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1. 发明授权

US08753785B2 Shaped part 有权
标题翻译：形状部分
公开(公告)号：US08753785B2
公开(公告)日：2014-06-17
申请号：US12969067
申请日：2010-12-15
申请人： Marco Brandner , Stefan Gerzoskovitz , Wolfgang Kraussler , Alexander Leuprecht , Andreas Venskutonis
发明人： Marco Brandner , Stefan Gerzoskovitz , Wolfgang Kraussler , Alexander Leuprecht , Andreas Venskutonis
IPC分类号： H01M8/02
CPC分类号： B22F3/12 , B22F3/02 , B22F5/00 , B22F5/06 , B22F5/08 , C22C27/06 , C22C33/0207 , C22C33/0285 , H01M8/0206 , H01M8/021 , Y02P70/56
摘要： A shaped part that is particularly suited as an interconnector or an end plate for a fuel cell stack, is produced by pressing and sintering a pulverulent starting material. The shaped part has a basic body with a multiplicity of knob-like and/or ridge-like elevations with a height h. Each elevation has two inclined side flanks which lead, proceeding from an end contour of the elevation, via rounded corner portions, with a radius r or r′ directly or via intermediate rectilinear portions, into curved portions, with a radius R or R′, which in turn merge into the surface contour, of the basic body. The rectilinear portions, or, in the case of a direct transition of the rounded corner portions into the curved portions, the tangents at the point of the transition, have an angle of inclination relative to the surface contour, between 95° and 135°.
摘要翻译：特别适合用作燃料电池堆的互连器或端板的成形部件是通过压制和烧结粉末起始材料来制造的。成形部件具有具有高度为h的多个旋钮状和/或脊状高度的基体。每个仰角具有两个倾斜的侧面，其从高度的端部轮廓通过圆角部分直接或经由中间直线部分以半径r或r'引导成具有半径R或R'的弯曲部分，其又合并到基体的表面轮廓中。直线部分，或者在圆角部分直接转变成弯曲部分的情况下，转变点处的切线在95°和135°之间具有相对于表面轮廓的倾斜角。

2. 发明申请

US20110143261A1 SHAPED PART 有权
标题翻译：形状部分
公开(公告)号：US20110143261A1
公开(公告)日：2011-06-16
申请号：US12969067
申请日：2010-12-15
申请人： Marco Brandner , Stefan Gerzoskovitz , Wolfgang Kraussler , Alexander Leuprecht , Andreas Verskutonis
发明人： Marco Brandner , Stefan Gerzoskovitz , Wolfgang Kraussler , Alexander Leuprecht , Andreas Verskutonis
IPC分类号： H01M8/02
CPC分类号： B22F3/12 , B22F3/02 , B22F5/00 , B22F5/06 , B22F5/08 , C22C27/06 , C22C33/0207 , C22C33/0285 , H01M8/0206 , H01M8/021 , Y02P70/56
摘要： A shaped part that is particularly suited as an interconnector or an end plate for a fuel cell stack, is produced by pressing and sintering a pulverulent starting material. The shaped part has a disc-shaped or plate-shaped basic body with a multiplicity of knob-like and/or ridge-like elevations with a height h. In cross section, each elevation has two inclined side flanks which lead, proceeding from an end contour of the elevation, via rounded corner portions, with a radius r or r′ directly or via intermediate rectilinear portions, into curved portions, with a radius R or R′, which in turn merge into the surface contour, of the basic body. The rectilinear portions, or, in the case of a direct transition of the rounded corner portions, into the curved portions, the tangents at the point of the transition, have an angle of inclination α or α′ with respect to the surface contour, in the range of 95° to 135°. The radius R or R′ is in the range of 0.15 to 1 mm and the height h is dimensioned such that the ratio R:h or R′:h is in a range of 0.25 to 1.
摘要翻译：特别适合用作燃料电池堆的互连器或端板的成形部件是通过压制和烧结粉末起始材料来制造的。成形部件具有盘形或板状的基体，其具有多个具有高度h的凸起状和/或脊状高度。在横截面中，每个仰角具有两个倾斜侧面，其从高度的端部轮廓经由圆角部分直接或经由中间直线部分以半径r或r'引导到具有半径R的弯曲部分或R'，其又合并到基体的表面轮廓中。直线部分，或者在圆角部分直接转移到曲线部分的情况下，在转变点处的切线相对于表面轮廓具有倾斜角α或α'，在范围为95°至135°。半径R或R'在0.15至1mm的范围内，并且高度h的尺寸使得R:h或R'：h的比值在0.25至1的范围内。

