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1. 发明授权

US4397769A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4397769A
公开(公告)日：1983-08-09
申请号：US250446
申请日：1981-04-02
申请人： Max P. McDaniel , John A. Sanbrano , Marvin M. Johnson
发明人： Max P. McDaniel , John A. Sanbrano , Marvin M. Johnson
IPC分类号： B01J23/26 , C08F10/00 , B01J21/06
CPC分类号： B01J23/26 , C08F10/00
摘要： A supported chromium oxide polymerization catalyst is prepared by a process which includes the steps of heating silica-supported chromium oxide or a substance oxidizable to chromium oxide in a nonoxidizing atmosphere in the presence of formaldehyde or a compound thermally decomposable to formaldehyde, and then heating the thus-treated catalyst in an oxygen-containing atmosphere. The temperatures of the respective heating steps can vary depending upon the properties desired in the polymer to be produced with the invention catalyst; however, the invention catalyst preparation method enables the production of a catalyst having a high melt index potential at relatively low treatment temperatures, e.g. no higher than about 600.degree. C.
摘要翻译：一种负载型氧化铬聚合催化剂的制备方法包括以下步骤：在甲醛或可热分解成甲醛的化合物的存在下，在非氧化性气氛中加热二氧化硅负载的氧化铬或氧化铬的物质，然后加热在含氧气氛中处理的催化剂。各加热步骤的温度可以根据本发明催化剂生产的聚合物中所需的性能而变化; 然而，本发明的催化剂制备方法使得能够在相对低的处理温度下制备具有高熔体指数电位的催化剂，例如，不高于约600℃

2. 发明授权

US4460756A Olefin polymerization method 失效
标题翻译：烯烃聚合法
公开(公告)号：US4460756A
公开(公告)日：1984-07-17
申请号：US479238
申请日：1983-03-28
申请人： Max P. McDaniel , John A. Sanbrano , Marvin M. Johnson
发明人： Max P. McDaniel , John A. Sanbrano , Marvin M. Johnson
IPC分类号： B01J23/26 , C08F10/00
CPC分类号： B01J23/26 , C08F10/00
摘要： A supported chromium oxide polymerization catalyst is prepared by a process which includes the steps of heating silica-supported chromium oxide or a substance oxidizable to chromium oxide in a nonoxidizing atmosphere in the presence of formaldehyde or a compound thermally decomposable to formaldehyde, and then heating the thus-treated catalyst in an oxygen-containing atmosphere. The temperatures of the respective heating steps can vary depending upon the properties desired in the polymer to be produced with the invention catalyst; however, the invention catalyst preparation method enables the production of a catalyst having a high melt index potential at relatively low treatment temperatures, e.g. no higher than about 600.degree. C.
摘要翻译：一种负载型氧化铬聚合催化剂的制备方法包括以下步骤：在甲醛或可热分解成甲醛的化合物的存在下，在非氧化性气氛中加热二氧化硅负载的氧化铬或氧化铬的物质，然后加热在含氧气氛中处理的催化剂。各加热步骤的温度可以根据本发明催化剂生产的聚合物中所需的性能而变化; 然而，本发明的催化剂制备方法使得能够在相对低的处理温度下制备具有高熔体指数电位的催化剂，例如，不高于约600℃

3. 发明授权

US06395666B1 Organometal catalyst compositions 有权
标题翻译：有机金属催化剂组合物
公开(公告)号：US06395666B1
公开(公告)日：2002-05-28
申请号：US09408904
申请日：1999-09-29
申请人： Max P. McDaniel , Kathy S. Collins , James L. Smith , Elizabeth A. Benham , Marvin M. Johnson , Anthony P. Eaton , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
发明人： Max P. McDaniel , Kathy S. Collins , James L. Smith , Elizabeth A. Benham , Marvin M. Johnson , Anthony P. Eaton , Michael D. Jensen , Joel L. Martin , Gil R. Hawley
IPC分类号： B01J2116
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F4/025 , C08F4/65916 , C08F2500/12 , C08F2500/03
摘要： This invention provides catalyst composition for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises as organometal compound, as organoaluminum compound, and a fluorided solid oxide compound.
摘要翻译：本发明提供了用于使至少一种单体聚合以制备聚合物的催化剂组合物，其中所述催化剂组合物包含有机金属化合物作为有机铝化合物和氟化固体氧化物化合物。

