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1. 发明授权

US08889932B2 Methods of producing jet fuel from natural oil feedstocks through oxygen-cleaved reactions 有权
标题翻译：通过氧裂解反应从天然油原料生产喷气燃料的方法
公开(公告)号：US08889932B2
公开(公告)日：2014-11-18
申请号：US13129172
申请日：2009-11-25
申请人： Melvin L. Luetkens, Jr. , Steven A. Cohen
发明人： Melvin L. Luetkens, Jr. , Steven A. Cohen
IPC分类号： C10G3/00 , C10G67/12 , C10G65/08 , C10G27/14 , C10L1/06 , C10G27/04 , C10G65/04 , C10L1/04
CPC分类号： C10G3/50 , C10G3/00 , C10G7/00 , C10G27/04 , C10G27/14 , C10G31/00 , C10G31/09 , C10G31/10 , C10G65/043 , C10G65/08 , C10G67/12 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/30 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L2200/0484 , C10L2270/04 , C10L2290/543 , C10L2290/547 , Y02P30/20
摘要： Methods are provided for producing a jet fuel composition from a feedstock comprising a natural oil. The methods comprise reacting the feedstock with oxygen under conditions sufficient to form an oxygen-cleaved product. The methods further comprise hydrogenating the oxygen-cleaved product under conditions sufficient to form a jet fuel composition.
摘要翻译：提供了从包含天然油的原料生产喷气燃料组合物的方法。所述方法包括在足以形成氧切割产物的条件下使原料与氧气反应。所述方法还包括在足以形成喷气燃料组合物的条件下氢化氧切割产物。

2. 发明申请

US20110113679A1 METHODS OF REFINING AND PRODUCING FUEL FROM NATURAL OIL FEEDSTOCKS 有权
标题翻译：从天然油原料精炼和生产燃料的方法
公开(公告)号：US20110113679A1
公开(公告)日：2011-05-19
申请号：US12901829
申请日：2010-10-11
申请人： Steven A. Cohen , Melvin L. Luetkens, JR. , Chander Balakrishnan , Robert Snyder
发明人： Steven A. Cohen , Melvin L. Luetkens, JR. , Chander Balakrishnan , Robert Snyder
IPC分类号： C10L1/19 , C07C5/02
CPC分类号： C10G3/42 , C07C2/862 , C07C6/04 , C07C51/09 , C07C67/03 , C07C67/54 , C07C2531/14 , C07C2531/24 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/02 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1092 , C10G2300/1096 , C10G2300/202 , C10G2300/30 , C10G2300/301 , C10G2300/307 , C10G2300/308 , C10G2300/44 , C10G2400/00 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/04 , C10L1/08 , C10L2200/0469 , C11B3/00 , C11C1/08 , C11C3/003 , Y02E50/13 , Y02P30/20 , Y02T50/678 , C07C69/533 , C07C57/03 , C07C57/12 , C07C11/02
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译：提供了用于精炼天然油原料的方法。所述方法包括在复分解催化剂存在下，在足以形成包含烯烃和酯的复分解产物的条件下使原料反应。在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。在某些实施方案中，所述方法还包括在足以形成燃料组合物的条件下氢化所述烯烃。在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。

3. 发明申请

US20110237850A1 METHODS OF PRODUCING JET FUEL FROM NATURAL OIL FEEDSTOCKS THROUGH METATHESIS REACTIONS 有权
标题翻译：通过生物反应从天然油料生产喷射燃料的方法
公开(公告)号：US20110237850A1
公开(公告)日：2011-09-29
申请号：US13129170
申请日：2009-11-25
申请人： Melvin L. Luetkens, JR. , Steven A. Cohen , Chander Balakrishnan
发明人： Melvin L. Luetkens, JR. , Steven A. Cohen , Chander Balakrishnan
IPC分类号： C10G1/00
CPC分类号： C10L1/08 , C10G3/50 , C10G2300/1014 , C10G2300/1088 , C10G2300/30 , C10G2400/08 , C10L1/04 , C10L2200/0484 , C10L2270/04 , Y02P30/20
摘要： Methods are provided for producing a jet fuel composition from a feedstock comprising a natural oil. The methods comprise reacting the feedstock with a low-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product. The methods further comprise hydrogenating the metathesized product under conditions sufficient to form a jet fuel composition.
摘要翻译：提供了从包含天然油的原料生产喷气燃料组合物的方法。所述方法包括在复分解催化剂存在下在足以形成复分解产物的条件下使原料与低重量烯烃反应。所述方法还包括在足以形成喷气燃料组合物的条件下氢化复分解产物。