3. 发明申请

US20100233576A1 INTERCONNECTOR FOR A HIGH-TEMPERATURE SOLID ELECTROLYTE FUEL CELL, METHOD OF PRODUCING A FUEL CELL, AND HIGH-TEMPERATURE SOLID ELECTROLYTE FUEL CELL 有权
标题翻译：用于高温固体电解质燃料电池的互连器，制造燃料电池的方法和高温固体电解质燃料电池
公开(公告)号：US20100233576A1
公开(公告)日：2010-09-16
申请号：US12721804
申请日：2010-03-11
申请人： Marco Brandner , Wolfgang Kraussler , Gerhard Leichtfried , Andreas Venskutonis
发明人： Marco Brandner , Wolfgang Kraussler , Gerhard Leichtfried , Andreas Venskutonis
IPC分类号： H01M8/10 , H01M4/64 , B22F3/26 , B22F3/12
CPC分类号： H01M8/0232 , B22F2998/00 , B22F2999/00 , C22C32/00 , H01M8/0245 , H01M2008/1293 , Y02E60/50 , Y02E60/525 , Y02P70/56 , C22C32/0026 , B22F3/11 , B22F2201/01
摘要： An interconnector, or bipolar plate, for a high-temperature solid electrolyte fuel cell is composed of a sintered chromium alloy which has sintering pores and contains >90% by weight of Cr, from 3 to 8% by weight of Fe and optionally from 0.001 to 2% by weight of at least one element of the group of rare earth metals. The chromium alloy contains from 0.1 to 2% by weight of Al and the sintering pores are at least partially filled with an oxidic compound containing Al and Cr. The interconnector has a high impermeability to gas and dimensional stability.
摘要翻译：用于高温固体电解质燃料电池的互连器或双极板由具有烧结孔的烧结铬合金组成，其含有> 90重量％的Cr，3至8重量％的Fe和任选的0.001 至2重量％的稀土金属组中的至少一种元素。铬合金含有0.1至2重量％的Al，并且烧结孔至少部分地填充有含有Al和Cr的氧化化合物。互连器对气体和尺寸稳定性具有很高的不渗透性。

4. 发明授权

US09029044B2 Interconnector for a high-temperature solid electrolyte fuel cell, method of producing a fuel cell, and high-temperature solid electrolyte fuel cell 有权
标题翻译：高温固体电解质燃料电池用互连器，燃料电池的制造方法以及高温固体电解质型燃料电池
公开(公告)号：US09029044B2
公开(公告)日：2015-05-12
申请号：US12721804
申请日：2010-03-11
申请人： Marco Brandner , Wolfgang Kraussler , Gerhard Leichtfried , Andreas Venskutonis
发明人： Marco Brandner , Wolfgang Kraussler , Gerhard Leichtfried , Andreas Venskutonis
IPC分类号： H01M8/10 , H01M8/02 , C22C32/00 , H01M8/12
CPC分类号： H01M8/0232 , B22F2998/00 , B22F2999/00 , C22C32/00 , H01M8/0245 , H01M2008/1293 , Y02E60/50 , Y02E60/525 , Y02P70/56 , C22C32/0026 , B22F3/11 , B22F2201/01
摘要： An interconnector, or bipolar plate, for a high-temperature solid electrolyte fuel cell is composed of a sintered chromium alloy which has sintering pores and contains >90% by weight of Cr, from 3 to 8% by weight of Fe and optionally from 0.001 to 2% by weight of at least one element of the group of rare earth metals. The chromium alloy contains from 0.1 to 2% by weight of Al and the sintering pores are at least partially filled with an oxidic compound containing Al and Cr. The interconnector has a high impermeability to gas and dimensional stability.
摘要翻译：用于高温固体电解质燃料电池的互连器或双极板由具有烧结孔的烧结铬合金组成，其含有> 90重量％的Cr，3至8重量％的Fe和任选的0.001 至2重量％的稀土金属组中的至少一种元素。铬合金含有0.1至2重量％的Al，并且烧结孔至少部分地填充有含有Al和Cr的氧化化合物。互连器对气体和尺寸稳定性具有很高的不渗透性。

