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1. 发明授权

US6025525A Highly pure monoalkylphosphine and method for producing same 失效
标题翻译：高纯度单烷基膦及其制备方法
公开(公告)号：US6025525A
公开(公告)日：2000-02-15
申请号：US216917
申请日：1998-12-21
申请人： Masashi Sugiya , Tsutomu Watanabe , Natsuhiro Sano
发明人： Masashi Sugiya , Tsutomu Watanabe , Natsuhiro Sano
IPC分类号： C07F9/50 , C07F9/28
CPC分类号： C07F9/5004 , C07F9/5059 , C07F9/5095
摘要： A highly pure monoalkylphosphine which is useful as a starting material for producing a compound semiconductor, and a method for producing same in high yield are provided. The highly pure monoalkylphosphine is represented by the general formula RPH.sub.2 (wherein R is an alkyl group having 1 to 8 carbon atoms), has a purity of not less than 99.999%, and is substantially free of sulfur and silica. In the method of producing said highly pure monoalkylphosphine, anhydrous hydrofluoric acid is used as a catalyst for a reaction between phosphine and an alkene, and the reaction is carried out in the presence of an organic solvent having a boiling point higher than that of the resulting monoalkylphosphine; the resulting reaction mixture is contacted with an alkali solution so that the remaining catalyst is removed into an aqueous phase in the form of a fluoride salt; next, the obtained reaction mixture is contacted with an alkali hydride and the impurities are removed, then distillation is carried out.
摘要翻译：提供了可用作制备化合物半导体的起始材料的高纯度单烷基膦及其高产率制备方法。高纯度单烷基膦由通式RPH 2（其中R是具有1至8个碳原子的烷基）表示，纯度不低于99.999％，并且基本上不含硫和二氧化硅。在制造高纯度单烷基膦的方法中，使用无水氢氟酸作为膦与烯烃反应的催化剂，反应在沸点高于所得到的有机溶剂的存在下进行单烷基膦; 将所得反应混合物与碱溶液接触，使剩余的催化剂以氟化物盐的形式除去到水相中; 接着，将得到的反应混合物与碱金属氢化物接触，除去杂质，然后进行蒸馏。

2. 发明授权

US5892120A Highly pure monoalkylphosphine and method for producing same 失效
标题翻译：高纯度单烷基膦及其制备方法
公开(公告)号：US5892120A
公开(公告)日：1999-04-06
申请号：US977807
申请日：1997-11-25
申请人： Masashi Sugiya , Tsutomu Watanabe , Natsuhiro Sano
发明人： Masashi Sugiya , Tsutomu Watanabe , Natsuhiro Sano
IPC分类号： C07F9/50 , C07F9/52
CPC分类号： C07F9/5004 , C07F9/5059 , C07F9/5095
摘要： A highly pure monoalkylphosphine which is useful as a starting material for producing a compound semiconductor, and a method for producing same in high yield are provided. A highly pure monoalkylphosphine represented by the general formula RPH.sub.2 (wherein R is an alkyl group having 1 to 8 carbon atoms) has a purity of not less than five nines, and is substantially free of sulfur and silica. In the method of producing said highly pure monoalkylphosphine, anhydrous hydrofluoric acid is used as a catalyst for a reaction between phosphine and an alkene, and the reaction is carried out in the presence of an organic solvent having a boiling point higher than that of the resulting monoalkylphosphine; the resulting reaction mixture is contacted with an alkali solution so that the remaining catalyst is removed into an aqueous phase in the form of a fluoride salt; next, the obtained reaction mixture is contacted with an alkali hydride and the impurities are removed, then distillation is carried out.
摘要翻译：提供了可用作制备化合物半导体的起始材料的高纯度单烷基膦及其高产率制备方法。由通式RPH2（其中R是具有1至8个碳原子的烷基）表示的高纯度单烷基膦的纯度不低于5个，并且基本上不含硫和二氧化硅。在制造高纯度单烷基膦的方法中，使用无水氢氟酸作为膦与烯烃反应的催化剂，反应在沸点高于所得到的有机溶剂的存在下进行单烷基膦; 将所得反应混合物与碱溶液接触，使剩余的催化剂以氟化物盐的形式除去到水相中; 接着，将得到的反应混合物与碱金属氢化物接触，除去杂质，然后进行蒸馏。

