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1. 发明申请

US20090173912A1 MIXTURES OF HYDROLYSIS RESISTANT ORGANOMODIFIED TRISILOXANE IONIC SURFACTANTS 审中-公开
标题翻译：耐水溶性有机硅氧烷离子表面活性剂的混合物
公开(公告)号：US20090173912A1
公开(公告)日：2009-07-09
申请号：US11964167
申请日：2007-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： C09K3/00
CPC分类号： A01N25/30 , B01F17/0071 , C11D3/3738
摘要： The present invention provides for a mixture comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3 R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8-RA, R9-RC, and R10-RZ; RA being an anionic substituent, RC a cationic substituent or RZ a zwitterionic substituent on the D group and an additional component selected from the group consisting of agricultural components, coating components, personal care components, home care components, oil or gas treating components, water processing components, and pulp or paper treating components, wherein said mixture has an enhanced resistance to hydrolysis.
摘要翻译：本发明提供了一种包含具有下式的硅氧烷的混合物：<？in-line-formula description =“In-Line Formulas”end =“lead”？> M1DM2 <？in-line-formula description =“In-line 公式“end =”tail“？> <？in-line-formula description =”In-line Formulas“end =”lead“？>其中<？in-line-formula description =”In-line Formulas“end =” 尾部“？> <？in-line-formula description =”In-line Formulas“end =”lead“？> M1 =（R1）（R2）（R3）SiO1 / 2; “直线公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> M2 =（R4）（R5）（R6）SiO1 / 2和 <？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> D =（R7） Z）SiO 2/2 <？在线公式描述=“在线公式”end =“tail”？>其中R1，R2，R3 R4，R5，R6和R7各自独立地选自1 至4碳一价烃基，芳基和含有芳基gr的4至9个碳的烃基对了 Z是选自R8-RA，R9-RC和R10-RZ的侧链亲水离子基团; RA为阴离子取代基，RC为阳离子取代基或RZ为D基团上的两性离子取代基，另外的组分选自农业组分，涂料组分，个人护理组分，家庭护理组分，油或气体处理组分，水处理组分和纸浆或纸处理组分，其中所述混合物具有增强的抗水解性。

2. 发明授权

US08470894B2 Hydrolysis resistant organomodified trisiloxane ionic surfactants 有权
标题翻译：耐水解的有机改性的三硅氧烷离子表面活性剂
公开(公告)号：US08470894B2
公开(公告)日：2013-06-25
申请号：US13251667
申请日：2011-10-03
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： B01F3/08 , C07F7/10
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C11D3/3738 , C11D3/3742
摘要： The present invention provides for a composition comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3 R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9-RC, and R10—RZ; RA being an anionic substituent, RC a cationic substituent or RZ a zwitterionic substituent on the D group wherein said siloxane has an enhanced resistance to hydrolysis at a pH below 6 or a pH above 7.5.
摘要翻译：本发明提供包含具有下式的硅氧烷的组合物：M1DM2其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3 R4，R5，R6和R7各自独立地选自1〜 4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9-RC和R10-RZ的侧链亲水离子基团; RA为阴离子取代基，RC为阳离子取代基或RZ为D基团上的两性离子取代基，其中所述硅氧烷在pH低于6或pH高于7.5时具有增强的水解抗性。

3. 发明申请

US20090176893A1 HYDROLYSIS RESISTANT ORGANOMODIFIED TRISILOXANE IONIC SURFACTANTS 审中-公开
标题翻译：耐水溶性有机硅氧烷离子表面活性剂
公开(公告)号：US20090176893A1
公开(公告)日：2009-07-09
申请号：US11964186
申请日：2007-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： B01F3/12 , C07F7/08 , C07C43/10
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C11D3/3738 , C11D3/3742
摘要： The present invention provides for a composition comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3, R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9—RC, and R10—RZ; RA being an anionic substituent, RC a cationic substituent or RZ a zwitterionic substituent on the D group wherein the composition is resistant to hydrolysis under either basic or acidic conditions.
摘要翻译：本发明提供包含具有下式的硅氧烷的组合物：<？in-line-formula description =“In-line formula”end =“lead”？> M1DM2 <？in-line-formula description =“In-line 其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3，R4，R5，R6和R7各自独立地选自1 至4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9-RC和R10-RZ的侧链亲水离子基团; RA为阴离子取代基，RC为阳离子取代基或RZ为D基团上的两性离子取代基，其中所述组合物在碱性或酸性条件下具有抗水解性。

