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1. 发明授权

US3591657A Blending resin and high transparency high impact strength vinyl chloride polymer blends containing same 失效
标题翻译：混合树脂和高透明度高冲击强度氯乙烯聚合物共混物
公开(公告)号：US3591657A
公开(公告)日：1971-07-06
申请号：US3591657D
申请日：1968-07-19
申请人： MITSUBISHI RAYON CO
发明人： IDE FUMIO , DEGUCHI SEJI
IPC分类号： C08F279/02 , C08L25/10 , C08L27/06 , C08L51/04 , C08F29/24 , C08D9/08 , C08F41/12
CPC分类号： C08F279/02 , C08L27/06 , C08L51/04 , C08L9/06 , C08L25/04 , C08L33/12 , C08F212/08 , C08F220/14 , C08F220/44 , C08L2666/24
摘要： A RESINOUS ADDITIVE CONTAINING A STYRENE, N-BUTYL ACRYLATE AND BUTADIENE-1,3 ELASTOMER IN ADMIXTURE WITH A COPOLYMERIZATE OF STYRENE AND METHYL METHACRYLATE AND/OR ACRYLONITRILE. VINYL CHLORIDE POLYMER COMPOSITIONS CONTAINING THIS RESINOUS ADDITIVE AND HAVING BOTH EXCELLENT TRANSPARENCY AND IMPACT RESISTANCE.

2. 发明授权

US3925510A Vinyl chloride polymer composition 失效
标题翻译：氯乙烯聚合物组合物
公开(公告)号：US3925510A
公开(公告)日：1975-12-09
申请号：US45354374
申请日：1974-03-21
申请人： MITSUBISHI RAYON CO
发明人： IDE FUMIO , KISHIDA KAZUO , HASEGAWA AKIRA
IPC分类号： C08L27/06 , C08L51/00 , C08L51/04 , C08L31/02
CPC分类号： C08L27/06 , C08L51/003 , Y10S525/902 , C08L2666/24
摘要： A thermoplastic vinyl chloride polymer composition superior in processing properties is provided. The composition comprises (I) polyvinyl chloride or a copolymer predominantly comprised of vinyl chloride and (II) a methyl methacrylate composite polymer characterized by the combination of 10 TO 60% OF COMPONENT A consisting essentially of, in polymerized form, 80 to 100% of methyl methacrylate, 0 to 20% of a copolymerizable monoethylenically unsaturated monomer and 0 to 2% of a copolymerizable polyfunctional monomer having at least two ethylenically unsaturated bonds, and having a reduced viscosity of at least 2.0; 40 TO 80% OF COMPONENT B consisting essentially of in polymerized form, 30 to 80% of styrene or substituted styrene and 70 to 20% of an acrylic or methacrylic acid ester, and having a reduced viscosity of not greater than 1.0; and 0 TO 40% OF COMPONENT C consisting essentially of in polymerized form, 80 to 100% of methyl methacrylate, 0 to 20% of a copolymerizable monoethylenically unsaturated monomer, and 0 to 2% of a copolymerizable polyfunctional monomer having at least two ethylenically unsaturated bonds. The methyl methacrylate composite polymer (II) is either a twoor three-stage polymer prepared by the sequential two- or threestage emulsion polymerization procedure.
摘要翻译：提供了加工性能优异的热塑性氯乙烯聚合物组合物。该组合物包含（I）聚氯乙烯或主要由氯乙烯组成的共聚物和（II）甲基丙烯酸甲酯复合聚合物，其特征在于组合物10至60％的组分A，其基本上由聚合形式，80至100％ 0〜20％的可共聚单烯属不饱和单体和0〜2％的具有至少2个烯属不饱和键的可共聚的多官能单体，并且具有至少2的比浓粘度。

