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1. 发明申请

US20070218370A1 NonAqueous Electrolyte Secondary Battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US20070218370A1
公开(公告)日：2007-09-20
申请号：US11547172
申请日：2005-03-31
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa , Masamichi Onuki , Shinichi Kinoshita
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa , Masamichi Onuki , Shinichi Kinoshita
IPC分类号： H01M6/18
CPC分类号： H01M4/505 , H01M4/131 , H01M4/133 , H01M4/525 , H01M6/168 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/0587 , H01M10/4235 , H01M2004/8689 , H01M2300/0025 , Y02T10/7011
摘要： A non-aqueous electrolyte secondary battery including a positive electrode and a negative electrode each capable of absorbing and desorbing lithium, a separator interposed therebetween, and a non-aqueous electrolyte, wherein the positive electrode includes a positive electrode active material represented by: LiM1-xLxO2 where 0.005≦x≦0.1 is satisfied, M is at least one selected from the group consisting of Mn, Co and Ni, and L is at least one selected from the group consisting of Mg, Al, Ti, Sr, Zn, B, Ca, Cr, Si, Ga, Sn, P, V, Sb, Nb, Ta, Mo, W, Zr, Y and Fe, and the non-aqueous electrolyte includes a phosphinate compound represented by: where R1, R2 and R3 are each independently an aryl group, or an alkyl group, an alkenyl group or an alkynyl group each having 1 to 5 carbon atoms.
摘要翻译：一种非水电解质二次电池，其特征在于，具有能够吸收和解吸锂的正极和负极，隔着隔膜的非水电解质二次电池和非水电解质，其中，所述正极具有由LiM < 其中满足0.005 <= x <= 0.1，其中M是选自Mn，Mn，，Co和Ni，L为选自Mg，Al，Ti，Sr，Zn，B，Ca，Cr，Si，Ga，Sn，P，V，Sb，Nb，Ta，Mo ，W，Zr，Y和Fe，非水电解质包括由以下化合物表示的次膦酸盐化合物：其中R 1，R 2和R 3， SUP>各自独立地为具有1〜5个碳原子的芳基或烷基，烯基或炔基。

2. 发明授权

US07468225B2 Non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US07468225B2
公开(公告)日：2008-12-23
申请号：US11547172
申请日：2005-03-31
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa , Masamichi Onuki , Shinichi Kinoshita
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa , Masamichi Onuki , Shinichi Kinoshita
IPC分类号： H01M6/18
CPC分类号： H01M4/505 , H01M4/131 , H01M4/133 , H01M4/525 , H01M6/168 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/0587 , H01M10/4235 , H01M2004/8689 , H01M2300/0025 , Y02T10/7011
摘要： A non-aqueous electrolyte secondary battery including a positive electrode and a negative electrode each capable of absorbing and desorbing lithium, a separator interposed therebetween, and a non-aqueous electrolyte, wherein the positive electrode includes a positive electrode active material represented by: LiM1-xLxO2 where 0.005≦x≦0.1 is satisfied, M is at least one selected from the group consisting of Mn, Co and Ni, and L is at least one selected from the group consisting of Mg, Al, Ti, Sr, Zn, B, Ca, Cr, Si, Ga, Sn, P, V, Sb, Nb, Ta, Mo, W, Zr, Y and Fe, and the non-aqueous electrolyte includes a phosphinate compound represented by: where R1, R2 and R3 are each independently an aryl group, or an alkyl group, an alkenyl group or an alkynyl group each having 1 to 5 carbon atoms.
摘要翻译：一种非水电解质二次电池，包括能够吸收和解吸锂的正极和负极，隔着隔板的非水电解质二次电池和非水电解质，其中所述正极包括由LiM1- xLxO2，其中满足0.005 <= x <= 0.1，M是选自Mn，Co和Ni中的至少一种，L是选自Mg，Al，Ti，Sr，Zn ，B，Ca，Cr，Si，Ga，Sn，P，V，Sb，Nb，Ta，Mo，W，Zr，Y和Fe，非水电解质包括由下式表示的次膦酸盐化合物：其中R1，R2 和R 3各自独立地为具有1〜5个碳原子的芳基或烷基，烯基或炔基。

