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1. 发明授权

US06217985B1 Transfer printing film and golf ball marked by the same 有权
标题翻译：转印印刷膜和高尔夫球标记相同
公开(公告)号：US06217985B1
公开(公告)日：2001-04-17
申请号：US09168345
申请日：1998-10-07
申请人： Masaru Hirukawa , Ryuhei Kametani , Susumu Muta , Takashi Ohira
发明人： Masaru Hirukawa , Ryuhei Kametani , Susumu Muta , Takashi Ohira
IPC分类号： B41M526
CPC分类号： B41M3/12 , A63B37/0003 , A63B37/0022 , A63B45/02 , Y10S428/913 , Y10S428/914 , Y10T428/24802 , Y10T428/31511 , Y10T428/31551 , Y10T428/31786
摘要： The invention provides a transfer printing film, an ink layer of which comprises a urethane resin having a predetermined hydroxyl value and a polyester resin and/or an epoxy resin having an another predetermined hydroxyl value, and provides a golf ball marked by the film. The hydroxyl-functional urethane resin and polyester resin and/or epoxy resin in the ink layer react with isocyanate functional resins in the urethane clear top coat of a golf ball to form urethane bondings respectively, whereby the strong adhesion between the urethane clear top coat and the ink layer is realised, and the transferred pattern becomes to be hardly removed from the golf ball surface and to be superior in hitting durability. Furthermore, because not only the urethane resin but also the polyester resin and/or epoxy resin is incorporated in the ink layer, a transfer temperature of the ink layer as a whole becomes low, and thus, in the operation of thermal transfer of the pattern, the heat damage of distortion of dimples, golf ball, and the pattern are respectively decreased as well as the required thermal energy being lowered.
摘要翻译：本发明提供一种转印膜，其油墨层包含具有预定羟值的聚氨酯树脂和具有另一预定羟基值的聚酯树脂和/或环氧树脂，并提供由该膜标记的高尔夫球。油墨层中的羟基官能聚氨酯树脂和聚酯树脂和/或环氧树脂与高分子聚氨酯透明顶层中的异氰酸酯官能树脂反应，分别形成氨基甲酸酯键，从而使氨基甲酸酯清漆面漆与油墨层被实现，并且转印图案几乎不会从高尔夫球表面移除并且具有优异的打击耐久性。此外，由于不仅聚氨酯树脂，而且聚酯树脂和/或环氧树脂被引入到墨水中层，墨层的转印温度整体变低，因此在图案的热转印操作中，热损伤变形的凹坑，高尔夫球和图案分别降低，并且所需的热能降低。

2. 发明授权

US07607993B2 Ink for golf ball, transfer printing film for golf ball and marked golf ball 有权
标题翻译：高尔夫球墨水，高尔夫球转印印花膜和高尔夫球
公开(公告)号：US07607993B2
公开(公告)日：2009-10-27
申请号：US11224290
申请日：2005-09-13
申请人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
发明人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
IPC分类号： A63B37/00
CPC分类号： C08G18/8093 , A63B37/0003 , A63B37/0024 , A63B37/0075 , A63B45/02 , C08L75/04 , C08L75/06 , C09D11/102 , C08L2666/20
摘要： Provided as ink for a golf ball for use in marking a golf ball is ink for a golf ball including an ink resin having a predetermined hydroxyl value and block isocyanate. When marking a golf ball by using the ink of the present invention, a hydroxyl group in the ink resin in an ink layer and an isocyanate group derived from the block isocyanate react with each other to increase hardness of the ink layer, thereby improving abrasion resistance of the marking. In addition, the isocyanate group derived from the block isocyanate and a functional group of an ionomer resin on the ball surface react with each other to improve adhesiveness of marking to the ball surface. Furthermore, the hydroxyl group of the ink resin and an isocyanate group in a urethane top coat layer react with each other to increase strength of the ink layer, thereby improving hitting resistance of the marking. Then, nitrogen in urethane bonding generated by the reaction between the hydroxyl group in the ink layer and the isocyanate group and the isocyanate group in the urethane top coat layer react with each other to further improve abrasion resistance of the marking.
摘要翻译：提供用于标记高尔夫球的高尔夫球的油墨是包括具有预定羟基值的油墨树脂和嵌段异氰酸酯的高尔夫球用油墨。当通过使用本发明的油墨标记高尔夫球时，油墨层中的油墨树脂中的羟基和源自嵌段异氰酸酯的异氰酸酯基彼此反应以增加油墨层的硬度，从而提高耐磨性的标记。此外，衍生自嵌段异氰酸酯的异氰酸酯基团和球形表面上的离聚物树脂的官能团彼此反应以提高标记对球表面的粘附性。此外，油墨树脂中的羟基和聚氨酯顶涂层中的异氰酸酯基彼此反应以提高油墨层的强度，从而提高标记的耐击穿性。然后，通过油墨层中的羟基与异氰酸酯基团之间的反应产生的氨基甲酸酯键和氮氧化物顶涂层中的异氰酸酯基团之间的氮彼此反应，以进一步提高标记的耐磨性。

