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1. 发明申请

US20120295504A1 CARBON FIBER REINFORCED COMPOSITE MATERIALS 审中-公开
标题翻译：碳纤维增强复合材料
公开(公告)号：US20120295504A1
公开(公告)日：2012-11-22
申请号：US13512716
申请日：2010-11-25
申请人： Masahiko Miyauchi , Takahisa Iwahara , Masato Kusakabe
发明人： Masahiko Miyauchi , Takahisa Iwahara , Masato Kusakabe
IPC分类号： C08K7/06 , C08L23/12 , B32B37/12 , B32B5/02
CPC分类号： C08J5/042 , B29C70/46 , C08J2351/06 , Y10T442/2984
摘要： The invention provides a carbon fiber-reinforced composite material including reinforcing fibers which are continuous carbon fibers in the form of a unidirectional (UD) material, a woven fabric, or a knitted fabric, and a matrix resin including a modified polyolefin resin, thereby achieving better adhesion and mechanical strength. The matrix resin forms a polyphase structure having a sea-island structure which has an average island (independent phase) diameter of not greater than 0.5 μm. The composite material includes as a matrix resin a modified polyolefin resin obtained by, for example, graft-modifying a polyolefin resin with a monomer that contains an ethylenic double bond and a polar group in the same molecule; and includes as reinforcing fibers continuous carbon fibers. For example, the fiber-reinforced composite material is obtained by stacking the modified polyolefin resin and carbon fibers in a mold with a predetermined shape, and impregnating the carbon fibers with the modified polyolefin resin in a molten state under pressure, followed by cooling and curing.
摘要翻译：本发明提供一种碳纤维增强复合材料，其包括作为单向（UD）材料，织造织物或针织物形式的连续碳纤维的增强纤维和包含改性聚烯烃树脂的基质树脂，从而实现更好的附着力和机械强度。基质树脂形成具有平均岛（独立相））不大于0.5μm的海岛结构的多相结构。复合材料包括作为基质树脂的改性聚烯烃树脂，其通过例如在同一分子中用含有烯属双键和极性基团的单体接枝改性聚烯烃树脂而获得; 并且包括作为增强纤维的连续碳纤维。例如，纤维增强复合材料通过将改性聚烯烃树脂和碳纤维堆叠在具有预定形状的模具中，并在压力下在熔融状态下用改性聚烯烃树脂浸渍碳纤维，然后冷却和固化。

2. 发明授权

US10230112B2 Conductive film, current collector using same, battery and bipolar battery 有权
公开(公告)号：US10230112B2
公开(公告)日：2019-03-12
申请号：US14119308
申请日：2012-05-22
申请人： Yusuke Kato , Takashi Ito , Masami Yanagida , Satoshi Oku , Hiroyuki Ogino , Masato Kusakabe , Ryutaro Mukai , Masahiro Kojima , Takashi Kikuchi , Akiko Waki , Shiho Inoue , Shigeo Ibuka , Yasuyuki Tanaka , Yoshio Shimoida , Yuji Muroya , Norihisa Waki
发明人： Yusuke Kato , Takashi Ito , Masami Yanagida , Satoshi Oku , Hiroyuki Ogino , Masato Kusakabe , Ryutaro Mukai , Masahiro Kojima , Takashi Kikuchi , Akiko Waki , Shiho Inoue , Shigeo Ibuka , Yasuyuki Tanaka , Yoshio Shimoida , Yuji Muroya , Norihisa Waki
IPC分类号： H01M4/66 , H01M10/052 , H01M4/02
摘要： A conductive film includes a layer 1 formed by a conductive material 1 that includes a polymer material 1 containing any of (1) an amine and an epoxy resin (where the epoxy resin and the amine are mixed in a ratio of 1.0 or more in terms of the ratio of the number of active hydrogen atoms in the amine with respect to the number of functional groups in the epoxy resin), (2) a phenoxy resin and an epoxy resin, (3) a saturated hydrocarbon polymer having a hydroxyl group, and (4) a curable resin and an elastomer and conductive particles 1. The conductive film has excellent stability in an equilibrium potential environment in a negative electrode and low electric resistance per unit area in the thickness direction. A multilayer conductive film including the conductive film achieves excellent interlayer adhesion, and using them as a current collector enables the production of a battery satisfying both weight reduction and durability.

