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    • 3. 发明授权
    • Polybutadiene and polyisoprene thermosetting compositions and method of
manufacture thereof
    • 聚丁二烯和聚异戊二烯热固性组合物及其制造方法
    • US6071836A
    • 2000-06-06
    • US176788
    • 1998-10-22
    • Michael E. St. LawrenceDoris I. Hand
    • Michael E. St. LawrenceDoris I. Hand
    • C08J5/24H05K1/02H05K1/03H05K1/16B32B7/00
    • C08J5/24H05K1/032H05K1/0373C08J2309/00H05K1/0203H05K1/0366H05K1/162H05K2201/012H05K2201/0133H05K2201/0158H05K2201/0209H05K2201/0212H05K2201/0251H05K2201/0278H05K2201/029H05K2201/0293
    • An electrical substrate material is presented comprising a thermosetting matrix of polybutadiene or polyisoprene in an amount of about 15 to about 50 volume %; a fabric reinforcement in an amount of 0 to about 40 volume %; a particulate filler, preferably ceramic, in an amount of from 0 to about 60 volume %; microballoons in an amount from 0 to about 60 volume %; and optionally a flame retardant. A peroxide cure initiator and/or crosslinking agent may optionally be added. The presence of a very high surface area particulate filler, preferably fumed silica, is also preferred, in that its presence results in a prepreg which has very little tackiness and can therefore be easily handled by operators. This low tackiness feature allows for the use of conventional automated layup processing, including foil cladding, using one or more known roll laminators. While the prepreg of this invention is tack-free enough to be handled relatively easily by hand, it is also tacky enough to be tacked to itself using a roll laminator (e.g., nip roller) at room temperature. The composition of this invention is particularly well suited for making electrical circuit substrates for microwave and digital circuits, typically in the form of the thermosetting composition being laminated onto one or both opposed surfaces to a metal conductive foil such as copper.
    • 呈现的电气基材材料包含约15至约50体积%的量的聚丁二烯或聚异戊二烯的热固性基质; 织物增强物的量为0至约40体积%; 量为0至约60体积%的颗粒填料,优选陶瓷; 量为0至约60体积%的微球; 和任选的阻燃剂。 可以任选加入过氧化物固化引发剂和/或交联剂。 存在非常高的表面积的颗粒填料,优选热解法二氧化硅也是优选的,因为其存在导致预浸料,其具有非常小的粘性,因此可以容易地由操作者处理。 这种低粘性特征允许使用一种或多种已知的辊式层压机来使用常规的自动铺层处理,包括箔包层。 虽然本发明的预浸料无粘性足以用手相对容易地处理,但是它也是粘性足以在室温下使用辊式层压机(例如夹辊)粘合到其自身上。 本发明的组合物特别适用于制造用于微波和数字电路的电路基板,通常将热固性组合物的形式层压在诸如铜的金属导电箔的一个或两个相对的表面上。