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1. 发明申请

US20050118433A1 Method for the production of protective layers with dirt and water repelling properties 审中-公开
标题翻译：用于生产具有污垢和防水性能的保护层的方法
公开(公告)号：US20050118433A1
公开(公告)日：2005-06-02
申请号：US10502804
申请日：2003-02-05
申请人： Markus Oles , Edwin Nun , Michael Droscher
发明人： Markus Oles , Edwin Nun , Michael Droscher
IPC分类号： B05D5/00 , B05D5/06 , B05D5/08 , B08B17/06 , C03C17/06 , C03C17/22 , C03C17/23 , C03C17/32 , C09D1/00 , C09D1/04 , C09D5/00 , C09D5/03 , C09D201/00 , B32B9/00 , B05D1/12 , B05D3/02 , B32B5/16
CPC分类号： C09D5/008 , B05D5/08 , B08B17/06 , B08B17/065 , C09D5/00 , Y10T428/25 , Y10T428/26 , Y10T428/31612 , Y10T428/31663
摘要： The present invention describes a process by which a coating which has dirt- and water-repellant properties can be applied non-permanently to any article. It is usual nowadays for articles to be provided with self-cleaning properties by generating, on the surface of the article, a surface structure made from elevations and depressions which have to have a certain height and a certain separation. This is usually achieved by impressing such structures, or by securing structure-forming particles by means of a carrier system. In this way the surfaces are provided with a permanent self-cleaning surface. If scratching, discoloration, or some other type of damage causes impairment of the surface or surface structure, this cannot be simply removed and reapplied, but instead the article then has to be retreated, freed from the surface structure by a complicated method, or disposed of. In contrast, the inventive coating can be removed again from the articles by relatively simple mechanical means. The inventive coating is also simple to produce, by applying a suspension of an alcohol and structure-imparting particles to the article.
摘要翻译：本发明描述了一种具有防污和防水性能的涂层可以永久地施加到任何物品的方法。现在通常在制品的表面上产生必须具有一定高度和一定分离的由高低凹部形成的表面结构，现在通常产生制品的自洁性。这通常通过施加这样的结构来实现，或通过借助于载体系统固定结构形成颗粒来实现。以这种方式，表面设置有永久的自洁表面。如果刮伤，变色或某种其他类型的损坏会导致表面或表面结构的损坏，则不能简单地去除和重新施加，而是必须通过复杂的方法将物品退回到表面结构中，或者处理的。相比之下，本发明的涂层可以通过相对简单的机械装置再次从制品中去除。通过将醇和结构赋予颗粒的悬浮液施用于制品，本发明的涂层也易于制备。

2. 发明申请

US20060127643A1 Light-scattering materials which have self-cleaning sufraces 审中-公开
$Light-scattering materials which have self-cleaning sufraces$
标题翻译：具有自洁性的光散射材料
公开(公告)号：US20060127643A1
公开(公告)日：2006-06-15
申请号：US11346427
申请日：2006-02-03
申请人： Edwin Nun , Markus Oles
发明人： Edwin Nun , Markus Oles
IPC分类号： E01F9/04 , B05D7/00
CPC分类号： C03C17/007 , C03C2217/42 , C08J7/047 , Y10T428/24355 , Y10T428/24372
摘要： A light-scattering material includes a coating with self-cleaning properties on a transparent substrate. Particles randomly distributed in and on the coating roughen the coating and provide a surface structure that scatters light. The light-scattering material is useful in providing indirect illumination, particularly using daylight. The coating can have antimicrobial properties. The light-scattering material can require significantly less maintenance than conventional light-scattering materials.
摘要翻译：光散射材料包括在透明基底上具有自清洁性能的涂层。随机分布在涂层中和涂层上的颗粒粗糙化涂层，并提供散射光的表面结构。光散射材料可用于提供间接照明，特别是使用日光。涂层可具有抗菌性能。光散射材料可能需要比传统的光散射材料少得多的维护。

