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1. 发明申请

US20120172624A1 PROCESS FOR PREPARING DECANECARBOXYLIC ACIDS 有权
标题翻译：制备癸酰氧基酸的方法
公开(公告)号：US20120172624A1
公开(公告)日：2012-07-05
申请号：US13386523
申请日：2010-05-25
申请人： Michael Grass , Alfred Kaizik , Hans-Gerd Lueken , Wilfried Bueschken
发明人： Michael Grass , Alfred Kaizik , Hans-Gerd Lueken , Wilfried Bueschken
IPC分类号： C07C51/373
CPC分类号： C07C45/74 , C07C45/50 , C07C45/62 , C07C51/235 , C07C47/02 , C07C47/21 , C07C53/128
摘要： The invention relates to a process for preparing a mixture of isomeric decane-carboxylic acids, which comprises the following steps:a) hydroformylation of a hydrocarbon mixture containing linear C4-olefins using a rhodium-containing catalyst system;b) aldol condensation of a mixture of aliphatic C5-aldehydes obtained from step a);c) selective hydrogenation of the mixture of unsaturated C10-aldehydes from step b) to aliphatic C10-aldehydes;d) uncatalysed oxidation of the mixture of aliphatic C10-aldehydes from step c) to give a mixture having a proportion of at least 70% by mass of 2-propylheptanoic acid, based on the total content of isomeric decanecarboxylic acids.
摘要翻译：本发明涉及一种制备异构癸烷 - 羧酸的混合物的方法，其包括以下步骤：a）使用含铑催化剂体系加氢甲酰化含有线性C 4 - 烯烃的烃混合物; b）从步骤a）获得的脂族C 5 - 醛的混合物的醛醇缩合; c）选自氢化来自步骤b）的不饱和C10-醛的混合物至脂族C 10 - 醛; d）来自步骤c）的脂族C 10 - 醛混合物的未催化氧化，得到基于异构癸烷羧酸的总含量的至少70质量％的2-丙基庚酸的混合物。

2. 发明授权

US08907129B2 Process for preparing decanecarboxylic acids 有权
标题翻译：癸烷羧酸的制备方法
公开(公告)号：US08907129B2
公开(公告)日：2014-12-09
申请号：US13386523
申请日：2010-05-25
申请人： Michael Grass , Alfred Kaizik , Hans-Gerd Lueken , Wilfried Bueschken
发明人： Michael Grass , Alfred Kaizik , Hans-Gerd Lueken , Wilfried Bueschken
IPC分类号： C07C51/235 , C07C45/74 , C07C45/62 , C07C45/50
CPC分类号： C07C45/74 , C07C45/50 , C07C45/62 , C07C51/235 , C07C47/02 , C07C47/21 , C07C53/128
摘要： The invention relates to a process for preparing a mixture of isomeric decane-carboxylic acids, which comprises the following steps: a) hydroformylation of a hydrocarbon mixture containing linear C4-olefins using a rhodium-containing catalyst system; b) aldol condensation of a mixture of aliphatic C5-aldehydes obtained from step a); c) selective hydrogenation of the mixture of unsaturated C10-aldehydes from step b) to aliphatic C10-aldehydes; d) uncatalysed oxidation of the mixture of aliphatic C10-aldehydes from step c) to give a mixture having a proportion of at least 70% by mass of 2-propylheptanoic acid, based on the total content of isomeric decanecarboxylic acids.
摘要翻译：本发明涉及一种制备异构癸烷 - 羧酸的混合物的方法，其包括以下步骤：a）使用含铑催化剂体系加氢甲酰化含有线性C 4 - 烯烃的烃混合物; b）从步骤a）获得的脂族C 5 - 醛的混合物的醛醇缩合; c）选自氢化来自步骤b）的不饱和C10-醛的混合物至脂族C 10 - 醛; d）来自步骤c）的脂族C 10 - 醛混合物的未催化氧化，得到基于异构癸烷羧酸的总含量的至少70质量％的2-丙基庚酸的混合物。