3. 发明授权

US3644250A Polyvinyl chloride resin composition having excellent transparency and impact strength 失效
标题翻译：具有优异透明度和抗冲击强度的聚氯乙烯树脂组合物
公开(公告)号：US3644250A
公开(公告)日：1972-02-22
申请号：US3644250D
申请日：1969-07-09
申请人： MITSUBISHI RAYON CO , NITTO CHEMICAL INDUSTRY CO LTD
发明人： IDE FUMIO , OKANO KENJI , DEGUCHI SEIJI
IPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , C08L51/04 , C08F29/22
CPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , C08L51/04 , C08F220/14 , C08F212/08 , C08L2666/24
摘要： PVC resin compositions of improved transparency and impact are obtained by mixing the PVC with a graft polymer. The graft is produced by grafting first styrene and then methyl methacrylate onto an elastomer of butadiene, n-butyl acrylate, and styrene in the proportions shown in the accompanying ternary constitutional diagram. When the monomer(s) used in preparing the aforesaid graft polymer have a small quantity of C10 to C18 saturated fatty acid dissolved therein, the PVC compositions prepared from the graft polymer show further improvements in their properties.
摘要翻译：通过将PVC与接枝聚合物混合，可获得改善透明度和冲击性的PVC树脂组合物。接枝是通过以下列三元结构图所示的比例将第一苯乙烯和甲基丙烯酸甲酯接枝到丁二烯，丙烯酸正丁酯和苯乙烯的弹性体上制备的。当用于制备上述接枝聚合物的单体具有溶解在其中的少量C10至C18饱和脂肪酸时，由接枝聚合物制备的PVC组合物显示出其性能的进一步改进。

4. 发明授权

US3448070A Method for preparing trioxane-styrene and/or norbornylene copolymers and stabilization thereof 失效
标题翻译：三芳基苯乙烯和/或异丙烯共聚物的制备方法及其稳定性
公开(公告)号：US3448070A
公开(公告)日：1969-06-03
申请号：US3448070D
申请日：1966-12-23
申请人： MITSUBISHI RAYON CO
发明人： NAKATSUKA KAZUO , IDE FUMIO , TAKAMURA MASAYOSHI
IPC分类号： C08G2/00 , C08G2/32 , C08G1/20 , C08G1/18
CPC分类号： C08G2/06 , C08G2/10 , C08G2/26 , C08G2/32

5. 发明授权

US3919157A Thermoplastic resin composition having high transparency and high impact strength 失效
标题翻译：具有高透明度和高冲击强度的热塑性树脂组合物
公开(公告)号：US3919157A
公开(公告)日：1975-11-11
申请号：US44189174
申请日：1974-02-12
申请人： MITSUBISHI RAYON CO
发明人： IDE FUMIO , KISHIDA KAZUO , SAKURAI TOSHIO , KAWAKAMI SYOICHI
IPC分类号： C08F279/04 , C08L9/06 , C08L25/08 , C08L33/12 , C08L51/04 , C08L83/04 , C08C11/66 , C08D7/00 , C08F19/18
CPC分类号： C08F279/04 , C08L9/06 , C08L25/08 , C08L33/12 , C08L51/04 , C08L83/04 , C08F2/22 , C08L2666/14 , C08L2666/02
摘要： A novel resin composition having high transparency and high impact strength comprises (I) 97 to 99.99 percent by weight of a resin composed of (A) 10 parts by weight of polybutadiene or a styrene-butadiene rubber containing at least 60 percent by weight of butadiene which has a weight average particle diameter of 0.20 to 0.35 Mu with a particle diameter distribution in the range of 0.05 to 1.5 Mu and a degree of swelling of at least 10, and (B) 15 to 190 parts by weight of a terpolymer of a monomer mixture comprising 30 to 65 percent by weight of styrene, 15 to 68 percent by weight of methyl methacrylate and 2 to 20 percent by weight of acrylonitrile (said resin may be a mixture of (A) and (B) or may be a graft-copolymer of (B) and (A)) and (II) 0.01 to 3 percent by weight of a polyorganosiloxane having a viscosity of 10 to 30 centistokes. From such composition, a transparent and impact resistant molded article can be produced regardless of the molding conditions. Further, the composition, when used in combination with a vinyl chloride polymer, can give an impact resistant resin which is transparent or translucent and has a self-extinguishing property.
摘要翻译：具有高透明度和高冲击强度的新型树脂组合物包含（I）97至99.99重量％的由（A）10重量份的聚丁二烯或含有至少60重量％的丁二烯的苯乙烯 - 丁二烯橡胶组成的树脂其重均粒径为0.20〜0.35μm，粒径分布范围为0.05〜1.5μm，溶胀度为10以上，（B）15〜190重量份的三元共聚物单体混合物，其包含30至65重量％的苯乙烯，15至68重量％的甲基丙烯酸甲酯和2至20重量％的丙烯腈[所述树脂可以是（A）和（B）的混合物，或者可以是接枝（B）和（A）]的共聚物和（II）0.01至3重量％的粘度为10至30厘沲的聚有机硅氧烷。通过这样的组合物，无论成型条件如何，都可以制造透明且耐冲击的模制品。此外，当与氯乙烯聚合物组合使用时，该组合物可以产生透明或半透明并具有自熄性的耐冲击树脂。