3. 发明申请

US20060049376A1 Production of suspensions of hydrophobic oxide particles 失效
标题翻译：生产疏水性氧化物颗粒的悬浮液
公开(公告)号：US20060049376A1
公开(公告)日：2006-03-09
申请号：US10527641
申请日：2003-09-26
申请人： Edwin Nun , Markus Oles , Frank Menzel
发明人： Edwin Nun , Markus Oles , Frank Menzel
IPC分类号： D06M11/00 , B01F3/12 , B32B9/04
CPC分类号： C09C3/12 , B08B17/065 , B82Y30/00 , C01P2004/54 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/11 , C01P2006/19 , C01P2006/22 , C09C1/3081 , C09D7/61 , C09D17/007 , C09K3/18 , D06M11/45 , D06M11/46 , D06M11/79 , D06M23/10 , D06M2200/12 , Y10T428/31663
摘要： Disclosed are a process for producing a suspension of hydrophobic oxidic particles which has a defined, adjustable viscosity, which comprises suspending low structured hydrophobic oxidic particles in at least one organic suspension agent and then adding from 0.05% to 15% by weight based on the suspension medium of high structured hydrophobic oxidic particles, a suspension of hydrophobic oxidic particles which has a defined, adjustable viscosity and the use thereof for producing soil and water repellent coatings on articles.
摘要翻译：公开了一种制备具有确定的可调节粘度的疏水性氧化物颗粒的悬浮液的方法，其包括将低结构化疏水性氧化物颗粒悬浮在至少一种有机悬浮剂中，然后基于悬浮液添加0.05至15重量％高结构疏水性氧化物颗粒的介质，疏水性氧化物颗粒的悬浮液，其具有确定的可调节的粘度，以及其用于在制品上产生防水和防水涂料的用途。

4. 发明申请

US20050253302A1 Release agents comprising hydrophobic, nanoscalar particles, and the use of these mold release agents 失效
标题翻译：脱模剂包括疏水性纳米级颗粒，以及使用这些脱模剂
公开(公告)号：US20050253302A1
公开(公告)日：2005-11-17
申请号：US10506995
申请日：2003-02-03
申请人： Edwin Nun , Markus Oles
发明人： Edwin Nun , Markus Oles
IPC分类号： B08B17/06 , B29C33/60 , B29C37/00 , B29C45/14 , B60C11/00 , B60C13/00 , C08L1/00
CPC分类号： B29C33/60 , B08B17/06 , B08B17/065 , B29C37/0032 , B29C37/0067 , B29C45/14778 , B60C1/00
摘要： The invention relates to mold-release agents, in particular mold-release agents which can be used for demolding moldings from molding tools, and also to the use of these mold-release agents. The mold-release agents of the invention, which are preferably based on suspensions of nanostructured microparticles, have the advantage of being markedly more environmentally compatible than the known mold-release agents based on organic or organosilicon compounds, since they can remain on the surfaces of the moldings. The use of the mold-release agents of the invention is very simple, since advantage can be taken of existing equipment. An example of a usual method is to produce injection moldings by means of injection molds into which the material is injected. The mold-release agent of the invention is applied, e.g. by spray-application, to the injection mold prior to the actual injection-molding process. Depending on the setting of the molding parameters, the microparticles are impressed into the surfaces of the moldings and anchored, and therefore another favorable effect is that the surfaces of the injection molding can have self-cleaning properties.
摘要翻译：本发明涉及脱模剂，特别是脱模剂，其可用于从成形工具脱模模制品，以及这些脱模剂的使用。本发明的脱模剂优选基于纳米结构微粒的悬浮液，具有比已知的基于有机或有机硅化合物的脱模剂显着更环境相容的优点，因为它们可以保留在模具。使用本发明的脱模剂非常简单，因为可以利用现有的设备。通常的方法的一个例子是通过注射模具来生产注射模制品，注射模具注入材料。本发明的脱模剂，例如，通过喷雾施加到注射模具之前，在实际的注射成型过程之前。根据成型参数的设定，将微粒压入模制品的表面并锚固，因此另外一个有利的效果是注模的表面可以具有自清洁性。

