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1. 发明授权

US4830939A Radiation cured solid electrolytes and electrochemical devices employing the same 失效
标题翻译：辐射固化固体电解质和采用其的电化学装置
公开(公告)号：US4830939A
公开(公告)日：1989-05-16
申请号：US173385
申请日：1988-03-25
申请人： Mei-Tsu Lee , Dale R. Shackle , Gerhart Schwab
发明人： Mei-Tsu Lee , Dale R. Shackle , Gerhart Schwab
IPC分类号： C08F299/02 , H01M6/18
CPC分类号： C08F299/022 , H01M6/181
摘要： A method for forming an interpenetrating polymeric network containing a liquid electrolyte for use in solid state electrochemical cells which comprises forming a mixture of a liquid monomeric or prepolymeric radiation polymerizable, compound, a radiation inert ionically conducting liquid, and an ionizable alkaline metal salt; subjecting said mixture to actinic radiation to thereby crosslink said radiation polymerizable ionically conducting material and form a solid matrix containing said ionically conducting liquid; and electrode half elements and electrochemical cells incorporating said network.
摘要翻译：一种用于形成含有用于固态电化学电池的液体电解质的互穿聚合物网络的方法，其包括形成液体单体或预聚物可辐射聚合的化合物，辐射惰性离子导电液体和可电离的碱金属盐的混合物; 使所述混合物经受光化辐射从而使所述可辐射聚合的离子导电材料交联并形成含有所述离子导电液体的固体基质; 以及包含所述网络的电极半元件和电化学电池。

2. 发明授权

US5238758A Badiation cured solid electrolytes and electrochemical devices employing the same 失效
标题翻译：固化固体电解质和使用其的电化学装置
公开(公告)号：US5238758A
公开(公告)日：1993-08-24
申请号：US776722
申请日：1991-10-15
申请人： Mei-Tsu Lee , Dale R. Shackle , Gerhart Schwab
发明人： Mei-Tsu Lee , Dale R. Shackle , Gerhart Schwab
IPC分类号： H01M6/18
CPC分类号： H01M6/181
摘要： A method for forming an interpenetrating polymeric network containing a liquid electrolyte for use in solid state electrochemical cells which comprises forming a mixture of a liquid monomeric or prepolymeric radiation polymerizable, compound, a radiation inert ionically conducting liquid, and an ionizable alkaline metal salt; subjecting said mixture to actinic radiation to thereby crosslink said radiation polymerizable ionically conducting material and form a solid matrix containing said ionically conducting liquid; and electrode half elements and electrochemical cells incorporating said network.
摘要翻译：一种用于形成含有用于固态电化学电池的液体电解质的互穿聚合物网络的方法，其包括形成液体单体或预聚物可辐射聚合的化合物，辐射惰性离子导电液体和可电离的碱金属盐的混合物; 使所述混合物经受光化辐射从而使所述可辐射聚合的离子导电材料交联并形成含有所述离子导电液体的固体基质; 以及包含所述网络的电极半元件和电化学电池。

