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1. 发明授权

US07858202B2 Composite bodies having a polyacetal portion and a thermoplastic vulcanized elastomer portion, processes for making the same, articles including such bodies and uses therefor 有权
标题翻译：复合体由聚缩醛和热塑性硫化弹性体制成
公开(公告)号：US07858202B2
公开(公告)日：2010-12-28
申请号：US11576309
申请日：2005-09-28
申请人： Marco Prigandt , Frank Reil , Ursula Ziegler , Werner Aumüller , Uwe Stenglin , Bernhard Ulmer
发明人： Marco Prigandt , Frank Reil , Ursula Ziegler , Werner Aumüller , Uwe Stenglin , Bernhard Ulmer
IPC分类号： B32B27/08 , B32B27/30 , B32B27/32 , B32B27/42 , B29C45/14
CPC分类号： B29C45/1676 , B29C45/1657 , B29K2059/00 , B29K2221/003 , B32B25/08 , Y10T428/31507 , Y10T428/31594 , Y10T428/31761 , Y10T428/31786 , Y10T428/31833 , Y10T428/31859 , Y10T428/31942
摘要： Composite bodies, processes for making them, and their uses are disclosed, the composite bodies comprising a polyacetal portion and a modified thermoplastic vulcanizate portion bonded together, wherein the modified thermoplastic vulcanizate portion comprises a modified thermoplastic vulcanizate elastomer having a hardness of 30 to 90 Shore A and wherein the modified thermoplastic vulcanizate elastomer comprises: (a) 2 to 75% by weight of an at least partially crosslinked ethylene-propylene-diene rubber in from 1 to 50% by weight of a polyolefinic matrix further comprising 0.05 to 10% by weight of an ingredient selected from the group consisting of stabilizers, crosslinking aids, and mixtures thereof; (b) 1 to 30% by weight of a compatibilizer; and (c) 10 to 70% by weight of a non-olefinic thermoplastic material, all percentages by weight based on a total weight of the modified thermoplastic vulcanizate elastomer.
摘要翻译：公开了复合体，其制造方法及其用途，所述复合体包含聚缩醛部分和改性热塑性硫化橡胶部分结合在一起，其中改性热塑性硫化橡胶部分包含硬度为30〜90 Shore的改性热塑性硫化橡胶弹性体 A，其中所述改性的热塑性硫化橡胶弹性体包含：（a）2至75重量％的至少部分交联的乙烯 - 丙烯 - 二烯橡胶，其含量为1-50重量％的聚烯烃基体，还包含0.05至10重量％选自稳定剂，交联助剂及其混合物的成分的重量; （b）1〜30重量％的增容剂; 和（c）10至70重量％的非烯烃热塑性材料，所有重量百分数均为改性热塑性硫化橡胶弹性体的总重量。

2. 发明申请

US20070264514A1 Composite Body Made From Polyacetal and Thermoplastic Vulcanised Elastomer 有权
标题翻译：复合体由聚缩醛和热塑性硫化弹性体制成
公开(公告)号：US20070264514A1
公开(公告)日：2007-11-15
申请号：US11576309
申请日：2005-09-28
申请人： Marco Prigandt , Frank Reil , Ursula Ziegler , Werner Aumuller , Uwe Stenglin , Bernhard Ulmer
发明人： Marco Prigandt , Frank Reil , Ursula Ziegler , Werner Aumuller , Uwe Stenglin , Bernhard Ulmer
IPC分类号： B29C45/18 , C08L53/02
CPC分类号： B29C45/1676 , B29C45/1657 , B29K2059/00 , B29K2221/003 , B32B25/08 , Y10T428/31507 , Y10T428/31594 , Y10T428/31761 , Y10T428/31786 , Y10T428/31833 , Y10T428/31859 , Y10T428/31942
摘要： Composite bodies, processes for making them, and their uses are disclosed, the composite bodies comprising a polyacetal portion and a modified thermoplastic vulcanizate portion bonded together, wherein the modified thermoplastic vulcanizate portion comprises a modified thermoplastic vulcanizate elastomer having a hardness of 30 to 90 Shore A and wherein the modified thermoplastic vulcanizate elastomer comprises: (a) 2 to 75% by weight of an at least partially crosslinked ethylene-propylene-diene rubber in from 1 to 50% by weight of a polyolefinic matrix further comprising 0.05 to 10% by weight of an ingredient selected from the group consisting of stabilizers, crosslinking aids, and mixtures thereof; (b) 1 to 30% by weight of a compatibilizer; and (c) 10 to 70% by weight of a non-olefinic thermoplastic material, all percentages by weight based on a total weight of the modified thermoplastic vulcanizate elastomer.
摘要翻译：公开了复合体，其制造方法及其用途，所述复合体包含聚缩醛部分和改性热塑性硫化橡胶部分结合在一起，其中改性热塑性硫化橡胶部分包含硬度为30〜90 Shore的改性热塑性硫化橡胶弹性体 A，其中所述改性的热塑性硫化橡胶弹性体包含：（a）2至75重量％的至少部分交联的乙烯 - 丙烯 - 二烯橡胶，其含量为1-50重量％的聚烯烃基体，还包含0.05至10重量％选自稳定剂，交联助剂及其混合物的成分的重量; （b）1〜30重量％的增容剂; 和（c）10至70重量％的非烯烃热塑性材料，所有重量百分数均为改性热塑性硫化橡胶弹性体的总重量。