3. 发明授权

US06554723B1 Golf ball 有权
标题翻译：高尔夫球
公开(公告)号：US06554723B1
公开(公告)日：2003-04-29
申请号：US09168083
申请日：1998-10-08
申请人： Ryuhei Kametani , Susumu Muta , Takashi Ohira
发明人： Ryuhei Kametani , Susumu Muta , Takashi Ohira
IPC分类号： A63B3114
CPC分类号： C09D11/037 , A63B37/0003 , A63B37/0022 , A63B37/0074 , A63B37/14 , A63B45/02
摘要： A golf ball is provided which bears a mark having a distinct metallic lustered appearance, being superior in durability. The mark is printed by using a transfer printing film having an ink layer containing a pigment and metal particles. An ink composition, defining the ink layer, contains 20 to 35 parts by weight of a metal dispersion relative to 1 to 5 parts by weight of a pigment. The metal particle is in a flattened form and a content of the particles in the dispersion is 5 to 15%. An average thickness of the flattened metal particles is 50 to 500 angstroms and an average diameter 10 to 60 microns. Aluminum, chromium, cobalt, steel, silver, gold or nickel alloy are employed as the metal of the particle.
摘要翻译：提供具有不同金属光泽外观的标记的高尔夫球，耐久性优异。通过使用具有含有颜料和金属颗粒的油墨层的转印印刷膜印刷标记。定义油墨层的油墨组合物相对于1至5重量份的颜料含有20至35重量份的金属分散体。金属颗粒呈扁平形状，分散体中的颗粒含量为5〜15％。扁平金属颗粒的平均厚度为50至500埃，平均直径为10至60微米。使用铝，铬，钴，钢，银，金或镍合金作为颗粒的金属。

4. 发明申请

US20060100034A1 Ink for golf ball, transfer printing film for golf ball and marked golf ball 有权
公开(公告)号：US20060100034A1
公开(公告)日：2006-05-11
申请号：US11224290
申请日：2005-09-13
申请人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
发明人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
IPC分类号： A63B37/00
CPC分类号： C08G18/8093 , A63B37/0003 , A63B37/0024 , A63B37/0075 , A63B45/02 , C08L75/04 , C08L75/06 , C09D11/102 , C08L2666/20
摘要： Provided as ink for a golf ball for use in marking a golf ball is ink for a golf ball including an ink resin having a predetermined hydroxyl value and block isocyanate. When marking a golf ball by using the ink of the present invention, a hydroxyl group in the ink resin in an ink layer and an isocyanate group derived from the block isocyanate react with each other to increase hardness of the ink layer, thereby improving abrasion resistance of the marking. In addition, the isocyanate group derived from the block isocyanate and a functional group of an ionomer resin on the ball surface react with each other to improve adhesiveness of marking to the ball surface. Furthermore, the hydroxyl group of the ink resin and an isocyanate group in a urethane top coat layer react with each other to increase strength of the ink layer, thereby improving hitting resistance of the marking. Then, nitrogen in urethane bonding generated by the reaction between the hydroxyl group in the ink layer and the isocyanate group and the isocyanate group in the urethane top coat layer react with each other to further improve abrasion resistance of the marking.

5. 发明授权

US06748867B2 Marked golf ball and method for marking golf ball 有权
标题翻译：标记高尔夫球和高尔夫球标记方法
公开(公告)号：US06748867B2
公开(公告)日：2004-06-15
申请号：US10155984
申请日：2002-05-29
申请人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
发明人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
IPC分类号： A63B3704
CPC分类号： C09D11/03 , A63B37/0003 , A63B37/0022 , A63B45/02 , Y10S101/40
摘要： A golf ball having a mark with a distinct appearance unrealizable by only changing in tint. Ink can be prepared by mixing one or more components which provide luster such as pearl particles, shell particles, mica particles and the like in an ink medium. Therefore, ink can be used for marking the surface of the golf ball by an indirect printing used with a transfer printing film or a direct printing such as a pad printing, a screen printing and the like. The composition of the ink is 5 to 150 parts by weight of the mica, pearl particles and the like. The mica, the pearl particles and the like are employed for flat forms.
摘要翻译：具有不同外观的标记的高尔夫球，只有通过改变色调才能实现。油墨可以通过在油墨介质中混合提供光泽的一种或多种成分（例如珍珠颗粒，壳颗粒，云母颗粒等）来制备。因此，油墨可用于通过与转印印刷膜间接印刷或直接印刷如印刷，丝网印刷等来标记高尔夫球的表面。墨水的组成为云母，珍珠粒子等5〜150重量份。云母，珍珠颗粒等用于平面形式。