3. 发明授权

US5037712A Preparation of radiation cured solid electrolytes and electrochemical devices employing the same 失效
标题翻译：辐射固化固体电解质的制备和采用该电解质的电化学装置
公开(公告)号：US5037712A
公开(公告)日：1991-08-06
申请号：US506408
申请日：1990-04-06
申请人： Dale R. Shackle , Mei-Tsu Lee
发明人： Dale R. Shackle , Mei-Tsu Lee
IPC分类号： C08F20/28 , C08F20/10 , C08F283/06 , C08F283/12 , C08F290/00 , C08F299/02 , C08K3/00 , C08L71/02 , C08L83/04 , H01B1/06 , H01M6/18 , H01M10/052 , H01M10/0565 , H01M10/36
CPC分类号： H01M10/0565 , C08F283/06 , C08F283/12 , C08L71/02 , H01M6/181 , H01M10/052
摘要： A method is described for forming a solid electrolyte comprising a polymeric network structure containing an ionically conducting liquid for use in solid state electrochemical cells which comprises forming a mixture of a crosslinkable polysiloxane or a crosslinkable polyethylene oxide, an ionically conducting liquid, and an ionizable ammonium or alkali metal salt, and subjecting said mixture to actinic radiation to thereby crosslink said crosslinkable polysiloxane or crosslinkable polyethylene oxide to form a solid matrix through which said ionically conducting liquid interpenetrates to provide continuous paths of high conductivity in all directions throughout said matrix.
摘要翻译：描述了一种用于形成固体电解质的方法，该固体电解质包含含有用于固态电化学电池的离子导电液体的聚合物网络结构，其包括形成可交联聚硅氧烷或可交联聚环氧乙烷，离子导电液体和可离子化铵的混合物或碱金属盐，并使所述混合物进行光化辐射，从而使所述可交联聚硅氧烷或可交联聚环氧乙烷交联以形成固体基质，通过所述固体基质，所述离子导电液体通过该固体基质互穿，从而在所有基体上沿所有方向提供高导电性的连续路径。

4. 发明授权

US4720910A Method for preparing encapsulated cathode material 失效
标题翻译：密封阴极材料的制备方法
公开(公告)号：US4720910A
公开(公告)日：1988-01-26
申请号：US63336
申请日：1987-06-16
申请人： John K. Rourke , Gerhart Schwab , Dale R. Shackle
发明人： John K. Rourke , Gerhart Schwab , Dale R. Shackle
IPC分类号： H01M4/04 , H01M4/36
CPC分类号： H01M4/0416 , H01M4/04 , H01M4/0404 , H01M4/0419 , H01M4/043 , H01M4/36 , Y10T29/49115
摘要： A method for preparing a cathode material is provided. An insertion compound is ground until small particles of the insertion compound are formed. The insertion compound particles are encapsulated in an electronic and ionic conducting polymer to form the cathode material by using a spray dryer.
摘要翻译：提供了制备阴极材料的方法。将插入化合物研磨直到形成插入化合物的小颗粒。将插入化合物颗粒包封在电子和离子导电聚合物中以通过使用喷雾干燥器形成阴极材料。

5. 发明授权

US4143890A Pressure-sensitive carbonless transfer sheets using hot melt systems 失效
标题翻译：使用热熔体系的压敏无碳转印片材
公开(公告)号：US4143890A
公开(公告)日：1979-03-13
申请号：US747682
申请日：1976-12-06
申请人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
发明人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
IPC分类号： B41L1/36 , B41M5/132 , B41M5/155 , B41M5/165 , B41M5/22
CPC分类号： B41L1/36 , B41M5/132 , Y10S428/914 , Y10T428/264 , Y10T428/265 , Y10T428/277 , Y10T428/2984 , Y10T428/2987
摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating compositon adhered to at least one of the front and back surfaces of the paper substrate. The coating composition is set to a flexible, tack-free coat, and the coating composition includes a solvent free non-aqueous hot melt suspending medium which is characterized by being substantially water insoluble, being characterized by the presence of one or more functional groups selected from the group consisting of: carboxyl, carbonyl, hydroxyl, ester, amide, amine, heterocyclic groups and combinations thereof to impart polarity thereto and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. In addition the coating composition includes an encapsulated, chromogenic material which is substantially dispersed therein, the hot melt suspending medium being compatible with the color forming characteristics of the capsular chromogenic material. This invention further includes a liquid chromogenic coating compositon which comprises a hot melt suspending medium in combination with a microencapsulated chromogenic material. The chromogenic material is a color precursor of the electron donating type which is mixed with a carrier oil to form an oil solution of the chromogenic color precursor material which is then combined with one or more wall forming compounds.
摘要翻译：一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘合到纸基材的前表面和后表面中的至少一个上的涂料组合物。该涂料组合物被设定为柔性，无粘性的涂层，并且该涂料组合物包括无溶剂的非水热熔悬浮介质，其特征在于基本上不溶于水，其特征在于存在一个或多个选自由羧基，羰基，羟基，酯，酰胺，胺，杂环基及其组合构成的组中，赋予极性，熔点为约60℃至约140℃，熔点范围为小于约15℃。此外，涂料组合物包括基本上分散在其中的包封的显色材料，热熔悬浮介质与荚膜发色材料的着色特性相容。本发明还包括液体显色涂料组合物，其包含与微胶囊化显色材料组合的热熔悬浮介质。显色材料是供电类型的彩色前体，其与载体油混合以形成显色前体材料的油溶液，然后将其与一种或多种形成壁的化合物组合。

