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1. 发明授权

US4260704A Resins based on novolaks, their production and their use as tackifiers 失效
标题翻译：基于酚醛清漆的树脂，其生产和作为增粘剂的用途
公开(公告)号：US4260704A
公开(公告)日：1981-04-07
申请号：US949417
申请日：1978-10-10
申请人： Manfred Schmidt , Theo Kemperman , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Theo Kemperman , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08L7/00 , C08G8/00 , C08G8/04 , C08G8/12 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L61/12 , C08L101/00 , C08G8/28 , C08L61/14
CPC分类号： C08L21/00 , C08G8/04 , C08L61/12
摘要： Resins having a softening point of from 50.degree. to 130.degree. C., an OH-number of from 250 to 400 and an iodine number of from 90 to 160, obtainable by reacting an alkyl phenol-formaldehyde novolak or an alkyl phenol mixture-formaldehyde novolak under acid-catalysed conditions with a polunuclear phenol or polynuclear phenol mixture and formaldehyde and/or an aliphatic aldehyde or aliphatic aldehyde mixture, the ratio by weight of the alkyl phenol or alkyl phenol mixture to the polynuclear phenol or polynyclear phenol mixture being from 2.2:1 to 1:10.
摘要翻译：软化点为50〜130℃，OH值为250〜400，碘值为90〜160的树脂，可通过使烷基酚 - 甲醛酚醛清漆或烷基苯酚混合物 - 甲醛酚醛清漆在酸催化条件下用聚核苯酚或多核酚混合物和甲醛和/或脂族醛或脂族醛混合物，烷基苯酚或烷基苯酚混合物与多核苯酚或多环苯酚混合物的重量比为2.2 1：1:10。

2. 发明授权

US4182697A Process for the preparation of boron-containing phenol-formaldehyde resins 失效
标题翻译：含硼酚醛树脂的制备方法
公开(公告)号：US4182697A
公开(公告)日：1980-01-08
申请号：US9121
申请日：1979-02-02
申请人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08G8/00 , C08G8/20 , C08G8/28 , C08L21/00 , C08G8/30 , C08G8/32
CPC分类号： C08G8/28 , C08L21/00
摘要： The invention relates to a process for the preparation of boron-containing phenol/formaldehyde resins be reacting diphenylol alkane novolaks with unsaturated fatty acids or fatty acid esters and boron compounds, characterized in that diphenylol alkane novolaks having a molecular weight of from 400 to 1600 are reacted with from 15 to 35 parts by weight of an unsaturated fatty acid or its esters, accompanied by the azeotropic removal of water, and then with from 20 to 100 parts by weight of a boric acid trialkyl ester containing from 1 to 4 carbon atoms per alkyl group or with 14 to 72 parts by weight of a boric acid alkyl ester anhydride of the general formula (RO).sub.2 B--O--B--(OR).sub.2 with 1 to 4 carbon atoms per alkyl group R or with from 10 to 50 parts by weight, preferably from 15 to 20 parts by weight of boron trioxide or with from 18 to 90 parts by weight, preferably from 25 to 36 parts by weight of boric acid in the presence of a C.sub.1 -C.sub.4 alcohol.
摘要翻译：本发明涉及一种制备含硼酚醛树脂的方法，是使二羟甲基烷烃酚醛清漆与不饱和脂肪酸或脂肪酸酯和硼化合物反应，其特征在于分子量为400至1600的二羟甲基烷烃酚醛清漆是与15至35重量份的不饱和脂肪酸或其酯反应，伴随着共沸除去水，然后与20至100重量份含有1至4个碳原子的硼酸三烷基酯或具有14至72重量份的通式（RO）2 BOB-（OR）2的硼酸烷基酯酸酐，每个烷基R为1至4个碳原子或10至50重量份，优选15至20重量份的三氧化硼或18至90重量份，优选25至36重量份的硼酸，在C1-C4醇的存在下。

3. 发明授权

US4073757A Hardenable, boron-containing reinforcing resins for rubber 失效
标题翻译：用于橡胶的可固化的含硼增强树脂
公开(公告)号：US4073757A
公开(公告)日：1978-02-14
申请号：US749456
申请日：1976-12-10
申请人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08L7/00 , C08G8/00 , C08G8/20 , C08G8/28 , C08G79/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08C4/00 , C08G8/32
CPC分类号： C08G8/28 , C08L21/00
摘要： Boron-containing resins suitable for reinforcing rubber are obtained by reacting diphenylol alkane novolaks with boron compounds and unsaturated fatty acids or fatty acid esters.
摘要翻译：适用于增强橡胶的含硼树脂通过二羟甲基烷烃酚醛清漆与硼化合物和不饱和脂肪酸或脂肪酸酯反应获得。

4. 发明授权

US4110119A Release agents 失效
标题翻译：脱模剂
公开(公告)号：US4110119A
公开(公告)日：1978-08-29
申请号：US742201
申请日：1976-11-16
申请人： Gunther Boehmke , Hermann Fries , Erich Esch
发明人： Gunther Boehmke , Hermann Fries , Erich Esch
IPC分类号： B29B13/00 , B29C33/00 , B29C33/60 , B29C37/00 , C10M105/72 , C10N10/02 , C10N10/04 , C10N40/36 , B28B7/38
CPC分类号： B29C33/60 , B29K2021/00 , C10M2219/042
摘要： N-acyl taurides can be used as release agents for reducing the adhesion of mouldings of a rubber or plastics material to the surface of a mould and for preventing sheet-form compounds from sticking together.
摘要翻译： N-酰基牛磺酸盐可用作脱模剂，用于降低橡胶或塑料材料的模制品对模具表面的粘附性，并防止片状化合物粘在一起。

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