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1. 发明申请

US20050090684A1 Chiral copper complex and production processes thereof and using the same 失效
标题翻译：手性铜络合物及其制备方法及其使用
公开(公告)号：US20050090684A1
公开(公告)日：2005-04-28
申请号：US10625604
申请日：2003-07-24
申请人： Masashi Kamitamari , Gohfu Suzukamo , Michio Yamamoto , Koji Hagiya , Makoto Itagaki
发明人： Masashi Kamitamari , Gohfu Suzukamo , Michio Yamamoto , Koji Hagiya , Makoto Itagaki
IPC分类号： C07C205/22 , C07C67/347 , C07C251/24 , C07C251/02
CPC分类号： C07C251/24 , C07B2200/07 , C07C67/347 , C07C2601/02 , C07C69/747 , C07C69/74
摘要： There is disclosed an optically active salicylideneaminoalcohol compound of formula (1): wherein R1 represents an alkyl group or the like, R2 represents an aryl group and the like, and when X1 represents a nitro, X2 is a hydrogen atom, when X1 represents a chlorine atom, X2 is a chlorine atom, and when X1 is a hydrogen atom, X2 is a fluorine atom; and the carbon atom denoted by “*” is an asymmetric carbon atom having either an S or R configuration, and a chiral copper complex produced from the optically active salicylidenaminoalcohol compound and a copper compound.
摘要翻译：公开了式（1）的光学活性亚水杨基氨基醇化合物：其中R 1代表烷基等，R 2代表芳基等，和当X 1代表硝基时，X 2是氢原子，当X 1表示氯原子时，X 2是氢原子， SUB>是氯原子，当X 1是氢原子时，X 2是氟原子; 并且由“*”表示的碳原子是具有S或R构型的不对称碳原子和由光学活性水杨酰氨基醇化合物和铜化合物制备的手性铜络合物。

2. 发明授权

US06858559B2 Asymmetric copper complex and cyclopropanation reaction using the same 失效
标题翻译：不对称铜络合物和环丙烷化反应使用相同
公开(公告)号：US06858559B2
公开(公告)日：2005-02-22
申请号：US10128237
申请日：2002-04-24
申请人： Michio Yamamoto , Gohfu Suzukamo , Makoto Itagaki
发明人： Michio Yamamoto , Gohfu Suzukamo , Makoto Itagaki
IPC分类号： C07F1/08 , B01J27/06 , B01J31/02 , B01J31/18 , C07C67/347 , C07F1/00 , B01J31/00
CPC分类号： C07F1/005 , B01J27/06 , B01J31/0231 , B01J31/182 , B01J2231/325 , B01J2531/16 , C07B2200/07 , C07C67/347 , C07C69/74 , C07C69/747
摘要： Disclosed is an asymmetric copper catalyst composition comprising, as components, (a) an optically active bisoxazoline compound of formula (1): wherein R1 and R2 are different and each represents a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, R3 and R4 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, or R3 and R4 may be bonded to each other to form a C3-5 cyclic alkylene group, R5 represents a hydrogen atom or a C1-6 alkyl group, or the two R5 groups may be bonded to each other to represent a C3-5 cyclic alkylene group, (b) a monovalent or divalent copper compound, and (c) a strong acid or a Lewis acid or a mixture thereof, and a process for producing an optically active cyclopropanecarboxylate using the same.
摘要翻译：公开了一种不对称铜催化剂组合物，其包含作为组分的（a）式（1）的光学活性双恶唑啉化合物：其中R 1和R 2不同，并且各自表示氢原子，烷基，环烷基基团或可被取代的苯基或芳烷基，R 3和R 4各自表示氢原子，烷基，环烷基或可被取代的苯基或芳烷基， 3>和R 4可以彼此键合以形成C 3-5环状亚烷基，R 5表示氢原子或C 1-6烷基，或者两个R 5基团可以键合彼此表示C3-5环状亚烷基，（b）单价或二价铜化合物，和（c）强酸或路易斯酸或其混合物，以及使用该方法制备光学活性环丙烷羧酸酯的方法相同。