3. 发明授权

US6080885A Process for preparing a phosphonium salt compound having an acryl group 失效
标题翻译：制备具有丙烯酰基的鏻盐化合物的方法
公开(公告)号：US6080885A
公开(公告)日：2000-06-27
申请号：US153083
申请日：1998-09-15
申请人： Masashi Sugiya , Tsutomu Watanabe
发明人： Masashi Sugiya , Tsutomu Watanabe
IPC分类号： C07F9/54 , C07C69/52 , C07F9/02
CPC分类号： C07F9/5407
摘要： A phosphonium salt compound having an acryl group which is represented by the following general formula (3) can be made in simple operations: ##STR1## (wherein A represents a alkylene group, Y represents Cl, Br or I, R.sup.1 represents H or CH.sub.3, and R.sup.2, R.sup.3 and R.sup.4 represent a alkyl group having 1-8 carbon atoms, cycloalkyl, aryl, alkaryl or aralkyl group) by reacting an unsaturated aliphatic carboxylic acid halide of the following general formula (1):CH.sub.2 .dbd.CR.sup.1 --COX (1)(wherein R.sup.1 represents H or CH.sub.3 and X represents Cl, Br or I) with a hydroxyalkyl phosphonium salt compound of the following general formula (2):[HO--A--P.sup.+ R.sup.2 R.sup.3 R.sup.4 ]Y.sup.- (2)(wherein A, Y, R.sup.2, R.sup.3 and R.sup.4 have the same meanings as defined above). The present invention is industrially advantageous since the product can have a very high purity and be obtained in high yield by an easy operation.
摘要翻译：具有以下通式（3）表示的具有丙烯酰基的鏻盐化合物可以简单地进行：（其中A表示亚烷基，Y表示Cl，Br或I，R1表示H或CH3，R2表示通过使下列通式（1）的不饱和脂族羧酸卤化物：CH2 = CR1-COX（1）（其中，R3和R4表示具有1-8个碳原子的烷基，环烷基，芳基，烷芳基或芳烷基）其中R1表示H或CH3，X表示Cl，Br或I）与下列通式（2）的羟烷基鏻盐化合物：[HO-A-P + R2R3R4] Y-（2）（其中A，Y， R2，R3和R4具有与上述相同的含义）。本发明在工业上是有利的，因为产品可以具有非常高的纯度，并且通过容易的操作可以高产率获得。

4. 发明授权

US5872279A Bis(1,1,3,3-tetramethylbutyl) phosphinic acid compound, a production method thereof and an extracting agent 失效
标题翻译：二（1,1,3,3-四甲基丁基）次膦酸化合物及其制备方法和提取剂
公开(公告)号：US5872279A
公开(公告)日：1999-02-16
申请号：US44237
申请日：1998-03-19
申请人： Masashi Sugiya , Tsutomu Watanabe , Kaoru Takeuchi
发明人： Masashi Sugiya , Tsutomu Watanabe , Kaoru Takeuchi
IPC分类号： C07F9/50 , B01J31/02 , C07F5/02 , C07F9/30 , C07F9/53 , C22B3/06 , C22B3/16 , C22B3/38
CPC分类号： C22B23/0476 , C07F9/301 , C22B3/0066 , C22B3/007 , Y02P10/234
摘要： A bis(1,1,3,3-tetramethylbutyl)phosphinic acid compound represented by the formula (1) and an extracting agent using the same for separating Co from an aged electroless Ni plating solution. A di(1,1,3,3-tetramethylbutyl)phosphine is produced by carrying out a reaction between phosphine and trimethylpentene in the presence of an organic solvent and a catalyst, then said phosphine is reacted with an oxidizing agent or sulfur to obtain the compound (1): ##STR1## (wherein X.sup.1 and X.sup.2 are O or S).
摘要翻译：由式（1）表示的双（1,1,3,3-四甲基丁基）次膦酸化合物和使用它的提取剂用于从老化的化学镀Ni溶液中分离出Co。通过在有机溶剂和催化剂的存在下进行膦与三甲基戊烯之间的反应制备二（1,1,3,3-四甲基丁基）膦，然后使所述膦与氧化剂或硫反应，得到化合物（1）：其中X 1和X 2为O或S。