3. 发明授权

US06296797B1 Method for producing composite bodies 有权
标题翻译：复合体的制造方法
公开(公告)号：US06296797B1
公开(公告)日：2001-10-02
申请号：US09509599
申请日：2000-05-22
申请人： Ursula Ziegler , Klaus Kurz , Frank Reil
发明人： Ursula Ziegler , Klaus Kurz , Frank Reil
IPC分类号： B28B722
CPC分类号： B29C45/1676 , B29K2059/00 , B60R13/04
摘要： Process for producing a composite article from a polyacetal (component a) with directly molded-on functional elements made from one or more thermoplastic elastomers (component b), and wherein components a and b have differing hardness, and the material with the greater hardness (component a) is initially premolded in a first step in a mold, and then is either cooled and removed from the mold and then placed into another, larger cavity, or is partially removed from the mold, but remains in a portion of the mold, and is then moved to a larger cavity, or, without removal from the mold, remains in the same mold, which is enlarged by means of a movable device, and in a second step, by overmolding with the material with the lesser hardness (component b), the molding formed from component a is firmly bonded to this material and is then removed from the mold as a composite article.
摘要翻译：由聚缩醛（组分a）和由一种或多种热塑性弹性体（组分b）制成的直接成型的功能元件制备复合制品的方法，其中组分a和b具有不同的硬度，以及硬度较高的材料组件a）最初在模具中的第一步骤中预成型，然后被冷却并从模具中取出，然后被放置到另一个更大的空腔中，或者部分地从模具中移除，但是保留在模具的一部分中，然后移动到更大的空腔，或者不从模具中取出，保持在相同的模具中，该模具通过可移动装置而被扩大，并且在第二步骤中，通过用较低硬度的材料（部件 b），由组分a形成的模制品牢固地粘合到该材料上，然后作为复合制品从模具中取出。

4. 发明授权

US08236430B2 Composite bodies, method for the production thereof and use thereof 有权
标题翻译：复合体，其制造方法及其用途
公开(公告)号：US08236430B2
公开(公告)日：2012-08-07
申请号：US10584745
申请日：2004-12-22
申请人： Ursula Ziegler , Frank Reil , Klaus Kurz
发明人： Ursula Ziegler , Frank Reil , Klaus Kurz
IPC分类号： B32B27/08 , B29B13/02 , C08G2/08
CPC分类号： B29C45/1676 , B29C45/1657 , B29C66/71 , B29C66/73152 , B29C2045/1659 , B29K2059/00 , B29K2077/00 , B29K2221/003 , Y10T428/31725 , B29K2021/003 , B29K2019/00
摘要： Composites are described, comprising polyacetal and at least one thermoplastic polyamide elastomer formed by a polyacetal molding which has been partially or completely coated with the thermoplastic polyamide elastomer or onto which one or more moldings composed of the thermoplastic polyamide elastomer have been directly molded. The composites are characterized in that the polyacetal and the thermoplastic polyamide elastomer have been bonded adhesively or cohesively to one another via injection of the polyamide elastomer onto the polyacetal molding, and in that the tensile bond strength between the polyacetal and the thermoplastic polyamide elastomer is at least 0.5 N/mm2. The composites may be used as connectors, as functional components with integrated sealing properties and/or with integrated damping properties, or else as non-slip and easy-grip elements.
摘要翻译：描述了包含聚缩醛和至少一种热塑性聚酰胺弹性体的复合材料，所述热塑性聚酰胺弹性体通过已经部分或完全地涂覆有热塑性聚酰胺弹性体的聚缩醛成型体形成，或者由热塑性聚酰胺弹性体组成的一个或多个模制品已被直接模塑。复合材料的特征在于聚缩醛和热塑性聚酰胺弹性体通过将聚酰胺弹性体注入到聚缩醛成型体上而粘合地或内聚地粘合，并且聚缩醛和热塑性聚酰胺弹性体之间的拉伸粘合强度在至少0.5 N / mm2。复合材料可用作连接器，作为具有集成密封性能和/或具有整体阻尼性能的功能部件，或者作为防滑和易抓握元件。

