂组合物1）和约5至约20重量％的第二气体发生剂组合物2）的约80至约95重量％的非均相混合物）加2）。第一气体发生剂组合物1）包含约20至约40重量％的燃料A）和约20至约60重量％的氧化剂B）。约50至约85重量％的燃料A）为三唑或四唑化合物A1），约15至约50重量％的燃料为水溶性燃料A2）。至少约20重量％的氧化剂B），至多100重量％的过渡金属氧化物B1）; 氧化剂的平衡选自由碱金属和/或碱土金属硝酸盐，氯酸盐或高氯酸盐组成的组B2）。第二气体发生剂组合物2）包含约30至约65重量％的仅含有碳，氢和氧元素的有机化合物的燃料C），氧含量为约35至约65重量％有机化合物和约35至约70重量％的氧化剂D），其选自碱金属氯酸盐，碱金属高氯酸盐及其混合物。混合发电剂电荷比单独的第一气体发生剂组合物产生更少的不希望的气体，而不是单独的第二气体发生剂组合物的较少的颗粒物质。

6. 发明授权

US5431103A Gas generant compositions 失效
标题翻译：气体发生剂组合物
公开(公告)号：US5431103A
公开(公告)日：1995-07-11
申请号：US310019
申请日：1994-09-21
申请人： Christopher Hock , Michael P. Jordan , Virginia E. Chandler , Robert D. Taylor , Thomas M. Deppert , Michael W. Barnes
发明人： Christopher Hock , Michael P. Jordan , Virginia E. Chandler , Robert D. Taylor , Thomas M. Deppert , Michael W. Barnes
IPC分类号： C06D5/00 , B60R21/26 , C06B23/00 , C06D5/06 , C06B45/00
CPC分类号： C06B23/009 , C06D5/06
摘要： A gas generant composition contains as a fuel a mixture of a major portion of a triazole or tetrazole and a minor portion of a water soluble fuel; and an oxidizer component, at least 20 wt % of said oxidizer component being a transition metal oxide, such as CuO. Generant compositions in accordance with the invention autoignite in a range around 170.degree. C., providing autoignition of the generant without the need for separate autoignition devices. Also, the generant compositions are useful as autoignition pyrotechnic in autoignition devices.
摘要翻译：气体发生剂组合物含有三唑或四唑的主要部分和少量水溶性燃料的混合物作为燃料; 和氧化剂组分，至少20wt％的所述氧化剂组分是过渡金属氧化物，例如CuO。根据本发明的发生组合物在约170℃的范围内的自发火焰，提供发电机的自动点火，而不需要单独的自燃装置。此外，发生剂组合物可用作自燃装置中的自燃火药。

7. 发明授权

US5635668A Gas generant compositions containing copper nitrate complexes 失效
标题翻译：含有硝酸铜络合物的气体发生剂组合物
公开(公告)号：US5635668A
公开(公告)日：1997-06-03
申请号：US616606
申请日：1996-03-15
申请人： Michael W. Barnes , Robert D. Taylor , Christopher Hock
发明人： Michael W. Barnes , Robert D. Taylor , Christopher Hock
IPC分类号： C06B31/00 , C06D5/06
CPC分类号： C06B31/00 , C06D5/06
摘要： Gas generant compositions utilize cupric nitrate complexes of nitrogen-containing compounds as fuels in conjunction with an oxidizer.
摘要翻译：气体发生剂组合物使用含氮化合物的硝酸铜络合物作为燃料与氧化剂结合使用。