6. 发明授权

US4139218A Process for producing pressure-sensitive carbonless manifolds 失效
标题翻译：制造压敏无碳歧管的方法
公开(公告)号：US4139218A
公开(公告)日：1979-02-13
申请号：US828533
申请日：1977-08-29
申请人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
发明人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
IPC分类号： B41L1/36 , B41M5/132 , B41M5/155 , B41M5/165 , B41M5/22
CPC分类号： B41L1/36 , B41M5/132 , Y10S428/914 , Y10T428/264 , Y10T428/265 , Y10T428/277 , Y10T428/2984 , Y10T428/2987
摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating composition adhered to at least one of the front and back surfaces of the paper substrate. A novel process is provided for producing a pressure-sensitive carbonless transfer sheet which comprises the steps of preparing a hot melt suspending medium, the hot melt suspending medium being water insoluble and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. A microencapsulated chromogenic material is prepared and dispersed in the hot melt suspending medium, the chromogenic material being a color precursor of the electron donating type. A coating dispersion is prepared by combining the hot melt suspending medium with the microencapsulated chromogenic color precursor material, the hot melt suspending medium being compatible with the color forming or developing characteristics of the chromogenic material. The coating dispersion is then applied to a substrate, the coating dispersion being applied at a coat weight of from about 1.0 pounds to about 8.0 pounds per 3300 square feet of substrate at a coat thickness of from about 1 micron to about 50 microns. The coated substrate is set by cooling the coating dispersion.
摘要翻译：一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘附到纸基材的前表面和后表面中的至少一个上的涂料组合物。提供一种用于生产压敏无碳转印片的新方法，其包括制备热熔悬浮介质的步骤，该热熔悬浮介质是水不溶性的，熔点为约60℃至约140℃ 并且熔点范围小于约15℃。制备微胶囊化的显色材料并将其分散在热熔悬浮介质中，显色材料是供电类型的彩色前体。通过将热熔悬浮介质与微胶囊化的显色前体材料组合，制备涂层分散体，热熔悬浮介质与显色材料的成色或显色特性相容。然后将涂料分散体施加到基材上，涂层分散体以约1磅至约8.0磅/ 3300平方英尺的基材以约1微米至约50微米的涂层厚度施用。涂覆的基材通过冷却涂层分散体来设定。

7. 发明授权

US5045430A Method for making printing plates and assembly useful therein 失效
标题翻译：制造印版和组装的方法
公开(公告)号：US5045430A
公开(公告)日：1991-09-03
申请号：US791185
申请日：1985-10-25
申请人： Dale R. Shackle , Michael J. Cousin , Gerhart Schwab , Christina M. Narrick , Howard A. Fromson
发明人： Dale R. Shackle , Michael J. Cousin , Gerhart Schwab , Christina M. Narrick , Howard A. Fromson
IPC分类号： G03F7/004 , B41C1/06 , G03F7/00
CPC分类号： B41C1/06 , G03F7/002
摘要： A process for forming printing plates using an imaging sheet which carries a layer of microcapsules containing a photohardenable composition; the imaging sheet is preferably assembled with a printing plate support, exposed and subjected to pressure to rupture the microcapsules and differentially transfer the photohardenable composition to the support; the transferred composition is hardened to provide ink-receptive images useful in printing.
摘要翻译：一种使用承载含有可光硬化组合物的微胶囊层的成像片形成印版的方法; 成像片优选地与印版支撑件组装，暴露并经受压力以使微胶囊破裂并将可光硬化组合物差异地转移到支撑体上; 转移的组合物被硬化以提供可用于印刷的油墨接收图像。