5. 发明授权

US5679849A Method of producing a bis(2-carboxyethyl)alkyl phosphine oxide and a derivative thereof 失效
标题翻译：双（2-羧乙基）烷基氧化膦及其衍生物的制备方法
公开(公告)号：US5679849A
公开(公告)日：1997-10-21
申请号：US587529
申请日：1996-01-17
申请人： Masashi Sugiya , Tsutomu Watanabe , Kaoru Takeuchi
发明人： Masashi Sugiya , Tsutomu Watanabe , Kaoru Takeuchi
IPC分类号： A01N57/20 , C07F9/53 , C08G63/692 , C09K3/16 , C09K21/12 , C07C55/00
CPC分类号： C08G63/692 , C07F9/5304
摘要： A method of producing a bis(2-carboxyethyl)-alkyl phosphine oxide represented by the following general formula (1) is disclosed. ##STR1## The method comprises the following Steps 1-4: step 1 wherein phosphine is reacted with acrylonitrile to produce bis(2-cyanoethyl)phosphine and then, in step 2, reacted with an alkene to produce a bis(2-cyanoethyl)alkyl phosphine, and in step 3, reacted with an oxidizing agent to produce a bis(2-cyanoethyl)alkyl phosphine oxide, and in step 4, said bis(2-cyanoethyl)alkyl phosphine oxide is reacted with water or a lower alcohol to give a bis(2-carboxyethyl)alkyl phosphine oxide or a derivative thereof.
摘要翻译：公开了由以下通式（1）表示的双（2-羧乙基）烷基氧化膦的制造方法。（1）该方法包括以下步骤1-4：步骤1，其中膦与丙烯腈反应生成双（2-氰基乙基）膦，然后在步骤2中与烯烃反应生成双（2-氰基乙基）膦 - 氰基乙基）烷基膦，在步骤3中，与氧化剂反应生成双（2-氰乙基）烷基氧化膦，在步骤4中，所述双（2-氰基乙基）烷基氧化膦与水或低级醇，得到双（2-羧乙基）烷基氧化膦或其衍生物。

6. 发明授权

US5925784A Bis (1,1,3,3-tetramethylbutyl) phosphinic acid compound, a production method thereof and an extracting agent 失效
标题翻译：二（1,1,3,3-四甲基丁基）次膦酸化合物及其制备方法和提取剂
公开(公告)号：US5925784A
公开(公告)日：1999-07-20
申请号：US607454
申请日：1996-02-27
申请人： Masashi Sugiya , Tsutomu Watanabe , Kaoru Takeuchi
发明人： Masashi Sugiya , Tsutomu Watanabe , Kaoru Takeuchi
IPC分类号： C07F9/50 , B01J31/02 , C07F5/02 , C07F9/30 , C07F9/53 , C22B3/06 , C22B3/16 , C22B3/38 , C01G1/00
CPC分类号： C22B23/0476 , C07F9/301 , C22B3/0066 , C22B3/007 , Y02P10/234
摘要： A bis(1,1,3,3-tetramethylbutyl)phosphinic acid compound represented by the formula (1) and an extracting agent using the same for separating Co from an aged electroless Ni plating solution. A di(1,1,3,3-tetramethylbutyl)phosphine is produced by carrying out a reaction between phosphine and trimethylpentene in the presence of an organic solvent and a catalyst, then said phosphine is reacted with an oxydizing agent or sulfur to obtain the compound (1): ##STR1##
摘要翻译：由式（1）表示的双（1,1,3,3-四甲基丁基）次膦酸化合物和使用它的提取剂用于从老化的化学镀Ni溶液中分离出Co。通过在有机溶剂和催化剂的存在下进行膦和三甲基戊烯之间的反应来制备二（1,1,3,3-四甲基丁基）膦，然后使所述膦与氧化剂或硫反应，得到化合物（1）：