8. 发明授权

US5608183A Gas generant compositions containing amine nitrates plus basic copper (II) nitrate and/or cobalt(III) triammine trinitrate 失效
标题翻译：含有硝酸亚胺和碱式硝酸铜（II）和/或三（硝酸钴）三硝酸三钠的气体发生剂组合物
公开(公告)号：US5608183A
公开(公告)日：1997-03-04
申请号：US616408
申请日：1996-03-15
申请人： Michael W. Barnes , Robert D. Taylor
发明人： Michael W. Barnes , Robert D. Taylor
IPC分类号： C06B31/28 , C06B31/00 , C06B33/14 , C06B45/00 , C06D5/00 , C06D5/06
CPC分类号： C06B31/00 , C06D5/06
摘要： A gas generant composition comprises between about 30 and about 85 wt. % of A) fuel, and between about 15 and about 70 wt % of B) oxidizer based on total weight of A) plus B). At least about 60 wt %, up to 100 wt % of the fuel A) comprises an nitrate salt of a polyamine of the general formula selected from the group consisting of: ##STR1## wherein in formulae (I)-(III) the Zs are the same or different and are selected from H and NH.sub.2,(IV) C.sub.2 -C.sub.3 -alkyl diamine, and mixtures thereof. At least about 60 wt %, up to 100 wt % of the oxidizer B) comprises basic copper(II) nitrate, i.e. Cu(NO.sub.3).sub.2.3Cu(OH).sub.2 and/or cobalt(III)triammine trinitrate, i.e., Co(NH.sub.3).sub.3.(NO.sub.3).sub.3.
摘要翻译：气体发生剂组合物包含约30-约85wt。 A）燃料的％，以及基于A）+ B）的总重量的B）氧化剂的约15至约70重量％。至少约60重量％，至多100重量％的燃料A）包含通式的多胺的硝酸盐，其选自：ZHNCONHZ，（I）rmulae（I） - （III）Z 相同或不同，并且选自H和NH 2，（Ⅳ）C 2 -C 3 - 烷基二胺及其混合物。至少约60重量％，至多100重量％的氧化剂B）包括碱式硝酸铜（II），即Cu（NO 3）2 Cl 2（OH）2和/或钴（III）三硝酸三苯胺盐，即Co NH3）3.（NO3）3。

9. 发明授权

US08101033B2 Alkali metal perchlorate-containing gas generants 有权
标题翻译：碱金属高氯酸盐气体发生剂
公开(公告)号：US08101033B2
公开(公告)日：2012-01-24
申请号：US10899452
申请日：2004-07-26
申请人： Michael W. Barnes , Ivan V. Mendenhall , Robert D. Taylor
发明人： Michael W. Barnes , Ivan V. Mendenhall , Robert D. Taylor
IPC分类号： C06B31/00 , C06B29/00 , C06B29/02 , D03D23/00 , D03D43/00
CPC分类号： C06D5/06
摘要： Alkali metal perchlorate-containing gas generant compositions which, upon combustion, produce or result in an improved effluent and related methods for generating an inflation gas for use in an inflatable restraint system are provided. Such alkali metal perchlorate-containing gas generant compositions include at least one alkali metal perchlorate present with a mean particle size in excess of 100 microns. Such alkali metal perchlorate-containing gas generant compositions also include or contain a suitable non-azide, organic, nitrogen-containing fuel and at least one copper-containing compound selected from the group consisting of basic copper nitrate, cupric oxide, copper diammine dinitrate-ammonium nitrate mixture wherein ammonium nitrate is present in the mixture in a range of about 3 to about 90 weight percent, copper diammine bitetrazole, a copper-nitrate complex resulting from reaction of 5-aminotetrazole with basic copper nitrate and combinations thereof.
摘要翻译：提供了在燃烧时产生或导致改进的流出物的碱金属高氯酸盐气体发生剂组合物，以及用于产生用于可充气约束系统的充气气体的相关方法。这种含高氯酸高氯酸的气体发生剂组合物包括至少一种平均粒度超过100微米的碱金属高氯酸盐。这种含碱金属高氯酸盐气体发生剂组合物还包括或含有合适的非叠氮化物，有机，含氮燃料和至少一种选自碱式硝酸铜，氧化铜，二硝酸铜二氧化钛 - 硝酸铵混合物，其中硝酸铵在约3至约90重量％的范围内存在于混合物中，铜二氨基四唑，由5-氨基四唑与碱式硝酸铜的反应产生的硝酸铜络合物及其组合。

10. 发明授权

US6143102A Burn rate-enhanced basic copper nitrate-containing gas generant compositions and methods 有权
标题翻译：燃烧速率增强型碱式含硝酸铜的气体发生剂组合物和方法
公开(公告)号：US6143102A
公开(公告)日：2000-11-07
申请号：US306304
申请日：1999-05-06
申请人： Ivan V. Mendenhall , Robert D. Taylor , Michael W. Barnes , David W. Parkinson
发明人： Ivan V. Mendenhall , Robert D. Taylor , Michael W. Barnes , David W. Parkinson
IPC分类号： C06B23/00 , C06B41/00 , C06D5/06 , G06B31/00 , D03D23/00 , G06B31/02
CPC分类号： C06D5/06 , C06B23/007 , C06B41/00
摘要： Basic copper nitrate-containing gas generant compositions and associated methods are provided for producing or resulting in increased burn rates via the inclusion of an effective amount of one or more metal (e.g., Al, Ti, Zn, Mg and/or Zr) oxide additives.
摘要翻译：提供了含有硝酸铜的气体发生剂组合物和相关方法，用于通过包含有效量的一种或多种金属（例如Al，Ti，Zn，Mg和/或Zr）氧化物添加剂来生产或导致燃烧速率增加。

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