3. 发明授权

US07893170B2 Curable composition having improved curability and adhesion 有权
标题翻译：可固化组合物具有改进的固化性和粘附性
公开(公告)号：US07893170B2
公开(公告)日：2011-02-22
申请号：US11579551
申请日：2005-04-25
申请人： Masayuki Wakioka , Katsuyu Wakabayashi , Toshihiko Okamoto , Masato Kusakabe
发明人： Masayuki Wakioka , Katsuyu Wakabayashi , Toshihiko Okamoto , Masato Kusakabe
IPC分类号： C08F283/12 , C08G77/16 , C08G77/18 , C08G77/08
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译：提供了通过使用非有机锡催化剂具有良好固化性和粘合性的可固化组合物。可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，（C）含有可水解硅基且分子量为100〜1000的低分子量化合物，其特征在于钛原子，铝原子和锆的总摩尔数（a）的比（a / b）组分（B）的原子与组分（c）的硅原子的总摩尔数（b）大于0.08。

4. 发明授权

US07202310B2 Polymers, processes for producing the same, and curable compositions produced therefrom 失效
标题翻译：聚合物，其制备方法以及由其制备的可固化组合物
公开(公告)号：US07202310B2
公开(公告)日：2007-04-10
申请号：US10763268
申请日：2004-01-26
申请人： Kenichi Kitano , Yoshiki Nakagawa , Masato Kusakabe
发明人： Kenichi Kitano , Yoshiki Nakagawa , Masato Kusakabe
IPC分类号： C08F8/00 , C08F14/00 , C08F14/16 , C08F4/46 , C08F220/10 , C08L83/00 , C08C19/24
CPC分类号： C08F8/42
摘要： An alkenyl- or crosslinkable silyl-terminated vinyl polymer is provided. Such a functional group is introduced into its terminus at a high ratio, not via sulfur atoms. Those polymers can be prepared by polymerizing a vinyl monomer for obtaining a halogen-terminated vinyl polymer, and then substituting an oxy anion or carbanion having such a functional group for the terminal halogen of said polymer.
摘要翻译：提供烯基或可交联甲硅烷基封端的乙烯基聚合物。这种官能团以高比例引入其末端，而不是通过硫原子引入。这些聚合物可以通过聚合乙烯基单体以获得卤素封端的乙烯基聚合物，然后用具有这种官能团的氧阴离子或碳负离子代替所述聚合物的末端卤素来制备。

5. 发明授权

US06274688B1 Functional groups-terminated vinyl polymers 失效
标题翻译：官能团封端的乙烯基聚合物
公开(公告)号：US06274688B1
公开(公告)日：2001-08-14
申请号：US09122896
申请日：1998-07-28
申请人： Yoshiki Nakagawa , Kenichi Kitano , Masato Kusakabe
发明人： Yoshiki Nakagawa , Kenichi Kitano , Masato Kusakabe
IPC分类号： C08F12016
CPC分类号： G01J3/2823 , C08F2/38 , C08F4/00
摘要： A vinyl polymer which has at least one terminal functional group per molecule and has a ratio of weight average molecular weight to number average molecular weight of less than 1.8 as determined by gel permeation chromatography, said terminal functional group being a crosslinking silyl group, an alkenyl group, or a hydroxyl group. Curable compositions containing this vinyl polymer is easy to handle.
摘要翻译：一种乙烯基聚合物，每分子具有至少一个末端官能团，并且通过凝胶渗透色谱法测定的重均分子量与数均分子量之比小于1.8，所述末端官能团是交联甲硅烷基，烯基基团或羟基。含有该乙烯基聚合物的可固化组合物易于处理。