4. 发明申请

US20090173913A1 HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE IONIC SURFACTANTS 审中-公开
标题翻译：水解抗坏血酸的离子表面活性剂
公开(公告)号：US20090173913A1
公开(公告)日：2009-07-09
申请号：US11964231
申请日：2007-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： C07F7/10 , C09K3/00
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C08G77/388 , C08G77/46 , C11D3/3738 , C11D3/3742
摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.
摘要翻译：具有下式的不对称有机改性的二硅氧烷表面活性剂：<？in-line-formula description =“In-line Formulas”end =“lead”？> MM'<？in-line-formula description =“In-line Formulas”end = “尾”→其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基，其中二硅氧烷表面活性剂在pH约3之间具有增强的抗水解性至约12。

5. 发明申请

US20090171108A1 MIXTURES COMPRISING HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE IONIC SURFACTANTS 审中-公开
标题翻译：包含水解抗坏血酸的离子性离子表面活性剂的混合物
公开(公告)号：US20090171108A1
公开(公告)日：2009-07-02
申请号：US11964203
申请日：2007-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： C07F7/18
CPC分类号： A01N25/30 , A01N25/04 , B01F17/0071 , C11D3/3738 , C11D3/3742
摘要： A surfactant mixture comprising a) an asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituents that may be combined as one moiety; and b) an additional component selected from the group consisting of agricultural components, coating components, personal care components, home care components, oil or gas treating components, water processing components and pulp or paper treating components; c) wherein the mixture has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.
摘要翻译：一种表面活性剂混合物，其包含a）不对称有机改性的二硅氧烷表面活性剂，其具有下式：<？in-line-formula description =“In-line formula”end =“lead”？> MM'<？in-line-formula description =“In 其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基; 和b）选自农业组分，涂料组分，个人护理组分，家庭护理组分，油或气体处理组分，水处理组分和纸浆或纸处理组分的另外组分; c）其中所述混合物在约3至约12的pH之间具有增强的水解抗性。

6. 发明申请

US20120142535A1 HYDROLYSIS RESISTANT ORGANOMODIFIED TRISILOXANE IONIC SURFACTANTS 有权
标题翻译：耐水溶性有机硅氧烷离子表面活性剂
公开(公告)号：US20120142535A1
公开(公告)日：2012-06-07
申请号：US13251667
申请日：2011-10-03
申请人： MARK D. LEATHERMAN , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： MARK D. LEATHERMAN , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： A01N25/30 , A01N25/02 , A01P13/00 , A01P21/00 , A01P3/00 , C09K5/10 , C10L1/28 , D21H17/13 , C08K5/544 , C11D17/00 , C11D3/60 , C02F5/00 , A61K8/58 , A01P7/04
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C11D3/3738 , C11D3/3742
摘要： The present invention provides for a composition comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3, R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9-RC, and R10—RZ; RA being an anionic substituent, RC a cationic substituent or RZ a zwitterionic substituent on the D group wherein said siloxane has an enhanced resistance to hydrolysis at a pH below 6 or a pH above 7.5.
摘要翻译：本发明提供包含具有下式的硅氧烷的组合物：M1DM2其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3，R4，R5，R6和R7各自独立地选自1 至4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9-RC和R10-RZ的侧链亲水离子基团; RA为阴离子取代基，RC为阳离子取代基或RZ为D基团上的两性离子取代基，其中所述硅氧烷在pH低于6或pH高于7.5时具有增强的水解抗性。

