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1. 发明申请

US20080168901A1 Liners For Ion Transport Membrane Systems 有权
标题翻译：离子传输膜系统衬垫
公开(公告)号：US20080168901A1
公开(公告)日：2008-07-17
申请号：US11838477
申请日：2007-08-14
申请人： Michael Francis Carolan , Christopher Francis Miller
发明人： Michael Francis Carolan , Christopher Francis Miller
IPC分类号： B01J20/28 , B01J35/10
CPC分类号： B01D53/22 , B01D53/228 , B01D63/06 , B01D63/08 , B01D2256/12 , B01D2313/14 , B01D2313/42 , B01D2317/02 , B01D2317/04 , C01B3/382 , C01B13/0251 , C01B13/0255 , C01B2203/0233 , C01B2203/0811 , C01B2203/143 , C01B2210/0046 , Y02P20/52
摘要： Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and(d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.
摘要翻译：离子传输膜系统，包括（a）压力容器，其包括内部，外部，入口，入口导管，出口和出口导管; （b）多个平面离子传递膜组件，其设置在所述压力容器的内部并串联布置，每个膜组件包括混合的金属氧化物陶瓷材料并具有内部区域和外部区域，其中所述入口和出口压力容器与膜组件的外部区域流动连通; （c）具有内表面的气体歧管，其中所述气体歧管与所述平面离子迁移膜模块的每个的内部区域以及所述压力容器的外部流动连通; 和（d）设置在任何入口导管，出口导管和气体歧管内表面内的衬垫。

2. 发明申请

US20080178736A1 FEED GAS CONTAMINANT REMOVAL IN ION TRANSPORT MEMBRANE SYSTEMS 有权
标题翻译：离子运输膜系统中的进料污染物去除
公开(公告)号：US20080178736A1
公开(公告)日：2008-07-31
申请号：US11028124
申请日：2005-01-03
申请人： Michael Francis Carolan , Christopher Francis Miller
发明人： Michael Francis Carolan , Christopher Francis Miller
IPC分类号： B01D53/22
CPC分类号： C01B13/0255 , B01D53/22 , B01D53/228 , B01D53/229 , B01D53/64 , B01D63/084 , B01D69/141 , B01D71/024 , B01D2251/30 , B01D2251/40 , B01D2256/12 , B01D2257/60 , B01D2257/708 , B01D2313/42 , B01D2319/04 , C01B3/382 , C01B3/384 , C01B2203/0216 , C01B2203/0222 , C01B2203/0244 , C01B2203/0811 , C01B2203/0844 , C01B2203/1241 , C01B2203/141 , C01B2203/142 , C01B2203/1614 , C01B2203/82 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , H01M8/04089 , H01M2008/1293 , Y02P20/52
摘要： Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.
摘要翻译：用于气体净化的方法，其包括（a）获得含有一种或多种选自挥发性金属氧化物，挥发性金属氧化物和挥发性氢氧化硅的污染物的进料气流; （b）将进料气流与反应性固体材料接触在保护床中，并使至少一部分污染物与反应性固体材料反应，以在保护床中形成固体反应产物; 和（c）从护罩中取出纯净气流。

3. 发明授权

US07771519B2 Liners for ion transport membrane systems 有权
标题翻译：离子传输膜系统的衬垫
公开(公告)号：US07771519B2
公开(公告)日：2010-08-10
申请号：US11838477
申请日：2007-08-14
申请人： Michael Francis Carolan , Christopher Francis Miller
发明人： Michael Francis Carolan , Christopher Francis Miller
IPC分类号： B01D53/22
CPC分类号： B01D53/22 , B01D53/228 , B01D63/06 , B01D63/08 , B01D2256/12 , B01D2313/14 , B01D2313/42 , B01D2317/02 , B01D2317/04 , C01B3/382 , C01B13/0251 , C01B13/0255 , C01B2203/0233 , C01B2203/0811 , C01B2203/143 , C01B2210/0046 , Y02P20/52
摘要： Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and (d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.
摘要翻译：离子传输膜系统，包括（a）压力容器，其包括内部，外部，入口，入口导管，出口和出口导管; （b）多个平面离子传递膜组件，其设置在所述压力容器的内部并串联布置，每个膜组件包括混合的金属氧化物陶瓷材料并具有内部区域和外部区域，其中所述入口和出口压力容器与膜组件的外部区域流动连通; （c）具有内表面的气体歧管，其中所述气体歧管与所述平面离子迁移膜模块的每个的内部区域以及所述压力容器的外部流动连通; 和（d）设置在任何入口导管，出口导管和气体歧管内表面内的衬垫。