6. 发明申请

US20080269405A1 Single-Component Curable Composition 审中-公开
标题翻译：单组分可固化组合物
公开(公告)号：US20080269405A1
公开(公告)日：2008-10-30
申请号：US11547030
申请日：2005-03-18
申请人： Toshihiko Okamoto , Katsuyu Wakabayashi , Masato Kusakabe
发明人： Toshihiko Okamoto , Katsuyu Wakabayashi , Masato Kusakabe
IPC分类号： C08L83/04
CPC分类号： C08K5/0025 , C08K5/098 , C08K5/544 , C08L71/02
摘要： The present invention has its object to provide a one package curable composition which has good adhesion while containing an organotin-free catalyst.The present invention provides a one package curable composition which comprises (A) an organic polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a carboxylic acid metal salt (b1) and/or a carboxylic acid (b2), (C) a filler, and (D) an amino group-containing silane coupling agent: and has the total amount of carbonyl group composing an acid group in the component (B) per 100 g of the component (A) of 12 mmol or lower; contains substantially no organotin compound; and has the water content of 2,000 ppm or lower.
摘要翻译：本发明的目的是提供一种包含无机锡催化剂的粘合性良好的一包装可固化组合物。本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）羧酸金属盐（b1）和/或羧酸（ b2），（C）填料和（D）含氨基的硅烷偶联剂，并且组合物（B）中的每100克组分（A）中构成酸基的羰基的总量为 12 mmol或更低; 基本上不含有机锡化合物; 水含量为2000ppm以下。

7. 发明授权

US06407146B1 Curable composition 有权
标题翻译：可固化组合物
公开(公告)号：US06407146B1
公开(公告)日：2002-06-18
申请号：US09463623
申请日：2000-04-27
申请人： Masayuki Fujita , Yoshiki Nakagawa , Masato Kusakabe
发明人： Masayuki Fujita , Yoshiki Nakagawa , Masato Kusakabe
IPC分类号： C08F242
CPC分类号： C08L63/00 , C08F8/42 , C08G65/336 , C08L71/02 , C08L2666/04
摘要： A curable composition which comprises the following two components: (I) a vinyl polymer having at least one crosslinkable silyl group represented by the general formula (1) given below, and (II) an epoxy resin or a polyether polymer having at least one crosslinkable silyl group; —[Si(R1)2−b(Y)bO]m—Si(R2)3−a(Y)a (1) {wherein R1 and R2 each represents an alkyl group containing 1 to 20 carbon atoms, an aryl group containing 6 to 20 carbon atoms, an aralkyl group containing 7 to 20 carbon atoms, or a triorganosiloxy group represented by the formula (R′)3SiO— (in which R′ represents a monovalent hydrocarbon group containing 1 to 20 carbon atoms and the three R's may be the same or different) and, when there are two or more R1 or R2 groups, they may be the same or different; Y represents a hydroxy group or a hydrolyzable group and, when there are two or more Y groups, they may be the same or different; a represents 0, 1, 2 or 3; b represents 0, 1 or 2; and m represents an integer of 0 to 19; with the condition that a, b and m satisfy the relation a+mb≧1}.
摘要翻译：一种可固化组合物，其包含以下两种组分：（I）具有由下述通式（1）表示的至少一个可交联甲硅烷基的乙烯基聚合物和（II）具有至少一个可交联的环氧树脂或聚醚聚合物甲硅烷基; {其中R 1和R 2各自表示含有1至20个碳原子的烷基，含有6至20个碳原子的芳基，含有7至20个碳原子的芳烷基或由式（R 3）表示的三有机甲硅烷氧基 '）3SiO-（其中R'表示含有1至20个碳原子的一价烃基，并且三个R可以相同或不同），并且当有两个或更多个R 1或R 2基团时，它们可以相同或不同; Y表示羟基或可水解基团，当存在两个以上Y基时，它们可以相同或不同; a表示0,1,2或3; b表示0,1或2; m表示0〜19的整数。条件是a，b和m满足关系a + mb> = 1}。