5. 发明申请

US20140023957A1 LAYER STRUCTURE AND USE THEREOF TO FORM A CERAMIC LAYER STRUCTURE BETWEEN AN INTERCONNECT AND A CATHODE OF A HIGH-TEMPERATURE FUEL CELL 有权
标题翻译：层状结构及其用于形成高温燃料电池的互连和阴极之间的陶瓷层结构
公开(公告)号：US20140023957A1
公开(公告)日：2014-01-23
申请号：US13985104
申请日：2012-02-14
申请人： Marco Brandner , Johannes Schmid , Andreas Venskutonis , Nikolai Trofimenko , Viktar Sauchuk , Mihails Kusnezoff , Karin Lucke , Alexander Michaelis
发明人： Marco Brandner , Johannes Schmid , Andreas Venskutonis , Nikolai Trofimenko , Viktar Sauchuk , Mihails Kusnezoff , Karin Lucke , Alexander Michaelis
IPC分类号： H01M8/02
CPC分类号： H01M8/0236 , B32B18/00 , C04B35/01 , C04B35/016 , C04B2235/3213 , C04B2235/3227 , C04B2235/3265 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , C04B2235/5436 , C04B2235/763 , C04B2235/768 , C04B2235/786 , C04B2235/79 , C04B2235/80 , C04B2237/34 , C23C24/08 , C23C28/04 , H01M8/021 , H01M8/0217 , H01M8/0228 , H01M2008/1293 , Y02E60/50 , Y02E60/525
摘要： The invention relates to a layer structure which is formed between an interconnect and a cathode of a solid oxide fuel cell and can be used for forming a ceramic layer structure between an interconnect and a cathode. In this respect, the interconnect comprises a metal alloy containing chromium. The object of the present invention is to provide a layer structure between an interconnect and a cathode of a solid oxide fuel cell with which a good protective function (from corrosion and from chromium vaporization), a high electrical conductivity and also a good thermal expansion behavior adapted to the materials of an interconnect and of a cathode can be achieved. The layer structure in the green state is formed by a powdery spinel as well as at least one of the below-named metal oxides CuO, NiO, CoOx and MnOx as a sintering additive and at least one powdery perovskite. In this respect, chromium is not contained in any of these chemical compounds and the portion of spinel contained with the metal oxides as a sintering additive is reduced starting from the side facing the interconnect up to the side facing the cathode and the portion of perovskite is reduced starting from the side facing the cathode in the direction of the side facing the interconnect.
摘要翻译：本发明涉及一种在固体氧化物燃料电池的互连和阴极之间形成的层结构，可用于在互连和阴极之间形成陶瓷层结构。在这方面，互连包括含有铬的金属合金。本发明的目的是提供在固体氧化物燃料电池的互连和阴极之间的层结构，其具有良好的保护功能（来自腐蚀和来自铬蒸发），高导电性和良好的热膨胀性能可以实现适合于互连和阴极的材料。绿色状态的层结构由粉末状尖晶石以及作为烧结添加剂的至少一种以下的金属氧化物CuO，NiO，CoO x，MnO x和至少一种粉状钙钛矿形成。在这方面，这些化合物中不含有铬，作为烧结添加剂的金属氧化物所含的尖晶石部分从面向互连的一面向着面向阴极的一侧开始减少，钙钛矿的部分为从面向互连的一侧的面向阴极的一侧开始减小。