3. 发明授权

US08221922B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08221922B2
公开(公告)日：2012-07-17
申请号：US12443799
申请日：2008-04-10
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
IPC分类号： H01M6/16
CPC分类号： H01M2/1646 , H01M2/1653 , H01M4/525 , H01M10/052 , H01M10/0569
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode that contains a transition metal oxide capable of absorbing and desorbing lithium ions; a negative electrode that is capable of absorbing and desorbing lithium ions; a porous film that is interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte, wherein at least one selected from inorganic oxide and polyamide is contained in the porous film, and 5 to 15 vol % of ethylene carbonate is contained in a non-aqueous solvent that is contained in the non-aqueous electrolyte.
摘要翻译：一种非水电解质二次电池，包括：含有能够吸收和解吸锂离子的过渡金属氧化物的正极; 能够吸收和解吸锂离子的负极; 介于正极和负极之间的多孔膜; 和非水电解质，其中在多孔膜中含有选自无机氧化物和聚酰胺中的至少一种，在非水电解质中所含的非水溶剂中含有5〜15体积％的碳酸亚乙酯。

4. 发明授权

US08067119B2 Non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US08067119B2
公开(公告)日：2011-11-29
申请号：US12096262
申请日：2007-05-18
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
IPC分类号： H01M6/04 , H01M6/16
CPC分类号： H01M10/4235 , H01M2/16 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0567
摘要： A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including an active material absorbing and desorbing lithium ions, a negative electrode including an active material absorbing and desorbing lithium ions, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The separator includes a material containing a substituent group with electron-withdrawing property. The non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, and the non-aqueous solvent includes at least one selected from the group consisting of a fluorine-containing aromatic solvent, a fluorine-containing cyclic carbonic acid ester, and a fluorine-containing cyclic carboxylic acid ester.The combination of the foregoing separator and the foregoing non-aqueous electrolyte makes it possible to suppress the deterioration in the rate performance of the battery even when the battery is stored under high voltage and high temperature.
摘要翻译：本发明的非水电解质二次电池包括：包含吸收和解吸锂离子的活性物质的正极，包含吸收和解吸锂离子的活性物质的负极;插入正极和负极之间的隔膜; 和非水电解质。隔膜包括含有具有吸电子性的取代基的材料。非水电解质包含非水溶剂和溶解于其中的溶质，非水溶剂包括选自含氟芳香族溶剂，含氟环状碳酸酯和含氟环状碳酸酯中的至少一种，含氟环状羧酸酯。上述隔膜和上述非水电解液的组合使得即使在高电压和高温下储存电池的情况下也可以抑制电池的速率性能的劣化。

5. 发明申请

US20090130565A1 Non-aqueous electrolyte and electrochemical energy storage device using the same 审中-公开
标题翻译：非水电解质和电化学储能装置使用相同
公开(公告)号：US20090130565A1
公开(公告)日：2009-05-21
申请号：US11919419
申请日：2006-07-13
申请人： Tooru Matsui , Masaki Deguchi , Hiroshi Yoshizawa
发明人： Tooru Matsui , Masaki Deguchi , Hiroshi Yoshizawa
IPC分类号： H01M6/16 , H01G9/022 , H01G9/00 , H01M4/36
CPC分类号： H01G9/038 , H01G11/58 , H01G11/60 , H01G11/62 , H01M6/162 , H01M6/164 , H01M6/168 , H01M10/0566 , H01M10/0567 , H01M10/0569 , H01M2300/0025 , Y02E60/13
摘要： A non-aqueous electrolyte of the present invention contains a lithium salt (A), a quaternary ammonium salt (B) containing a straight chain alkyl group having carbon atoms of 4 or less and a solvent (C) composed of at least one compound selected from the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, γ-butyrolactone, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, dimethoxyethane, ethoxymethoxyethane and diethoxyethane. The molar ratio C/A of the solvent (C) to the lithium salt (A) or the molar ratio C/B of the solvent (C) to the ammonium salt (B) is 6 or less. The non-aqueous electrolyte has a single phase. Consequently, there can be obtained a non-aqueous electrolyte of a high ion concentration having an excellent oxidation resistance and reduction resistance.
摘要翻译：本发明的非水电解质含有锂盐（A），含有碳原子数为4以下的直链烷基的季铵盐（B）和选自由至少一种化合物构成的溶剂（C）由碳酸亚乙酯，碳酸亚丙酯，碳酸亚丁酯，γ-丁内酯，碳酸二甲酯，碳酸甲乙酯，碳酸二乙酯，二甲氧基乙烷，乙氧基甲氧基乙烷，二乙氧基乙烷构成的组。溶剂（C）与锂盐（A）的摩尔比C / A或溶剂（C）与铵盐（B）的摩尔比C / B为6以下。非水电解质具有单相。因此，可以获得具有优异的抗氧化性和耐还原性的高离子浓度的非水电解质。

