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1. 发明申请

US20120202954A1 Synthesis of Chabazite-Containing Molecular Sieves and Their Use in the Conversion of Oxygenates to Olefins 有权
标题翻译：含有含异噻唑啉的分子筛的合成及其在烯烃转化中的应用
公开(公告)号：US20120202954A1
公开(公告)日：2012-08-09
申请号：US13449424
申请日：2012-04-18
申请人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R.M. Martens , Mobae Afeworki
发明人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R.M. Martens , Mobae Afeworki
IPC分类号： C08F10/02 , C08F10/06 , C08F2/00
CPC分类号： C07C1/20 , B01J29/85 , B01J29/90 , B01J2229/42 , C01B39/54 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.
摘要翻译：在合成具有90％+ CHA骨架类型特征的硅铝磷酸盐分子筛的方法中，制备反应混合物，其包括首先将活性的铝源与磷的反应源混合以形成老化的初级混合物。然后可以加入硅的反应性源和用于引导分子筛形成的模板以形成合成混合物。然后在合成混合物中诱导结晶。有利地，（i）硅源包含有机硅酸盐，（ii）磷源任选地包含有机磷酸盐，和（iii）结晶的硅铝磷酸盐分子筛具有使其平均晶体尺寸不大于5的晶体尺寸分布 μm。分子筛可以优选用于烃（含氧化合物 - 烯烃）转化过程中。

2. 发明授权

US08293854B2 Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
公开(公告)号：US08293854B2
公开(公告)日：2012-10-23
申请号：US13449424
申请日：2012-04-18
申请人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R. M. Martens , Mobae Afeworki
发明人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R. M. Martens , Mobae Afeworki
IPC分类号： C08F2/00 , C01B37/08 , B01J27/182
CPC分类号： C07C1/20 , B01J29/85 , B01J29/90 , B01J2229/42 , C01B39/54 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

3. 发明授权

US08182780B2 Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途
公开(公告)号：US08182780B2
公开(公告)日：2012-05-22
申请号：US12477750
申请日：2009-06-03
申请人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R. M. Martens , Mobae Afeworki
发明人： Machteld M. Mertens , Stephen N. Vaughn , Guang Cao , Luc R. M. Martens , Mobae Afeworki
IPC分类号： C01B37/08 , B01J27/182 , C07C1/24
CPC分类号： C07C1/20 , B01J29/85 , B01J29/90 , B01J2229/42 , C01B39/54 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.
摘要翻译：在合成具有90％+ CHA骨架类型特征的硅铝磷酸盐分子筛的方法中，制备反应混合物，其包括首先将活性的铝源与磷的反应源混合以形成老化的初级混合物。然后可以加入硅的反应性源和用于引导分子筛形成的模板以形成合成混合物。然后在合成混合物中诱导结晶。有利地，（i）硅源包含有机硅酸盐，（ii）磷源任选地包含有机磷酸盐，和（iii）结晶的硅铝磷酸盐分子筛具有使其平均晶体尺寸不大于5的晶体尺寸分布 μm。分子筛可以优选用于烃（含氧化合物 - 烯烃）转化过程中。

4. 发明授权

US07094389B2 Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛，其合成及其在含氧化合物转化为烯烃中的应用
公开(公告)号：US07094389B2
公开(公告)日：2006-08-22
申请号：US11017286
申请日：2004-12-20
申请人： Guang Cao , Machteld M. Mertens , Karl G. Strohmaier , Richard B. Hall , Thomas Herman Colle , Mobae Afeworki , Antonie J. Bons , Wilfried J. Mortier , Chris Kliewer , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder
发明人： Guang Cao , Machteld M. Mertens , Karl G. Strohmaier , Richard B. Hall , Thomas Herman Colle , Mobae Afeworki , Antonie J. Bons , Wilfried J. Mortier , Chris Kliewer , Hailian Li , Anil S. Guram , Robert J. Saxton , Mark T. Muraoka , Jeffrey C. Yoder
IPC分类号： C01B39/48
CPC分类号： C01B39/46 , C01B37/02 , C01B39/023 , C01B39/48 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：基本上不含骨架磷的结晶物质，其包含具有堆垛层错的CHA骨架型分子筛或CHA骨架型分子筛和AEI骨架型分子筛的至少一个共生相，其中所述材料以其煅烧的无水形式具有涉及摩尔关系的组成：<？in-line-formula description =“In-line Formulas”end =“lead”？>（n）X＆lt; 2＆lt; 3＆lt; 3＆其中X是三价元素;其中X是三价元素;其中X是三价元素; Y是四价元素; 且n为0至约0.5。该材料在甲醇转化为低级烯烃，特别是乙烯和丙烯时具有活性和选择性。