6. 发明授权

US06450900B2 Marked golf ball and method for marking a golf ball 失效
标题翻译：标记高尔夫球和标记高尔夫球的方法
公开(公告)号：US06450900B2
公开(公告)日：2002-09-17
申请号：US09310988
申请日：1999-05-12
申请人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
发明人： Ryuhei Kametani , Takashi Ohira , Susumu Muta
IPC分类号： A63B3704
CPC分类号： C09D11/03 , A63B37/0003 , A63B37/0022 , A63B45/02 , Y10S101/40
摘要： A golf ball is provided which bears a mark having a distinct appearance unrealizable by only changing in tint. Ink can be prepared by mixing one or more than two components which can afford luster such as pearl particles, shell particles, mica particles and the like in an ink medium. Thereafter the ink can be used for marking the surface of the golf ball by an indirect printing used with a transfer printing film or a direct printing such as a pad printing, a screen printing and the like. The composition of the ink is 5 to 150 parts by weight of the mica, pearl particles and the like. The mica, the pearl particles and the like are employed for flat forms.
摘要翻译：提供一种高尔夫球，其具有通过仅在色调上变化而具有不可见的不同外观的标记。油墨可以通过在油墨介质中混合一种或多于两种可以提供光泽的组分，如珍珠颗粒，壳颗粒，云母颗粒等来制备。此后，墨水可以用于通过使用转印印刷膜的间接印刷或诸如印刷，丝网印刷等的直接印刷来标记高尔夫球的表面。墨水的组成为云母，珍珠粒子等5〜150重量份。云母，珍珠颗粒等用于平面形式。

7. 发明授权

US6057043A Transfer printing film 失效
标题翻译：转印膜
公开(公告)号：US6057043A
公开(公告)日：2000-05-02
申请号：US56781
申请日：1998-04-08
申请人： Ryuhei Kametani , Masaru Hirukawa
发明人： Ryuhei Kametani , Masaru Hirukawa
IPC分类号： A63B45/00 , A63B45/02 , B41M5/26 , B41M5/30 , B41M5/395
CPC分类号： B41M5/395 , Y10S428/913 , Y10S428/914
摘要： The invention provides a transfer printing film for thermally printing patterns on golf balls. An ink layer disposed on one side of a substrate film contains as a main vehicle a polyamide bearing methoxymethyl group or a vinylchloride-vinylacetate-vinylalcohol copolymer bearing hydroxyl group. Softening point of the polyamide or the copolymer is relatively low, and thus, the pattern formed by the ink layer is transfered at a lower temperature. Both the methoxymethyl group of the polyamide and the hydroxyl group of the copolymer reacts with isocyanate group to form urethane bond, and thus, in the operation of finishing the golf ball with a two-component urethane paint, urethane bondings are formed between the urethane clear top coat and the printed pattern.
摘要翻译：本发明提供了一种用于在高尔夫球上热打印图案的转印印刷膜。设置在基材膜的一侧的油墨层含有带有羟基的聚酰胺担载甲氧基甲基或氯乙烯 - 乙酸乙烯酯 - 乙烯醇共聚物作为主要载体。聚酰胺或共聚物的软化点相对较低，因此在较低温度下转印由油墨层形成的图案。聚酰胺的甲氧基甲基和共聚物的羟基都与异氰酸酯基团反应形成氨基甲酸酯键，因此，在用双组分氨基甲酸酯涂料对高尔夫球进行精加工的操作中，在氨基甲酸酯清漆之间形成氨基甲酸酯键外套和印花图案。

8. 发明授权

US6120394A Marked golf ball and manufacturing process thereof 失效
标题翻译：标记高尔夫球及其制造工艺
公开(公告)号：US6120394A
公开(公告)日：2000-09-19
申请号：US238931
申请日：1999-01-28
申请人： Ryuhei Kametani
发明人： Ryuhei Kametani
IPC分类号： B44C1/17 , A63B37/00 , A63B43/00 , A63B45/02 , B41F17/30 , B41M3/12 , B44C1/175 , A63B37/12 , A63B37/14
CPC分类号： B41M3/12 , A63B37/0003 , A63B45/02 , B44C1/1752 , A63B37/0024 , A63B43/008
摘要： A marked golf ball is provided. The mark on the ball surface contains a holographic portion in a solid color portion of printing ink. The mark is printed on the ball surface by use of a transfer printing film. In a manufacturing process of the printing film, a desired shape is printed in ink on a cover layer, the ink portion is masked by a water-soluble layer, a thin metal layer is deposited all around, and then the water-soluble layer is washed off to remove the metal layer on the water-soluble layer and to leave the metal layer adjacent to the ink portion on the cover layer. The remaining portion of the metal layer turns to be the holographic portion due to a rough boundary between the cover layer. The mark has a novel appearance and makes the golf ball a quality, decorative, distinct and well discriminative value added product.
摘要翻译：提供一个高尔夫球。球表面上的标记包含印刷油墨的纯色部分中的全息部分。通过使用转印印刷膜将标记印刷在球表面上。在印刷膜的制造工序中，将期望的形状印刷在覆盖层上的油墨中，油墨部分被水溶性层掩蔽，薄层金属层全部沉积，然后水溶性层为洗去去除水溶性层上的金属层，并使金属层与覆盖层上的墨水部分相邻。由于覆盖层之间的粗糙边界，金属层的剩余部分变为全息部分。该标记具有新颖的外观，使高尔夫球成为一种质量，装饰性，鲜明的，差异化的增值产品。

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