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1. 发明授权

US08105700B2 Materials and structures for enhancing the performance of organic light emitting devices 有权
标题翻译：用于增强有机发光器件性能的材料和结构
公开(公告)号：US08105700B2
公开(公告)日：2012-01-31
申请号：US11974020
申请日：2007-10-10
申请人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
发明人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
IPC分类号： H01L51/54
CPC分类号： H01L51/5016 , C07C13/567 , C07C13/66 , C07C15/24 , C07C15/38 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , H01L51/0034 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0052 , H01L51/0054 , H01L51/0081 , H01L51/0085 , H01L51/5048 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： A device is provided, having an anode, a cathode, and two adjacent organic layers disposed between the anode and the cathode. One organic layer is a phosphorescent emissive material. The other organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic non-heterocyclic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a molecular dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd m2.
摘要翻译：提供一种具有阳极，阴极和设置在阳极和阴极之间的两个相邻有机层的器件。一个有机层是磷光发光材料。另一有机层可以包括芳族烃材料，其包含任选取代的芳族非杂环烃核心，并且其中取代基相同或不同，并且各自选自烷基，烯基，炔基，芳基，杂烷基取代的芳基，取代的杂芳基和杂环基。第二有机层可以包括具有小于约2.0德拜兹的分子偶极矩的材料，使得该器件在初始亮度约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 100至约1000cd m2。

2. 发明授权

US08465851B2 Materials and structures for enhancing the performance of organic light emitting devices 有权
标题翻译：用于增强有机发光器件性能的材料和结构
公开(公告)号：US08465851B2
公开(公告)日：2013-06-18
申请号：US13334498
申请日：2011-12-22
申请人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
发明人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
IPC分类号： H01L51/54
CPC分类号： H01L51/5016 , C07C13/567 , C07C13/66 , C07C15/24 , C07C15/38 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , H01L51/0034 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0052 , H01L51/0054 , H01L51/0081 , H01L51/0085 , H01L51/5048 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： A device is provided, having an anode, a cathode, and two adjacent organic layers disposed between the anode and the cathode. One organic layer is a phosphorescent emissive material. The other organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic non-heterocyclic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a molecular dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd/m2.
摘要翻译：提供一种具有阳极，阴极和设置在阳极和阴极之间的两个相邻有机层的器件。一个有机层是磷光发光材料。另一有机层可以包括芳族烃材料，其包含任选取代的芳族非杂环烃核心，并且其中取代基相同或不同，并且各自选自烷基，烯基，炔基，芳基，杂烷基取代的芳基，取代的杂芳基和杂环基。第二有机层可以包括具有小于约2.0德拜兹的分子偶极矩的材料，使得该器件在初始亮度约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 100至约1000cd / m 2。

3. 发明授权

US07011897B2 Organic light emitting materials and devices 有权
标题翻译：有机发光材料和器件
公开(公告)号：US07011897B2
公开(公告)日：2006-03-14
申请号：US10643413
申请日：2003-08-18
申请人： Mark E. Thompson , Peter Djurovich , Raymond Kwong , Yeh-Jiun Tung , David B. Knowles , Jason Brooks , Robert W. Walters , Bin Ma
发明人： Mark E. Thompson , Peter Djurovich , Raymond Kwong , Yeh-Jiun Tung , David B. Knowles , Jason Brooks , Robert W. Walters , Bin Ma
IPC分类号： C09K11/06 , H05B33/14
CPC分类号： C09K11/06 , C07F15/004 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , Y10S428/917
摘要： An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between the anode and the cathode, the emissive layer further comprising an emissive material having the structure: wherein each of the variables are defined herein.
摘要翻译：提供有机发光装置。该装置具有阳极，阴极和布置在阳极和阴极之间的发射层，发射层还包括具有以下结构的发射材料：其中每个变量在本文中定义。