6. 发明授权

US3644249A Polyvinyl chloride resin composition having excellent transparency, surface gloss and impact strength 失效
标题翻译：具有优异透明度，表面光泽和抗冲击强度的聚氯乙烯树脂组合物
公开(公告)号：US3644249A
公开(公告)日：1972-02-22
申请号：US3644249D
申请日：1969-07-08
申请人： MITSUBISHI RAYON CO , NITTO CHEMICAL
发明人： IDE FUMIO , OKANO KENJI , DEGUCHI SEIJI
IPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , C08L51/04 , C08F29/22
CPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , C08L51/04 , C08F220/14 , C08F212/08 , C08L2666/24
摘要： PVC resin compositions of improved transparency, surface gloss and impact resistance are obtained by mixing the PVC with a graft polymer. The graft is produced by grafting first methyl methacrylate and then styrene onto an elastomer of butadiene, nbutyl acrylate, and styrene in the proportions shown in the accompanying ternary constitutional diagram. When the monomer(s) used in preparing the aforesaid graft polymer have a small quantity of C10 to C18 saturated fatty acid dissolved therein, the PVC compositions prepared from the graft polymer show further improvements in their properties.
摘要翻译：通过将PVC与接枝聚合物混合，可获得改善透明度，表面光泽和耐冲击性的PVC树脂组合物。接枝是通过以下列三元结构图所示的比例将第一甲基丙烯酸甲酯和苯乙烯接枝到丁二烯，丙烯酸正丁酯和苯乙烯的弹性体上而制备的。当用于制备上述接枝聚合物的单体具有溶解在其中的少量C10至C18饱和脂肪酸时，由接枝聚合物制备的PVC组合物显示出其性能的进一步改进。

