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    • 1. 发明授权
    • Electrochemical sensor
    • 电化学传感器
    • US06270639B1
    • 2001-08-07
    • US09239291
    • 1999-01-29
    • Martin LenfersOlaf JachHarald NeumannWalter StrassnerJohann RiegelLothar Diehl
    • Martin LenfersOlaf JachHarald NeumannWalter StrassnerJohann RiegelLothar Diehl
    • G01N27409
    • G01N27/417
    • An electrochemical sensor determining a gas concentration of the measuring gas. The sensor has an electrochemical element including a first solid electrolyte body having an electrochemical pump cell and a first (external pump) and a second (internal pump) electrode and having a gas chamber which is connected to the measuring gas chamber via a gas supply opening and in which the second electrode is arranged. The electrochemical element also includes a second solid electrolyte body having an electrochemical sensor cell (e.g., a Nernst cell) and a third and fourth electrode, each electrode having a lead for the electrical contacting. The leads of the first and second electrodes are decoupled capacitively from the lead of at least the fourth electrode by a device.
    • 确定测量气体的气体浓度的电化学传感器。 传感器具有电化学元件,其包括具有电化学泵电池的第一固体电解质体和第一(外部泵)和第二(内部泵)电极,并且具有通过气体供给开口连接到测量气体室的气体室 并且其中布置有第二电极。 电化学元件还包括具有电化学传感器单元(例如能斯特电池)和第三和第四电极的第二固体电解质体,每个电极具有用于电接触的引线。 第一和第二电极的引线通过器件从至少第四电极的引线电容性地去耦合。
    • 2. 发明授权
    • Measurement sensor for determining an oxygen concentration in a gas mixture
    • 用于测定气体混合物中的氧浓度的测量传感器
    • US06818111B1
    • 2004-11-16
    • US09554041
    • 2000-10-12
    • Martin LenfersWalter StrassnerJohann RiegelLothar Diehl
    • Martin LenfersWalter StrassnerJohann RiegelLothar Diehl
    • G01N27409
    • G01N27/4065
    • A probe is described for determining an oxygen concentration in a gas mixture, in particular in the exhaust gas of internal combustion engines, having a Nernst measuring cell, which has a first electrode (Nernst electrode) which is exposed to the gas mixture to be measured via a diffusion barrier, a second electrode (reference electrode) which is exposed to a reference gas, and a solid electrolyte body arranged between the first and the second electrode, and having a pump cell, which has a first electrode (inner pump electrode) which is exposed to the gas mixture via the diffusion barrier, a second electrode (outer pump electrode) which is exposed to the gas mixture, and a solid electrolyte body arranged between the first and the second electrode. The Nernst electrode and the inner pump electrode are connected at least in some sections via a joint supply conductor to a circuit arrangement for controlling and evaluating the probe. A joint supply conductor resistor of the Nernst electrode and of the inner pump electrode is formed by a loaded voltage divider whose individual resistors are arranged so that the negative feedback of a Nernst voltage circuit and of a pump voltage circuit is optimized, in particular maximized.
    • 描述了一种用于确定气体混合物中的氧浓度的探针,特别是在具有能斯特测量池的内燃机的排气中的氧浓度,该能斯特测量池具有暴露于要测量的气体混合物的第一电极(能斯特电极) 通过扩散阻挡层,暴露于参考气体的第二电极(参考电极)和布置在第一和第二电极之间的固体电解质体,并且具有泵电池,其具有第一电极(内部泵电极) 其经由扩散阻挡层暴露于气体混合物,暴露于气体混合物的第二电极(外部泵电极)和布置在第一和第二电极之间的固体电解质体。 能斯特电极和内泵电极至少在某些部分经由接头供电导体连接到用于控制和评估探针的电路装置。 能斯特电极和内泵电极的联合供电导体电阻器由负载分压器形成,负载分压器的各个电阻器被布置成使得能斯特电压电路和泵浦电压电路的负反馈最优化,特别是最大化。
    • 3. 发明授权
    • Electrochemical sensor element
    • 电化学传感元件
    • US06811664B2
    • 2004-11-02
    • US10016787
    • 2001-10-26
    • Martin LenfersHarry BraunWalter StrassnerLothar Diehl
    • Martin LenfersHarry BraunWalter StrassnerLothar Diehl
    • G01N2741
    • G01N27/419
    • A sensor element for determining the concentration of a gas component in a gas mixture, particularly for determining the oxygen concentration in exhaust gases of internal combustion engines. The sensor element includes at least one pump cell, which has at least one first pump electrode located in a measuring gas chamber and at least one second pump electrode, located on a surface of the sensor element facing the gas mixture, as well as at least one concentration cell, which has at least one reference electrode located in a reference gas chamber and at least one measuring electrode, located in the measuring gas chamber, which cooperates with the reference electrode. The measuring gas chamber and the reference gas chamber are essentially located in the same layer level (plane) of the sensor element which has a layered construction. At least one barrier layer is provided which, at least to a large extent, prevents ionic conduction between at least one electrode of the pump cell and at least one electrode of the concentration cell.
