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    • 5. 发明申请
    • Thermally conductive adhesive composition and process for device attachment
    • 导热粘合剂组合物和装置连接方法
    • US20060194920A1
    • 2006-08-31
    • US10550408
    • 2004-03-30
    • Miguel CapoteAlan Grieve
    • Miguel CapoteAlan Grieve
    • C08K3/10C08F20/02
    • C09J9/00C08F220/26C08F222/1006C08K3/08C08K5/0025C08L63/00C09J4/00C09J11/04H01L23/3737H01L2924/0002H05K1/0203H05K3/305H05K3/321H05K2201/0215H05K2201/0272H05K2203/0425Y02P70/613C08F220/10H01L2924/00
    • Thermally conductive, sinterable, adhesive compositions, free of fugitive solvents, that include a powder of a relatively high melting point metal or metal alloy, a powder of a relatively low melting point metal or metal alloy powder and a thermally curable adhesive flux composition that comprises (i) a polymerizable fluxing agent; (ii) an inerting agent to react with the fluxing agent at elevated temperature, rendering it inert. The fluxing agent preferably comprises a compound with formula RCOOH, wherein R comprises a moiety having one or more polymerizable carbon-carbon double bonds. Optionally, the inventive compositions also include (a) a diluent that is capable of polymerizing with the fluxing agent's polymerizable carbon-carbon double bonds; (b) free radical initiators; (c) a curable resin; and (d) crosslinking agents and accelerators. The compositions can be applied directly onto the surfaces of devices to be joined mechanically and/or electrically and are ideally suited for semiconductor die attachment. During heating, the fluxing agent promotes wetting of the high melting point powder by the molten low melting point powder, causing liquid phase sintering of the powders. The fluxing agent also promotes wetting of the metallizations on the die and substrate by the molten low melting point alloy, providing improved thermal conductivity. Simultaneously, the fluxing agent itself crosslinks to further mechanically bond the adherent surfaces. The absence of fugitive solvents creates a void-free bond.
    • 包含相对高熔点金属或金属合金的粉末,相对低熔点的金属或金属合金粉末的粉末以及可热固化的粘合剂助焊剂组合物的导热,可烧结,粘合剂组合物,不含挥发性溶剂,其包含 (i)可聚合助熔剂; (ii)惰性剂在升高的温度下与助熔剂反应,使其惰性。 助熔剂优选包含具有式RCOOH的化合物,其中R包含具有一个或多个可聚合碳 - 碳双键的部分。 任选地,本发明的组合物还包括(a)能够与助熔剂的可聚合碳 - 碳双键聚合的稀释剂; (b)自由基引发剂; (c)可固化树脂; 和(d)交联剂和促进剂。 组合物可以直接施加到机械和/或电连接的装置的表面上,并且理想地适用于半导体芯片附接。 在加热过程中,助熔剂通过熔融的低熔点粉末促进高熔点粉末的润湿,引起粉末的液相烧结。 助熔剂还通过熔融的低熔点合金促进模具和衬底上的金属化的润湿,提供改进的导热性。 同时,助熔剂本身交联以进一步机械地结合附着表面。 没有挥发性溶剂会产生无空隙的键。