8. 发明授权

US4170483A Process for the production of self-contained carbonless copy record sheets and coating composition for use therein 失效
标题翻译：用于生产独立无碳复制记录纸和其中使用的涂料组合物的方法
公开(公告)号：US4170483A
公开(公告)日：1979-10-09
申请号：US710201
申请日：1976-07-30
申请人： Dale R. Shackle , Gerhart Schwab
发明人： Dale R. Shackle , Gerhart Schwab
IPC分类号： B41M5/132 , C09D11/00
CPC分类号： B41M5/132 , Y10T428/254 , Y10T428/2984
摘要： In accordance with certain of its aspects, the novel process of this invention for making pressure-sensitive record sheets comprises the steps of forming a dispersion of microcapsules, the microcapsules being the product of microencapsulating a solution of a color precursor in an oil carrier; the walls of the microcapsules being substantially oil and water impermeable; forming an aqueous mixture containing a color developer for the encapsulated color precursor; adding a color suppressant to the dispersion of microcapsules, to the aqueous mixture or partially to both in an amount or amounts effective to substantially prevent color formation between the color developer and any unencapsulated color precursor; the color suppressant being a nitrogen containing basic organic compound selected from the group consisting of: amines, imines and aziridines; combining the aqueous mixture containing the color developer, the color suppressant and the microcapsules to form an aqueous coating composition; and applying the aqueous coating composition to a substrate in a single pass through substrate coating apparatus.In accordance with certain other aspects of this invention, the novel product of this invention is an aqueous slurry for coating pressure-sensitive record sheets, the novel slurry including a plurality of microcapsules, the microcapsules containing a solution of a color precursor in an oil carrier, the walls of the microcapsules comprising a reaction product of a wall forming compound and a cross-linking agent; a color developer for the color precursor; and a color suppressant comprising a nitrogen containing basic organic compound selected from the group consisting of: amines, imines and aziridines, the color suppressant being present in the aqueous slurry in an amount sufficient to substantially prevent color formation between the color developer and any unencapsulated color precursor.
摘要翻译：根据其某些方面，用于制造压敏记录片的本发明的新方法包括形成微胶囊的分散体的步骤，所述微胶囊是将油墨载体中的着色前体的溶液微囊化的产物; 微胶囊的壁基本上是油和水不渗透的; 形成包含用于所述包封的颜色前体的彩色显影剂的含水混合物; 向微胶囊的分散体中加入抑制剂至水性混合物或部分至少两者的量或有效量以显着防止显色剂与任何未包封的着色前体之间的着色形成; 所述除色剂是选自以下的含氮碱性有机化合物：胺，亚胺和氮丙啶; 将含有显色剂的水性混合物，除色剂和微胶囊组合以形成水性涂料组合物; 以及在单次通过基底涂布装置中将所述水性涂料组合物施用于基材。

