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    • 3. 发明申请
    • Polymers Comprising Hydroxyl Groups And Ester Groups And Method For The Production Thereof
    • 包含羟基和酯基的聚合物及其制备方法
    • US20130289206A1
    • 2013-10-31
    • US13977468
    • 2011-12-08
    • Matthias KrullRoman MorschhaeuserHans Juergen ScholzJochen Stock
    • Matthias KrullRoman MorschhaeuserHans Juergen ScholzJochen Stock
    • C08F218/04
    • C08F218/04C08F8/14C08G81/025C08J5/18C08F16/06
    • The invention relates to polymers comprising ester/hydroxyl groups, containing repetitive structural units of formulae (I) and (II) in blocks, alternating, or random sequence wherein D represents a direct bond between the polymer backbone and the hydroxyl group, a C1- to C6-alkylene group, a C5- to C12-arylene group, a oxyalkylene group of formula —O—R2—, an ester group of formula —C(O)—O—R2— or an amide group of formula —C(O)—N(R3)R2—, E represents a hydrocarbon group having 1 to 10 C-atoms, R1 represents hydrogen, a hydrocarbon group having 1 to 50 C-atoms or an acyl group of formula —C(O)—R4, R2 represents a C2- to C10-alkylene group, R3 represents hydrogen or a C1- to C10-alkyl group, which can have substituents, R4 represents a hydrocarbon group having 1 to 50 C-atoms, A represents a C2- to C10-alkylene group, k represents a number between 1 and 100, n represents a number from 0 to 4999, m represents a number from 1 to 5000, n+m for a number from 10 to 5000, under the proviso that a) the molar fraction of the structural units (I) on the polymer is between 0 and 99.9 mol-%, and b) the molar fraction of the structural units (II) on the polymers between 0.1 and 100 mol-% of repetitive units. The invention also relates to a method for the production of said polymers by exposing a polymer reaction mixture containing hydroxyl groups and ether carbon esters to microwaves.
    • 本发明涉及包含酯/羟基的聚合物,其包含以嵌段,交替或无规顺序的式(I)和(II)的重复结构单元,其中D表示聚合物主链和羟基之间的直接键,C1- C 6 - 亚烷基,C 5〜C 12亚芳基,式-O-R 2 - 的氧化烯基,式-C(O)-O-R 2 - 或酰胺基的式 O)-N(R 3)R 2 - ,E表示具有1〜10个碳原子的烃基,R 1表示氢,具有1〜50个碳原子的烃基或式-C(O)-R 4的酰基 ,R 2表示C 2〜C 10亚烷基,R 3表示氢或可具有取代基的C 1至C 10烷基,R 4表示具有1至50个C原子的烃基,A表示C 2至C 10 - 亚烷基,k表示1〜100的数,n表示0〜4999的数,m表示1〜5000的数,n + m的数为10〜5000,条件是 a)聚合物上的结构单元(I)的摩尔分数为0至99.9mol%,b)聚合物上的结构单元(II)的摩尔分数为0.1至100mol%的重复单元 。 本发明还涉及通过将含有羟基和醚碳酯的聚合物反应混合物暴露于微波来生产所述聚合物的方法。
    • 5. 发明授权
    • Method for modifying polymers comprising hydroxyl groups
    • 用于改性包含羟基的聚合物的方法
    • US09243116B2
    • 2016-01-26
    • US13976787
    • 2011-12-08
    • Matthias KrullRoman MorschhaeuserHans Juergen Scholz
    • Matthias KrullRoman MorschhaeuserHans Juergen Scholz
    • C08F2/42C08L29/02C08J3/28C08F8/14C08F8/34
    • C08J3/28C08F8/14C08F8/34C08F2810/20C08F16/06C08F8/00
    • The invention relates to a method for reacting polymers (A) comprising hydroxyl groups and which have repetitive structural units of general formula (I), wherein D represents a direct bond between the polymer backbone and a hydroxyl group, a C1- to C6-alkene group, a C5- to C12-arylene group, an oxyalkylene group of formula —O—R2—, an ester group of formula —C(O)—O—R2— or an amide group of formula —C(O)—N(R8)R2—, R2 represents a C2- to C10-alkene group, R8 represents hydrogen or an optionally substituted C2- to C10-alkyl group and n represents a number between 3 and 5000, with carboxylic acids B1) of formula (II) or carboxylic acid esters B2) of formula (III) R1—COOH (II) R1—COOR7 (III), wherein R1 represents a hydrocarbon group having 2 to 50 C atoms, and R7 represents a C1C4-alkyl group, in which the polymers (A); comprising the hydroxyl groups are exposed to microwaves in the presence of carboxylic acids of formula (II) or carboxylic acid esters of formula (III) and in the presence of water. The reaction mixture is heated to temperatures over 100° C. by microwave rays.