5. 发明申请

US20050154244A1 Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛，其合成及其在含氧化合物转化为烯烃中的应用
公开(公告)号：US20050154244A1
公开(公告)日：2005-07-14
申请号：US11017286
申请日：2004-12-20
申请人： Guang Cao , Machteld Mertens , Karl Strohmaier , Richard Hall , Thomas Colle , Mobae Afeworki , Antonie Bons , Wilfried Mortier , Chris Kliewer , Hailian Li , Anil Guram , Robert Saxton , Mark Murakoa , Jeffrey Yoder
发明人： Guang Cao , Machteld Mertens , Karl Strohmaier , Richard Hall , Thomas Colle , Mobae Afeworki , Antonie Bons , Wilfried Mortier , Chris Kliewer , Hailian Li , Anil Guram , Robert Saxton , Mark Murakoa , Jeffrey Yoder
IPC分类号： C01B37/02 , C01B39/02 , C01B39/46 , C01B39/48 , C10G3/00 , C07C1/00
CPC分类号： C01B39/46 , C01B37/02 , C01B39/023 , C01B39/48 , C10G3/45 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：基本上不含骨架磷的结晶物质，其包含具有堆垛层错的CHA骨架型分子筛或CHA骨架型分子筛和AEI骨架型分子筛的至少一个共生相，其中所述材料以其煅烧的无水形式具有涉及摩尔关系的组成：<？in-line-formula description =“In-line Formulas”end =“lead”？>（n）X＆lt; 2＆lt; 3＆lt; 3＆其中X是三价元素;其中X是三价元素;其中X是三价元素; Y是四价元素; 且n为0至约0.5。该材料在甲醇转化为低级烯烃，特别是乙烯和丙烯时具有活性和选择性。

6. 发明授权

US07901664B2 Synthesis of aluminophosphate and metalloaluminophosphate molecular sieves 有权
标题翻译：铝磷酸盐和金属铝磷酸盐分子筛的合成
公开(公告)号：US07901664B2
公开(公告)日：2011-03-08
申请号：US12059178
申请日：2008-03-31
申请人： Guang Cao , Mobae Afeworki , Matu J. Shah , Machteld Maria Mertens
发明人： Guang Cao , Mobae Afeworki , Matu J. Shah , Machteld Maria Mertens
IPC分类号： C01B39/04 , C01B39/54 , C07C1/20
CPC分类号： C01B37/08 , B01J29/83 , B01J29/85 , C01B37/04 , C01B39/54 , C07C1/20 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.
摘要翻译：在合成磷酸铝或金属铝磷酸盐分子筛的方法中，提供了合成混合物，其包含水，铝源，磷源，任选的除铝之外的金属源，叔胺和烷基化剂，其能够与所述叔胺反应形成能够引导所述分子筛合成的季铵化合物。将合成混合物保持在足以使烷基化剂与叔胺反应以产生季铵化合物并诱导分子筛结晶的条件下。

7. 发明申请

US20090247802A1 Synthesis Of Aluminophosphate And Metalloaluminophosphate Molecular Sieves 有权
标题翻译：磷酸铝和金属铝磷酸盐分子筛的合成
公开(公告)号：US20090247802A1
公开(公告)日：2009-10-01
申请号：US12059178
申请日：2008-03-31
申请人： Guang Cao , Mobae Afeworki , Matu J. Shah , Machteld Maria Mertens
发明人： Guang Cao , Mobae Afeworki , Matu J. Shah , Machteld Maria Mertens
IPC分类号： C01B25/12 , C07C1/02
CPC分类号： C01B37/08 , B01J29/83 , B01J29/85 , C01B37/04 , C01B39/54 , C07C1/20 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.
摘要翻译：在合成磷酸铝或金属铝磷酸盐分子筛的方法中，提供了合成混合物，其包含水，铝源，磷源，任选的除铝之外的金属源，叔胺和烷基化剂，其能够与所述叔胺反应形成能够引导所述分子筛合成的季铵化合物。将合成混合物保持在足以使烷基化剂与叔胺反应以产生季铵化合物并诱导分子筛结晶的条件下。

