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1. 发明授权

US08263290B2 Precious metal oxide catalyst for water electrolysis 有权
标题翻译：贵金属氧化物催化剂用于水电解
公开(公告)号：US08263290B2
公开(公告)日：2012-09-11
申请号：US13150310
申请日：2011-06-01
申请人： Marco Lopez , Andreas Schleunung , Peter Biberbach
发明人： Marco Lopez , Andreas Schleunung , Peter Biberbach
IPC分类号： H01M4/02 , H01M4/13 , H01M4/36 , H01M4/58 , H01M4/90 , H01M8/00 , C25F7/00 , B01J20/00 , B01J21/00 , B01J21/04 , B01J23/00
CPC分类号： B01J23/468 , B01J35/1014 , B01J35/1019 , B01J37/031 , C02F1/46109 , C02F2001/46142 , C02F2201/46115 , C25B9/10 , C25B11/04 , C25B11/0484 , H01M4/9016 , H01M8/186 , H01M2008/1095 , Y02E60/366 , Y02E60/528
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterized by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.
摘要翻译：本发明涉及用于PEM水电解中的阳极催化剂的氧化铱基催化剂。要求保护的复合催化剂材料包括氧化铱（IrO 2）和任选的氧化钌（RuO 2）与高表面积无机氧化物（例如TiO 2，Al 2 O 3，ZrO 2及其混合物）的组合。无机氧化物的BET表面积在50〜400m 2 / g的范围内，水溶性低于0.15g / l，且其含量小于20wt。％，基于催化剂的总重量。要求保护的催化剂材料的特征在于低电压过电压和长时间的水电解。催化剂用于电极，催化剂涂覆的膜和用于PEM电解器以及再生燃料电池（RFC），传感器和其他电化学装置的膜 - 电极组件。

2. 发明授权

US07976989B2 Precious metal oxide catalyst for water electrolysis 有权
标题翻译：贵金属氧化物催化剂用于水电解
公开(公告)号：US07976989B2
公开(公告)日：2011-07-12
申请号：US10595480
申请日：2004-10-29
申请人： Marco Lopez , Andreas Schleunung , Peter Biberbach
发明人： Marco Lopez , Andreas Schleunung , Peter Biberbach
IPC分类号： H01M8/00 , H01M4/00 , B23H3/04 , B23H5/10 , B23H7/22 , C25B11/00 , C25C7/02 , C25D17/10 , C25F7/00 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J23/468 , B01J35/1014 , B01J35/1019 , B01J37/031 , C02F1/46109 , C02F2001/46142 , C02F2201/46115 , C25B9/10 , C25B11/04 , C25B11/0484 , H01M4/9016 , H01M8/186 , H01M2008/1095 , Y02E60/366 , Y02E60/528
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterised by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.
摘要翻译：本发明涉及用于PEM水电解中的阳极催化剂的氧化铱基催化剂。要求保护的复合催化剂材料包括氧化铱（IrO 2）和任选的氧化钌（RuO 2）与高表面积无机氧化物（例如TiO 2，Al 2 O 3，ZrO 2及其混合物）的组合。无机氧化物的BET表面积在50〜400m 2 / g的范围内，水溶性低于0.15g / l，且其含量小于20wt。％，基于催化剂的总重量。要求保护的催化剂材料的特征在于低电压过电压和长时间的水电解。催化剂用于电极，催化剂涂覆的膜和用于PEM电解器以及再生燃料电池（RFC），传感器和其他电化学装置的膜 - 电极组件。

3. 发明申请

US20110223523A1 Precious Metal Oxide for Water Electrolysis 有权
标题翻译：贵金属氧化物水电解
公开(公告)号：US20110223523A1
公开(公告)日：2011-09-15
申请号：US13150310
申请日：2011-06-01
申请人： Marco Lopez , Andreas Schleunung , Peter Biberbach
发明人： Marco Lopez , Andreas Schleunung , Peter Biberbach
IPC分类号： B01J23/46 , H01M4/92 , C25B11/06 , C25B9/00 , B01J37/03 , B01J37/08 , B01J35/10 , B01J21/06 , B01J21/08 , B01J21/04 , B01J23/62 , B01J27/135 , B01J23/63 , B01J23/648 , B01J35/00
CPC分类号： B01J23/468 , B01J35/1014 , B01J35/1019 , B01J37/031 , C02F1/46109 , C02F2001/46142 , C02F2201/46115 , C25B9/10 , C25B11/04 , C25B11/0484 , H01M4/9016 , H01M8/186 , H01M2008/1095 , Y02E60/366 , Y02E60/528
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterised by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.
摘要翻译：本发明涉及用于PEM水电解中的阳极催化剂的氧化铱基催化剂。要求保护的复合催化剂材料包括氧化铱（IrO 2）和任选的氧化钌（RuO 2）与高表面积无机氧化物（例如TiO 2，Al 2 O 3，ZrO 2及其混合物）的组合。无机氧化物的BET表面积在50〜400m 2 / g的范围内，水溶性低于0.15g / l，且其含量小于20wt。％，基于催化剂的总重量。要求保护的催化剂材料的特征在于低电压过电压和长时间的水电解。催化剂用于电极，催化剂涂覆的膜和用于PEM电解器以及再生燃料电池（RFC），传感器和其他电化学装置的膜 - 电极组件。

