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1. 发明授权

US5112775A Method of making diamond N-type semiconductor diamond p-n junction diode using diphosphorus pentoxide and hot filament CVD method 失效
标题翻译：使用五氧化二磷和热丝CVD法制造金刚石N型半导体金刚石p-n结二极管的方法
公开(公告)号：US5112775A
公开(公告)日：1992-05-12
申请号：US609792
申请日：1990-11-07
申请人： Masamori Iida , Tateki Kurosu , Ken Okano
发明人： Masamori Iida , Tateki Kurosu , Ken Okano
IPC分类号： C30B29/04 , H01L21/04 , H01L21/205
CPC分类号： H01L29/6603 , H01L21/0237 , H01L21/02527 , H01L21/02576 , H01L21/0262 , Y10S148/122 , Y10S252/95 , Y10S252/951
摘要： A diamond n-type semiconductor including a substrate and a phosphorus element-doped diamond thin film disposed on the substrate. The diamond thin film is deposited by vaporizing a solution comprising a liquid organic compound as the diamond material with diphosphorus pentoxide (P.sub.2 O.sub.5) dissolved therein, and subjecting the resultant gas to a hot filament CVD method.
摘要翻译：金刚石n型半导体，其包括基板和设置在基板上的磷元素掺杂金刚石薄膜。通过将包含液体有机化合物作为金刚石材料的溶液与五氧化二磷（P 2 O 5）溶解在其中，并使所得气体经受热丝CVD法沉积金刚石薄膜。

2. 发明授权

US5223721A Diamond n-type semiconductor diamond p-n junction diode 失效
标题翻译：金刚石n型半导体金刚石p-n结二极管
公开(公告)号：US5223721A
公开(公告)日：1993-06-29
申请号：US832584
申请日：1992-02-07
申请人： Masamori Iida , Tateki Kurosu , Ken Okano
发明人： Masamori Iida , Tateki Kurosu , Ken Okano
IPC分类号： H01L21/04 , H01L21/205
CPC分类号： H01L21/0237 , H01L21/02381 , H01L21/02444 , H01L21/02527 , H01L21/02576 , H01L21/02579 , H01L21/0262 , H01L29/6603
摘要： A diamond n-type semiconductor including a substrate and a phosphorus element-doped diamond thin film disposed on the substrate. The diamond thin film is deposited by vaporizing a solution comprising a liquid organic compound as the diamond material with diphosphorus pentoxide (P.sub.2 O.sub.5) dissolved therein, and subjecting the resultant gas to a hot filament CVD method.
摘要翻译：金刚石n型半导体，其包括基板和设置在基板上的磷元素掺杂金刚石薄膜。通过将包含液体有机化合物作为金刚石材料的溶液与五氧化二磷（P 2 O 5）溶解在其中，并使所得气体经受热丝CVD法沉积金刚石薄膜。

3. 发明授权

US5900127A Electrode for electrolysis and electrolytic cell using the electrode 失效
标题翻译：用于电解的电极和使用该电极的电解槽
公开(公告)号：US5900127A
公开(公告)日：1999-05-04
申请号：US825866
申请日：1997-04-02
申请人： Masamori Iida , Yoshinori Nishiki , Takayuki Shimamune , Setsuro Ogata , Masashi Tanaka , Shuhei Wakita , Shun Takahashi
发明人： Masamori Iida , Yoshinori Nishiki , Takayuki Shimamune , Setsuro Ogata , Masashi Tanaka , Shuhei Wakita , Shun Takahashi
IPC分类号： C02F1/461 , C02F1/72 , C02F1/78 , C25B11/04 , C25B11/00
CPC分类号： C25B11/0478 , C02F1/46109 , C02F1/4618 , C02F1/722 , C02F1/78 , C02F2001/46138 , C02F2001/46161 , C02F2201/4611 , C02F2201/46115 , C02F2201/46195
摘要： An electrode for electrolysis comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. The electrode substance having an electrically conductive diamond structure may be a diamond containing an impurity selected from boron, phosphorus and graphite. Alternatively, the electrode substance having an electrically conductive diamond structure may comprise a composite of a diamond and an electrically conductive material. In a preferred embodiment, the electrode further comprises an interlayer comprising at least one of the carbide of a valve metal and silicon carbide disposed between the electrode base material and the electrode substance having an electrically conductive diamond structure. Also disclosed is an electrolytic cell having two chambers including an anode chamber and a cathode chamber partitioned by an ion-exchange membrane. At least one of the anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. An electrolytic cell having three chambers is also disclosed, including an anode chamber, an intermediate chamber and a cathode chamber partitioned by ion-exchange membranes. At least one of an anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material.
摘要翻译：一种电解用电极，其特征在于，具有电极基材和覆盖所述电极基材表面的导电性金刚石结构的电极物质。具有导电金刚石结构的电极物质可以是含有选自硼，磷和石墨的杂质的金刚石。或者，具有导电金刚石结构的电极物质可以包括金刚石和导电材料的复合物。在优选实施例中，电极还包括中间层，其包括设置在电极基材和具有导电金刚石结构的电极物质之间的阀金属和碳化硅的碳化物中的至少一种。还公开了一种具有两个腔室的电解池，该腔室包括由离子交换膜隔开的阳极室和阴极室。放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材和覆盖电极基材表面的导电金刚石结构的电极物质的电极。还公开了一种具有三个室的电解池，包括由离子交换膜分隔的阳极室，中间室和阴极室。放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材的电极和具有覆盖电极母材表面的导电金刚石结构的电极物质。

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