3. 发明授权

US08258325B2 Mixture of diesters of dianhydrohexitol derivatives with carboxylic acids of the empirical formula C8H17COOH, process for preparing these diesters, and use of these mixtures 有权
标题翻译：二脱水己糖醇衍生物的二酯与经验式C8H17COOH的羧酸的混合物，制备这些二酯的方法以及这些混合物的使用
公开(公告)号：US08258325B2
公开(公告)日：2012-09-04
申请号：US12523906
申请日：2007-12-21
申请人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
发明人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
IPC分类号： C07D307/93 , C07D493/00 , C08G73/06
CPC分类号： C07D493/04 , C08K5/1535 , C08L27/06
摘要： The present invention relates to a mixture comprising diesters of the formula (I) where R1 to R8═H or alkyl group having from 1 to 6 carbon atoms, where the R1 to R8 radicals may be the same or different, which is characterized in that at least two different diesters I are present in the mixture, said diesters differing in the structure of at least one of the carboxylic acid radicals C8H17COO present, to a process for preparing diesters of an isosorbide derivative of the formula I, in which a hexahydric alcohol and/or a monoanhydro or dianhydro derivative of the alcohol is esterified with a mixture of at least two different carboxylic acids of the empirical formula C8H17COOH, and to the use of these mixtures in paints, inks or coatings, in plastisols, adhesives or adhesive components, in sealants, as plasticizers in polymers or polymer components, as solvents, as lubricant oil components and as assistants in metal processing, and also PVC compositions or plastisols comprising PVC and from 5 to 250 parts by mass of the mixture per 100 parts by mass of PVC.
摘要翻译：本发明涉及包含式（I）的二酯的混合物，其中R 1至R 8 = H或具有1至6个碳原子的烷基，其中R 1至R 8基团可以相同或不同，其特征在于混合物中存在至少两种不同的二酯I，所述二酯在存在的羧酸基团C 8 H 17 COO中的至少一种的结构上不同，制备式I的异山梨醇衍生物的二酯的制备方法，其中六元醇和/或醇的单酐或二氢衍生物与经验式C 8 H 17 COOH的至少两种不同羧酸的混合物酯化，并且在涂料，油墨或涂料中，在增塑溶胶，粘合剂或粘合剂组分中使用这些混合物在密封剂中，作为聚合物或聚合物组分中的增塑剂，作为溶剂，作为润滑油组分和作为金属加工助剂，以及PVC组合物或增塑溶胶，其包含PVC和相对于100质量份的PVC，为5〜250质量份的混合物。