    • 一种传感器元件,用于确定气体混合物中气体组分的浓度,特别是用于确定内燃机废气中的氧气浓度。 传感器元件包括至少一个泵电池,其具有位于测量气室中的至少一个第一泵电极和位于传感器元件面向气体混合物的表面上的至少一个第二泵电极,以及至少 一个浓度单元,其具有位于参考气室中的至少一个参考电极和位于测量气室中的与参考电极配合的至少一个测量电极。 测量气室和参考气室基本上位于具有分层结构的传感器元件的相同层级(平面)中。 提供至少一个阻挡层,其至少在很大程度上防止泵浦电池的至少一个电极和浓缩电池的至少一个电极之间的离子传导。
    • 4. 发明授权
    • Control and analysis circuit device for measuring reaction heat
    • 用于测量反应热的控制和分析电路装置
    • US5360266A
    • 1994-11-01
    • US79617
    • 1993-06-18
    • Martin LenfersJohann Riegel
    • Martin LenfersJohann Riegel
    • G01N25/30G01N27/16G01N27/18G01N25/22G01N27/12
    • G01N27/16
    • The reaction heat sensor and control and analysis devices for measuring the concentration of reactive species in a medium includes a temperature dependent measuring resistor and a reference resistor connected in series. Both resistors, which are supplied with a constant alternating current by a constant current generator, are heated with a heating resistor. By analysis of the voltage drop at the reference resistor the heating resistor is regulated so that the temperature of the reference resistor and thus its reference resistance is kept constant. Thus it is guaranteed by control circuitry that the temperature of the measuring resistance is kept constant when no heat is generated by reaction on exposure to the medium. If a reaction occurs at the measuring resistor, the temperature of the measuring resistance changes and with it the voltage drop across the measuring resistor, which is analyzed and is a direct measure of the heat produced by the reaction.
    • 用于测量介质中反应物种浓度的反应热传感器和控制和分析装置包括温度依赖测量电阻器和串联连接的参考电阻器。 通过恒定电流发生器供给恒定交流电流的两个电阻都用加热电阻加热。 通过分析参考电阻器的电压降,加热电阻器被调节,使得参考电阻器的温度和因此其参考电阻保持恒定。 因此,控制电路保证测量电阻的温度在通过暴露于介质时反应产生热量时保持恒定。 如果测量电阻器发生反应,则测量电阻的温度会随测量电阻器的电压下降而变化,并进行分析,并直接测量反应产生的热量。
    • 5. 发明授权
    • Method of controlling a sensor for determining an oxygen concentration in a gas mixture
    • 控制用于测定气体混合物中的氧浓度的传感器的方法
    • US06301951B1
    • 2001-10-16
    • US09382516
    • 1999-08-25
    • Martin LenfersLothar DiehlJürgen Schwarz
    • Martin LenfersLothar DiehlJürgen Schwarz
    • G01N27419
    • G01N27/417
    • In a method of controlling a sensor for determining an oxygen concentration in a gas mixture, in particular in the exhaust gas of internal combustion engines, a detection voltage supplied by a Nernst measurement cell and corresponding to the oxygen concentration is transformed by a circuit arrangement into a pump voltage for a pump cell, and an anodic or cathodic limit current flows over the pump cell, depending on the oxygen content of the gas mixture. In stable operation of the sensor, during which an anodic limit current flows for a selectable period of time, the pump cell and/or the Nernst measurement cell receives at least one voltage pulse supplied independently by the measured detection voltage or the pump current thus established, so that the sensor is depolarized.
    • 在控制用于确定气体混合物中的氧气浓度的传感器的方法中,特别是在内燃机的废气中,由能斯特测量单元提供并对应于氧气浓度的检测电压由电路装置转换成 根据气体混合物的氧含量,泵电池的泵电压和阳极或阴极极限电流流过泵电池。 在传感器的稳定运行期间,阳极极限电流在其中流动可选择的时间段,泵电池和/或能斯特测量单元接收由测量的检测电压或所建立的泵浦电流独立提供的至少一个电压脉冲 ,使传感器去极化。