6. 发明授权

US09048498B2 Anode for a high-temperature fuel cell and production thereof 有权
标题翻译：高温燃料电池用阳极及其制造方法
公开(公告)号：US09048498B2
公开(公告)日：2015-06-02
申请号：US13510057
申请日：2010-11-04
申请人： Robert Muecke , Norbert H. Menzler , Hans Peter Buchkremer , Matthias Ruettinger , Marco Brandner , Thomas Franco , Andreas Venskutonis
发明人： Robert Muecke , Norbert H. Menzler , Hans Peter Buchkremer , Matthias Ruettinger , Marco Brandner , Thomas Franco , Andreas Venskutonis
IPC分类号： H01M4/90 , H01M4/04 , H01M4/86 , H01M4/88 , H01M8/12
CPC分类号： H01M4/8636 , H01M4/8652 , H01M4/8825 , H01M4/8885 , H01M4/9016 , H01M2008/1293 , Y02E60/50 , Y02E60/525
摘要： The substrate-supported anode for a high-temperature fuel cell comprises an at least three-layer anode laminate on a metallic substrate. Each of the layers of the anode laminate comprises yttria-stabilized zirconia and nickel, wherein the mean particle size of the nickel decreases from one layer to the next as the distance from the substrate increases. The last layer of the anode laminate, which is provided for contact with the electrolyte, has a root mean square roughness of less than 4 μm. The overall mean pore size of this layer is typically between 0.3 and 1.5 μm. Starting powders having a bimodal particle size distribution of yttria-stabilized zirconia and nickel-containing powder are used at least for the first and second layers of the anode laminate. The mean particle size of the nickel-containing powder is reduced from one layer to the next, whereby it is advantageously no more than 0.5 μm in the last layer of the anode laminate.
摘要翻译：用于高温燃料电池的衬底支撑的阳极包括在金属衬底上的至少三层阳极层叠体。阳极层压板的每个层包括氧化钇稳定的氧化锆和镍，其中随着离开衬底的距离增加，镍的平均粒度从一层下降到下一层。提供用于与电解质接触的阳极层压板的最后层具有小于4μm的均方根粗糙度。该层的总平均孔径通常为0.3-1.5μm。至少对阳极层叠体的第一层和第二层使用具有氧化钇稳定的氧化锆和含镍粉末的双峰粒度分布的起始粉末。含镍粉末的平均粒径从一层减少到下一层，由此在阳极层压板的最后一层中有利地不超过0.5μm。

7. 发明授权

US09472816B2 Molded part 有权
标题翻译：模压件
公开(公告)号：US09472816B2
公开(公告)日：2016-10-18
申请号：US14234037
申请日：2012-07-18
申请人： Marco Brandner , Oliver Hirsch , Wolfgang Kraussler , Thomas Leiter
发明人： Marco Brandner , Oliver Hirsch , Wolfgang Kraussler , Thomas Leiter
IPC分类号： B21C37/02 , H01M8/02 , B22F5/08 , B22F3/02 , B22F3/12 , B22F5/00 , B22F5/06
CPC分类号： H01M8/0247 , B22F3/02 , B22F3/12 , B22F5/00 , B22F5/06 , B22F5/08 , B22F2998/10 , H01M8/0206 , H01M8/021 , H01M8/026 , Y02E60/50 , Y10T428/12201 , B22F2009/045 , B22F3/10
摘要： A powder metallurgical molded part includes a disk or plate-like main body and a row of knob-shaped and/or ridge-shaped elevations in a row direction having a height perpendicular to a main plane of the main body and a cross section with side flanks leading from an outer end contour in height direction of the elevation via rounded corner portions into curved portions with a curve radius. The curve radius merges into the surface contour of the main body and a rectilinear flank portion or tangent of the side flank lying at the point where the rounded corner portion merges into the curved portion is disposed at an angle of inclination to the main plane. At least two different angles of inclination are on the same side of the main body and the at least two different angles of inclination represent at least first and second geometries.
摘要翻译：粉末冶金成型部件包括圆盘或板状主体以及具有与主体的主平面垂直的高度的行方向上的一排旋钮形和/或脊形凸起，以及具有侧面的横截面从通过圆角部分的高度方向的外端轮廓引导到具有曲线半径的弯曲部分的侧面。曲线半径合并到主体的表面轮廓中，并且位于圆角部分合并到弯曲部分中的侧面的直线侧面部分或切线设置成与主平面成倾斜的角度。至少两个不同的倾斜角位于主体的同一侧上，并且至少两个不同的倾斜角至少表示第一和第二几何形状。