4. 发明申请

US20110263912A1 Control Of Kinetic Decomposition In Mixed Conducting Ion Transport Membranes 审中-公开
标题翻译：混合导电离子传输膜中动力学分解的控制
公开(公告)号：US20110263912A1
公开(公告)日：2011-10-27
申请号：US11936351
申请日：2007-11-07
申请人： Christopher Francis Miller , Michael Francis Carolan
发明人： Christopher Francis Miller , Michael Francis Carolan
IPC分类号： C07C27/12 , B01J19/00 , C04B35/64 , H01B1/02
CPC分类号： C04B35/2641 , B01D53/228 , B01D63/082 , B01D67/0046 , B01D71/024 , B01D2323/08 , B01D2323/12 , B01D2325/26 , C01B3/36 , C01B2203/0255 , C04B35/6262 , C04B35/6263 , C04B37/001 , C04B37/005 , C04B37/04 , C04B2235/3208 , C04B2235/3227 , C04B2235/3274 , C04B2235/5409 , C04B2235/6025 , C04B2235/656 , C04B2235/6567 , C04B2235/658 , C04B2235/661 , C04B2235/786 , C04B2237/10 , C04B2237/34 , C04B2237/343 , C04B2237/704 , C04B2237/765 , C04B2237/80
摘要： Mixed conducting ion transport membrane comprising a multi-component metallic oxide compound represented by the formula LnxA′x′A″x″ByB′y′O3-z wherein (a) Ln is an element selected from the f block lanthanides, A′ is selected from Group 2, A″ is selected from Groups 1, 2 and 3 and the f block lanthanides, and B and B′ are independently selected from the d block transition metals, excluding titanium and chromium, wherein 0≦x y+y′≧1.0 and z is a number which renders the compound charge neutral, and (b) the average grain size of the multicomponent metallic oxide is in the range of about 4 μm to about 20 μm.
摘要翻译：混合导电离子迁移膜，其包含由式LnxA'x'A“x”ByB''O3-z表示的多组分金属氧化物化合物，其中（a）Ln是选自f嵌段镧系元素的元素，A' 选自第2组，A“选自第1组，第2组和第3组，f组镧系元素，B和B'独立地选自d嵌段过渡金属，不包括钛和铬，其中0和nlE; x <1,0 y + y' 这使得化合物电荷为中性，和（b）多组分金属氧化物的平均晶粒尺寸在约4μm至约20μm的范围内。

5. 发明授权

US07425231B2 Feed gas contaminant removal in ion transport membrane systems 有权
标题翻译：离子传输膜系统中的进料气体污染物去除
公开(公告)号：US07425231B2
公开(公告)日：2008-09-16
申请号：US11028124
申请日：2005-01-03
申请人： Michael Francis Carolan , Christopher Francis Miller
发明人： Michael Francis Carolan , Christopher Francis Miller
IPC分类号： B01D53/22 , C01B13/02
CPC分类号： C01B13/0255 , B01D53/22 , B01D53/228 , B01D53/229 , B01D53/64 , B01D63/084 , B01D69/141 , B01D71/024 , B01D2251/30 , B01D2251/40 , B01D2256/12 , B01D2257/60 , B01D2257/708 , B01D2313/42 , B01D2319/04 , C01B3/382 , C01B3/384 , C01B2203/0216 , C01B2203/0222 , C01B2203/0244 , C01B2203/0811 , C01B2203/0844 , C01B2203/1241 , C01B2203/141 , C01B2203/142 , C01B2203/1614 , C01B2203/82 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , H01M8/04089 , H01M2008/1293 , Y02P20/52
摘要： Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.
摘要翻译：用于气体净化的方法，其包括（a）获得含有一种或多种选自挥发性金属氧化物，挥发性金属氧化物和挥发性氢氧化硅的污染物的进料气流; （b）将进料气流与反应性固体材料接触在保护床中，并使至少一部分污染物与反应性固体材料反应，以在保护床中形成固体反应产物; 和（c）从护罩中取出纯净气流。