5. 发明授权

US07846529B2 Self-cleaning surfaces comprising elevations formed by hydrophobic particles and having improved mechanical strength 有权
标题翻译：自清洁表面包括由疏水性颗粒形成的凸起并具有改善的机械强度
公开(公告)号：US07846529B2
公开(公告)日：2010-12-07
申请号：US11312469
申请日：2005-12-21
申请人： Edwin Nun , Markus Oles
发明人： Edwin Nun , Markus Oles
IPC分类号： G11B5/64
CPC分类号： B08B17/06 , B05D5/08 , B08B17/065 , C08K3/22 , C08K3/36 , C08L91/06 , C09D5/00 , C09D7/40 , C09D7/61 , C09D7/65 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , Y10T156/1092 , Y10T428/24355 , Y10T428/24372
摘要： The present invention relates to self-cleaning surfaces having improved mechanical stability and a process for the production thereof. The present invention is achieved by producing self-cleaning, hydrophobic, structured surfaces having mixtures of particles, which are fixed on their surface and which comprise structure-producing particles selected from semimetal or metal oxides, silicas and metal powders, and wax particles. Structured surfaces that are structured by such mixtures of particles are distinguished by substantially higher mechanical stability of the structure and are therefore especially suitable for the production of self-cleaning surfaces, which are exposed to relatively high mechanical loads, such as, for example, the surfaces of tarpaulins, awnings, greenhouse elements, conservatories or truck tarpaulins.
摘要翻译：本发明涉及具有改善的机械稳定性的自清洁表面及其生产方法。本发明通过制备具有固定在其表面上并且包含选自半金属或金属氧化物的结构产生颗粒，二氧化硅和金属粉末以及蜡颗粒的颗粒混合物的自清洁疏水结构表面来实现。由这种颗粒混合物构成的结构化表面的特征在于该结构的机械稳定性明显更高，因此特别适用于生产暴露于较高机械载荷的自清洁表面，例如，篷布，遮阳篷，温室元素，温室或卡车篷布的表面。

6. 发明授权

US07211313B2 Surfaces rendered self-cleaning by hydrophobic structures and a process for their production 失效
标题翻译：表面通过疏水结构进行自清洁和其生产过程
公开(公告)号：US07211313B2
公开(公告)日：2007-05-01
申请号：US10137445
申请日：2002-05-03
申请人： Edwin Nun , Markus Oles , Bernhard Schleich
发明人： Edwin Nun , Markus Oles , Bernhard Schleich
IPC分类号： D06N7/04 , C08K9/04
CPC分类号： C09D5/00 , B05D5/08 , B05D7/02 , B05D2601/20 , B08B17/00 , B08B17/02 , B08B17/06 , B08B17/065 , Y10T428/24372 , Y10T428/2438 , Y10T428/24388 , Y10T428/24405 , Y10T428/25
摘要： A self-regenerating, self-cleaning hydrophobic surface is formed when particles are secured on a carrier that is itself a mixture of particles and binder. When particles on the surface are ablated by erosion, new particles in the carrier are exposed to regenerate the self-cleaning surface, resulting in a long-lasting self-cleaning action. The self-cleaning surface may be used with particular advantage outdoors, e.g. on vehicles, where self-cleaning materials are particularly exposed to the effects of the environment.
摘要翻译：当颗粒固定在本身是颗粒和粘合剂的混合物的载体上时，形成自再生的自清洁疏水表面。当表面上的颗粒被侵蚀消融时，载体中的新颗粒被暴露以再生自清洁表面，导致持久的自清洁作用。自清洁表面可以在室外特别有用。在自洁材料特别暴露于环境影响的车辆上。

