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    • 3. 发明申请
    • Polyimide film, process for preparing the same and controlling isotropy of the same
    • 聚酰亚胺膜,其制备方法及其各向同性的控制
    • US20060138707A1
    • 2006-06-29
    • US11357275
    • 2006-02-17
    • Hidehito NishimuraKazuhiro OnoMasaru NishinakaKiyokazu Akahori
    • Hidehito NishimuraKazuhiro OnoMasaru NishinakaKiyokazu Akahori
    • B29C71/00
    • C08J5/18B29C71/02B29C2071/0027B29K2079/08B29L2007/008C08J2379/08
    • To provide a polyimide film having an original film width of at least 500 mm, whose isotropy in a width direction is improved to have uniform properties, which polyimide film has been apt to cause property difference in the width direction by continuous molding. The polyimide film has an original film width of at least 500 mm and a thickness of at most 50 μm, wherein the maximum value of MOR-c is at most 1.35 and a tensile elastic modulus is at least 5.0 GPa at any part of the film. The polyimide film is prepared by the method which comprises steps of: forming a green sheet containing a volatile component, and heating the green sheet by transferring the same through a furnace with both ends of the green sheet being fixed, wherein at the heating step, the original film has an orientation axis angle θ of a positive value at both ends in the original film width direction, and temperature is lower than the boiling point of a main volatile component in a zone where the original film is transferred for a distance equal to the film width between both fixed ends.
    • 为了提供具有至少500mm的原始膜宽度的聚酰亚胺膜,其在宽度方向上的各向同性被改善以具有均匀的性质,该聚酰亚胺膜已经通过连续成型容易导致宽度方向上的性能差异。 聚酰亚胺薄膜的原始薄膜宽度为至少500mm,厚度最多为50μm,其中MOR-c的最大值为1.35以下,拉伸弹性模量为5.0GPa以上 。 聚酰亚胺膜的制备方法包括以下步骤:形成含有挥发性成分的生片,并通过将生片的两端固定而通过转炉加热生片,其中在加热步骤中, 原始膜在原始膜宽度方向上的两端具有正值的取向轴角度θ,并且温度低于原始膜转移距离等于的区域中的主挥发性成分的沸点 两个固定端之间的胶片宽度。