6. 发明授权

US08262755B2 Staged membrane oxidation reactor system 有权
标题翻译：分期膜氧化反应器系统
公开(公告)号：US08262755B2
公开(公告)日：2012-09-11
申请号：US11758231
申请日：2007-06-05
申请人： John Michael Repasky , Michael Francis Carolan , VanEric Edward Stein , Christopher Ming-Poh Chen
发明人： John Michael Repasky , Michael Francis Carolan , VanEric Edward Stein , Christopher Ming-Poh Chen
IPC分类号： B01D53/22 , B01D59/10 , B01D59/12 , C10L3/00
CPC分类号： B01J12/007 , B01J19/2475 , B01J2219/00006 , B01J2219/0004 , B01J2219/00065 , B01J2219/00103 , C01B3/38 , C01B13/0251 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/0283 , C01B2203/1241 , C01B2203/127 , C01B2203/142 , C01B2210/0046 , Y02P20/52
摘要： Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.
摘要翻译：离子传输膜氧化系统，其包含（a）两个或更多个膜氧化阶段，每个阶段包括反应物区域，氧化剂区域，将反应物区域与氧化剂区域分离的一个或多个离子迁移膜，反应物气体入口区域，反应物气体出口区域，氧化剂气体入口区域和氧化剂气体出口区域; （b）级间反应气体流动路径，设置在每对膜氧化阶段之间，并适于将该对的第一级的反应气体出口区域与该对的第二级的反应气体入口区域流动连通; 和（c）一个或多个反应物级间进料气体管线，每条管路与任何级间反应物气体流动路径流通或与任何膜氧化阶段的反应物区域接收阶段间反应气体。

7. 发明授权

US08246719B2 Use of impure inert gases in the controlled heating and cooling of mixed conducting metal oxide materials 有权
标题翻译：在混合导电金属氧化物材料的受控加热和冷却中使用不纯的惰性气体
公开(公告)号：US08246719B2
公开(公告)日：2012-08-21
申请号：US12567167
申请日：2009-09-25
申请人： Michael Francis Carolan , John Charles Bernhart
发明人： Michael Francis Carolan , John Charles Bernhart
IPC分类号： B01D53/22
CPC分类号： B01D71/024 , B01D53/228 , B01D67/0093 , C01B13/0255 , C01B2210/0046 , C01B2210/005 , C01B2210/0051 , C01B2210/0062 , C01B2210/0075
摘要： Method for processing an article comprising mixed conducting metal oxide material. The method comprises contacting the article with an oxygen-containing gas and either reducing the temperature of the oxygen-containing gas during a cooling period or increasing the temperature of the oxygen-containing gas during a heating period; during the cooling period, reducing the oxygen activity in the oxygen-containing gas during at least a portion of the cooling period and increasing the rate at which the temperature of the oxygen-containing gas is reduced during at least a portion of the cooling period; and during the heating period, increasing the oxygen activity in the oxygen-containing gas during at least a portion of the heating period and decreasing the rate at which the temperature of the oxygen-containing gas is increased during at least a portion of the heating period.
摘要翻译：用于加工包含混合导电金属氧化物材料的制品的方法。该方法包括使制品与含氧气体接触，并且在冷却期间降低含氧气体的温度或在加热期间增加含氧气体的温度; 在冷却期间，在冷却期间的至少一部分期间降低含氧气体中的氧活度，并且在冷却期间的至少一部分期间提高含氧气体的温度降低的速度; 并且在加热期间，在加热期间的至少一部分期间增加含氧气体中的氧活性，并且在加热期间的至少一部分期间降低含氧气体的温度升高的速率。

8. 发明授权

US5750279A Series planar design for solid electrolyte oxygen pump 失效
标题翻译：固体电解质氧泵系列平面设计
公开(公告)号：US5750279A
公开(公告)日：1998-05-12
申请号：US240054
申请日：1994-05-09
申请人： Michael Francis Carolan , Paul Nigel Dyer , Eric Minford , Steven Lee Russek , Merrill Anderson Wilson , Dale M. Taylor , Brett Tamatea Henderson
发明人： Michael Francis Carolan , Paul Nigel Dyer , Eric Minford , Steven Lee Russek , Merrill Anderson Wilson , Dale M. Taylor , Brett Tamatea Henderson
IPC分类号： B01D53/32 , C25B1/02 , C25B9/00 , C25B9/06 , C25B9/08 , C25B9/18 , G01N27/41 , G01N27/419 , H01M8/02 , H01M8/06 , H01M8/12 , H01M8/24 , H01M8/04
CPC分类号： B01D53/326 , C25B9/066 , C25B9/18 , G01N27/419 , H01M8/0271 , H01M8/2425 , H01M8/243
摘要： An electrochemical device is disclosed comprising a plurality of planar electrolytic cells connected in series, each cell having an oxygen ion-conducting electrolyte layer, an anode layer and a cathode layer associated with the electrolyte layer, electrically conductive interconnect layers having gas passages situated therein for transporting gaseous streams, which interconnect layers electrically connect the anode layer of each electrolytic cell to the cathode layer of an adjacent planar cell, and sealing means positioned between the interconnect layers and the electrolytic cells to provide a gas-tight seal therebetween. The configuration of the interconnect layer and the placement of the seal means provides a separation between the seal and the conductive pathway of electrons between the anode layer and cathode layer which prevents corrosion or deterioration of the seal.
摘要翻译：公开了一种电化学装置，其包括串联连接的多个平面电解池，每个电池具有氧离子传导电解质层，阳极层和与电解质层相连的阴极层，导电互连层具有位于其中的气体通道，用于输送气流，其中互连层将每个电解池的阳极层电连接到相邻平面单元的阴极层，以及位于互连层和电解池之间的密封装置，以在其间提供气密密封。互连层的配置和密封装置的放置提供了密封和阳极层和阴极层之间的电子传导路径之间的隔离，防止了密封的腐蚀或劣化。