3. 发明授权

US06670500B2 Chiral copper complex and production processes thereof and using the same 有权
标题翻译：手性铜络合物及其制备方法及其使用
公开(公告)号：US06670500B2
公开(公告)日：2003-12-30
申请号：US09766575
申请日：2001-01-23
申请人： Masashi Kamitamari , Gohfu Suzukamo , Michio Yamamoto , Koji Hagiya , Makoto Itagaki
发明人： Masashi Kamitamari , Gohfu Suzukamo , Michio Yamamoto , Koji Hagiya , Makoto Itagaki
IPC分类号： C07C25124
CPC分类号： C07C251/24 , C07B2200/07 , C07C67/347 , C07C2601/02 , C07C69/747 , C07C69/74
摘要： There is disclosed an optically active salicylideneaminoalcohol compound of formula (1): wherein R1 represents an alkyl group or the like, R2 represents an aryl group and the like, and when X1 represents a nitro, X2 is a hydrogen atom, when X1 represents a chlorine atom, X2 is a chlorine atom, and when X1 is a hydrogen atom, X2 is a fluorine atom; and the carbon atom denoted by “*” is an asymmetric carbon atom having either an S or R configuration, and a chiral copper complex produced from the optically active salicylidenaminoalcohol compound and a copper compound.
摘要翻译：公开了式（1）的光学活性亚水杨基氨基醇化合物：其中R1表示烷基等，R2表示芳基等，当X1表示硝基时，X2表示氢原子，当X1表示氯原子时 X2是氯原子，当X1是氢原子时，X2是氟原子; 由“*”表示的碳原子是具有S或R构型的不对称碳原子和由光学活性水杨酰氨基醇化合物和铜化合物制备的手性铜络合物。

4. 发明授权

US5349115A Dimerization of low .alpha.-olefins 失效
标题翻译：低α-烯烃的二聚
公开(公告)号：US5349115A
公开(公告)日：1994-09-20
申请号：US57843
申请日：1993-05-07
申请人： Kotohiro Nomura , Masaru Ishino , Michio Yamamoto , Gohfu Suzukamo , Makoto Itagaki
发明人： Kotohiro Nomura , Masaru Ishino , Michio Yamamoto , Gohfu Suzukamo , Makoto Itagaki
IPC分类号： C07C2/36 , C07C2/24
CPC分类号： C07C2/36 , C07C2531/02 , C07C2531/025 , C07C2531/04 , C07C2531/14 , C07C2531/24
摘要： A process for preparing a dimer of a lower .alpha.-olefin in the presence of Catalyst (A) containing a nickel compound, a trialkylaluminum, a halogenated phenol, a phosphorus compound and a sulfur compound, Catalyst (B) containing a nickel compound, a trialkylaluminum, a fluorinated isopropyl alcohol, a phosphorus compound, a sulfonic acid and water, or Catalyst (C) containing a nickel compound, a trialkylaluminum, a halogenated phenol, a phosphorus compound, a sulfonic acid and water, by which method, the dimer of the lower .alpha.-olefin is prepared in a high yield and high selectivity.
摘要翻译：在含有镍化合物，三烷基铝，卤代酚，磷化合物和硫化合物的催化剂（A）存在下制备低级α-烯烃的二聚体的方法，含有镍化合物的催化剂（B），三烷基铝，氟化异丙醇，磷化合物，磺酸和水，或含有镍化合物，三烷基铝，卤化苯酚，磷化合物，磺酸和水的催化剂（C），通过该方法，二聚体的低级α-烯烃以高产率和高选择性制备。

5. 发明授权

US06388160B1 Method for producing of 2,3-dimethylbutene-1 and 2,3-dimethylbutene-2 失效
标题翻译： 2,3-二甲基丁烯-1和2,3-二甲基丁烯-2的制备方法
公开(公告)号：US06388160B1
公开(公告)日：2002-05-14
申请号：US09577840
申请日：2000-05-25
申请人： Makoto Itagaki , Gohfu Suzukamo , Michio Yamamoto
发明人： Makoto Itagaki , Gohfu Suzukamo , Michio Yamamoto
IPC分类号： C07C200
CPC分类号： C07C11/107 , B01J31/0202 , B01J31/0232 , B01J31/143 , B01J31/2404 , B01J2231/52 , B01J2531/847 , C07C2/36 , C07C2527/128 , C07C2531/02 , C07C2531/025 , C07C2531/04 , C07C2531/10 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： There is disclosed a method for producing 2,3-dimethylbutene-1 and 2,3-dimethylbutene-2, which is characterized by the steps of (a) dimerizing propylene in a propylene-dimerization step using a nickel complex catalyst as described below as a propylene-dimerization catalyst having propylene-dimerization activity and DMB-1 selectivity, (b) rectifying the resulting reaction solution to obtain 2,3-dimethylbutene-1 as a distillate and a distillation residue containing 2,3-dimethylbutene-1 in a 2,3-dimethylbutene-1 distillation step, (c) allowing the distillation residue to contact with sulfuric acid, sulfonic acid or hetetopolyacid to isomerize 2,3-dimethylbutene-1 in said distillation residue into 2,3-dimethylbutene-2 in an isomerization step, and (d) rectifying the resulting isomerization reaction solution to obtain 2,3-dimethylbutene-2 in a 2,3-dimethylbutene-2 distillation step, wherein said nickel complex catalyst containing (A) at least one nickel compound and the like, (B) a trialkylaluminum, (C) a trivalent phosphorus compound, (D) a fluorinated isopropanol or a halogenated phenol (E) at least one sulfur compound selected from a sulfonic acid and a dialkylsulfuric acid.
摘要翻译：公开了2,3-二甲基丁烯-1和2,3-二甲基丁烯-2的制备方法，其特征在于以下步骤：（a）使用如下所述的镍络合物催化剂在丙烯二聚步骤中使丙烯二聚具有丙烯二聚活性和DMB-1选择性的丙烯 - 二聚催化剂，（b）将所得反应溶液精馏，得到作为馏出物的2,3-二甲基丁烯-1和含有2,3-二甲基丁烯-1的蒸馏残余物 2,3-二甲基丁烯-1蒸馏步骤，（c）使蒸馏残余物与硫酸，磺酸或氢过氧酸接触，将所述蒸馏残余物中的2,3-二甲基丁烯-1异构化为2,3-二甲基丁烯-2 异构化步骤，和（d）在2,3-二甲基丁烯-2蒸馏步骤中精制所得异构化反应溶液得到2,3-二甲基丁烯-2，其中所述镍络合物催化剂含有（A）至少一种镍化合物和（B）三烷基铝 m，（C）三价磷化合物，（D）氟化异丙醇或卤代苯酚（E）至少一种选自磺酸和二烷基硫酸的硫化合物。