4. 发明授权

US5087789A Olefin oligomerization 失效
标题翻译：烯烃低聚
公开(公告)号：US5087789A
公开(公告)日：1992-02-11
申请号：US571684
申请日：1990-08-23
申请人： Max P. McDaniel , M. Bruce Welch , Marvin M. Johnson
发明人： Max P. McDaniel , M. Bruce Welch , Marvin M. Johnson
IPC分类号： B01J23/26 , B01J27/16 , B01J27/18 , C07C2/18 , C07C2/30
CPC分类号： C07C2/30 , B01J23/26 , B01J27/16 , B01J27/18 , C07C2/18 , C07C2527/167 , C07C2531/14 , Y02P20/52
摘要： In accordance with this invention oligomers are produced by a process comprising contacting propylene, ethylene, or a mixture thereof in a reaction zone, under a reaction temperature within the range of about 130.degree. C. to about 300.degree. C., with a catalyst comprising a chromium component on an aluminophosphate support.
摘要翻译：根据本发明，低聚物通过包括使反应区中的丙烯，乙烯或其混合物在约130℃至约300℃的反应温度下接触的方法制备，所述催化剂包含在磷酸铝载体上的铬组分。

5. 发明授权

US4640964A Olefin polymerization with polyphosphate supported chromium catalysts 失效
标题翻译：用多磷酸盐负载的铬催化剂进行烯烃聚合
公开(公告)号：US4640964A
公开(公告)日：1987-02-03
申请号：US741514
申请日：1985-06-05
申请人： Marvin M. Johnson , Max P. McDaniel
发明人： Marvin M. Johnson , Max P. McDaniel
IPC分类号： C08F4/24 , C08F10/00 , C08F4/78
CPC分类号： C08F10/00
摘要： A catalyst support based on aluminum polyphosphate or polyphosphoric acid-impregnated alumina is provided by two alternative techniques. In the first embodiment, an aluminum polyphosphate composition is heated in a dry atmosphere and thereafter impregnated with a zerovalent chromium component under anhydrous conditions. The resulting catalyst is active for olefin polymerization. In the second embodiment, alumina is impregnated with a polyphosphoric acid composition. This resulting polyphosphoric acid impregnated alumina can be used as a support for zerovalent chromium or can be impregnated with a chromium component and oxidized to give an active hexavalent chromium species. The resulting catalysts are advantageous because of their unusual sensitivity to hydrogen thus allowing great leeway in molecular weight control.
摘要翻译：通过两种替代技术提供了基于聚磷酸铝或多磷酸浸渍的氧化铝的催化剂载体。在第一实施方案中，将聚磷酸铝组合物在干燥气氛中加热，然后在无水条件下用零价铬组分浸渍。所得催化剂对于烯烃聚合是有活性的。在第二实施方案中，用多磷酸组合物浸渍氧化铝。所得多磷酸浸渍的氧化铝可用作零价铬的载体，或可用铬成分浸渍并氧化，得到活性六价铬物质。所得到的催化剂是有利的，因为它们对氢气具有不寻常的敏感性，从而允许在分子量控制方面具有很大的余地。

6. 发明授权

US4504638A Ethylene polymers made from phosphate supported chromium catalyst 失效
标题翻译：由磷酸盐负载的铬催化剂制成的乙烯聚合物
公开(公告)号：US4504638A
公开(公告)日：1985-03-12
申请号：US549511
申请日：1983-11-07
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/44 , C08F4/24 , C08F4/62 , C08F110/02
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a chromium catalyst supported on an aluminum phosphate-containing base is used in conjunction with a boron component either as a part of the base or as a cocatalyst. The resulting catalyst is unique both in its favorable sensitivity to molecular weight control agents such as hydrogen and in its ability to produce a fundamentally different olefin polymer. In accordance with another embodiment of this invention, the chromium is supported on a phosphate base produced using a melt of the aluminum salt.
摘要翻译：根据本发明的一个实施方案，负载在含磷酸铝的碱上的铬催化剂与作为碱的一部分的硼组分或作为助催化剂一起使用。所得催化剂在其对分子量控制剂如氢气的良好的敏感性以及其产生基本上不同的烯烃聚合物的能力方面是独特的。根据本发明的另一个实施方案，将铬负载在使用铝盐熔体制备的磷酸盐基底上。