7. 发明申请

US20080167269A1 HYDROLYSIS RESISTANT ORGANOMODIFIED SILYLATED IONIC SURFACTANTS 审中-公开
标题翻译：水解抗性有机硅化物离子表面活性剂
公开(公告)号：US20080167269A1
公开(公告)日：2008-07-10
申请号：US11953174
申请日：2007-12-10
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： C10M169/04 , A01N55/00 , D21C3/00 , A61K31/695
CPC分类号： A61K8/585 , A01N25/30 , A61Q19/00 , C10G33/04 , C11D3/162 , D21C9/002 , D21H17/59
摘要： The present invention provides for a composition comprising a silane having the formula: (R1)(R2)(R3)Si—R4—Si(R5)(R6)(R7) wherein R1, R2, R3, R5, and R6 are each independently selected from the group consisting of 1 to 6 monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 7 to 10 carbons containing an aryl group; R4 is a hydrocarbon group of 1 to 3 carbons; R7 comprises an anionic, cationic or zwitterionic substituent. The silanes of the present invention exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：本发明提供包含具有下式的硅烷的组合物：<？in-line-formula description =“In-Line Formulas”end =“lead”？>（R 1）（R 3）S（R 5）S（R 5）（R 6）其中R 1，R 2，R 2，R 3，R 3， O 2，R 3，R 5和R 6各自独立地选自1至6个芳基和含有芳基的7〜10个碳原子的烃基; R 4是1至3个碳的烃基; R 7包括阴离子，阳离子或两性离子取代基。本发明的硅烷在宽的pH范围内表现出抗水解性。

8. 发明授权

US08367740B2 Hydrolysis resistant organomodified disiloxane ionic surfactants 有权
标题翻译：耐水解的有机改性的二硅氧烷离子表面活性剂
公开(公告)号：US08367740B2
公开(公告)日：2013-02-05
申请号：US12810967
申请日：2008-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
IPC分类号： B01F3/08 , C07F7/08
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C08G77/388 , C08G77/46 , C11D3/3738 , C11D3/3742
摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.
摘要翻译：具有下式的不对称有机改性二硅氧烷表面活性剂：其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基，其中二硅氧烷表面活性剂具有增强的抗水解性在约3至约12的pH之间。

9. 发明申请

US20110201505A1 MIXTURES COMPRISING HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE IONIC SURFACTANTS 审中-公开
标题翻译：包含水解抗坏血酸的离子性离子表面活性剂的混合物
公开(公告)号：US20110201505A1
公开(公告)日：2011-08-18
申请号：US12810972
申请日：2008-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
IPC分类号： A01N25/30 , C05F11/00 , C09D7/12 , A61K47/24 , C09K3/00 , A01P1/00 , A01P3/00 , A01P7/04 , A01P13/00 , A01P15/00 , C11D3/60 , A61K8/58 , A61Q19/10 , A61Q19/00 , A61Q5/00 , A61Q1/02 , A61Q1/12 , A61Q3/00 , C11D17/00 , C09G1/04
CPC分类号： A01N25/30 , A01N25/04 , B01F17/0071 , C11D3/3738 , C11D3/3742
摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.
摘要翻译：具有下式的不对称有机改性的二硅氧烷表面活性剂：其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基，其中二硅氧烷表面活性剂具有增强的抗水解性在约3至约12的pH之间。

10. 发明申请

US20110011308A1 HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE IONIC SURFACTANTS 有权
标题翻译：水解抗坏血酸的离子表面活性剂
公开(公告)号：US20110011308A1
公开(公告)日：2011-01-20
申请号：US12810967
申请日：2008-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
IPC分类号： C07F7/18 , C09D7/12
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C08G77/388 , C08G77/46 , C11D3/3738 , C11D3/3742
摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.
摘要翻译：具有下式的不对称有机改性二硅氧烷表面活性剂：其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基，其中二硅氧烷表面活性剂具有增强的抗水解性在约3至约12的pH之间。

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