4. 发明申请

US20120133276A1 MATERIALS AND STRUCTURES FOR ENHANCING THE PERFORMANCE OF ORGANIC LIGHT EMITTING DEVICES 有权
标题翻译：用于增强有机发光装置性能的材料和结构
公开(公告)号：US20120133276A1
公开(公告)日：2012-05-31
申请号：US13334498
申请日：2011-12-22
申请人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
发明人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
IPC分类号： H01J1/62
CPC分类号： H01L51/5016 , C07C13/567 , C07C13/66 , C07C15/24 , C07C15/38 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , H01L51/0034 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0052 , H01L51/0054 , H01L51/0081 , H01L51/0085 , H01L51/5048 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： A device is provided, having an anode, a cathode, and two adjacent organic layers disposed between the anode and the cathode. One organic layer is a phosphorescent emissive material. The other organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic non-heterocyclic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a molecular dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd/m2.
摘要翻译：提供一种具有阳极，阴极和设置在阳极和阴极之间的两个相邻有机层的器件。一个有机层是磷光发光材料。另一有机层可以包括芳族烃材料，其包含任选取代的芳族非杂环烃核心，并且其中取代基相同或不同，并且各自选自烷基，烯基，炔基，芳基，杂烷基取代的芳基，取代的杂芳基和杂环基。第二有机层可以包括具有小于约2.0德拜兹的分子偶极矩的材料，使得该器件在初始亮度约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 100至约1000cd / m 2。

5. 发明申请

US20080309222A1 Materials and structures for enhancing the performance of organic light emitting devices 有权
标题翻译：用于增强有机发光器件性能的材料和结构
公开(公告)号：US20080309222A1
公开(公告)日：2008-12-18
申请号：US11974020
申请日：2007-10-10
申请人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
发明人： Mark E. Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
IPC分类号： H01J1/63
CPC分类号： H01L51/5016 , C07C13/567 , C07C13/66 , C07C15/24 , C07C15/38 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , H01L51/0034 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0052 , H01L51/0054 , H01L51/0081 , H01L51/0085 , H01L51/5048 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： A device is provided, having an anode, a cathode, and two adjacent organic layers disposed between the anode and the cathode. One organic layer is a phosphorescent emissive material. The other organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic non-heterocyclic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a molecular dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd m2.
摘要翻译：提供一种具有阳极，阴极和设置在阳极和阴极之间的两个相邻有机层的器件。一个有机层是磷光发光材料。另一有机层可以包括芳族烃材料，其包含任选取代的芳族非杂环烃核心，并且其中取代基相同或不同，并且各自选自烷基，烯基，炔基，芳基，杂烷基取代的芳基，取代的杂芳基和杂环基。第二有机层可以包括具有小于约2.0德拜兹的分子偶极矩的材料，使得该器件在初始亮度约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 100至约1000cd m2。

6. 发明申请

US20050025993A1 Materials and structures for enhancing the performance of organic light emitting devices 审中-公开
标题翻译：用于增强有机发光器件性能的材料和结构
公开(公告)号：US20050025993A1
公开(公告)日：2005-02-03
申请号：US10785287
申请日：2004-02-23
申请人： Mark Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
发明人： Mark Thompson , Raymond Kwong , Yeh-Jiun Tung , Jason Brooks
IPC分类号： C07C13/567 , C07C13/66 , C07C15/24 , C07C15/38 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14 , H05B33/12
CPC分类号： H01L51/5016 , C07C13/567 , C07C13/66 , C07C15/24 , C07C15/38 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , H01L51/0034 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0052 , H01L51/0054 , H01L51/0081 , H01L51/0085 , H01L51/5048 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： A device is provided, having an anode, a cathode, and a first organic layer disposed between the anode and the cathode. The first organic layer comprises a material that produces phosphorescent emission when a voltage is applied between the anode and the cathode. A second organic layer is disposed between the first organic layer and the cathode. The second organic layer is in direct contact with the first organic layer. The second organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic non-heterocyclic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a molecular dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd/m2. The second organic layer may be in direct contact with the cathode, or there may be a separate organic layer between the second organic layer and the cathode.
摘要翻译：提供一种具有阳极，阴极和设置在阳极和阴极之间的第一有机层的器件。第一有机层包括当在阳极和阴极之间施加电压时产生磷光发射的材料。第二有机层设置在第一有机层和阴极之间。第二有机层与第一有机层直接接触。第二有机层可以包括芳族烃材料，其包含任选取代的芳族非杂环烃核心，并且其中取代基相同或不同，并且各自选自烷基，烯基，炔基，芳基，杂烷基取代的芳基，取代的杂芳基和杂环基。第二有机层可以包括具有小于约2.0德拜兹的分子偶极矩的材料，使得该器件在初始亮度约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 100至约1000cd / m 2。第二有机层可以与阴极直接接触，或者在第二有机层和阴极之间可以存在单独的有机层。