7. 发明授权

US5663419A Bifunctional alkyl phosphine oxide and production method thereof 失效
标题翻译：双官能烷基氧化膦及其制备方法
公开(公告)号：US5663419A
公开(公告)日：1997-09-02
申请号：US628511
申请日：1996-04-05
申请人： Masashi Sugiya , Tsutomu Watanabe , Seiji Shimura
发明人： Masashi Sugiya , Tsutomu Watanabe , Seiji Shimura
IPC分类号： C07F9/50 , C07F9/53 , C08K5/5397
CPC分类号： C08K5/5397 , C07F9/5304
摘要： A bifunctional alkyl phosphine oxide which is represented by the following general formula (1), ##STR1## wherein R.sup.1 represents tert-butyl or 1,1,3,3-tetramethylbutyl, and a production method thereof. This organophosphorus compound is useful a wide variety of fields including a flame retardant, antistatic additive, antibacterial agent, dyeing-improving agent, resin modifier, stain-proofing agent, and rust preventives. This compound can be produced industrially advantageously.
摘要翻译：由下列通式（1）表示的双官能烷基氧化膦及其制备方法，其中R1表示叔丁基或1,1,3,3-四甲基丁基。该有机磷化合物可用于各种领域，包括阻燃剂，抗静电添加剂，抗菌剂，染色改进剂，树脂改性剂，防污剂和防锈剂。该化合物可以在工业上有利地生产。

8. 发明申请

US20130172597A1 METHOD FOR PRODUCING OPTICALLY ACTIVE 1,2-BIS(DIALKYLPHOSPHINO)BENZENE DERIVATIVE 有权
标题翻译：用于生产光学活性的1,2-双（对羟基苯基）苯甲醛衍生物的方法
公开(公告)号：US20130172597A1
公开(公告)日：2013-07-04
申请号：US13808692
申请日：2011-07-03
申请人： Ken Tamura , Masashi Sugiya , Tsuneo Imamoto
发明人： Ken Tamura , Masashi Sugiya , Tsuneo Imamoto
IPC分类号： C07F9/54
CPC分类号： C07F9/5449 , B01J31/2409 , B01J2231/645 , B01J2531/822 , C07B53/00 , C07B2200/07 , C07C67/303 , C07C231/12 , C07C231/18 , C07D207/337 , C07D307/54 , C07F9/5022 , C07F9/5027 , C07F15/0073 , C07C69/34 , C07C233/47
摘要： An industrially advantageous method for producing an optically active 1,2-bis(dialkylphosphino)benzene derivative of the present invention is provided. The method is characterized in that a phosphine-borane compound represented by the following general formula (1) is subjected to a deboronation reaction, followed by lithiation, then the reaction product is subjected to reaction with an alkyldihalogenophosphine represented by RaPX′2, and thereafter the reaction product is subjected to reaction with a Grignard reagent represented by RbMgX″ to produce an optically active 1,2-bis(dialkylphosphino)benzene derivative (A). R1 and R2 respectively represent an alkyl group having 1 to 8 carbon atoms, and the number of carbon atoms is different between R1 and R2. Ra is either R1 or R2 and Rb is the other of R1 and R2. X, X′, and X″ each represent a halogen atom.
摘要翻译：提供了用于制备本发明的光学活性1,2-双（二烷基膦基）苯衍生物的工业上有利的方法。该方法的特征在于将由以下通式（1）表示的膦 - 硼烷化合物进行脱硼反应，然后进行锂化，然后使反应产物与由RaPX'2表示的烷基二卤代膦反应，然后使反应产物与由RbMgX“表示的格氏试剂反应，生成光学活性的1,2-双（二烷基膦基）苯衍生物（A）。 R1和R2分别表示碳原子数1〜8的烷基，R1和R2之间的碳原子数不同。 R a是R 1或R 2，R b是R 1和R 2中的另一个。 X，X'和X“各自表示卤素原子。