7. 发明授权

US4444964A Polymerization process using phosphate supported chromium catalyst 失效
标题翻译：使用磷酸盐负载型铬催化剂的聚合方法
公开(公告)号：US4444964A
公开(公告)日：1984-04-24
申请号：US423596
申请日：1982-09-27
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/02 , C08F4/24 , C08F4/78
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a chromium catalyst supported on an aluminum phosphate-containing base is used in conjunction with a boron component either as a part of the base or as a cocatalyst. The resulting catalyst is unique both in its favorable sensitivity to molecular weight control agents such as hydrogen and in its ability to produce a fundamentally different olefin polymer. In accordance with another embodiment of this invention, the chromium is supported on a phosphate base produced using a melt of the aluminum salt.
摘要翻译：根据本发明的一个实施方案，负载在含磷酸铝的碱上的铬催化剂与作为碱的一部分的硼组分或作为助催化剂一起使用。所得催化剂在其对分子量控制剂如氢气的良好的敏感性以及其产生基本上不同的烯烃聚合物的能力方面是独特的。根据本发明的另一个实施方案，将铬负载在使用铝盐熔体制备的磷酸盐基底上。

8. 发明授权

US4397761A Phosphate containing support for vanadium catalyst 失效
标题翻译：含磷载体的钒催化剂
公开(公告)号：US4397761A
公开(公告)日：1983-08-09
申请号：US221752
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： B01J27/198 , B01J31/14 , C08F10/00 , B01J23/22 , C08F4/02
CPC分类号： B01J31/143 , C08F10/00
摘要： A supported vanadium catalyst comprising a vanadium compound on a phosphate-containing base. This catalyst in conjunction with an organoaluminum cocatalyst is capable of giving good activity and producing a polymer having broad molecular weight distribution. The catalyst system is sufficiently sensitive to hydrogen to allow broad leeway in controlling the molecular weight of the resulting polymers.
摘要翻译：在含磷酸盐的碱上含有钒化合物的负载型钒催化剂。该催化剂与有机铝助催化剂结合能够提供良好的活性并产生具有宽分子量分布的聚合物。催化剂体系对氢足够敏感，以便在控制所得聚合物的分子量方面具有广泛的余地。

9. 发明授权

US4364840A Phosphated silica-chromium catalyst with boron-containing cocatalyst 失效
标题翻译：磷化二氧化硅 - 铬催化剂与含硼助催化剂
公开(公告)号：US4364840A
公开(公告)日：1982-12-21
申请号：US221754
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/02 , C08F4/62
CPC分类号： C08F10/00
摘要： A catalyst system suitable for olefin polymerization comprising a catalyst component made up of chromium on a phosphated silica-containing base and a boron-containing cocatalyst. The resulting catalyst is particularly sensitive to the effects of hydrogen as a molecular weight control agent, thus allowing the production of polymers of having a melt flow varying over a wide spectrum utilizing the same catalyst.
摘要翻译：一种适用于烯烃聚合的催化剂体系，包括由磷化二氧化硅基底上的铬构成的催化剂组分和含硼助催化剂。所得到的催化剂对氢作为分子量控制剂的作用特别敏感，从而允许使用相同的催化剂制备在宽谱上具有变化的熔体流动的聚合物。

10. 发明授权

US4364839A Catalyst comprising chromium on silica/phosphate support 失效
标题翻译：包含二氧化硅/磷酸盐载体上的铬的催化剂
公开(公告)号：US4364839A
公开(公告)日：1982-12-21
申请号：US221746
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F4/00 , C08F4/02 , C08F4/24 , C08F4/60 , C08F4/62 , C08F10/00
CPC分类号： C08F10/00
摘要： In one embodiment of this invention, a chromium component is supported on a silica/aluminum orthophosphate combination and used with an organometal cocatalyst. In accordance with other embodiments of the invention, the silica/phosphate combination for a chromium catalyst support is produced by either impregnating a silica xerogel with aluminum phosphate or boron phosphate, precipitating aluminum phosphate in the presence of a silica hydrogel, or physically mixing silica and aluminum phosphate xerogels. The resulting catalysts are capable of producing high melt flow olefin polymers and exhibit high activity. The resulting polymers have many unusual and desirable characteristics, such as high density and good environmental stress crack resistance.
摘要翻译：在本发明的一个实施方案中，铬组分负载在二氧化硅/正磷酸铝组合上并与有机金属助催化剂一起使用。根据本发明的其它实施方案，用于铬催化剂载体的二氧化硅/磷酸盐组合是通过用磷酸铝或磷酸硼浸渍二氧化硅干凝胶，在二氧化硅水凝胶的存在下沉淀磷酸铝，或物理混合二氧化硅和磷酸铝干凝胶。所得催化剂能够生产高熔体流动的烯烃聚合物并表现出高的活性。所得到的聚合物具有许多不寻常和期望的特征，例如高密度和良好的耐环境应力开裂性。

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