7. 发明授权

US3651175A Polyvinyl chloride resin composition having excellent impact resistance and weatherability 失效
标题翻译：聚氯乙烯树脂组合物具有优异的耐冲击性和耐候性
公开(公告)号：US3651175A
公开(公告)日：1972-03-21
申请号：US3651175D
申请日：1970-11-09
申请人： MITSUBISHI RAYON CO
发明人： IDE FUMIO , MIURA MASANOBU
IPC分类号： C08L27/00 , C08F285/00 , C08L1/00 , C08L23/00 , C08L27/06 , C08L27/24 , C08L51/00 , C08L51/02 , C08L101/00 , C08F29/24 , C08F41/12 , C08F45/24
CPC分类号： C08L27/06 , C08F285/00 , C08L27/24 , C08L51/003 , Y10S525/902 , C08L2666/24
摘要： A POLYVINYL CHLORIDE RESIN COMPOSITION HAVING EXCELLENT IMPACE RESISTANCE AND WEATHERABILITY CAN BE OBTAINED BY BLENDING 100 PARTS BY WEIGHT OF A VINYL CHLORIDE POLYMER WITH 5 TO 80 PARTS BY WEIGHT OF A RESIN WHICH COMPRISES 20 TO 80 PARTS BY WEIGHT OF A CORE-CRUST STRUCTURAL CROSSLINKED POLYTALKYL ACRYLATE ELASTOMER (A) AND 80 TO 20 PARTS BY WEIGHT OF A POLYMER (B) OBTAINED BY POLYMERIZATION OF A VINYL MONOMER OR A MIXTURE THEREOF, AT LEAST A PART OF THE MONOMER FOR A POLYMER (B) BEING GRAFTPOLYMERIZED IN THE PRESENCE OF ELASTOMER (A), ELASTOMER (A) BEING OBTAINED BY THE STEPS OF DISSOLVING AN ORGANIC PEROXIDE HAVING A DECOMPOSITION TEMPERATURE HIGHER THAN 60*C. IN A MONOMER COMPRISING 80 TO 100% BY WEIGHT OF AT LEAST ONE ALKYL ACRYLATE WHOSE ALKYL GROUP HAS 1 TO 10 CARBON ATOMS AND 0 TO 20% BY WEIGHT OF A VINYL MONOMER, POLYMERIZING SAID MONOMER IN AN AQUEOUS SOLUTION CONTAINING A WATER SOLUBLE REDOX INITIATOR AND AN EMULSIFIER AT A TEMPERATURE LOWER THAN THE DECOMPOSITION TEMPERATURE OF SAID ORGANIC PEROXIDE TO OBTAIN AN ELASTOMER LATEX, HEATING AND STIRRING SAID ELASTOMER LATEX AT A TEMPERATURE HIGHER THAN THE DECOMPOSITION TEMPERATURE OF SAID ORGANIC PERIOXIDE TO OBTAIN A CROSSLINKED ELASTOMER LATEX ADDING TO A LATEX CONTAINING 100 PARTS BY WEIGHT OF SAID CROSSLINKED ELASTOMER 30 TO 150 PARTS BY WEIGHT OF A MONOMER WHICH COMPRISES 80 TO 100% BY WEIGHT OF AT LEAST ONE ALKYL ACRYLATE WHOSE ALKYL GROUP HAS 1 TO 10 CARBON ATOMS AND 0 TO 20% BH WEIGHT OF A VINYL MONOMER AND IN WHICH AN ORGANIC PEROXIDE HAVING A DECOMPOSITION TEMPERATURE HIGHER THAN 60*C. IS DISSOLVED, SEED POLYMERIZING THE MONOMER WITH A WATER SOLUBLE REDOX INITIATOR AT A TEMPERATURE LOWER THAN 60*C. IN THE PRESENCE OF SAID LATEX CONTAINING CROSSLINKED ELASTOMER AND HEATING THE THUS OBTAINED LATEX TO A TEMPERATURE HIGHER THAN 60*C.

8. 发明授权

US3539542A Process for producing alpha-methylacrylonitrile polymers 失效
标题翻译：制备α-甲基丙烯酸酯聚合物的方法
公开(公告)号：US3539542A
公开(公告)日：1970-11-10
申请号：US3539542D
申请日：1968-03-14
申请人： MITSUBISHI RAYON CO
发明人： NAKATSUKA KAZUO , JOH YASUSHI , KOTAKE YAHIDE , IDE FUMIO
IPC分类号： C08F20/50 , C08F3/78 , C08F15/22
CPC分类号： C08F20/50

9. 发明授权

US3502604A Impact resistant resin compositions and method of production thereof 失效
标题翻译：抗冲击树脂组合物及其生产方法
公开(公告)号：US3502604A
公开(公告)日：1970-03-24
申请号：US3502604D
申请日：1966-12-13
申请人： MITSUBISHI RAYON CO
发明人： NAKATSUKA KAZUO , IDE FUMIO , HANDA RYOJI , DEGUCHI SEIJI
IPC分类号： C08F265/04 , C08L25/04 , C08L27/06 , C08L31/04 , C08L33/06 , C08L51/00 , C08F29/46 , C08F29/38 , C09D5/02
CPC分类号： C08L27/06 , C08F265/04 , C08L25/04 , C08L31/04 , C08L33/06 , C08L51/003 , C08L57/00 , C08L2666/24

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