8. 发明授权

US09337497B2 Layer structure and use thereof to form a ceramic layer structure between an interconnect and a cathode of a high-temperature fuel cell 有权
标题翻译：层结构及其用途，以在高温燃料电池的互连和阴极之间形成陶瓷层结构
公开(公告)号：US09337497B2
公开(公告)日：2016-05-10
申请号：US13985104
申请日：2012-02-14
申请人： Marco Brandner , Johannes Schmid , Andreas Venskutonis , Nikolai Trofimenko , Viktar Sauchuk , Mihails Kusnezoff , Karin Lucke , Alexander Michaelis
发明人： Marco Brandner , Johannes Schmid , Andreas Venskutonis , Nikolai Trofimenko , Viktar Sauchuk , Mihails Kusnezoff , Karin Lucke , Alexander Michaelis
IPC分类号： H01M8/02 , B32B18/00 , C04B35/01 , C23C24/08 , C23C28/04 , H01M8/12
CPC分类号： H01M8/0236 , B32B18/00 , C04B35/01 , C04B35/016 , C04B2235/3213 , C04B2235/3227 , C04B2235/3265 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , C04B2235/5436 , C04B2235/763 , C04B2235/768 , C04B2235/786 , C04B2235/79 , C04B2235/80 , C04B2237/34 , C23C24/08 , C23C28/04 , H01M8/021 , H01M8/0217 , H01M8/0228 , H01M2008/1293 , Y02E60/50 , Y02E60/525
摘要： The invention relates to a layer structure which is formed between an interconnect and a cathode of a solid oxide fuel cell and can be used for forming a ceramic layer structure between an interconnect and a cathode. In this respect, the interconnect comprises a metal alloy containing chromium. The object of the present invention is to provide a layer structure between an interconnect and a cathode of a solid oxide fuel cell with which a good protective function (from corrosion and from chromium vaporization), a high electrical conductivity and also a good thermal expansion behavior adapted to the materials of an interconnect and of a cathode can be achieved. The layer structure in the green state is formed by a powdery spinel as well as at least one of the below-named metal oxides CuO, NiO, CoOx and MnOx as a sintering additive and at least one powdery perovskite. In this respect, chromium is not contained in any of these chemical compounds and the portion of spinel contained with the metal oxides as a sintering additive is reduced starting from the side facing the interconnect up to the side facing the cathode and the portion of perovskite is reduced starting from the side facing the cathode in the direction of the side facing the interconnect.
摘要翻译：本发明涉及一种在固体氧化物燃料电池的互连和阴极之间形成的层结构，可用于在互连和阴极之间形成陶瓷层结构。在这方面，互连包括含有铬的金属合金。本发明的目的是提供在固体氧化物燃料电池的互连和阴极之间的层结构，其具有良好的保护功能（来自腐蚀和来自铬蒸发），高导电性和良好的热膨胀性能可以实现适合于互连和阴极的材料。绿色状态的层结构由粉末状尖晶石以及作为烧结添加剂的至少一种以下的金属氧化物CuO，NiO，CoO x，MnO x和至少一种粉状钙钛矿形成。在这方面，这些化合物中不含有铬，作为烧结添加剂的金属氧化物所含的尖晶石部分从面向互连的一面向着面向阴极的一侧开始减少，钙钛矿的部分为从面向互连的一侧的面向阴极的一侧开始减小。