9. 发明授权

US4139392A Chromogenic hot melt coating compositions 失效
标题翻译：显色热熔涂料组合物
公开(公告)号：US4139392A
公开(公告)日：1979-02-13
申请号：US828535
申请日：1977-08-29
申请人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
发明人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
IPC分类号： B41L1/36 , B41M5/132 , B41M5/155 , B41M5/165 , C09K3/00
CPC分类号： B41L1/36 , B41M5/132 , Y10S428/914 , Y10T428/264 , Y10T428/265 , Y10T428/277 , Y10T428/2984 , Y10T428/2987
摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating composition adhered to at least one of the front and back surfaces of the paper substrate. The coating composition is set to a flexible, tack-free coat, and the coating composition includes a solvent free non-aqueous hot melt suspending medium which is characterized by being substantially water insoluble, being characterized by the presence of one or more functional groups selected from the group consisting of: carboxyl, carbonyl, hydroxyl, ester, amide, amine, heterocyclic groups and combinations thereof to impart polarity thereto and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. In addition the coating composition includes an encapsulated, chromogenic material which is substantially dispersed therein, the hot melt suspending medium being compatible with the color forming characteristics of the capsular chromogenic material. This invention further includes a liquid chromogenic coating composition which comprises a hot melt suspending medium in combination with a microencapsulated chromogenic material. The chromogenic material is a color precursor of the electron donating type which is mixed with a carrier oil to form an oil solution of the chromogenic color precursor material which is then combined with one or more wall forming compounds.
摘要翻译：一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘附到纸基材的前表面和后表面中的至少一个上的涂料组合物。该涂料组合物被设定为柔性，无粘性的涂层，并且该涂料组合物包括无溶剂的非水热熔悬浮介质，其特征在于基本上不溶于水，其特征在于存在一个或多个选自由羧基，羰基，羟基，酯，酰胺，胺，杂环基及其组合构成的组中，赋予极性，熔点为约60℃至约140℃，熔点范围为小于约15℃。此外，涂料组合物包括基本上分散在其中的包封的显色材料，热熔悬浮介质与荚膜发色材料的着色特性相容。本发明还包括液体显色涂料组合物，其包含与微囊化显色材料组合的热熔悬浮介质。显色材料是供电类型的彩色前体，其与载体油混合以形成显色前体材料的油溶液，然后将其与一种或多种形成壁的化合物组合。

10. 发明授权

US4137343A Process for producing pressure-sensitive carbonless transfer sheets 失效
标题翻译：制造压敏碳无转印片的方法
公开(公告)号：US4137343A
公开(公告)日：1979-01-30
申请号：US828534
申请日：1977-08-29
申请人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
发明人： Gerald T. Davis , Gerhart Schwab , Dale R. Shackle
IPC分类号： B41L1/36 , B41M5/132 , B41M5/155 , B41M5/165 , B41M5/22
CPC分类号： B41L1/36 , B41M5/132 , Y10S428/914 , Y10T428/264 , Y10T428/265 , Y10T428/277 , Y10T428/2984 , Y10T428/2987
摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating composition adhered to at least one of the surfaces of the paper substrate. A novel process is provided for producing a pressure-sensitive carbonless transfer sheet which comprises the steps of preparing a hot melt suspending medium, the hot melt suspending medium being water insoluble and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. A microencapsulated chromogenic material is prepared and dispersed in the hot melt suspending medium, the chromogenic material being a color precursor of the electron donating type. A coating dispersion is prepared by combining the hot melt suspending medium with the microencapsulated chromogenic color precursor material, the hot melt suspending medium being compatible with the color forming or developing characteristics of the chromogenic material. The coating dispersion is then applied to a substrate, the coating dispersion being applied at a coat weight of from about 1.0 pound to about 8.0 pounds per 3300 square feet of substrate at a coat thickness of from about 1 micron to about 50 microns. The coated substrate is set by cooling the coating dispersion.
摘要翻译：一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘附到所述纸基材的至少一个表面上的涂料组合物。提供一种用于生产压敏无碳转印片的新方法，其包括制备热熔悬浮介质的步骤，该热熔悬浮介质是水不溶性的，熔点为约60℃至约140℃ 并且熔点范围小于约15℃。制备微胶囊化的显色材料并将其分散在热熔悬浮介质中，显色材料是供电类型的彩色前体。通过将热熔悬浮介质与微胶囊化的显色前体材料组合，制备涂层分散体，热熔悬浮介质与显色材料的成色或显色特性相容。然后将涂料分散体施加到基材上，涂层分散体以约1磅至约8磅/平方英尺的基材以大约1微米至大约50微米的涂层厚度施用。涂覆的基材通过冷却涂层分散体来设定。

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