4. 发明申请

US20070292744A1 Precious Metal Oxide Catalyst for Water Electrolysis 有权
标题翻译：贵金属氧化物水电解催化剂
公开(公告)号：US20070292744A1
公开(公告)日：2007-12-20
申请号：US10595480
申请日：2004-10-29
申请人： Marco Lopez , Andreas Schleunung , Peter Biberbach
发明人： Marco Lopez , Andreas Schleunung , Peter Biberbach
IPC分类号： B01J23/46 , C02F1/461 , C25B1/10 , C25B11/04 , H01M4/92 , H01M8/18
CPC分类号： B01J23/468 , B01J35/1014 , B01J35/1019 , B01J37/031 , C02F1/46109 , C02F2001/46142 , C02F2201/46115 , C25B9/10 , C25B11/04 , C25B11/0484 , H01M4/9016 , H01M8/186 , H01M2008/1095 , Y02E60/366 , Y02E60/528
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterised by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.
摘要翻译：本发明涉及用于PEM水电解中的阳极催化剂的氧化铱基催化剂。要求保护的复合催化剂材料包括氧化铱（IrO 2 N 2）和任选的氧化钌（RuO 2 N 2）与高表面积无机氧化物（例如TiO 2） 2个，2个O 3，3个ZrO 2和它们的混合物）。无机氧化物的BET表面积在50〜400m 2 / g的范围内，水溶解度低于0.15g / l，且其含量小于20wt。％，基于催化剂的总重量。要求保护的催化剂材料的特征在于低电压过电压和长时间的水电解。催化剂用于电极，催化剂涂覆的膜和用于PEM电解器以及再生燃料电池（RFC），传感器和其他电化学装置的膜 - 电极组件。

5. 发明申请

US20080214389A1 Platinum/Ruthenium Catalyst for Direct Methanol Fuel Cells 有权
标题翻译：用于直接甲醇燃料电池的铂/钌催化剂
公开(公告)号：US20080214389A1
公开(公告)日：2008-09-04
申请号：US11573936
申请日：2005-08-13
申请人： Marco Lopez , Peter Biberbach
发明人： Marco Lopez , Peter Biberbach
IPC分类号： B01J21/18 , B01J23/42 , B01J23/46 , H01M4/96
CPC分类号： H01M4/921
摘要： The invention relates to a carbon-supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt. %, preferably in the range from 85 to 98 wt. %, particularly preferably in the range from 85 to 95 wt. % (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m2/g by means of a reduction process using chemical reducing agents with addition of organic acids. Electrodes and membrane-electrode units containing the catalyst according to the invention having a high precious metal loading have an electrode layer thickness of less than 80 μm at a PtRu loading per unit area of the electrode of from 6 to 12 mg of PtRu/cm and lead to improved electric power in direct methanol fuel cells.
摘要翻译：本发明涉及一种用于直接甲醇燃料电池（DMFC）的碳负载PtRu阳极催化剂，其具有80至98重量％的铂/钌含量。％，优选在85至98重量％的范围内。％，特别优选为85〜95重量％。％（基于催化剂的总重量），在碳基导电载体材料上，并且具有小于3nm的平均粒度。使用具有比表面积（通过BET法测量）在1000-2000m 2 / g范围内的碳黑载体材料通过使用化学还原剂的还原方法制备催化剂加入有机酸。含有贵金属负载量高的本发明催化剂的电极和膜 - 电极单元在每单位面积电极PtRu负载下具有小于80μm的电极层厚度，PtRu / cm 2为6至12mg，导致直接甲醇燃料电池的电力提高。