    • 本发明涉及一种使包含羟基并且具有通式(I)的重复结构单元的聚合物(A)的反应方法,其中D表示聚合物主链和羟基之间的直接键,C1-至C6-烯烃 基团,C5至C12亚芳基,式-O-R2-的氧化烯基,式-C(O)-O-R2-的酯基或式-C(O)-N的酰胺基 (R 8)R 2 - ,R 2表示C 2至C 10烯基,R 8表示氢或任选取代的C 2至C 10 - 烷基,n表示3至5000的数,式(II)的羧酸B1) )或式(III)的羧酸酯B2)R1-COOH(II)R1-COOR7(III),其中R1表示具有2-50个碳原子的烃基,R7表示C1C4-烷基,其中 聚合物(A); 在式(II)的羧酸或式(III)的羧酸酯存在下,在水的存在下,将羟基暴露于微波。 通过微波将反应混合物加热至超过100℃。
    • 6. 发明申请
    • Method For Modifying Polymers Comprising Hydroxyl Groups
    • 修饰包含羟基的聚合物的方法
    • US20130296457A1
    • 2013-11-07
    • US13976787
    • 2011-12-08
    • Matthias KrullRoman MorschhaeuserHans Juergen Scholz
    • Matthias KrullRoman MorschhaeuserHans Juergen Scholz
    • C08J3/28
    • C08J3/28C08F8/14C08F8/34C08F2810/20C08F16/06C08F8/00
    • The invention relates to a method for reacting polymers (A) comprising hydroxyl groups and which have repetitive structural units of general formula (I), wherein D represents a direct bond between the polymer backbone and a hydroxyl group, a C1- to C6-alkene group, a C5- to C12-arylene group, an oxyalkylene group of formula —O—R2—, an ester group of formula —C(O)—O—R2— or an amide group of formula —C(O)—N(R8)R2—, R2 represents a C2- to C10-alkene group, R8 represents hydrogen or an optionally substituted C2- to C10-alkyl group and n represents a number between 3 and 5000, with carboxylic acids B1) of formula (II) or carboxylic acid esters B2) of formula (III) R1—COOH (II) R1—COOR7 (III), wherein R1 represents a hydrocarbon group having 2 to 50 C atoms, and R7 represents a C1C4-alkyl group, in which the polymers (A); comprising the hydroxyl groups are exposed to microwaves in the presence of carboxylic acids of formula (II) or carboxylic acid esters of formula (III) and in the presence of water. The reaction mixture is heated to temperatures over 100° C. by microwave rays.
    • 本发明涉及一种使包含羟基并且具有通式(I)的重复结构单元的聚合物(A)的反应方法,其中D表示聚合物主链和羟基之间的直接键,C1-至C6-烯烃 基团,C5至C12亚芳基,式-O-R2-的氧化烯基,式-C(O)-O-R2-的酯基或式-C(O)-N的酰胺基 (R 8)R 2 - ,R 2表示C 2至C 10烯基,R 8表示氢或任选取代的C 2至C 10 - 烷基,n表示3至5000的数,式(II)的羧酸B1) )或式(III)的羧酸酯B2)R1-COOH(II)R1-COOR7(III),其中R1表示具有2-50个碳原子的烃基,R7表示C1C4-烷基,其中 聚合物(A); 在式(II)的羧酸或式(III)的羧酸酯存在下,在水的存在下,将羟基暴露于微波。 通过微波将反应混合物加热至超过100℃。
    • 7. 发明授权
    • Soil-release polymers having a grey-inhibiting effect and having high stability in solution
    • 具有灰色抑制作用并且在溶液中具有高稳定性的剥离聚合物
    • US08871702B2
    • 2014-10-28
    • US13512248
    • 2010-11-24
    • Roman MorschhaeuserBarbara DueckerHans Juergen Scholz
    • Roman MorschhaeuserBarbara DueckerHans Juergen Scholz
    • B08B3/04C08G63/672C08G63/688C11D3/00C11D3/37
    • C08G63/6886C08G63/672C11D3/0036C11D3/3715
    • The invention relates to polyesters, obtainable by means of polymerization of the components including (a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and N is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), in which m is an integer from 1 to 10 and X is hydrogen or an alkali metal ion, and g); optionally one or more crosslinking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.70.