8. 发明授权

US07754187B2 Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
标题翻译：含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途
公开(公告)号：US07754187B2
公开(公告)日：2010-07-13
申请号：US11820908
申请日：2007-06-21
申请人： Guang Cao , Machteld M. Mertens , Anil S. Guram , Hailian Li , Jeffrey C. Yoder
发明人： Guang Cao , Machteld M. Mertens , Anil S. Guram , Hailian Li , Jeffrey C. Yoder
IPC分类号： C01B37/02 , C01B39/04
CPC分类号： C01B39/48 , B01J29/70 , B01J29/80 , C01B39/023 , C07C1/20 , Y02P30/42 , C07C11/02
摘要： A method is disclosed of synthesizing a crystalline material comprising a CHA framework type molecular sieve and having a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to less than 0.01. The method comprises preparing a reaction mixture capable of forming said material, said mixture comprising a source of water, a source of an oxide of a tetravalent element Y and optionally a source of an oxide of a trivalent element X, wherein the reaction mixture is substantially free of fluoride ions added as HF; maintaining the reaction mixture under conditions sufficient to form crystals of the crystalline material; and than recovering the crystalline material. The reaction mixture comprises either a specific directing agent for directing the formation of a CHA framework type molecular sieve and/or a H2O:YO2 molar ratio of greater than 20. In one embodiment, the resultant crystalline material is free of stacking faults and/or any intergrown phase with an AEI framework type molecular sieve.
摘要翻译：公开了一种合成包含CHA骨架型分子筛并具有摩尔关系的组成的结晶材料的方法：（n）X 2 O 3：YO 2，其中X是三价元素; Y是四价元素; 并且n为0至小于0.01。该方法包括制备能够形成所述材料的反应混合物，所述混合物包含水源，四价元素Y的氧化物源和任选的三价元素X的氧化物源，其中反应混合物基本上不含氟离子作为HF添加; 在足以形成结晶材料晶体的条件下保持反应混合物; 而不是回收结晶材料。反应混合物包括用于引导形成CHA骨架型分子筛和/或H 2 O:YO 2摩尔比大于20的特定导向剂。在一个实施方案中，所得结晶材料不含堆垛层错和/或任何与AEI框架型分子筛的共生相。

9. 发明申请

US20100022723A1 Synthesis Of Chabazite-Containing Molecular Sieves And Their Use In The Conversion Of Oxygenates To Olefins 审中-公开
标题翻译：含有含异噻唑啉的分子筛的合成及其在烯烃转化中的应用
公开(公告)号：US20100022723A1
公开(公告)日：2010-01-28
申请号：US12477826
申请日：2009-06-03
申请人： Machteld M. Mertens , Guang Cao
发明人： Machteld M. Mertens , Guang Cao
IPC分类号： C08F4/16 , C01B39/04 , C07C5/333 , C07C1/20
CPC分类号： C07C1/20 , B01J29/85 , B01J29/90 , B01J2229/42 , C01B39/54 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： In a method of synthesizing a mostly CHA-type silicoaluminophosphate sieve, a reaction mixture comprises sources of water, silicon, aluminum, phosphorus, and a template. In one aspect, when the reaction mixture Si/Al2 ratio is less than 0.33, crystallization is induced at least 165° C. Advantageously, the sieve so crystallized exhibits a Si/Al2 ratio less than 0.33 and/or at least 0.10 greater than the synthesis mixture Si/Al2 ratio. In another aspect, the aluminum and phosphorus sources are first combined to form a primary mixture that is aged. The silicon source and template can then be added to form the synthesis mixture. After inducing crystallization, in this aspect, both the synthesis mixture and crystallized sieve exhibit a Si/Al2 ratio less than 0.33 and/or the crystallized sieve has an average crystal size not more than 3.0 μm. The molecular sieve from both aspects can be used in a hydrocarbon (oxygenates-to-olefins) conversion process.
摘要翻译：在合成大多数CHA型硅铝磷酸盐筛的方法中，反应混合物包含水，硅，铝，磷和模板的来源。一方面，当反应混合物Si / Al 2比小于0.33时，诱导至少165℃的结晶。有利的是，如此结晶的筛显示Si / Al 2比小于0.33和/或至少0.10 合成混合物Si / Al2比例。另一方面，首先将铝和磷源组合以形成老化的初级混合物。然后可以加入硅源和模板以形成合成混合物。诱导结晶后，在这一方面，合成混合物和结晶化筛都表现出小于0.33的Si / Al 2比例和/或结晶筛的平均晶体尺寸不大于3.0μm。来自两个方面的分子筛可用于烃（含氧化合物 - 烯烃）转化过程。

10. 发明授权

US07253331B2 Molecular sieve catalyst composition, its making and use in conversion processes 有权
标题翻译：分子筛催化剂组成，其制备和用途在转化过程中
公开(公告)号：US07253331B2
公开(公告)日：2007-08-07
申请号：US10844168
申请日：2004-05-12
申请人： Luc R. M. Martens , Marcel J. Janssen , Machteld M. Mertens , An Verberckmoes , Guang Cao
发明人： Luc R. M. Martens , Marcel J. Janssen , Machteld M. Mertens , An Verberckmoes , Guang Cao
IPC分类号： C07C1/00 , B01J27/182 , B01J29/04
CPC分类号： C07C1/20 , B01J29/85 , C10G3/49 , C10G3/56 , C10G3/62 , C10G2300/1022 , C10G2400/20 , Y02P30/20 , Y02P30/42 , Y10S423/30 , Y10S502/514 , C07C11/02
摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock in the presence of a molecular sieve having been synthesized in the presence of a flocculant.
摘要翻译：本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。特别地，本发明涉及在存在已在絮凝剂存在下合成的分子筛的存在下从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的转化方法。

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