7. 发明申请

US20060147675A1 Self-cleaning surfaces comprising elevations formed by hydrophobic particles and having improved mechanical strength 有权
标题翻译：自清洁表面包括由疏水性颗粒形成的凸起并具有改善的机械强度
公开(公告)号：US20060147675A1
公开(公告)日：2006-07-06
申请号：US11312469
申请日：2005-12-21
申请人： Edwin Nun , Markus Oles
发明人： Edwin Nun , Markus Oles
IPC分类号： G11B5/64
CPC分类号： B08B17/06 , B05D5/08 , B08B17/065 , C08K3/22 , C08K3/36 , C08L91/06 , C09D5/00 , C09D7/40 , C09D7/61 , C09D7/65 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , Y10T156/1092 , Y10T428/24355 , Y10T428/24372
摘要： The present invention relates to self-cleaning surfaces having improved mechanical stability and a process for the production thereof. The present invention is achieved by producing self-cleaning, hydrophobic, structured surfaces having mixtures of particles, which are fixed on their surface and which comprise structure-producing particles selected from semimetal or metal oxides, silicas and metal powders, and wax particles. Structured surfaces that are structured by such mixtures of particles are distinguished by substantially higher mechanical stability of the structure and are therefore especially suitable for the production of self-cleaning surfaces, which are exposed to relatively high mechanical loads, such as, for example, the surfaces of tarpaulins, awnings, greenhouse elements, conservatories or truck tarpaulins.
摘要翻译：本发明涉及具有改善的机械稳定性的自清洁表面及其生产方法。本发明通过制备具有固定在其表面上并且包含选自半金属或金属氧化物，二氧化硅和金属粉末以及蜡颗粒的结构产生颗粒的颗粒混合物的自清洁，疏水的结构化表面来实现。由这种颗粒混合物构成的结构化表面的特征在于该结构的机械稳定性明显更高，因此特别适用于生产暴露于较高机械载荷的自清洁表面，例如，篷布，遮阳篷，温室元素，温室或卡车篷布的表面。

8. 发明申请

US20050208269A1 Sheet extrudates with self-cleaning properties, and method for producing these extrudates of this type 审中-公开
标题翻译：具有自清洁性能的片材挤出物以及用于生产这种挤出物的方法
公开(公告)号：US20050208269A1
公开(公告)日：2005-09-22
申请号：US10506994
申请日：2003-02-05
申请人： Edwin Nun , Markus Oles , Bernhard Schleich , Gernot Dambacher
发明人： Edwin Nun , Markus Oles , Bernhard Schleich , Gernot Dambacher
IPC分类号： B08B17/06 , B29C70/64 , B32B1/00
CPC分类号： B29C70/64 , B08B17/06 , B08B17/065 , B29C2059/023 , B29C2059/028 , Y10T428/24372
摘要： The invention relates to sheet extrudates with surfaces which have self-cleaning properties, and also to a simple process for producing these self-cleaning surfaces. The process of the invention is very simple, since it can make use of existing equipment. Sheet extrudates are usually smoothed by means of rolls. The process of the invention makes use of these rolls by applying microparticles to these rolls. The particles are impressed into the surface of the extrudate and thus transferred thereto during smoothing of the extrudates. The process of the invention provides access to self-cleaning surfaces which comprise particles with a fissured structure, without any need to apply an additional emboss layer or a foreign-material carrier layer to the moldings. Extrudates of the invention may have the shape of a film or sheet, for example.
摘要翻译：本发明涉及具有自清洁性能的表面的片材挤出物，以及用于生产这些自清洁表面的简单方法。本发明的方法非常简单，因为它可以利用现有设备。片材挤出物通常通过辊平滑。本发明的方法通过将微粒施加到这些辊上来利用这些辊。将颗粒压入挤出物的表面，并因此在挤出物平滑期间转移到挤出物的表面。本发明的方法提供进入包含具有裂缝结构的颗粒的自清洁表面，而不需要向模制品施加额外的压花层或异物载体层。本发明的挤出物可以具有例如膜或片的形状。