6. 发明申请

US20090029248A1 Nonaqueous electrolyte and secondary battery containing same 审中-公开
标题翻译：非水电解质和含有相同的二次电池
公开(公告)号：US20090029248A1
公开(公告)日：2009-01-29
申请号：US11665076
申请日：2006-01-17
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
IPC分类号： H01M10/02
CPC分类号： H01M10/052 , H01M10/0567
摘要： Provided is a non-aqueous electrolyte for a secondary battery including a non-aqueous solvent, a solute dissolved in the non-aqueous solvent, and an additive, in which the additive includes an unsaturated chain hydrocarbon compound having two or more carbon-carbon unsaturated bonds and including a main chain having five or more carbon atoms. The unsaturated chain hydrocarbon compound preferable as the additive is 1,3-hexadiene or 2,4-hexadiene. The amount of the unsaturated chain hydrocarbon compound is preferably 0.1 to 10 parts by weight per 100 parts by weight of the non-aqueous solvent.
摘要翻译：本发明提供一种二次电池用非水电解质，其包含非水溶剂，溶解在非水溶剂中的溶质和添加剂，其中，所述添加剂包含具有两个以上碳 - 碳不饱和键的不饱和链烃化合物并且包括具有五个或更多个碳原子的主链。作为添加剂优选的不饱和链烃化合物是1,3-己二烯或2,4-己二烯。不饱和链烃化合物的量相对于100重量份的非水溶剂优选为0.1〜10重量份。

7. 发明授权

US07209342B2 Electric double layer capacitor 失效
标题翻译：双电层电容器
公开(公告)号：US07209342B2
公开(公告)日：2007-04-24
申请号：US11242903
申请日：2005-10-05
申请人： Tooru Matsui , Masaki Deguchi , Hiroshi Yoshizawa
发明人： Tooru Matsui , Masaki Deguchi , Hiroshi Yoshizawa
IPC分类号： H01G9/00
CPC分类号： H01G9/155 , H01G9/038 , H01G11/64 , Y02E60/13
摘要： A phosphazene compound and an ionic liquid are added to a non-aqueous electrolyte to provide a less flammable electric double layer capacitor in which decline in storage characteristics under a high temperature and deterioration under a high charging voltage are suppressed.
摘要翻译：将磷腈化合物和离子液体加入到非水电解质中以提供不易燃的双电层电容器，其中抑制高温下的储存特性的降低和高充电电压下的劣化。

8. 发明授权

US08067120B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08067120B2
公开(公告)日：2011-11-29
申请号：US11689817
申请日：2007-03-22
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
IPC分类号： H01M6/16
CPC分类号： H01M2/16 , H01M4/485 , H01M10/0569
摘要： The non-aqueous electrolyte secondary battery of the present invention includes a positive electrode containing a lithium-containing transition metal oxide as a positive electrode active material, a negative electrode, a separator interposed between the positive electrode and the negative electrode and a non-aqueous electrolyte. The non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, and the non-aqueous solvent includes a solvent having an electron-withdrawing substituent. The solvent having an electron-withdrawing substituent includes at least one selected from the group consisting of a sulfonic solvent, a nitrile solvent, a ketonic solvent, a fluorine-containing solvent, a chlorine-containing solvent and a carboxylic acid ester solvent. The separator includes a material containing an electron-withdrawing substituent or an atom having an unshared electron pair.
摘要翻译：本发明的非水电解质二次电池包括含有含锂过渡金属氧化物作为正极活性物质的正极，负极，夹在正极和负极之间的隔膜和非水电解质二次电池电解液非水电解质包括非水溶剂和溶解于其中的溶质，非水溶剂包括具有吸电子取代基的溶剂。具有吸电子取代基的溶剂包括选自磺酸溶剂，腈溶剂，酮溶剂，含氟溶剂，含氯溶剂和羧酸酯溶剂中的至少一种。分离器包括含有吸电子取代基或具有非共享电子对的原子的材料。

