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    • 1. 发明授权
    • Oil-resistant thermoplastic elastomer composition and moldings using the same
    • 耐油热塑性弹性体组合物及使用其的模塑制品
    • US06815506B2
    • 2004-11-09
    • US10268789
    • 2002-10-11
    • Masaaki TakashimaKatsutaka YokoiMinoru Tsuneyoshi
    • Masaaki TakashimaKatsutaka YokoiMinoru Tsuneyoshi
    • C08L3304
    • C08L23/16C08L23/00C08L23/0869C08L23/12C08L33/08C08L2207/04Y10T428/139C08L2666/04C08L2666/02
    • A thermoplastic elastomer composition having excellent heat aging characteristics, weather resistance, low-temperature physical properties, oil resistance and flexibility, and moldings using the same, such as hoses, are disclosed. The thermoplastic elastomer composition is obtained by dynamically heat treating a mixture containing (A) an olefin resin, (B) an unsaturated group-containing acrylic rubber, and (D) an inorganic filler in the presence of (E) a crosslinking agent, the component (B) comprising (B1) from 55 to 94.99% by weight of a structural unit derived from an acrylic acid alkyl ester monomer and/or an acrylic acid alkoxyalkyl ester monomer, (B2) from 0.01 to 20% by weight of a structural unit derived from a monomer having a carbon-carbon double bond in a side chain thereof, (B3) from 5 to 30% by weight of a structural unit derived from an unsaturated acrylonitrile monomer, and (B4) from 0 to 30% by weight of a structural unit derived from a monomer copolymerizable therewith, provided that the sum of (B1), (B2), (B3) and (B4) is 100% by weight.
    • 公开了具有优异的热老化特性,耐候性,低温物理性能,耐油性和柔软性的热塑性弹性体组合物和使用该热塑性弹性体组合物的软管。 热塑性弹性体组合物通过在(E)交联剂的存在下动态热处理含有(A)烯烃树脂,(B)不饱和基团的丙烯酸橡胶和(D)无机填料)的混合物, 组分(B),其包含(B1)55至94.99重量%的衍生自丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体的结构单元,(B2)0.01至20重量%的结构 来源于其侧链中具有碳 - 碳双键的单体的单元,(B3)5〜30重量%的衍生自不饱和丙烯腈单体的结构单元,和(B4)0〜30重量% (B1),(B2),(B3)和(B4)之和为100重量%的单体衍生自可与其共聚的单体的结构单元。
    • 3. 发明授权
    • Acrylic rubber, process for its production, and rubber compositions, oil-and weather-resistant rubber compositions, and oil-and weather -resistant rubbers, containing the same
    • 丙烯酸橡胶,其生产方法,橡胶组合物,耐油和耐候橡胶组合物,耐油和耐候的橡胶,含有它们
    • US07550536B2
    • 2009-06-23
    • US10498972
    • 2002-12-25
    • Nobutoshi KobayashiMinoru TsuneyoshiKatsutaka Yokoi
    • Nobutoshi KobayashiMinoru TsuneyoshiKatsutaka Yokoi
    • C08L33/08C08L33/10C08L33/20
    • C08L9/02C08F220/12C08F220/28C08L33/062C08L2666/04
    • The objective of the present invention is to provide an acrylic ester-based copolymer rubber which gives a rubber product excellent in fuel oil resistance and tensile strength and which is crosslinkable with sulfur and/or an organic peroxide and to provide a process for producing the same, as well as a rubber composition, an oil-resistant and weather-resistant rubber composition, and an oil-resistant and weather-resistant rubber product. The acrylic ester-based copolymer rubber of the present invention comprises a structural unit derived from at least one monomer selected from the group consisting of an acrylic acid alkyl ester and an acrylic acid alkoxyalkyl ester in an amount from 40 to 91.9% by mass, a structural unit derived from an unsaturated nitrile monomer in an amount from 8 to 40% by mass, and a structural unit derived from at least one monomer selected from the group consisting of a non-conjugated cyclic polyene and a compound having a specific structure in an amount from 0.1 to 20% by mass (provided 100% by mass of total of these), and has a Mooney viscosity [ML1+4(100° C.)] in the range from 10 to 200.
    • 本发明的目的是提供一种丙烯酸酯基共聚物橡胶,其给出耐燃油性和抗拉强度优异的橡胶产品,并且可与硫和/或有机过氧化物交联并提供其制备方法 ,以及橡胶组合物,耐油和耐候性橡胶组合物,以及耐油和耐候的橡胶制品。 本发明的丙烯酸酯类共聚物橡胶包含衍生自至少一种选自丙烯酸烷基酯和丙烯酸烷氧基烷基酯的单体的结构单元,其量为40〜91.9质量%,a 来自不饱和腈单体的结构单元的量为8〜40质量%,以及来自至少一种单体的结构单元,所述单体选自非共轭环状多烯和具有特定结构的化合物 的量为0.1〜20质量%(其总量为100质量%),门尼粘度[ML1 + 4(100℃)]为10〜200。