4. 发明申请

US20090301348A1 MIXTURE OF DIESTERS OF DIANHYDROHEXITOL DERIVATIVES WITH CARBOXYLIC ACIDS OF THE EMPIRICAL FORMULA C8H17COOH, PROCESS FOR PREPARING THESE DIESTERS, AND USE OF THESE MIXTURES 有权
标题翻译：二恶烷衍生物与实施方案C8H17COOH的羧酸的混合物，制备这些柴油的方法和这些混合物的使用
公开(公告)号：US20090301348A1
公开(公告)日：2009-12-10
申请号：US12523906
申请日：2007-12-21
申请人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
发明人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
IPC分类号： C09D5/08 , C09K3/00 , C08L27/06
CPC分类号： C07D493/04 , C08K5/1535 , C08L27/06
摘要： The present invention relates to a mixture comprising diesters of the formula (I) where R1 to R8═H or alkyl group having from 1 to 6 carbon atoms, where the R1 to R8 radicals may be the same or different, which is characterized in that at least two different diesters I are present in the mixture, said diesters differing in the structure of at least one of the carboxylic acid radicals C8H17COO present, to a process for preparing diesters of an isosorbide derivative of the formula I, in which a hexahydric alcohol and/or a monoanhydro or dianhydro derivative of the alcohol is esterified with a mixture of at least two different carboxylic acids of the empirical formula C8H17COOH, and to the use of these mixtures in paints, inks or coatings, in plastisols, adhesives or adhesive components, in sealants, as plasticizers in polymers or polymer components, as solvents, as lubricant oil components and as assistants in metal processing, and also PVC compositions or plastisols comprising PVC and from 5 to 250 parts by mass of the mixture per 100 parts by mass of PVC.
摘要翻译：本发明涉及包含式（I）的二酯的混合物，其中R 1至R 8 -H或具有1至6个碳原子的烷基，其中R 1至R 8基团可以相同或不同，其特征在于混合物中存在至少两种不同的二酯I，所述二酯在存在的羧酸基团C 8 H 17 COO中的至少一种的结构上不同，制备式I的异山梨醇衍生物的二酯的制备方法，其中六元醇和/或醇的单酐或二氢衍生物与经验式C 8 H 17 COOH的至少两种不同羧酸的混合物酯化，并且在涂料，油墨或涂料中，在增塑溶胶，粘合剂或粘合剂组分中使用这些混合物，作为聚合物或聚合物组分中的增塑剂，作为溶剂，作为润滑油组分和金属加工助剂，以及包含PVC和f的PVC组合物或增塑溶胶相对于100质量份的PVC为5〜250质量份的混合物。

5. 发明申请

US20150018576A1 METHOD AND DEVICE FOR THE HYDROFORMYLATION OF ISOBUTENE AND FOR THE SEPARATION OF THE PRODUCT MIXTURE 有权
标题翻译：用于分离产品混合物的方法和装置
公开(公告)号：US20150018576A1
公开(公告)日：2015-01-15
申请号：US14380647
申请日：2013-02-11
申请人： Goetz Baumgarten , Michael Grass , Alfred Kaizik , Markus Winterberg , Hans-Gerd Lueken , Bart Hamers , Markus Priske , Dirk Fridag , Robert Franke , Dieter Hess
发明人： Goetz Baumgarten , Michael Grass , Alfred Kaizik , Markus Winterberg , Hans-Gerd Lueken , Bart Hamers , Markus Priske , Dirk Fridag , Robert Franke , Dieter Hess
IPC分类号： C07C51/43 , C07C51/235 , C07C45/78 , C07C45/50
CPC分类号： C07C51/43 , B01D61/027 , C07C45/50 , C07C45/505 , C07C45/786 , C07C45/82 , C07C51/235 , C07C47/02
摘要： The invention relates to a method for producing a product mixture (2) by means of the technical hydroformylation of a hydrocarbon stream (1) that contains isobutene, and for separating the product mixture (2) that is obtained, as well as to a device for the claimed method and to the use of a claimed device. The problem addressed thereby is that of providing a method and an associated device that allow the amount of high-boiling substances in the product mixture (2) to be kept as low as possible and thus the yield of the reaction to be increased. The problem is solved by the use of a nano-filtration device (M) for separating the catalyst from the product mixture (2), said device having especially high permeability to 3-methylbutanoic acid.
摘要翻译：本发明涉及一种通过含有异丁烯的烃流（1）的技术加氢甲酰化以及用于分离获得的产物混合物（2）以及制备产物混合物（2）的方法，用于所要求保护的方法和所要求保护的装置的使用。由此提出的问题是提供一种方法和相关联的装置，其允许将产物混合物（2）中的高沸点物质的量保持尽可能低，从而提高反应的产率。通过使用纳米过滤装置（M）从产物混合物（2）中分离催化剂来解决该问题，所述装置对3-甲基丁酸具有特别高的渗透性。