6. 发明授权

US06469198B2 Chiral copper complex catalyst composition and asymmetric production process using the same 失效
标题翻译：手性铜络合物催化剂组成和不对称生产工艺使用相同
公开(公告)号：US06469198B2
公开(公告)日：2002-10-22
申请号：US09766579
申请日：2001-01-23
申请人： Gohfu Suzukamo , Makoto Itagaki , Michio Yamamoto
发明人： Gohfu Suzukamo , Makoto Itagaki , Michio Yamamoto
IPC分类号： C07C6974
CPC分类号： C07C251/24 , C07B2200/07 , C07C67/347 , C07C2601/02 , C07C69/74 , C07C69/747
摘要： There is disclosed chiral copper complex catalyst composition, which is obtained by contacting an optically active N-salicylideneaminoalcohol compound of formula (1): with a mono-valent or di-valent copper compound in an inert solvent, wherein R1 and R2 represent an alkyl group and the like, X1 and X2 represent a hydrogen atom, a halogen atom, a nitro group, an alkyl group, an alkoxy group, a cyano group or the like, and the amount of the mono-valent or di-valent copper compound is less than 1 mole per 1 mole of the optically active N-salicylideneaminoalcohol compound of formula (1), and a process for producing an optically active cylopropane-carboxylic acid ester using the same.
摘要翻译：公开了通过使式（1）的光学活性N-亚水杨基氨基醇化合物与一价或二价铜化合物在惰性溶剂中接触而获得的手性铜络合物催化剂组合物，其中R 1和R 2表示烷基基团等，X 1和X 2表示氢原子，卤素原子，硝基，烷基，烷氧基，氰基等，一价或二价铜化合物的量为相对于1摩尔式（1）的光学活性N-亚水杨基氨基醇化合物小于1摩尔，以及使用其制备光学活性的环丙烷 - 羧酸酯的方法。

7. 发明授权

US07009079B2 Chiral copper complex and production processes thereof and using the same 失效
标题翻译：手性铜络合物及其制备方法及其使用
公开(公告)号：US07009079B2
公开(公告)日：2006-03-07
申请号：US10625604
申请日：2003-07-24
申请人： Masashi Kamitamari , Gohfu Suzukamo , Michio Yamamoto , Koji Hagiya , Makoto Itagaki
发明人： Masashi Kamitamari , Gohfu Suzukamo , Michio Yamamoto , Koji Hagiya , Makoto Itagaki
IPC分类号： C07C251/24
CPC分类号： C07C251/24 , C07B2200/07 , C07C67/347 , C07C2601/02 , C07C69/747 , C07C69/74
摘要： There is disclosed an optically active salicylideneaminoalcohol compound of formula (1): wherein R1 represents an alkyl group or the like, R2 represents an aryl group and the like, and when X1 represents a nitro, X2 is a hydrogen atom, when X1 represents a chlorine atom, X2 is a chlorine atom, and when X1 is a hydrogen atom, X2 is a fluorine atom; and the carbon atom denoted by “*” is an asymmetric carbon atom having either an S or R configuration, and a chiral copper complex produced from the optically active salicylidenaminoalcohol compound and a copper compound.
摘要翻译：公开了式（1）的光学活性亚水杨基氨基醇化合物：其中R 1代表烷基等，R 2代表芳基等，和当X 1代表硝基时，X 2是氢原子，当X 1表示氯原子时，X 2是氢原子， SUB>是氯原子，当X 1是氢原子时，X 2是氟原子; 并且由“*”表示的碳原子是具有S或R构型的不对称碳原子和由光学活性水杨酰氨基醇化合物和铜化合物制备的手性铜络合物。