4. 发明授权

US08779152B2 Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes 有权
标题翻译：制备钌卡宾络合物前体和钌卡宾络合物的方法
公开(公告)号：US08779152B2
公开(公告)日：2014-07-15
申请号：US13272788
申请日：2011-10-13
申请人： Linda A. Kunz , Steven A. Cohen , Melvin L. Luetkens, Jr.
发明人： Linda A. Kunz , Steven A. Cohen , Melvin L. Luetkens, Jr.
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , B01J31/2295 , C07F15/0053
摘要： A method for preparing a ruthenium carbene complex precursor includes reacting a ruthenium refinery salt with a hydrogen halide to form a ruthenium intermediate, and reacting the ruthenium intermediate with an L-type ligand to form the ruthenium carbene complex precursor. A method for preparing a ruthenium vinylcarbene complex includes converting a ruthenium carbene complex precursor into a ruthenium hydrido halide complex, and reacting the ruthenium hydrido halide complex with a propargyl halide to form the ruthenium vinylcarbene complex. A method for preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR1R2R3)2Cl2Ru═CH—R4, wherein R1, R2, R3, and R4 are alike or different, and wherein covalent bonds may optionally exist between two or more of R1, R2, and R3.
摘要翻译：制备钌卡宾络合物前体的方法包括使钌精炼盐与卤化氢反应形成钌中间体，并使钌中间体与L型配体反应以形成钌卡宾复合物前体。制备钌乙烯基卡巴复合物的方法包括将钌卡宾络合物前体转化为卤化钌卤化物络合物，并使卤化钌卤化物络合物与炔丙基卤反应形成钌乙烯基卡巴复合物。制备钌卡宾络合物的方法包括将钌卡宾络合物前体转化成具有结构（PR1R2R3）2Cl2Ru=CH-R4的钌卡宾络合物，其中R 1，R 2，R 3和R 4相同或不同，并且其中共价键可以任选地存在于R 1，R 2和R 3中的两个或多个之间。

5. 发明申请

US20130096313A1 METHODS FOR PREPARING RUTHENIUM CARBENE COMPLEX PRECURSORS AND RUTHENIUM VINYLCARBENE COMPLEXES 有权
标题翻译：制备碳酸亚乙酯复合前体和乙烯基烯烃复合物的方法
公开(公告)号：US20130096313A1
公开(公告)日：2013-04-18
申请号：US13272788
申请日：2011-10-13
申请人： Linda A. Kunz , Steven A. Cohen , Melvin L. Luetkens, JR.
发明人： Linda A. Kunz , Steven A. Cohen , Melvin L. Luetkens, JR.
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , B01J31/2295 , C07F15/0053
摘要： A method for preparing a ruthenium carbene complex precursor includes reacting a ruthenium refinery salt with a hydrogen halide to form a ruthenium intermediate, and reacting the ruthenium intermediate with an L-type ligand to form the ruthenium carbene complex precursor. A method for preparing a ruthenium vinylcarbene complex includes converting a ruthenium carbene complex precursor into a ruthenium hydrido halide complex, and reacting the ruthenium hydrido halide complex with a propargyl halide to form the ruthenium vinylcarbene complex. A method for preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR1R2R3)2Cl2Ru═CH—R4, wherein R1, R2, R3, and R4 are alike or different, and wherein covalent bonds may optionally exist between two or more of R1, R2, and R3.
摘要翻译：制备钌卡宾络合物前体的方法包括使钌精炼盐与卤化氢反应形成钌中间体，并使钌中间体与L型配体反应以形成钌卡宾复合物前体。制备钌乙烯基卡巴复合物的方法包括将钌卡宾络合物前体转化为卤化钌卤化物络合物，并使卤化钌卤化物络合物与炔丙基卤反应形成钌乙烯基卡巴复合物。制备钌卡宾络合物的方法包括将钌卡宾络合物前体转化成具有结构（PR1R2R3）2Cl2Ru = CH-R4的钌卡宾络合物，其中R1，R2，R3和R4是相同或不同的，其中共价键可以任选地存在于R 1，R 2和R 3中的两个或多个之间。

6. 发明授权

US08933285B2 Methods of producing jet fuel from natural oil feedstocks through metathesis reactions 有权
标题翻译：通过复分解反应从天然油原料生产喷气燃料的方法
公开(公告)号：US08933285B2
公开(公告)日：2015-01-13
申请号：US13129170
申请日：2009-11-25
申请人： Melvin L. Luetkens, Jr. , Steven A. Cohen , Chander Balakrishnan
发明人： Melvin L. Luetkens, Jr. , Steven A. Cohen , Chander Balakrishnan
IPC分类号： C10G1/00 , C10L1/04
CPC分类号： C10L1/08 , C10G3/50 , C10G2300/1014 , C10G2300/1088 , C10G2300/30 , C10G2400/08 , C10L1/04 , C10L2200/0484 , C10L2270/04 , Y02P30/20
摘要： Methods are provided for producing a jet fuel composition from a feedstock comprising a natural oil. The methods comprise reacting the feedstock with a low-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product. The methods further comprise hydrogenating the metathesized product under conditions sufficient to form a jet fuel composition.
摘要翻译：提供了从包含天然油的原料生产喷气燃料组合物的方法。所述方法包括在复分解催化剂存在下在足以形成复分解产物的条件下使原料与低重量烯烃反应。所述方法还包括在足以形成喷气燃料组合物的条件下氢化复分解产物。

