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    • 9. 发明授权
    • Dispersions of amorphous urethanized unsaturated polyester resins based on particular dicidol isomers
    • 基于特定的二异构体异构体的无定形氨基甲酸酯化不饱和聚酯树脂的分散体
    • US07135522B2
    • 2006-11-14
    • US10743480
    • 2003-12-23
    • Patrick GloecknerLutz MindachMartina Ortelt
    • Patrick GloecknerLutz MindachMartina Ortelt
    • C08J3/00C08K3/20C08L75/00C08F8/30C08F283/04
    • C08J3/07C08F283/01C08G18/0823C08G18/341C08G18/686C08G63/553C08J2375/00
    • An aqueous dispersion, contains: a) an amorphous urethanized, unsaturated polyester resin, b) a nonvolatile content of from 20% to 60% by weight, c) from 0 to 60% by weight of a solvent, d) a pH of between 5.0 and 9.5, and e) a viscosity at 20° C. of from 20 to 500 mPas. The polyester resin is obtained from I. an alcohol component, II. i) from 20 to 100 mol % of an α,β-unsaturated carboxylic acid component, and ii) from 0 to 80 mol % of a further carboxylic acid component, and III. at least one isocyanate component. The alcohol component contains a dicidol mixture of the isomeric compounds 3,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane, 4,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane and 5,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane. Each isomer is present in a fraction of from 20 to 40% in the dicidol mixture. The sum of the three isomers in the dicidol mixture is from 90 to 100%. The dicidol mixture is present from 10 to 100 mol % in the alcohol component of the polyester.
    • 水分散体包含:a)无定形氨基甲酸酯化不饱和聚酯树脂,b)20%至60%重量的不挥发物含量,c)0至60%重量的溶剂,d) 5.0和9.5,e)20℃下的粘度为20-500mPas。 聚酯树脂是由I.一种醇组分II获得的。 i)20至100摩尔%的α,β-不饱和羧酸组分,和ii)0至80摩尔%的另外的羧酸组分,III。 至少一种异氰酸酯组分。 醇组分含有异构化合物3,8-双(羟甲基)三环[5.2.1.0 2,6]癸烷,4,8-双(羟甲基)三环[5.2.1.0 2,6-二甲基癸烷和5,8-双(羟甲基)三环[5.2.1.0 2,6]癸烷。 每种异构体在二糖混合物中的分数为20至40%。 二酯混合物中三种异构体的总和为90〜100%。 二聚体混合物在聚酯的醇组分中以10至100mol%存在。