8. 发明授权

US06410741B1 Optically active bisoxazoline compounds, production and use thereof 失效
标题翻译：光学活性的双恶唑啉化合物，其生产和使用
公开(公告)号：US06410741B1
公开(公告)日：2002-06-25
申请号：US09563914
申请日：2000-05-04
申请人： Makoto Itagaki , Gohfu Suzukamo
发明人： Makoto Itagaki , Gohfu Suzukamo
IPC分类号： C07D26308
CPC分类号： C07D263/12 , C07B2200/07 , C07C67/347 , C07C69/743 , C07C233/18
摘要： An optically active bisoxazoline compound of the formula [I]: wherein R1 represents alkyl group, cycloalkyl group, aralkyl group, phenyl group which may be substituted or alkoxy group and two geminal alkyl groups may be joined together to form a cyclic structure; R2 represents alkyl group, cycloalkyl group, aralkyl group, phenyl group which may be substituted; R3 represents hydrogen atom, (C2-C4)alkyl group or cycloalkyl group; and the asterisk * represents an asymmetric carbon atom
摘要翻译：式[I]的光学活性双恶唑啉化合物：其中R 1表示烷基，环烷基，芳烷基，可被取代的苯基或烷氧基和两个偕烷基可以连接在一起形成环状结构; R 2表示烷基，环烷基，芳烷基，可被取代的苯基; R3表示氢原子，（C2-C4）烷基或环烷基; 星号*表示不对称碳原子

9. 发明授权

US6072081A Optically active bisoxazoline compounds, production and use thereof 有权
标题翻译：光学活性的双恶唑啉化合物，其生产和使用
公开(公告)号：US6072081A
公开(公告)日：2000-06-06
申请号：US128971
申请日：1998-08-04
申请人： Makoto Itagaki , Gohfu Suzukamo
发明人： Makoto Itagaki , Gohfu Suzukamo
IPC分类号： C07C67/347 , C07C69/743 , C07C233/18 , C07D263/12 , C07C69/74
CPC分类号： C07D263/12 , C07C233/18 , C07C67/347 , C07C69/743 , C07B2200/07
摘要： An optically active bisoxazoline compound of the formula [I]: ##STR1## wherein R.sub.1 represents alkyl group, cycloalkyl group, aralkyl group, phenyl group which may be substituted or alkoxy group and two geminal alkyl groups may be joined together to form a cyclic structure;R.sub.2 represents alkyl group, cycloalkyl group, aralkyl group, phenyl group which may be substituted;R.sub.3 represents hydrogen atom, (C2-C4)alkyl group or cycloalkyl group; andthe asterisk * represents an asymmetric carbon atom.
摘要翻译：式[I]的光学活性双恶唑啉化合物：其中R1表示烷基，环烷基，芳烷基，可被取代的苯基或烷氧基和两个偕烷基可以连接在一起形成环状结构; R2代表烷基，环烷基，芳烷基，可被取代的苯基; R3表示氢原子，（C2-C4）烷基或环烷基; 星号*表示不对称碳原子。

10. 发明授权

US6011169A Process for producing optically active cyclopropanecaboxylic acid esters 失效
标题翻译：光学活性环丙烷甲酸酯的制备方法
公开(公告)号：US6011169A
公开(公告)日：2000-01-04
申请号：US113502
申请日：1998-07-10
申请人： Makoto Itagaki , Gohfu Suzukamo
发明人： Makoto Itagaki , Gohfu Suzukamo
IPC分类号： C07C67/347 , C07C69/74
CPC分类号： C07C67/347
摘要： A process for producing an optically active cyclopropanecarboxylic acid ester which is characterized by reacting a prochiral olefin with a diazoacetic acid ester in the presence of a copper complex obtained by reacting an optically active bisoxazoline ligand with a copper compound.
摘要翻译：一种光学活性环丙烷羧酸酯的制备方法，其特征在于使前手性烯烃与重氮乙酸酯在光学活性双恶唑啉配体与铜化合物反应得到的铜络合物存在下反应。

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