7. 发明申请

US20130035502A1 METHODS OF REFINING AND PRODUCING FUEL AND SPECIALTY CHEMICALS FROM NATURAL OIL FEEDSTOCKS 有权
标题翻译：从天然油料中精炼和生产燃料和特种化学品的方法
公开(公告)号：US20130035502A1
公开(公告)日：2013-02-07
申请号：US13647825
申请日：2012-10-09
申请人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
发明人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
IPC分类号： C07C1/22 , C07C67/02
CPC分类号： C10L1/02 , C10G3/42 , C10G29/205 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/123 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/08 , C11B3/00 , C11C3/003 , Y02P20/582
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock with a low-molecular-weight olefin or mid-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译：提供了用于精炼天然油原料的方法。所述方法包括在复分解催化剂存在下在足以形成包含烯烃和酯的复分解产物的条件下使原料与低分子量烯烃或中等重量的烯烃反应。在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。

8. 发明授权

US08957268B2 Methods of refining natural oil feedstocks 有权
标题翻译：天然油原料精炼方法
公开(公告)号：US08957268B2
公开(公告)日：2015-02-17
申请号：US12901829
申请日：2010-10-11
申请人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder
发明人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder
IPC分类号： C11C1/00 , C07C1/00 , C07C5/03 , C07C1/24 , C11B3/00 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/04 , C10L1/02 , C10L1/08 , C11C3/00 , C10G3/00 , C07C67/03 , C07C67/54 , C07C6/04 , C07C51/09 , C07C2/86
CPC分类号： C10G3/42 , C07C2/862 , C07C6/04 , C07C51/09 , C07C67/03 , C07C67/54 , C07C2531/14 , C07C2531/24 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/02 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1092 , C10G2300/1096 , C10G2300/202 , C10G2300/30 , C10G2300/301 , C10G2300/307 , C10G2300/308 , C10G2300/44 , C10G2400/00 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/04 , C10L1/08 , C10L2200/0469 , C11B3/00 , C11C1/08 , C11C3/003 , Y02E50/13 , Y02P30/20 , Y02T50/678 , C07C69/533 , C07C57/03 , C07C57/12 , C07C11/02
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise hydrogenating the olefins under conditions sufficient to form a fuel composition. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译：提供了用于精炼天然油原料的方法。所述方法包括在复分解催化剂存在下，在足以形成包含烯烃和酯的复分解产物的条件下使原料反应。在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。在某些实施方案中，所述方法还包括在足以形成燃料组合物的条件下氢化所述烯烃。在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。

9. 发明授权

US08735640B2 Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks 有权
标题翻译：从天然油原料精炼和生产燃料和特种化学品的方法
公开(公告)号：US08735640B2
公开(公告)日：2014-05-27
申请号：US13647825
申请日：2012-10-09
申请人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
发明人： Steven A. Cohen , Melvin L. Luetkens, Jr. , Chander Balakrishnan , Robert Snyder , Yenamandra Viswanath , Efimia Metsi-Guckel , Robin Weitkamp
IPC分类号： C07C6/02 , C07C6/04
CPC分类号： C10L1/02 , C10G3/42 , C10G29/205 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/123 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/08 , C11B3/00 , C11C3/003 , Y02P20/582
摘要： Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock with a low-molecular-weight olefin or mid-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.
摘要翻译：提供了用于精炼天然油原料的方法。所述方法包括在复分解催化剂存在下在足以形成包含烯烃和酯的复分解产物的条件下使原料与低分子量烯烃或中等重量的烯烃反应。在某些实施方案中，所述方法还包括将烯烃与复分解产物中的酯分离。在某些实施方案中，所述方法还包括在醇存在下酯交酯化以形成酯交换产物。

10. 发明申请

US20110230687A1 METHODS OF PRODUCING JET FUEL FROM NATURAL OIL FEEDSTOCKS THROUGH OXYGEN-CLEAVED REACTIONS 有权
标题翻译：通过氧气反应从天然油料生产喷射燃料的方法
公开(公告)号：US20110230687A1
公开(公告)日：2011-09-22
申请号：US13129172
申请日：2009-11-25
申请人： Melvin L. Luetkens, JR. , Steven A. Cohen
发明人： Melvin L. Luetkens, JR. , Steven A. Cohen
IPC分类号： C10L1/16
CPC分类号： C10G3/50 , C10G3/00 , C10G7/00 , C10G27/04 , C10G27/14 , C10G31/00 , C10G31/09 , C10G31/10 , C10G65/043 , C10G65/08 , C10G67/12 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/30 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L2200/0484 , C10L2270/04 , C10L2290/543 , C10L2290/547 , Y02P30/20
摘要： Methods are provided for producing a jet fuel composition from a feedstock comprising a natural oil. The methods comprise reacting the feedstock with oxygen under conditions sufficient to form an oxygen-cleaved product. The methods further comprise hydrogenating the oxygen-cleaved product under conditions sufficient to form a jet fuel composition.
摘要翻译：提供了从包含天然油的原料生产喷气燃料组合物的方法。所述方法包括在足以形成氧切割产物的条件下使原料与氧气反应。所述方法还包括在足以形成喷气燃料组合物的条件下氢化氧切割产物。

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