5. 发明授权

US07618714B2 Composite body made from polyacetal, bonding agent and polyolefin, method for production and use thereof 失效
标题翻译：由聚缩醛，粘合剂和聚烯烃制成的复合体，其制造方法和用途
公开(公告)号：US07618714B2
公开(公告)日：2009-11-17
申请号：US10533984
申请日：2003-11-03
申请人： Ursula Ziegler , Klaus Kurz , Frank Reil
发明人： Ursula Ziegler , Klaus Kurz , Frank Reil
IPC分类号： B32B27/08 , B32B27/30 , B32B27/32
CPC分类号： B32B7/12 , B32B27/08 , B32B27/28 , B32B27/32 , B32B37/12 , B32B37/153 , B32B2250/05 , B32B2250/24 , B32B2323/04 , B32B2439/00 , B32B2553/00 , B32B2597/00 , Y10T428/31859 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： Composite products are described and encompass at least one polyacetal molding and at least one polyolefin molding, which have been bonded at at least one of their surfaces using an adhesion-promoting layer which is substantially composed of a copolymer or of a mixture of these which derives from at least one alpha-olefin and from at least one ethylenically unsaturated carboxylic acid, and/or from at least one ethylenically unsaturated carboxylic acid derivative, where the molar ratio of alpha-olefin to ethylenically unsaturated carboxylic acid and/or to ethylenically unsaturated carboxylic acid derivative is selected so as to obtain composites with a bond strength (measured by the tensile test at 23° C.) of at least 0.2 N/mm2.The composite products described can in particular be used for producing components which come into contact with fuels.
摘要翻译：复合产品被描述并且包括至少一个聚缩醛模制品和至少一种聚烯烃模塑件，它们已使用基本上由共聚物或它们的混合物组成的粘合促进层在其至少一个表面上结合来自至少一种α-烯烃和至少一种烯键式不饱和羧酸和/或至少一种烯属不饱和羧酸衍生物，其中α-烯烃与烯属不饱和羧酸和/或烯属不饱和羧酸的摩尔比选择酸衍生物以获得具有至少0.2N / mm 2的粘合强度（通过23℃下的拉伸试验测量）的复合材料。所述的复合制品特别可用于制造与燃料接触的部件。