6. 发明授权

US08415520B2 Work-up of a 3-methyl-1-butene-containing mixture 失效
标题翻译：后处理含3-甲基-1-丁烯的混合物
公开(公告)号：US08415520B2
公开(公告)日：2013-04-09
申请号：US13375091
申请日：2010-04-29
申请人： Markus Winterberg , Alfred Kaizik , Armin Rix , Michael Grass , Wilfried Bueschken , Marc Becker
发明人： Markus Winterberg , Alfred Kaizik , Armin Rix , Michael Grass , Wilfried Bueschken , Marc Becker
IPC分类号： C07C7/04
CPC分类号： C07C7/04 , C07C1/24 , C07C7/06 , C07C11/10
摘要： The invention is a method for processing a mixture containing water, 3-methyl-1-butane and at least one other methylbutene. The method comprises primary distillation of the mixture, giving a gaseous primary overhead product containing methylbutene and water and a water-free primary bottom product containing 3-methyl-1-butene; condensation of the gaseous primary overhead product so as to give a condensate comprising a liquid aqueous phase and a liquid organic phase; separation of the condensate into a liquid aqueous phase and a liquid organic phase; discharge of the liquid aqueous phase; recirculation of the organic phase to the primary distillation; and finally secondary distillation of the water-free primary bottom product from the primary distillation so as to give a secondary overhead product comprising 3-methyl-1-butene and a secondary bottom product. The secondary overhead product obtained has a purity which enables it to be used directly as monomer or comonomer for preparing polymers or copolymers.
摘要翻译：本发明是一种处理含有水，3-甲基-1-丁烷和至少一种其它甲基丁烯的混合物的方法。该方法包括对该混合物进行一次蒸馏，得到含有甲基丁烯和水的气态初级塔顶馏出物和含有3-甲基-1-丁烯的无水初级底物产物; 气态一级塔顶产物的冷凝，以产生包含液态水相和液体有机相的冷凝物; 将冷凝物分离成液态水相和液体有机相; 液体水相的排出; 将有机相再循环至初级蒸馏; 最后从初级蒸馏二次蒸馏无水初级底部产物，得到包含3-甲基-1-丁烯和二级底部产物的二级塔顶产物。获得的二次塔顶产物具有使其能够直接用作制备聚合物或共聚物的单体或共聚单体的纯度。

7. 发明申请

US20120136190A1 PRODUCTION OF 3-METHYLBUT-1-EN BY MEANS OF DEHYDRATION OF 3-METHYLBUTANE-1-OL 审中-公开
标题翻译：通过3-甲基丁-1-醇脱水制备3-甲基-1-
公开(公告)号：US20120136190A1
公开(公告)日：2012-05-31
申请号：US13322527
申请日：2010-04-28
申请人： Alfred Kaizik , Thomas Quandt , Michael Grass , Markus Winterberg , Wilfried Bueschken
发明人： Alfred Kaizik , Thomas Quandt , Michael Grass , Markus Winterberg , Wilfried Bueschken
IPC分类号： C07C1/20
CPC分类号： C07C1/24 , C07C11/10
摘要： The invention relates to a process for preparing 3-methyl-1-butene by dehydration of 3-methyl-1-butanol over an aluminium-containing oxide in the temperature range from 200 to 450° C. in the gas phase or mixed liquid/gas phase, characterized in that an aluminium-containing oxide having a predominantly mesoporous pore structure whose:a) relative proportion of macropores is less than 15%;b) distribution of the pore diameter has a monomodal maximum in the range of mesopores from 3.6 to 50 nm;c) average pore diameter of all pores is in the range of mesopores and macropores from 5 to 20 nm;d) composition comprises more than 80% of gamma-aluminium oxide, is used.
摘要翻译：本发明涉及通过在气相或混合液体/液体中在200-450℃的含铝氧化物上脱水3-甲基-1-丁醇来制备3-甲基-1-丁烯的方法，气相，其特征在于具有主要介孔孔结构的含铝氧化物：a）大孔相对比例小于15％; b）孔径分布在介孔范围为3.6〜50nm的单峰最大值; c）所有孔的平均孔径在5〜20nm的介孔和大孔的范围内; d）组合物包含大于80％的γ-氧化铝。