7. 发明授权

US06902833B2 Materials and structures for enhancing the performance or organic light emitting devices 有权
标题翻译：用于增强性能的材料和结构或有机发光器件
公开(公告)号：US06902833B2
公开(公告)日：2005-06-07
申请号：US10405009
申请日：2003-04-01
申请人： Mark E. Thompson , Simona Garon , Raymond Kwong , Jason Brooks , Min-Hao Michael Lu
发明人： Mark E. Thompson , Simona Garon , Raymond Kwong , Jason Brooks , Min-Hao Michael Lu
IPC分类号： C09K11/06 , H01L51/00 , H01L51/10 , H01L51/30 , H01L51/50 , H05B33/12 , H05B33/14
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1029 , C09K2211/183 , C09K2211/188 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0077 , H01L51/0078 , H01L51/0085 , H01L51/5016 , H01L51/5048 , H01L51/5092 , H01L51/5096 , Y10S428/917 , Y10T428/24942
摘要： A device is provided, having an anode, a cathode, and a first organic layer disposed between the anode and the cathode. The first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode. A second organic layer disposed between the first organic layer and the cathode is also provided. The second organic layer is in direct contact with the first organic layer. The second organic layer may comprise a material having the structure: M may be selected from the group Ti, Zr, Hf, Nb, Re, Sn and Ge. The substituents R1 through R10 may be selected from the group consisting of alkyl and aryl groups. Each of R1 through R10 may represent no substitution, mono-, di-, or tri-substitution. The second organic layer may comprise a material having a dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial photon flux of about 1018 photons/sr-sec. The second organic layer may comprise a metal complex having a plurality of ligands, wherein each ligand makes the same contribution to the highest occupied molecular orbital and the lowest unoccupied molecular orbital of the metal complex. The second organic layer may be in direct contact with the cathode, or there may be a separate organic layer between the second organic layer and the cathode. Other metal complexes having quinolate ligands may be used.
摘要翻译：提供一种具有阳极，阴极和设置在阳极和阴极之间的第一有机层的器件。当在阳极和阴极之间施加电压时，第一有机层能够发磷光。还提供了设置在第一有机层和阴极之间的第二有机层。第二有机层与第一有机层直接接触。第二有机层可以包括具有以下结构的材料：M可以选自Ti，Zr，Hf，Nb，Re，Sn和Ge组。取代基R 1至R 10可以选自烷基和芳基。 R 1至R 10中的每一个可以不表示取代，单取代，二取代或三取代。第二有机层可以包括具有小于约2.0德拜的偶极矩的材料，使得该器件在初始光子通量约为约3％时具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 10个光子/ sr-sec。第二有机层可以包含具有多个配体的金属络合物，其中每个配体对金属络合物的最高占据分子轨道和最低未占据的分子轨道具有相同的贡献。第二有机层可以与阴极直接接触，或者在第二有机层和阴极之间可以存在单独的有机层。可以使用具有喹啉配体的其它金属络合物。