6. 发明申请

US20070166561A1 Composite bodies, method for the production thereof and use thereof 审中-公开
标题翻译：复合体，其制造方法及其用途
公开(公告)号：US20070166561A1
公开(公告)日：2007-07-19
申请号：US10584746
申请日：2004-12-22
申请人： Ursula Ziegler , Frank Reil , Klaus Kurz
发明人： Ursula Ziegler , Frank Reil , Klaus Kurz
IPC分类号： B32B27/36
CPC分类号： B29C45/1676 , B29C45/1657 , B29C2045/1659 , B29K2059/00 , B29K2221/003 , Y10T428/31786 , Y10T428/31942
摘要： Composites are described, comprising polyacetal and at least one thermoplastic polyester elastomer formed by a polyacetal molding which has been partially or completely coated with the thermoplastic polyester elastomer or onto which one or more moldings composed of the thermoplastic polyester elastomer have been directly molded. The composites are characterized in that the polyacetal and the thermoplastic polyester elastomer have been bonded adhesively or cohesively to one another via injection of the thermoplastic polyester elastomer onto the polyacetal molding, and in that the tensile bond strength between the polyacetal and the thermoplastic polyester elastomer is at least 0.5 N/mm2. The composites may be used as connectors, as functional components with integrated sealing properties and/or with integrated damping properties, or else as non-slip and easy-grip elements.
摘要翻译：描述了包含聚缩醛和至少一种热塑性聚酯弹性体的复合材料，所述热塑性聚酯弹性体通过已经部分或完全地涂覆有热塑性聚酯弹性体的聚缩醛成型体形成，或者由热塑性聚酯弹性体组成的一个或多个模制品已被直接模制。复合材料的特征在于聚缩醛和热塑性聚酯弹性体通过将热塑性聚酯弹性体注入到聚缩醛成型体上而粘合或粘合，并且聚缩醛和热塑性聚酯弹性体之间的拉伸粘合强度为至少0.5N / mm 2。复合材料可用作连接器，作为具有集成密封性能和/或具有整体阻尼性能的功能部件，或者作为防滑和易抓握元件。

7. 发明申请

US20080029934A1 COMPOSITE BODY MADE FROM POLYACETAL AND STYROL OLEFIN-ELASTOMERS 审中-公开
标题翻译：由聚乙烯和苯乙烯 - 烯烃弹性体组成的复合体
公开(公告)号：US20080029934A1
公开(公告)日：2008-02-07
申请号：US11846964
申请日：2007-08-29
申请人： Ursula Ziegler , Klaus Kurz , Frank Reil , Fritz Schmidt , Rudi Herbst
发明人： Ursula Ziegler , Klaus Kurz , Frank Reil , Fritz Schmidt , Rudi Herbst
IPC分类号： B29C45/03
CPC分类号： B32B25/08 , B29C45/16 , B29C45/1676 , B29K2059/00 , B29K2221/003 , B32B7/12 , B32B27/28 , B32B27/42 , B32B37/12 , B32B2037/243 , B32B2309/02 , C08J5/12 , C08J7/047 , C08J2359/02 , C08J2453/00
摘要： A composite article made from polyacetal and from at least one modified styrene-olefin elastomer, which comprises from 15 to 70% by weight, based on the weight of the modified styrene-olefin elastomer, of non-olefinic thermoplastic material, and also a process for producing the same, where a molding made from polyacetal is firstly molded, onto which is then molded a coating or at least one molding made from the modified styrene-olefin elastomer, and an adhesive bond is formed between the polyacetal and the modified styrene-olefin elastomer.
摘要翻译：由聚缩醛和至少一种改性的苯乙烯 - 烯烃弹性体制成的复合制品，其包含基于改性苯乙烯 - 烯烃弹性体的重量的15至70重量％的非烯烃热塑性材料，以及一种方法首先将由聚缩醛制成的模制品成型，然后将其上模塑成型或由改性苯乙烯 - 烯烃弹性体制成的至少一种模制品，并且在聚缩醛和改性苯乙烯 - 烯烃弹性体。