9. 发明授权

US08198471B2 2, 2′-bis (dialkylphosphino) biphenyl compound, production method thereof, and metal complex comprising the compound as ligand 失效
标题翻译： 2，二 - 二（二烷基膦基）联苯化合物及其制备方法，以及包含该化合物作为配体的金属络合物
公开(公告)号：US08198471B2
公开(公告)日：2012-06-12
申请号：US12719252
申请日：2010-03-08
申请人： Ken Tamura , Masashi Sugiya , Tsuneo Imamoto
发明人： Ken Tamura , Masashi Sugiya , Tsuneo Imamoto
IPC分类号： C07F15/00 , C07F9/02
CPC分类号： C07F15/008 , B01J31/2409 , B01J2231/645 , B01J2531/822 , C07F9/5027
摘要： A novel phosphine compound capable of forming a metal complex useful as a catalyst for various asymmetric synthesis reactions, a production method thereof, and a metal complex comprising the aforementioned compound as a ligand.
摘要翻译：能够形成可用作各种不对称合成反应的催化剂的金属络合物的新型膦化合物，其制备方法和包含上述化合物作为配体的金属络合物。

10. 发明申请

US20090118442A1 CURING ACCELERATOR FOR DEEP-ULTRAVIOLET-TRANSMITTING EPOXY RESIN, DEEP-ULTRAVIOLET-TRANSMITTING EPOXY RESIN COMPOSITION, AND DEEP-ULTRAVIOLET-TRANSMITTING EPOXY RESIN CURED PRODUCT 审中-公开
标题翻译：用于深层超紫外线发射环氧树脂的固化加速器，深紫外线发射环氧树脂组合物和深紫外线发射环氧树脂固化产物
公开(公告)号：US20090118442A1
公开(公告)日：2009-05-07
申请号：US12297073
申请日：2007-04-13
申请人： Katsuhiko Tsunashima , Masashi Sugiya
发明人： Katsuhiko Tsunashima , Masashi Sugiya
IPC分类号： C08L63/02
CPC分类号： C08G59/688 , C08G59/42 , C08K5/50 , C08K5/521
摘要： An object of the present invention is to provide a deep-ultraviolet-transmitting epoxy resin cured product having high heat resistance and high resistance to deep-ultraviolet light, and to provide a curing accelerator and an epoxy resin composition which are used for producing the epoxy resin cured product. The curing accelerator for deep-ultraviolet-transmitting epoxy resins comprises a tetraalkylphosphonium dialkyl phosphate represented by the following general formula (1): wherein R1, R2, R3, R4, R5, and R6 each represent an alkyl group or an alkyl group having a hydroxyl group, which has 1 to 8 carbon atoms and is linear, branched, or alicyclic; and R1, R2, R3, R4, R5, and R6 may be the same or different. Also disclosed are an epoxy resin composition comprising the curing accelerator and an epoxy resin cured product obtained by curing the resin composition.
摘要翻译：本发明的目的是提供一种具有高耐热性和高耐紫外光能力的深紫外线透过性环氧树脂固化物，并提供用于生产环氧树脂的固化促进剂和环氧树脂组合物树脂固化产品。用于深紫外线透过性环氧树脂的固化促进剂包括由以下通式（1）表示的四烷基鏻二烷基磷酸酯：其中R 1，R 2，R 3，R 4，R 5和R 6各自表示烷基或具有羟基，其具有1至8个碳原子并且是直链，支链或脂环族的; 并且R 1，R 2，R 3，R 4，R 5和R 6可以相同或不同。还公开了包含固化促进剂和通过固化树脂组合物获得的环氧树脂固化产物的环氧树脂组合物。

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