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    • 8. 发明授权
    • Process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer to produce a hydrogenated polymer
    • 在不饱和聚合物中连续氢化碳 - 碳双键以制备氢化聚合物的方法
    • US08314188B2
    • 2012-11-20
    • US12506510
    • 2009-07-21
    • Garry RempelQinmin PanLifeng Zhang
    • Garry RempelQinmin PanLifeng Zhang
    • C08F36/00C08F236/00C08F136/08B01J19/18
    • C08C19/02C08L15/005
    • Proposed is a process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer to produce a hydrogenated polymer, said unsaturated polymer being based on a conjugated diolefin and at least one other copolymerizable monomer, in the presence of a homogeneous or heterogeneous catalyst, wherein said unsaturated polymer, hydrogen and said homogeneous or heterogeneous catalyst is passed through a multistage agitated reactor, comprising a cylindrical, elongated shell having closed ends and separated by baffles into a multiplicity of discrete chambers with access from one chamber to another through concentric circular openings, axially centered with said baffles and a continuous rotatable shaft extending concentric with said baffles within said shell with at least one impeller attached thereto positioned in each chamber, said continuous rotatable shaft and said circular openings providing annular openings and said hydrogenated polymer being withdrawn at the opposite end of the multistage agitated reactor at which the feed is introduced.
    • 提出了在不饱和聚合物中连续氢化碳 - 碳双键以制备氢化聚合物的方法,所述不饱和聚合物基于共轭二烯烃和至少一种其它可共聚单体,在均相或非均相催化剂存在下 ,其中所述不饱和聚合物,氢气和所述均相或非均相催化剂通过多级搅拌反应器,其包括具有封闭端并由挡板分隔成多个离散室的圆柱形细长壳体,所述多个离散室室从一个室通过同心圆 开口,与所述挡板轴向居中,以及与所述壳体内的所述挡板同心延伸的连续可旋转轴,其中至少一个叶片连接到每个室中,所述连续可旋转轴和所述圆形开口提供环形开口,并且所述氢化聚合物在 对手 引入进料的多级搅拌反应器的位置端。
    • 10. 发明申请
    • Photoelectrochemical cell and method of manufacture
    • 光电化学电池及其制造方法
    • US20070119706A1
    • 2007-05-31
    • US11287599
    • 2005-11-28
    • Thomas McNultyLifeng Zhang
    • Thomas McNultyLifeng Zhang
    • C25B9/00
    • C25B1/003H01M14/005Y02P20/134Y02P20/135
    • A photoelectrochemical cell may include a cell housing defining an interior volume with a window affixed to the cell housing for allowing the passage of light into the interior volume of the cell. A polymeric film may be affixed within the interior volume defining an anterior compartment and a posterior compartment within the cell housing. A plurality of semiconductor particles embedded continuously within a through thickness of the polymeric film so that a first respective surface area of the plurality of semiconductor particles is exposed to the anterior portion of the cell and a second respective surface area of the plurality of semiconductor particles is exposed to the posterior portion of the cell. The membrane may be immersed within an electrolyte so that incident radiation on the semiconductor particles causes oxidation and reduction to occur within the cell to produce gaseous hydrogen and oxygen.
    • 光电化学电池可以包括限定具有固定到电池壳体的窗口的内部容积的电池壳体,用于允许光通过电池的内部容积。 聚合物膜可以固定在内部空间中,其限定电池壳体内的前隔室和后隔室。 多个半导体颗粒连续地嵌入到聚合物膜的贯穿厚度内,使得多个半导体颗粒的第一相应表面区域暴露于电池的前部,并且多个半导体颗粒的第二相应表面积为 暴露于细胞的后部。 膜可以浸入电解质中,使得半导体颗粒上的入射辐射导致氧化和还原发生在电池内以产生气态氢和氧。