9. 发明申请

US20090246641A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 失效
标题翻译：非水电解质二次电池
公开(公告)号：US20090246641A1
公开(公告)日：2009-10-01
申请号：US12096262
申请日：2007-05-18
申请人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
发明人： Masaki Deguchi , Tooru Matsui , Hiroshi Yoshizawa
IPC分类号： H01M6/16
CPC分类号： H01M10/4235 , H01M2/16 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0567
摘要： A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including an active material absorbing and desorbing lithium ions, a negative electrode including an active material absorbing and desorbing lithium ions, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The separator includes a material containing a substituent group with electron-withdrawing property. The non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, and the non-aqueous solvent includes at least one selected from the group consisting of a fluorine-containing aromatic solvent, a fluorine-containing cyclic carbonic acid ester, and a fluorine-containing cyclic carboxylic acid ester.The combination of the foregoing separator and the foregoing non-aqueous electrolyte makes it possible to suppress the deterioration in the rate performance of the battery even when the battery is stored under high voltage and high temperature.
摘要翻译：本发明的非水电解质二次电池包括：包含吸收和解吸锂离子的活性物质的正极，包含吸收和解吸锂离子的活性物质的负极;插入正极和负极之间的隔膜; 和非水电解质。隔膜包括含有具有吸电子性的取代基的材料。非水电解质包含非水溶剂和溶解于其中的溶质，非水溶剂包括选自含氟芳香族溶剂，含氟环状碳酸酯和含氟环状碳酸酯中的至少一种，含氟环状羧酸酯。上述隔膜和上述非水电解液的组合使得即使在高电压和高温下储存电池的情况下也可以抑制电池的速率性能的劣化。

10. 发明申请

US20090123848A1 Nonaqueous Electrolyte Solution for Electrochemical Energy-Storing Device and Electrochemical Energy-Storing Device Using the Same 审中-公开
标题翻译：用于电化学储能装置和使用其的电化学储能装置的非水电解质溶液
公开(公告)号：US20090123848A1
公开(公告)日：2009-05-14
申请号：US11885590
申请日：2006-01-30
申请人： Tooru Matsui , Masaki Deguchi , Hiroshi Yoshizawa
发明人： Tooru Matsui , Masaki Deguchi , Hiroshi Yoshizawa
IPC分类号： H01M10/40
CPC分类号： H01M10/0568 , H01G11/60 , H01G11/62 , H01M10/052 , Y02E60/13
摘要： A nonaqueous electrolyte solution for electrochemical energy-storing device, comprising (a) a lithium salt, (b) a quaternary ammonium salt containing a quaternary ammonium cation having three or more methyl groups, and (c) a nonaqueous solvent, that allows reliable insertion and extraction of lithium ions into and out of a negative-electrode material having a graphite structure even when the quaternary ammonium salt is dissolved in the nonaqueous electrolyte solution, provides an electrochemical energy-storing device that allows a higher voltage setting in charge and is resistant to capacity deterioration even after repeated charge/discharge cycles.
摘要翻译：一种电化学储能装置用非水电解液，其包含（a）锂盐，（b）含有三个以上甲基的季铵阳离子的季铵盐，和（c）非水溶剂，其允许可靠插入并且即使当季铵盐溶解在非水电解质溶液中时也将锂离子萃取到具有石墨结构的负极材料中和从其中提取，提供了一种电化学储能装置，其允许更高的电压设定并且具有抗性即使在重复的充电/放电循环之后容量劣化。

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