    • 本发明涉及通过组分的聚合可获得的聚酯,所述组分包括(a)一种或多种不含磺基的芳族二羧酸和/或其盐和/或其酸酐和/或其酯,b)任选的一种或多种 含有磺基的二羧酸,其盐和/或其酸酐和/或其酯,c)1,2-丙二醇,d)乙二醇,e)一种或多种式(1)化合物:R 1 O(CHR 2 CHR 3 O) nH(1)其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基,R 2和R 3彼此独立地是氢或具有1至4个碳原子的烷基,以及 N是1至50的整数,f)任选一种或多种式(2)H(OCH 2 CH 2)m -SO 3 X(2)的化合物,其中m是1至10的整数,X是氢或 碱金属离子,和g); 任选地一种或多种交联多官能化合物,条件是存在组分b)或f)中的至少一种,并且进一步提供组分c)1,2-丙二醇与d)乙二醇的摩尔比大于 或等于1.70。
    • 8. 发明申请
    • Colored Polyester
    • 彩色涤纶
    • US20130045912A1
    • 2013-02-21
    • US13637489
    • 2011-03-23
    • Roman MorschhaeuserBarbara DueckerHans Juergen ScholzUwe Bechtold
    • Roman MorschhaeuserBarbara DueckerHans Juergen ScholzUwe Bechtold
    • C11D3/60
    • C11D3/3715C08G63/672C08G63/6886C08K5/0041C11D3/40C08L67/02
    • The invention relates to colored polyester in solid form, characterized in that the colored polyester is obtained by polymerizing components comprising a) one or more aromatic dicarbolic acids having no sulfogroups and/or the salts thereof and/or the anhydrides thereof and/or the esters thereof, b) optionally one or more dicarbolic acids having sulfogroups and/or the salts thereof and/or the anhydrides thereof and/or the esters thereof, c) one or more dioles, d) optionally one or more compounds of the formula (1) R1O(CHR2CHR3O)nH  (1) where R1 is a linear or branched, saturated or unsaturated alkyl group having 1 to 22 C atoms, R2 and R3 are, independent of each other, hydrogen or an alkyl group having 1 to 4 carbon atoms, and n is a number from 1 to 50, e) optionally one or more compounds of the formula (2) H—(OCHR2CHR3)m—SO3X  (2) where R2 and R3 are, independent of each other, hydrogen or an alkyl group having 1 to 4 carbon atoms, and m is a number from 1 to 10, and X is hydrogen or an alkali metal ion, and f) optionally one or more polyfunctional compounds having a crosslinking effect and having 3 to 6 functions enabled for polycondensation, in particular acid, alcohol, or ester functions, under the condition that at least one of the components d) or e) is present, in the presence of g) one or more pigment(s).
    • 本发明涉及固体形式的着色聚酯,其特征在于着色聚酯是通过聚合组分获得的,其组分包括:a)一种或多种不含磺基的芳族二元酸和/或其盐和/或其酸酐和/或酯 b)任选的一种或多种具有磺基团和/或其盐和/或其酸酐和/或其酯的二元酸,c)一种或多种二元醇,d)任选的一种或多种式(1)的化合物 )R1O(CHR2CHR3O)nH(1)其中R1是具有1至22个C原子的直链或支链,饱和或不饱和的烷基,R2和R3彼此独立地为氢或具有1至4个碳原子的烷基 ,和n为1至50的数,e)任选的一种或多种式(2)的化合物,其中R 2和R 3彼此独立地为氢或烷基 具有1至4个碳原子的基团,m为1至10的数,X为 氢或碱金属离子,以及f)任选地一种或多种具有交联效应并且具有3-6个功能的多官能化合物,其能够进行缩聚,特别是酸,醇或酯官能团,条件是至少一种组分 d)或e)存在时,存在g)一种或多种颜料。
    • 9. 发明申请
    • Soil-Release Polymers Having A Grey-Inhibiting Effect And Having High Stability In Solution
    • 具有灰色抑制作用并在溶液中具有高稳定性的土壤释放聚合物
    • US20120309665A1
    • 2012-12-06
    • US13512248
    • 2010-11-24
    • Roman MorschhaeuserBarbara DueckerHans Juergen Scholz
    • Roman MorschhaeuserBarbara DueckerHans Juergen Scholz
    • C08G63/688C11D3/37
    • C08G63/6886C08G63/672C11D3/0036C11D3/3715
    • The invention relates to polyesters, obtainable by means of polymerisation of the components including (a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and N is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), in which m is an integer from 1 to 10 and X is hydrogen or an alkali metal ion, and g); optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.70.
    • 本发明涉及通过组分聚合获得的聚酯,所述组分包括(a)一种或多种不含磺基的芳族二羧酸和/或其盐和/或其酸酐和/或其酯,和b)任选的一种或多种 含有磺基的二羧酸,其盐和/或其酸酐和/或其酯,c)1,2-丙二醇,d)乙二醇,e)一种或多种式(1)化合物R 1 O(CHR 2 CHR 3 O) nH(1)其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基,R 2和R 3彼此独立地是氢或具有1至4个碳原子的烷基,以及 N是1至50的整数,f)任选一种或多种式(2)H(OCH 2 CH 2)m -SO 3 X(2)的化合物,其中m是1至10的整数,X是氢或 碱金属离子,和g); 任选的一种或多种交联多官能化合物,条件是存在组分b)或f)中的至少一种,并且进一步提供组分c)1,2-丙二醇与d)乙二醇的摩尔比为 大于或等于1.70。