6. 发明授权

US07776781B2 Platinum/ruthenium catalyst for direct methanol fuel cells 有权
标题翻译：用于直接甲醇燃料电池的铂/钌催化剂
公开(公告)号：US07776781B2
公开(公告)日：2010-08-17
申请号：US11573936
申请日：2005-08-13
申请人： Marco Lopez , Peter Biberbach
发明人： Marco Lopez , Peter Biberbach
IPC分类号： B01J21/18 , B01J23/40 , B01J23/74 , B01J23/00 , B01J23/42 , B01J23/44 , H01M4/02 , H01M4/58 , C22C5/04
CPC分类号： H01M4/921
摘要： The invention relates to a carbon-supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt. %, preferably in the range from 85 to 98 wt. %, particularly preferably in the range from 85 to 95 wt. % (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m2/g by means of a reduction process using chemical reducing agents with addition of organic acids. Electrodes and membrane-electrode units containing the catalyst according to the invention having a high precious metal loading have an electrode layer thickness of less than 80 μm at a PtRu loading per unit area of the electrode of from 6 to 12 mg of PtRu/cm2 and lead to improved electric power in direct methanol fuel cells.
摘要翻译：本发明涉及一种用于直接甲醇燃料电池（DMFC）的碳负载PtRu阳极催化剂，其具有80至98重量％的铂/钌含量。％，优选在85至98重量％的范围内。％，特别优选为85〜95重量％。％（基于催化剂的总重量），在碳基导电载体材料上，并且具有小于3nm的平均粒度。使用具有通过添加有机酸的化学还原剂的还原方法，使用具有1000-2000m 2 / g的比表面积（通过BET法测量）的炭黑载体材料制备催化剂。含有贵金属负载量高的本发明催化剂的电极和膜 - 电极单元，PtRu负载量为6〜12mg PtRu / cm 2时Pt电极厚度小于80μm，导致直接甲醇燃料电池的电力提高。

7. 发明授权

US08304362B2 Core/shell-type catalyst particles and methods for their preparation 有权
标题翻译：核/壳型催化剂颗粒及其制备方法
公开(公告)号：US08304362B2
公开(公告)日：2012-11-06
申请号：US12438978
申请日：2007-08-27
申请人： Marco Lopez , Michael Lennartz , Dan V. Goia , Carsten Becker , Stéphanie Chevalliot
发明人： Marco Lopez , Michael Lennartz , Dan V. Goia , Carsten Becker , Stéphanie Chevalliot
IPC分类号： H01M4/88 , H01M4/02 , H01M4/36 , H01M4/90 , H01M4/92 , H01M4/94 , B21D51/16 , B01D53/34 , B01J21/18 , B01J23/00 , B01J23/40 , B01J23/74 , B32B27/02 , B32B5/16 , B32B15/02 , B32B17/02 , B32B19/02 , B32B21/02 , B32B23/02
CPC分类号： B22F1/025 , B22F1/0018 , B22F2998/00 , B82Y30/00 , H01M4/8605 , H01M4/8842 , H01M4/921 , H01M4/926 , H01M8/1007 , Y10T29/49345 , Y10T428/2991 , B22F9/24
摘要： The invention discloses core/shell type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt-based shell, reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.
摘要翻译：本发明公开了包含Mcore / Mshell结构的核/壳型催化剂颗粒，其中Mcore =内颗粒核和Mshell =外颗粒壳，其中催化剂颗粒（dcore +壳）的介质直径在20至100nm的范围内，优选在20〜50nm的范围内。外壳的厚度（tshell）为所述催化剂颗粒的内颗粒芯的直径的约5至20％，优选包含至少3个原子层。核/壳型催化剂颗粒，特别是包含Pt基壳的颗粒显示高的比活性。催化剂颗粒优选负载在合适的载体材料如炭黑上，并用作燃料电池的电催化剂。

8. 发明申请

US20080191161A1 Ink for Producing Catalyst Layers 有权
标题翻译：用于生产催化剂层的油墨
公开(公告)号：US20080191161A1
公开(公告)日：2008-08-14
申请号：US11909767
申请日：2006-03-25
申请人： Walter Behl , Marco Lopez
发明人： Walter Behl , Marco Lopez
IPC分类号： H01G9/00
CPC分类号： H01M4/92 , H01M4/8807 , H01M4/881 , H01M4/8828 , H01M4/926 , H01M8/1004
摘要： The invention relates to an ink for producing catalyst layers for electrochemical devices. The ink comprises catalyst material, ionomer material, water and at least one organic solvent. The organic solvent belongs to the class of tertiary alcohol's and/or the class of aliphatic diketones and bears functional groups which are stable to oxidative degradation in the ink. This prevents formation of decomposition products in the ink. The ink of the invention displays a high storage stability and is used for producing catalyst-coated substrates for electrochemical devices, in particular fuel cells (PEMFCs, DMFCs).
摘要翻译：本发明涉及一种用于生产电化学装置的催化剂层的油墨。油墨包含催化剂材料，离聚物材料，水和至少一种有机溶剂。有机溶剂属于叔醇类和/或脂族二酮类，并具有对油墨中的氧化降解稳定的官能团。这防止在油墨中形成分解产物。本发明的油墨显示出高的储存稳定性，并且用于生产用于电化学装置，特别是燃料电池（PEMFC，DMFC）的催化剂涂覆的基材。