8. 发明授权

US07632961B2 Method for the production of alicyclic polycarboxylic acid esters from partial esters of aromatic polycarboxylic acids 失效
标题翻译：从芳族多元羧酸的偏酯生产脂环族多元羧酸酯的方法
公开(公告)号：US07632961B2
公开(公告)日：2009-12-15
申请号：US10474044
申请日：2002-09-14
申请人： Wilfried Bueschken , Michael Grass , Alfred Kaizik , Dietrich Maschmeyer , Franz Nierlich , Axel Tuchlenski
发明人： Wilfried Bueschken , Michael Grass , Alfred Kaizik , Dietrich Maschmeyer , Franz Nierlich , Axel Tuchlenski
IPC分类号： C07C69/74
CPC分类号： C07C67/08 , C07C67/303 , C07C69/75
摘要： The invention relates to a process for preparing full esters of alicyclic polycarboxylic acids from partial esters of aromatic polycarboxylic acids by hydrogenation of the partial ester followed by esterification of this compound.
摘要翻译：本发明涉及通过部分酯的氢化，然后酯化该化合物，由芳族多元羧酸的偏酯制备脂环族多元羧酸的全酯的方法。

9. 发明授权

US07361714B2 Catalyst and method for hydrogenating aromatic compounds 有权
标题翻译：用于氢化芳族化合物的催化剂和方法
公开(公告)号：US07361714B2
公开(公告)日：2008-04-22
申请号：US10511595
申请日：2003-04-26
申请人： Michael Grass , Alfred Kaizik , Wilfried Bueschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
发明人： Michael Grass , Alfred Kaizik , Wilfried Bueschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
IPC分类号： C08C19/02
CPC分类号： B01J35/10 , B01J23/40 , B01J23/462 , B01J23/74 , B01J35/1014 , B01J35/1061 , B01J35/108 , C07C67/303 , C07C69/75
摘要： The invention relates to the hydrogenation of aromatic compounds, in particular the preparation of alicyclic polycarboxylic acids or esters of these, via ring hydrogenation of the corresponding aromatic polycarboxylic acids or esters of these, and also to catalysts suitable for this purpose.
摘要翻译：本发明涉及芳族化合物的氢化，特别是通过相应的芳族多元羧酸或它们的酯的环加氢制备脂环族多元羧酸或它们的酯，以及适用于该目的的催化剂。

10. 发明授权

US08207375B2 Microporous catalyst and method for hydrogenating aromatic compounds 有权
标题翻译：微孔催化剂和芳烃化合物的加氢方法
公开(公告)号：US08207375B2
公开(公告)日：2012-06-26
申请号：US12025292
申请日：2008-02-04
申请人： Michael Grass , Alfred Kaizik , Wilfried Bueschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
发明人： Michael Grass , Alfred Kaizik , Wilfried Bueschken , Axel Tuchlenski , Dietrich Maschmeyer , Kurt-Alfred Gaudschun , Frank Brocksien
IPC分类号： C08C19/02 , C07C51/36 , B01J35/10
CPC分类号： B01J21/063 , B01J23/40 , B01J23/462 , B01J35/10 , B01J35/1061 , B01J35/108 , B01J37/0018 , C07C51/36 , C07C67/303 , C07C2601/14 , Y02P20/582 , C07C61/135 , C07C69/75
摘要： The invention relates to the hydrogenation of aromatic compounds, in particular the preparation of alicyclic polycarboxylic acids or their esters by core hydrogenation of the corresponding aromatic polycarboxylic acids or their esters, and also to catalysts suitable therefore.
摘要翻译：本发明涉及芳族化合物的氢化，特别是通过相应的芳族多元羧酸或其酯的核心氢化制备脂环族多元羧酸或其酯，以及由此合适的催化剂。

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