9. 发明申请

US20140147692A1 MOLDED PART 有权
标题翻译：模制件
公开(公告)号：US20140147692A1
公开(公告)日：2014-05-29
申请号：US14234037
申请日：2012-07-18
申请人： Marco Brandner , Oliver Hirsch , Wolfgang Kraussler , Thomas Leiter
发明人： Marco Brandner , Oliver Hirsch , Wolfgang Kraussler , Thomas Leiter
IPC分类号： H01M8/02
CPC分类号： H01M8/0247 , B22F3/02 , B22F3/12 , B22F5/00 , B22F5/06 , B22F5/08 , B22F2998/10 , H01M8/0206 , H01M8/021 , H01M8/026 , Y02E60/50 , Y10T428/12201 , B22F2009/045 , B22F3/10
摘要： A powder metallurgical molded part includes a disk or plate-like main body and a row of knob-shaped and/or ridge-shaped elevations in a row direction having a height perpendicular to a main plane of the main body and a cross section with side flanks leading from an outer end contour in height direction of the elevation via rounded corner portions into curved portions with a curve radius. The curve radius merges into the surface contour of the main body and a rectilinear flank portion or tangent of the side flank lying at the point where the rounded corner portion merges into the curved portion is disposed at an angle of inclination to the main plane. At least two different angles of inclination are on the same side of the main body and the at least two different angles of inclination represent at least first and second geometries.
摘要翻译：粉末冶金成型部件包括圆盘或板状主体以及具有与主体的主平面垂直的高度的行方向上的一排旋钮形和/或脊形凸起，以及具有侧面的横截面从通过圆角部分的高度方向的外端轮廓引导到具有曲线半径的弯曲部分的侧面。曲线半径合并到主体的表面轮廓中，并且位于圆角部分合并到弯曲部分中的侧面的直线侧面部分或切线设置成与主平面成倾斜的角度。至少两个不同的倾斜角位于主体的同一侧上，并且至少两个不同的倾斜角至少表示第一和第二几何形状。

10. 发明申请

US20130189606A1 ASSEMBLY FOR A FUEL CELL AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
标题翻译：燃料电池组件及其生产方法
公开(公告)号：US20130189606A1
公开(公告)日：2013-07-25
申请号：US13510080
申请日：2010-11-17
申请人： Matthias Ruettinger , Marco Brandner , Thomas Franco , Andreas Venskutonis , Robert Muecke , Norbert Menzler , Hans Peter Buchkremer
发明人： Matthias Ruettinger , Marco Brandner , Thomas Franco , Andreas Venskutonis , Robert Muecke , Norbert Menzler , Hans Peter Buchkremer
IPC分类号： H01M8/02
CPC分类号： H01M8/0202 , H01M4/8605 , H01M4/8657 , H01M4/8892 , H01M4/9033 , H01M8/1213 , H01M8/1246 , H01M8/1253 , H01M8/126 , Y02E60/525 , Y02P70/56
摘要： The invention relates to an assembly comprising an electrode, an electrolyte, and a carrier substrate. The assembly is suitable for a fuel cell. An adaptation layer for adapting the electrolyte to the electrode is disposed between the electrode and the electrolyte, wherein the mean pore size of the adaptation layer is smaller than the mean pore size of the electrode.
摘要翻译：本发明涉及一种包括电极，电解质和载体衬底的组件。该组件适用于燃料电池。用于使电解质适应电极的适配层设置在电极和电解质之间，其中适应层的平均孔径小于电极的平均孔径。

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