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    • 4. 发明授权
    • Preparation of aromatic cyanates
    • 芳香族氰酸酯的制备
    • US4748270A
    • 1988-05-31
    • US552515
    • 1983-11-16
    • Daniel J. MurrayEdmund P. Woo
    • Daniel J. MurrayEdmund P. Woo
    • C07D521/00C07C67/00C07C261/02C07C313/00C07C317/22C07C69/00
    • C07C261/02C07C2103/68
    • A process for the preparation of an aromatic cyanate which comprises (a) preparing in situ a cyanogen chloride by contacting a solution of chlorine in a chlorinated hydrocarbon with an aqueous solution of an alkali metal cyanide at a temperature of 0.degree. C. or below under conditions such that a cyanogen chloride is prepared; (b) physically separating the chlorinated hydrocarbon in which the cyanogen chloride is dissolved from the aqueous layer in which an alkali metal chloride salt is dissolved; and (c) contacting the cyanogen chloride dissolved in the chlorinated hydrocarbon with a hydroxy-substituted aromatic compound dissolved in a chlorinated hydrocarbon, a secondary alcohol or a tertiary alcohol, in the presence of a tertiary amine at a temperature of about 0.degree. C. or less under conditions such that a polyaromatic cyanate is prepared.
    • 一种制备芳族氰酸酯的方法,其包括(a)在0℃或更低的温度下将氯化烃中的氯溶液与碱金属氰化物的水溶液接触,原位制备氯化氰 制备氯化氰的条件; (b)从其中溶解有碱金属氯化物盐的水层物理分离溶解有氯化氰的氯化烃; 和(c)在叔胺的存在下,在约0℃的温度下,将溶解在氯化烃中的氯化氰与溶解在氯化烃,仲醇或叔醇中的羟基取代的芳族化合物接触。 或更少的条件,使得制备多芳族氰酸酯。
    • 5. 发明授权
    • Polyaromatic cyanate
    • 聚芳香氰酸酯
    • US4713442A
    • 1987-12-15
    • US833931
    • 1986-02-27
    • Edmund P. WooDaniel J. Murray
    • Edmund P. WooDaniel J. Murray
    • C07C261/02C08G73/06C08G73/00
    • C08G73/0655C07C261/02C07C2103/68
    • This invention relates to a polyaromatic cyanate which corresponds to the formula ##STR1## wherein: Ar is an aromatic radical;B is a C.sub.7-20 polycyclic aliphatic radical;D is independently in each occurrence any nonactive hydrogen-containing substituent;q, r and s are independently in each occurrence the integers 0, 1, 2, or 3; with the proviso that the sum of q, 4 and s is greater than or equal to 2;t is independently in each occurrence an integer of between about 0 and 4 inclusive; andx is a number between about 0 and 5 inclusive.Another aspect of this invention is a novel polytriazine which comprises the reaction product of the polyaromatic cyanate esters of this invention. The novel polytriazines may further comprise the reaction product of the novel polyaromatic cyanates of this invention in admixture with other cyanates known in the art as useful for the preparation of polytriazines.
    • 本发明涉及对应于下式的多芳族氰酸酯:其中:Ar是芳族基; B是C7-20多环脂族基团; 每次出现任何非活性含氢取代基; q,r和s在每次出现时都是独立的整数0,1,2或3; 条件是q,4和s之和大于或等于2; t在每次出现时独立地为约0和4之间的整数; x是包括0和5之间的数字。 本发明的另一方面是一种新的聚三嗪,其包括本发明的多芳族氰酸酯的反应产物。 新颖的三叉嗪可以进一步包括本发明的新型多芳族氰酸酯与本领域已知的用于制备聚三嗪的其它氰酸酯的混合物的反应产物。
    • 6. 发明授权
    • Novel polyaromatic cyanates
    • 新型多芳香族氰酸酯
    • US4751323A
    • 1988-06-14
    • US552234
    • 1983-11-16
    • Edmund P. WooDaniel J. Murray
    • Edmund P. WooDaniel J. Murray
    • C07C67/00C07C261/02C07C313/00C07D261/02C07D495/00C07D495/08C08G18/76C08G73/00C08G73/06C07C69/00C07D335/04C08G63/38
    • C08G73/0655C07C261/02C07C2103/68
    • This invention relates to a polyaromatic cyanate which corresponds to the formula ##STR1## wherein Ar is an aromatic radical;B is a C.sub.7-20 polycyclic aliphatic radical;D is independently in each occurrence any non-active hydrogen-containing substituent;q, r and s are independently in each occurrence the integers b 0, 1, 2, l or b 3l ; with the proviso that the sum of q, 4 and s is greater than or equal to 2;t is independently in each occurrence an integer of between about 0 and 4 inclusive; andx is a number between about 0 and 5 inclusive.Another aspect of this invention is a novel polytriazine which comprises the reaction product of the polyaromatic cyanate esters of this invention. The novel polytriazines may further comprise the reaction product of the novel polyaromatic cyanates of this invention in admixture with other cyanates known in the art as useful for the preparation of polytriazines.
    • 本发明涉及对应于式“IMAGE”的多芳族氰酸酯,其中Ar是芳族基团; B是C7-20多环脂族基团; D在每次出现时都是独立的任何非活性含氢取代基; q,r和s在每次出现时独立地为整数b 0,1,2,1或b 3l; 条件是q,4和s之和大于或等于2; t在每次出现时独立地为约0和4之间的整数; x是包括0和5之间的数字。 本发明的另一方面是一种新的聚三嗪,其包括本发明的多芳族氰酸酯的反应产物。 新颖的三叉嗪可以进一步包括本发明的新型多芳族氰酸酯与本领域已知的用于制备聚三嗪的其它氰酸酯的混合物的反应产物。