9. 发明申请

US20050112326A1 Shaping method for producing shaped bodies with at least one surface that has self-cleaning properties, and shaped bodies produced according to this method 审中-公开
标题翻译：用于制造具有至少一个具有自清洁性能的表面的成形体的成形方法，以及根据该方法制造的成形体
公开(公告)号：US20050112326A1
公开(公告)日：2005-05-26
申请号：US10506993
申请日：2003-02-03
申请人： Edwin Nun , Markus Oles , Arne Lang
发明人： Edwin Nun , Markus Oles , Arne Lang
IPC分类号： B08B17/02 , B08B17/06 , B29C49/20 , B29C51/12 , B29C70/64 , B29K105/16 , B65D1/00 , B32B1/00
CPC分类号： B29C70/64 , B08B17/06 , B08B17/065 , B29C2059/023 , B29C2059/028 , Y10T428/24372
摘要： The invention relates to shaping processes for producing moldings with at least one surface which has self-cleaning properties and has elevations formed by microparticles, by thermal shaping of materials comprising organic compounds by means of a mold, and also to the resultant moldings. The process of the invention generates surfaces with self-cleaning properties by, prior to the thermal shaping, applying microparticles to the inner surfaces of the mold and then carrying out the molding process, in which the microparticles are pressed into and anchored into the surface of the molding, where this surface has not yet solidified. The process of the invention may be used in thermal shaping processes selected from blow molding, extrusion blow molding, extrusion stretch blow molding, injection blow molding, injection stretch blow molding, thermoforming, vacuum stretch forming, pressure stretch forming, and rotary thermoforming. The process is suitable for producing three-dimensional articles, such as bottles, housing parts, drums, and many other items. The process of the invention is very simple, since it makes use of existing equipment. The process of the invention gives access to self-cleaning surfaces which have particles with a fissured structure, without any need to apply an additional emboss layer or foreign-material carrier layer to the moldings.
摘要翻译：本发明涉及具有至少一个表面的模制品的成型方法，该模塑制品具有自清洁性能，并且具有由微粒形成的高度，通过用模具对包含有机化合物的材料进行热成形，以及所得到的模制品。本发明的方法通过在热成形之前将微粒施加到模具的内表面，然后进行模塑过程，从而产生具有自清洁性能的表面，其中将微粒压入并固定到该表面尚未固化。本发明的方法可用于选自吹塑，挤出吹塑，挤出拉伸吹塑，注射吹塑，注射拉伸吹塑，热成型，真空拉伸成型，拉伸拉伸成形和旋转热成型的热成型工艺。该方法适用于生产三维制品，例如瓶子，外壳部件，鼓和许多其它物品。本发明的方法非常简单，因为它利用了现有的设备。本发明的方法允许进入具有裂缝结构的颗粒的自清洁表面，而不需要向模制品施加额外的压花层或异物载体层。

10. 发明申请

US20050103457A1 Production of sheet articles having self-cleaning surfaces by using a calendering process, sheet articles themselves and the use thereof 审中-公开
标题翻译：通过使用压延工艺，片材制品本身及其用途生产具有自清洁表面的片材制品
公开(公告)号：US20050103457A1
公开(公告)日：2005-05-19
申请号：US10506238
申请日：2003-02-03
申请人： Edwin Nun , Markus Oles
发明人： Edwin Nun , Markus Oles
IPC分类号： B32B3/16 , B29C43/22 , B29C59/02 , B29C59/04 , B29C70/64 , B32B9/00 , D06M11/79 , D06M23/08 , B32B5/16 , D21H19/66
CPC分类号： B29C70/64 , B29C43/222 , B29C59/022 , B29C59/04 , B29C2059/023 , B29C2059/028 , Y10T428/24372 , Y10T428/254 , Y10T428/259
摘要： The invention relates to calendered web products with surfaces which have self-cleaning properties, and also to a simple process for producing these self-cleaning surfaces. The process of the invention is very simple, since it can utilize existing equipment. Calenders are usually used to produce web products from high-melt-viscosity polymers or web products with a fabric core. The process of the invention utilizes these calenders by applying microparticles on at least one roll of the calender. During passage of the webs, the microparticles are transferred to these via impression of the particles into the surface of the web products. The process of the invention provides access to self-cleaning surfaces which have particles with a fissured structure, without any need to apply an additional embossed layer or carrier layer of foreign material to the web products. Examples of uses of web products of the invention are truck tarpaulins, protective tarpaulins, awnings, sunshade roofs, and tenting.
摘要翻译：本发明涉及具有自清洁性能的表面的压延纤维网产品，以及用于生产这些自清洁表面的简单方法。本发明的方法非常简单，因为它可以利用现有的设备。压延机通常用于从具有织物芯的高熔点粘度聚合物或纤维网产品生产纤维网产品。本发明的方法通过在至少一辊压延机上施加微粒来利用这些压光机。在幅材通过期间，微粒通过颗粒的印迹转移到这些纤维网产品的表面中。本发明的方法提供对具有裂缝结构的颗粒的自清洁表面的访问，而不需要向网产品施加额外的压花层或异物载体层。本发明的网状产品的使用实例是卡车篷布，保护性防水油布，遮阳篷，遮阳篷和帐篷。

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