8. 发明申请

US20070154727A1 Composite bodies, method for the production thereof and use thereof 有权
标题翻译：复合体，其制造方法及其用途
公开(公告)号：US20070154727A1
公开(公告)日：2007-07-05
申请号：US10584745
申请日：2004-12-22
申请人： Ursula Ziegler , Frank Reil , Klaus Kurz
发明人： Ursula Ziegler , Frank Reil , Klaus Kurz
IPC分类号： B32B27/34
CPC分类号： B29C45/1676 , B29C45/1657 , B29C66/71 , B29C66/73152 , B29C2045/1659 , B29K2059/00 , B29K2077/00 , B29K2221/003 , Y10T428/31725 , B29K2021/003 , B29K2019/00
摘要： Composites are described, comprising polyacetal and at least one thermoplastic polyamide elastomer formed by a polyacetal molding which has been partially or completely coated with the thermoplastic polyamide elastomer or onto which one or more moldings composed of the thermoplastic polyamide elastomer have been directly molded. The composites are characterized in that the polyacetal and the thermoplastic polyamide elastomer have been bonded adhesively or cohesively to one another via injection of the polyamide elastomer onto the polyacetal molding, and in that the tensile bond strength between the polyacetal and the thermoplastic polyamide elastomer is at least 0.5 N/mm2. The composites may be used as connectors, as functional components with integrated sealing properties and/or with integrated damping properties, or else as non-slip and easy-grip elements.
摘要翻译：描述了包含聚缩醛和至少一种热塑性聚酰胺弹性体的复合材料，所述热塑性聚酰胺弹性体通过已经部分或完全地涂覆有热塑性聚酰胺弹性体的聚缩醛成型体形成，或者由热塑性聚酰胺弹性体组成的一个或多个模制品已被直接模塑。复合材料的特征在于聚缩醛和热塑性聚酰胺弹性体通过将聚酰胺弹性体注入到聚缩醛成型体上而粘合地或内聚地粘合，并且聚缩醛和热塑性聚酰胺弹性体之间的拉伸粘合强度在至少0.5N / mm 2。复合材料可用作连接器，作为具有集成密封性能和/或具有整体阻尼性能的功能部件，或者作为防滑和易抓握元件。

9. 发明申请

US20060040120A1 Composite body made from polyacetal, bonding agent and polyolefin, method for production and use thereof 失效
标题翻译：由聚缩醛，粘合剂和聚烯烃制成的复合体，其制造方法和用途
公开(公告)号：US20060040120A1
公开(公告)日：2006-02-23
申请号：US10533984
申请日：2003-11-03
申请人： Ursula Ziegler , Klaus Kurz , Frank Reil
发明人： Ursula Ziegler , Klaus Kurz , Frank Reil
IPC分类号： B32B27/08 , B32B27/30 , B32B27/32
CPC分类号： B32B7/12 , B32B27/08 , B32B27/28 , B32B27/32 , B32B37/12 , B32B37/153 , B32B2250/05 , B32B2250/24 , B32B2323/04 , B32B2439/00 , B32B2553/00 , B32B2597/00 , Y10T428/31859 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： Composite products are described and encompass at least one polyacetal molding and at least one polyolefin molding, which have been bonded at at least one of their surfaces using an adhesion-promoting layer which is substantially composed of a copolymer or of a mixture of these which derives from at least one alpha-olefin and from at least one ethylenically unsaturated carboxylic acid, and/or from at least one ethylenically unsaturated carboxylic acid derivative, where the molar ratio of alpha-olefin to ethylenically unsaturated carboxylic acid and/or to ethylenically unsaturated carboxylic acid derivative is selected so as to obtain composites with a bond strength (measured by the tensile test at 23° C.) of at least 0.2 N/mm2. The composite products described can in particular be used for producing components which come into contact with fuels.
摘要翻译：复合产品被描述并且包括至少一个聚缩醛模制品和至少一种聚烯烃模塑件，它们已使用基本上由共聚物或它们的混合物组成的粘合促进层在其至少一个表面上结合来自至少一种α-烯烃和至少一种烯键式不饱和羧酸和/或至少一种烯属不饱和羧酸衍生物，其中α-烯烃与烯属不饱和羧酸和/或烯属不饱和羧酸的摩尔比选择酸衍生物以获得具有至少0.2N / mm 2的粘合强度（通过23℃的拉伸试验测量）的复合材料。所述的复合制品特别可用于制造与燃料接触的部件。

10. 发明申请

US20050077653A1 Method for producing shaped parts with a small flash 审中-公开
标题翻译：用于生产具有小闪光的成形部件的方法
公开(公告)号：US20050077653A1
公开(公告)日：2005-04-14
申请号：US10479133
申请日：2002-05-28
申请人： Klink Holger , Frank Reil
发明人： Klink Holger , Frank Reil
IPC分类号： B29C45/26 , B29C45/00 , B29K83/00 , C08L81/02 , C08J5/00
CPC分类号： C08L81/02 , B29C45/0001
摘要： The present invention relates to a process for producing moldings from polyarylene sulfides, in particular polyphenylene sulfide, the result of which can be a particularly low level of flash formation.
摘要翻译：本发明涉及一种由聚亚芳基硫醚，特别是聚苯硫醚生产模制品的方法，其结果可能是特别低的闪蒸水平。

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