8. 发明授权

US06869695B2 White light emitting OLEDs from combined monomer and aggregate emission 有权
公开(公告)号：US06869695B2
公开(公告)日：2005-03-22
申请号：US10112257
申请日：2002-03-29
申请人： Mark E. Thompson , Jason Brooks , Vadim Adamovich , Stephen R. Forrest , Brian D'Andrade
发明人： Mark E. Thompson , Jason Brooks , Vadim Adamovich , Stephen R. Forrest , Brian D'Andrade
IPC分类号： H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14 , C09K11/06
CPC分类号： H01L51/5016 , H01L51/0037 , H01L51/0059 , H01L51/0072 , H01L51/0085 , H01L51/0087 , H01L51/5036 , H01L51/5096 , H01L2251/308 , Y10S428/917 , Y10T428/24942
摘要： The present invention relates to efficient organic light emitting devices (OLEDs). More specifically, the present invention relates to white-emitting OLEDs, or WOLEDs. The devices of the present invention employ two emitters in a single emissive region to sufficiently cover the visible spectrum. White emission is achieved from two emitters in a single emissive region through the formation of an aggregate by one of the emissive centers. This allows the construction of simple, bright and efficient WOLEDs that exhibit a high color rendering index.

9. 发明授权

US08426041B2 Carbene metal complexes as OLED materials 有权
标题翻译：碳烯金属络合物作为OLED材料
公开(公告)号：US08426041B2
公开(公告)日：2013-04-23
申请号：US13347945
申请日：2012-01-11
申请人： Peter Djurovich , Jui-Yi Tsai , Chun Lin , Jason Brooks , Bert Alleyne , Mark E. Thompson , Peter B. MacKenzie , Bin Ma
发明人： Peter Djurovich , Jui-Yi Tsai , Chun Lin , Jason Brooks , Bert Alleyne , Mark E. Thompson , Peter B. MacKenzie , Bin Ma
IPC分类号： H01L51/54 , C09K11/06
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , H01L51/0067 , H01L51/0069 , H01L51/0072 , H01L51/0077 , H01L51/0079 , H01L51/0081 , H01L51/5016 , H01L51/5036 , H01L2251/308 , Y10S428/917
摘要： An organic light emitting device having an anode, a cathode and an organic layer disposed between the anode and the cathode is provided. In one aspect, the organic layer may be an emissive layer comprising one of the following compounds:
摘要翻译：提供一种具有设置在阳极和阴极之间的阳极，阴极和有机层的有机发光器件。一方面，有机层可以是包含以下化合物之一的发射层：

10. 发明授权

US07534505B2 Organometallic compounds for use in electroluminescent devices 有权
标题翻译：用于电致发光器件的有机金属化合物
公开(公告)号：US07534505B2
公开(公告)日：2009-05-19
申请号：US11032885
申请日：2005-01-10
申请人： Chun Lin , Jui-Yi Tsai , Jason Brooks , Bert Alleyne , Mark E. Thompson , Peter Djurovich , Arnold Tamayo , Tissa Sajoto , Robert Walters
发明人： Chun Lin , Jui-Yi Tsai , Jason Brooks , Bert Alleyne , Mark E. Thompson , Peter Djurovich , Arnold Tamayo , Tissa Sajoto , Robert Walters
IPC分类号： H01L51/54 , C09K11/06
CPC分类号： C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0078 , H01L51/0081 , H01L51/0085 , H01L51/5016 , H05B33/14 , Y10S428/917
摘要： An organic light emitting device having an anode, a cathode and an organic layer between the anode and the cathode is provided. The organic layer comprises a carbene-metal complex having the structure:
摘要翻译：提供了一种在阳极和阴极之间具有阳极，阴极和有机层的有机发光器件。有机层包含具有以下结构的卡宾 - 金属络合物：

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