9. 发明授权

US5683797A Inorganic membranes 失效
标题翻译：无机膜
公开(公告)号：US5683797A
公开(公告)日：1997-11-04
申请号：US618639
申请日：1996-03-19
申请人： Michael Francis Carolan , Paul Nigel Dyer , Stephen Mark Fine , Alexander Makitka, III , Robin Edward Richards , Leslie Errol Schaffer
发明人： Michael Francis Carolan , Paul Nigel Dyer , Stephen Mark Fine , Alexander Makitka, III , Robin Edward Richards , Leslie Errol Schaffer
IPC分类号： B01D71/02 , C01B13/14 , C01G49/00 , C04B41/52 , C23C16/04 , C23C16/40 , C23C16/46 , B32B3/26 , B32B5/14 , B32B5/18
CPC分类号： B01D67/0072 , B01D67/0044 , B01D71/02 , B01D71/022 , B01D71/024 , C04B41/52 , C23C16/045 , C23C16/46 , B01D2323/08 , B01D2323/12 , B01D2325/02 , Y10T428/12042 , Y10T428/12479 , Y10T428/249956 , Y10T428/249957 , Y10T428/24997 , Y10T428/249981 , Y10T428/249999
摘要： The present invention is a method for manufacturing inorganic membranes which are capable of separating oxygen from oxygen-containing gaseous mixtures. The membranes comprise a porous composite of a thin layer of a multicomponent metallic oxide which has been deposited onto a porous support wherein the pores of the multicomponent metallic oxide layer are subsequently filled or plugged with a metallic-based species. The inorganic membranes are formed by depositing a porous multicomponent metallic oxide layer onto the porous support to form a porous composite having a network of pores capable of transporting gases. The network of pores are plugged or filled by organometallic vapor infiltration to form an inorganic membrane having essentially no through porosity.
摘要翻译：本发明是一种能够从含氧气体混合物中分离氧的无机膜的制造方法。膜包括已经沉积到多孔载体上的多组分金属氧化物的薄层的多孔复合物，其中多组分金属氧化物层的孔随后用金属基物质填充或堵塞。通过将多孔多组分金属氧化物层沉积到多孔载体上以形成具有能够输送气体的孔网络的多孔复合材料形成无机膜。通过有机金属蒸气渗透堵塞或填充孔网，形成基本上不具有孔隙率的无机膜。

10. 发明授权

US07703472B2 Module isolation devices 失效
标题翻译：模块隔离装置
公开(公告)号：US07703472B2
公开(公告)日：2010-04-27
申请号：US11296633
申请日：2005-12-07
申请人： Michael Francis Carolan , John Albert Cooke , Michael David Buzinski
发明人： Michael Francis Carolan , John Albert Cooke , Michael David Buzinski
IPC分类号： F16K17/40 , B01D53/047
CPC分类号： F16K17/16 , B01D53/22 , B01D63/00 , B01D2257/102 , B01D2313/18 , B01D2319/04 , Y10T137/1789
摘要： A gas flow isolation device includes a gas flow isolation valve movable from an opened condition to a closed condition. The module isolation valve in one embodiment includes a rupture disk in flow communication with a flow of gas when the module isolation valve is in an opened condition. The rupture disk ruptures when a predetermined pressure differential occurs across it causing the isolation valve to close. In one embodiment the valve is mechanically linked to the rupture disk to maintain the valve in an opened condition when the rupture disk is intact, and which permits the valve to move into a closed condition when the rupture disk ruptures. In another embodiment a crushable member maintains the valve in an open condition, and the flow of gas passed the valve upon rupturing of the rupture disk compresses the crushable member to close the isolation valve.
摘要翻译：气体流隔离装置包括可从打开状态移动到关闭状态的气体流隔离阀。在一个实施例中，模块隔离阀包括当模块隔离阀处于打开状态时与气流流动连通的破裂盘。当在其上发生预定的压力差时，破裂盘破裂，导致隔离阀关闭。在一个实施例中，当破裂盘完好时，阀与破裂盘机械连接以将阀保持在打开状态，并且当破裂盘破裂时允许阀移动到关闭状态。在另一个实施例中，可压碎构件将阀保持在打开状态，并且在破裂盘破裂时气体流过阀的流动压缩可压碎构件以关闭隔离阀。

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