8. 发明授权

US06388006B1 Self-adhesive composition 有权
标题翻译：自粘组合物
公开(公告)号：US06388006B1
公开(公告)日：2002-05-14
申请号：US09485119
申请日：2000-05-22
申请人： Masayuki Fujita , Yoshiki Nakagawa , Masato Kusakabe
发明人： Masayuki Fujita , Yoshiki Nakagawa , Masato Kusakabe
IPC分类号： C09J100
CPC分类号： C09J4/00 , C08F8/42 , C08L2666/44 , C09J133/08 , C08F220/00
摘要： A pressure sensitive adhesive composition which comprises the following two components: (A) a vinyl polymer having at least one alkenyl group represented by the general formula (1): CH2═C(R1)— (1) wherein R1 represents a hydrogen atom or a methyl group; (B) a hydrosilyl group-containing compound is provided. The composition can give cured products having a high gel fraction and can be cured rapidly since the degree of alkenyl group introduction is high.
摘要翻译：一种压敏粘合剂组合物，其包含以下两种组分：（A）具有至少一个由通式（1）表示的烯基的乙烯基聚合物：其中R1表示氢原子或甲基;（B）氢化甲硅烷基提供化合物。组合物可以得到具有高凝胶分数的固化产物，并且可以快速固化，因为烯基导入程度高。

9. 发明授权

US5719230A Powder coating comprising novel curable polyester composition 失效
标题翻译：包含新型可固化聚酯组合物的粉末涂料
公开(公告)号：US5719230A
公开(公告)日：1998-02-17
申请号：US547831
申请日：1995-10-25
申请人： Hiroshi Ando , Toshinobu Nakata , Masato Kusakabe , Shigeki Hamaguchi
发明人： Hiroshi Ando , Toshinobu Nakata , Masato Kusakabe , Shigeki Hamaguchi
IPC分类号： C08G77/42 , C08G77/442 , C08G77/445 , C08L83/05 , C09D167/06
CPC分类号： C08G77/445 , C08G77/42 , C08G77/442 , C09D167/06
摘要： The present invention provides a powder coating having an excellent curability which can be baked without evaporation of a blocking agent as compared with the conventional powder coating to provide a coat having an excellent yellowing resistance an improved smoothness and weather resistance. A novel powder coating containing, as a main component, a polyester resin composition is provided, comprising (A) an alkenyl group-containing polyester resin with a number-average molecular weight of from 500 to 100,000 having at least 1.2 alkenyl groups on the average per molecule, (B) a Si--H group-containing curing agent having at least two Si--H groups per molecule, and (C) a catalyst active in hydrosilylation.
摘要翻译：本发明提供了一种具有优异的固化性的粉末涂料，与常规的粉末涂料相比可以在不蒸发封闭剂的情况下进行烘烤，从而提供耐黄变性优异的涂层，其平滑度和耐候性得到改善。提供了以聚酯树脂组合物为主要成分的新型粉末涂料，其包含（A）数均分子量为500〜100,000的含烯基的聚酯树脂，平均具有至少1.2个烯基（B）每分子具有至少两个Si-H基团的含Si-H基的固化剂，（C）在氢化硅烷化中活性较高的催化剂。

10. 发明授权

US07910681B2 Curable composition having improved adhesion 有权
标题翻译：可固化组合物具有改进的粘附性
公开(公告)号：US07910681B2
公开(公告)日：2011-03-22
申请号：US11579587
申请日：2005-04-25
申请人： Masayuki Wakioka , Katsuyu Wakabayashi , Toshihiko Okamoto , Masato Kusakabe
发明人： Masayuki Wakioka , Katsuyu Wakabayashi , Toshihiko Okamoto , Masato Kusakabe
IPC分类号： C08G77/08 , C08G77/46 , C08G77/48 , C08L83/14 , C08F283/06
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good adhesion by using a non-organotin catalyst.The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译：通过使用非有机锡催化剂提供具有良好粘附性的可固化组合物。可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，其特征在于在50％张力下的应力在0.01MPa至0.20MPa的范围内，当通过将1.5份辛酸锡，0.25重量份的月桂胺和0.6重量份的纯水加入并混合到100重量份的组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中，不混合气泡，将混合物在23℃下老化1小时，再在70℃下老化20小时，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min）。

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