9. 发明授权

US07244688B2 Method for in situ immobilization of water-soluble nanodispersed metal oxide colloids 失效
标题翻译：水溶性纳米分散金属氧化物胶体原位固定方法
公开(公告)号：US07244688B2
公开(公告)日：2007-07-17
申请号：US10507764
申请日：2003-02-25
申请人： Manfred T. Reetz , Marco Lopez
发明人： Manfred T. Reetz , Marco Lopez
IPC分类号： B01J21/18 , B01J23/00
CPC分类号： H01M4/921 , B01J21/18 , B01J23/40 , B01J23/626 , B01J23/6525 , B01J35/0013 , B01J37/0211 , H01M4/8605
摘要： The invention relates to heterogeneous catalysts which are particularly easy to produce. Said heterogeneous catalysts are generated by immobilizing preformed monometallic or multimetallic metal oxide particles in situ on an oxidic or non-oxidic carrier, wherefore metal oxide colloids which are stabilized by hydroxide ions and immobilized on carriers contained in the suspension are generated from conventional, water-soluble metal salts by means of hydrolysis and condensation. The inventive method makes it possible to produce fuel cell catalysts, for example.
摘要翻译：本发明涉及特别容易生产的多相催化剂。所述非均相催化剂通过将预制的单金属或多金属氧化物颗粒原位固定在氧化或非氧化载体上而产生，因此由常规的水溶性聚合物产生由氢氧根离子稳定并固定在悬浮液中的载体上的金属氧化物胶体，通过水解和缩合可溶性金属盐。本发明的方法使得可以制备例如燃料电池催化剂。

10. 发明申请

US20120238443A1 MANUFACTURE OF BASE METAL NANOPARTICLES USING A SEED PARTICLE METHOD 审中-公开
标题翻译：使用种子颗粒法制备碱金属纳米颗粒
公开(公告)号：US20120238443A1
公开(公告)日：2012-09-20
申请号：US13049165
申请日：2011-03-16
申请人： Dan V. Goia , Marco Lopez , Igor V. Sevonkaev
发明人： Dan V. Goia , Marco Lopez , Igor V. Sevonkaev
IPC分类号： H01B1/02 , C22C19/07 , C22C9/00 , B01J23/00 , B22F9/16 , C22C19/03 , B82Y99/00 , B82Y40/00
CPC分类号： B22F9/24 , B22F1/0018 , B22F2998/00 , B82Y30/00 , B22F2301/10 , B22F2301/15 , B22F2304/054 , B22F2304/056
摘要： The present invention is directed to a process for manufacture of base metal nano-particles using precious metal seed particles.The process comprises the steps of mixing at least one base metal precursor and at least one precious metal precursor in one or more polyol solvents, reacting the mixture at a temperature in the range of 110 to 150° C. to form precious metal seed particles (STEP A) and reacting the mixture at a temperature in the range of 180 to 220° C. to form the final metal particles (STEP B). Base metal particles of Co, Ni and Cu containing 100 to 10000 ppm of precious metals Ru, Pd, Pt or Ir are obtained.The resulting metal nano-particles with medium diameters of 20 to 200 nm are useful for electronic and catalytic applications and can be used as core materials for the manufacture core/shell type catalysts.
摘要翻译：本发明涉及使用贵金属种子颗粒制造贱金属纳米颗粒的方法。该方法包括以下步骤：在一种或多种多元醇溶剂中混合至少一种母体金属前体和至少一种贵金属前体，使该混合物在110-150℃的温度下反应，形成贵金属种子颗粒（步骤A），并使混合物在180-220℃的温度下反应以形成最终的金属颗粒（步骤B）。得到含有100〜10000ppm贵金属Ru，Pd，Pt或Ir的Co，Ni和Cu的母体金属颗粒。所得到的中等直径为20-200nm的金属纳米颗粒可用于电子和催化应用，可用作制造核/壳型催化剂的核心材料。

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