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    • 5. 发明授权
    • Liquid-crystalline silicones having increased UV stability
    • 具有增加的UV稳定性的液晶硅氧烷
    • US06358574B1
    • 2002-03-19
    • US09455875
    • 1999-12-06
    • Norman HäberleJürgen KüpferHorst Leigeber
    • Norman HäberleJürgen KüpferHorst Leigeber
    • C09K1938
    • C08G77/38C09K19/408Y10T428/1068
    • Crosslinkable LC organosiloxanes exhibiting excellent UV stability, contain units of the general formula 1 [RbMescSiO(4−b−c)/2]  (1) in which R are C1-C4-alkyl radicals, Mes is at least one group of the general formula 2 and, if desired, of the general formula 3, b has the value 0, 1 or 2, and c has the value 0, 1, 2, 3 or 4, with the proviso that the sum of the values of b and c is a maximum of 4, where the Mes groups of the general formulae 2 and 3 exhibit the following structure: —(CH2)p—(O)q—A—[B—A]r—E—F—VN  (2) —(CH2)m—(O)n—(A)t—Q—X  (3) in which A, B, Q, X, E, F, VN, m, p, n, q, t and r have the meanings given in claim 1, with the proviso that the LC organosiloxanes do not constitute a phenyl ester derivative of an aliphatic, aromatic or heteroaromatic carboxylic acids.
    • 显示出优异的UV稳定性的可交联的LC有机硅氧烷含有通式1的单元,其中R是C1-C4-烷基,Mes是至少一种通式2的基团,如果需要,通式3的b具有值 0,1或2,并且c具有值0,1,2,3或4,条件是b和c的值的总和最大为4,其中通式2和3的Mes基团 具有以下结构:其中A,B,Q,X,E,F,VN,m,p,n,q,t和r具有权利要求1中给出的含义,条件是LC有机硅氧烷不构成 苯基酯衍生物的脂族,芳族或杂芳族羧酸。