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    • 5. 发明申请
    • Method of selective region vapor phase aluminizing
    • 选择性区域气相镀铝的方法
    • US20050084706A1
    • 2005-04-21
    • US10685637
    • 2003-10-15
    • Nripendra DasJoseph RigneyJeffrey PfaendtnerMatthew Saylor
    • Nripendra DasJoseph RigneyJeffrey PfaendtnerMatthew Saylor
    • C23C10/02C23C10/06C23C10/14B32B15/10
    • C23C10/06C23C10/02C23C10/14Y02T50/67Y10T428/12736
    • The present invention is process for forming diffusion aluminide coatings on an uncoated surface of a substrate, without interdiffusing a sufficient amount of aluminum into a coating layer to adversely affect the coating growth potential and mechanical properties of said coating layer. A metal substrate is provided comprising an external surface and an internal passage therein defined by an internal surface, at least a portion of the external surface of the substrate being coated with a coating layer selected from the group consisting of β-NiAl-base, MCrAlX, a line-of-sight diffusion aluminide, a non-line-of-sight diffusion aluminide, a pack diffusion aluminide, and a slurry diffusion aluminide on said substrate. The external surface of the substrate is cleaned. The metal substrate is subjected to a aluminum vapor phase deposition process performed using a fluorine-containing activator selected from the group consisting of AlF3, CrF3, NH4F, and combinations thereof, at a rate in the range of about 0.036 mols of fluorine per ft3/hr of transport gas to about 0.18 mols of fluorine per ft3/hr of transport gas, at a temperature in the range of about 1350° F. (730° C.) to about 1925° F. (1050° C.), using a transport gas selected from the group consisting of argon, nitrogen, hydrogen, and combinations thereof, the transport gas being provided at a flow rate in the range of about 20 ft3/hr to about 120 ft3/hr for a period of time in the range of about 2 hours to about 10 hours. The substrate is then cooled. The present invention is also a superalloy article coated with a diffusion aluminide layer using the diffusion aluminide coating process of the present invention.
    • 本发明是在基材的未涂覆表面上形成扩散铝化物涂层的方法,而不会将足够量的铝相互扩散到涂层中,从而不利地影响涂层生长电位和所述涂层的机械性能。 提供了一种金属基底,其包括由内表面限定的外表面和内部通道,所述基底的外表面的至少一部分被涂覆有选自β-NiAl基,MCrAlX ,视线扩散铝化物,非视线扩散铝化物,包层扩散铝化物和在所述衬底上的浆料扩散铝化物。 清洁基板的外表面。 对金属基板进行铝蒸气相沉积工艺,该方法使用选自AlF 3 N 3,CrF 3 N,NH 4的含氟活化剂 F和它们的组合,以约0.036摩尔氟/ ft 3 /小时的运输气体至约0.18摩尔氟/ ft 3的范围内的速率, 在约1350°F(730℃)至约1925°F(1050℃)的温度范围内使用选自以下的输送气体: 氩气,氮气,氢气及其组合,输送气体的流速为约20ft 3 / hr至约120ft 3 / hr 一段时间在约2小时至约10小时的范围内。 然后将衬底冷却。 本发明也是使用本发明的扩散铝化物涂覆方法涂覆有扩散铝化物层的超级合金制品。
    • 6. 发明申请
    • PROCESS OF BRAZING SUPERALLOY COMPONENTS
    • 制动超级组件的过程
    • US20070158398A1
    • 2007-07-12
    • US11306711
    • 2006-01-09
    • David BudingerRonald GalleyNripendra Das
    • David BudingerRonald GalleyNripendra Das
    • B23K35/12B23K1/19B23K20/16
    • B23K1/0018B23K1/19B23K2101/001Y10T428/12493Y10T428/12944
    • A process for brazing components formed of superalloys that contain elements prone to oxidation during brazing. At least one braze tape is applied to at least one faying surface of at least a first of the components being joined by brazing. The braze tape comprises a braze tape alloy containing the base metal of the superalloys and a melting point suppressant, and is applied so as to substantially cover the faying surface. The braze tape is then bonded to the faying surface by heating the first component to a temperature not exceeding the brazing temperature required to join the components. Thereafter, the components are assembled so that the bonded braze tape are between the respective faying surfaces of the components. The components are then brazed together by applying and heating a braze alloy to the braze temperature.
    • 用于钎焊由超级合金形成的组分的方法,该组合含有在钎焊期间易于氧化的元素。 至少一个钎焊带被施加到通过钎焊连接的至少一个部件的至少一个接合表面。 钎焊带包括含有超级合金的贱金属和熔点抑制剂的钎焊合金,并且被施加以基本上覆盖引线表面。 然后通过将第一部件加热到不超过连接部件所需的钎焊温度的温度,将钎焊带粘合到接合表面。 此后,组件被组装成使得接合的钎焊带位于各部件的相应接合表面之间。 然后通过将钎焊合金施加并加热到钎焊温度将组分钎焊在一起。
    • 10. 发明申请
    • BOND COAT PROCESS FOR THERMAL BARRIER COATING
    • US20050058547A1
    • 2005-03-17
    • US10455649
    • 2003-06-05
    • Robert BruceNripendra DasThomas Mantkowski
    • Robert BruceNripendra DasThomas Mantkowski
    • F01D5/28B63H1/26
    • F01D5/288F05D2230/90F05D2300/611Y02T50/67
    • A bond coat process for thermal barrier coatings. The method includes, after cleaning and masking the external surface of the substrate, first applying a layer of NiCrZr alloy to the external surface of the substrate using a sputter coat or other suitable process. Aluminum is then applied to the substrate, using either a vapor phase aluminization (VPA) or chemical vapor deposition (CVD) process, wherein aluminum diffuses into the NiCrZr alloy layer wherein a diffusion layer is formed by the aluminum with the substrate material on the internal surface of the substrate. The coated substrate may then be subjected to a heat treatment in a protective atmosphere to further allow diffusion of the aluminide into the NiAlCrZr diffusion layer. The substantially Al outer layers of the NiAlCrZr diffusion layer, and the diffusion aluminide layer, will provide an aluminum source for the surface, which will oxidize to form a tightly adherent aluminum scale. The diffusion aluminide layer and the high Al portion of the NiAlCrZr diffusion layer will also function as a source of aluminum which will provide a reservoir to heal the alumina scale during operation.
    • 用于热障涂层的粘结涂层工艺。 该方法包括在清洁和掩蔽衬底的外表面之后,首先使用溅射涂层或其它合适的工艺将NiCrZr合金层施加到衬底的外表面上。 然后使用气相镀铝(VPA)或化学气相沉积(CVD)工艺将铝施加到衬底,其中铝扩散到NiCrZr合金层中,其中扩散层由铝形成,衬底材料在内部 基板的表面。 然后可以将涂覆的基底在保护气氛中进行热处理,以进一步允许铝化物扩散到NiAlCrZr扩散层中。 NiAlCrZr扩散层的基本Al外层和扩散铝化物层将为表面提供铝源,其将氧化以形成紧密粘附的铝垢。 NiAlCrZr扩散层的扩散铝化物层和高Al部分也将作为铝源,其将在操作期间提供用于愈合氧化铝垢的储存器。