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1. 发明授权

US09079985B2 Bridged metallocene catalysts 有权
标题翻译：桥接金属茂催化剂
公开(公告)号：US09079985B2
公开(公告)日：2015-07-14
申请号：US13996831
申请日：2011-12-20
申请人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
发明人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
IPC分类号： C08F4/6592 , C08F4/642 , C08F4/643 , C08F10/00 , C08F4/76 , C08F4/659 , B01J31/22 , C07F17/00 , C08F4/52 , C08F110/06 , C08F210/06
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and each R7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在原子团上分支到环戊二烯基的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在原子团分支的C 3 -C 20烃基其中原子是硅原子的环戊二烯基环; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

2. 发明申请

US20140018506A1 BRIDGED METALLOCENE CATALYSTS 有权
标题翻译： BRIDGED METALLOCENE催化剂
公开(公告)号：US20140018506A1
公开(公告)日：2014-01-16
申请号：US13996831
申请日：2011-12-20
申请人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
发明人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
IPC分类号： C08F4/76 , C08F4/52
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and each R7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β-原子处与环戊二烯基环分支的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β-原子处分支到环戊二烯基的C 3 -C 20烃基 β原子是Si原子的环; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

3. 发明申请

US20110306741A1 SYNTHESIS OF SUBSTITUTED TETRAHYDROINDENYL COMPLEXES 失效
标题翻译：取代的四氢萘基二烯化合物的合成
公开(公告)号：US20110306741A1
公开(公告)日：2011-12-15
申请号：US13140455
申请日：2009-12-15
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich , Abbas Razavi
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich , Abbas Razavi
IPC分类号： C08F4/6592 , C07F17/00 , C08F210/06 , C08F10/02 , C08F210/14 , C08F210/08 , C07F7/08 , C08F4/76
CPC分类号： C07F7/0814 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F7/081 , C07F7/0827 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F2420/05 , C08F4/65927
摘要： This invention relates to the synthesis of substituted tetrahydroindenyls and the use of the synthesised complexes in the homo- and co-polymerisation of ethylene and alpha-olefins.
摘要翻译：本发明涉及取代的四氢茚基的合成以及合成的络合物在乙烯和α-烯烃的均聚和共聚合中的用途。

4. 发明授权

US08426613B2 Synthesis of substituted tetrahydroindenyl complexes 失效
标题翻译：取代的四氢茚基配合物的合成
公开(公告)号：US08426613B2
公开(公告)日：2013-04-23
申请号：US13140455
申请日：2009-12-15
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich , Abbas Razavi
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich , Abbas Razavi
IPC分类号： C07C13/64 , C07C13/32 , C07D333/00 , C07D495/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F7/0814 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F7/081 , C07F7/0827 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F10/02 , C08F2420/05 , C08F4/65927
摘要： This invention relates to the synthesis of substituted tetrahydroindenyls and the use of the synthesized complexes in the homo- and co-polymerization of ethylene and alpha-olefins.
摘要翻译：本发明涉及取代的四氢茚基的合成以及合成的络合物在乙烯和α-烯烃的均聚和共聚中的用途。

5. 发明授权

US07446216B2 Halogen substituted metallocene compounds for olefin polymerization 有权
公开(公告)号：US07446216B2
公开(公告)日：2008-11-04
申请号：US11300054
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryahov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryahov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/6392 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound is represented by the formula (1): A2YyMXn-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.

6. 发明授权

US07214747B2 Phosphorus substituted metallocene compounds for olefin polymerization 失效
标题翻译：用于烯烃聚合的磷取代的茂金属化合物
公开(公告)号：US07214747B2
公开(公告)日：2007-05-08
申请号：US11078588
申请日：2005-03-11
申请人： Alexander Z. Voskoboynikov , Denis N. Kazyulkin , Vyatcheslav V. Izmer , Alexey N. Ryabov , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Denis N. Kazyulkin , Vyatcheslav V. Izmer , Alexey N. Ryabov , Jo Ann M. Canich
IPC分类号： C08F4/6192 , C08F4/64 , C07F17/00
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J31/2447 , B01J31/2457 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 Rn where each Rn is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent Rn substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是在茚基配体的两个位置被PR 2 N 2基团取代的茚基配体，其中每个R独立地是烃基，取代的烃基，卤代烃基或取代的卤代烃基取代基，另外 E可以被0,1,2,3,4,5或6个R n取代，其中每个R n独立地是烃基，取代的烃基，卤代烃基取代的卤代烃基，甲硅烷基，取代的甲硅烷基，甲硅烷基或取代的烯基羰基取代基，以及任选地，两个或多个相邻的R n取代基可以连接在一起以形成取代或未取代的，饱和的，部分不饱和的或芳族的环状或多环取代基; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体，或A可以独立地定义为E或X定义; 每个X独立地是一价阴离子配体，或者两者X连接并结合到金属原子以形成金属环，或者两者X连接形成螯合配体，二烯配体或亚烷基配体。

7. 发明授权

US07276567B2 Heterocyclic substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的杂环取代的金属茂化合物
公开(公告)号：US07276567B2
公开(公告)日：2007-10-02
申请号：US11078920
申请日：2005-03-11
申请人： Alexander Z. Voskoboynikov , Artyom Y. Lebedev , Vyatcheslav V. Izmer , Alexey N. Ryabov , Mikhail V. Nikulin , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Artyom Y. Lebedev , Vyatcheslav V. Izmer , Alexey N. Ryabov , Mikhail V. Nikulin , Jo Ann M. Canich
IPC分类号： C08F4/6392 , C08F4/64 , C07F17/00
CPC分类号： C08F10/00 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/06 , C08F4/65925 , C08F4/65927 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/02
摘要： This invention relates to compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition, lanthanide, or actinide metal atom; E is an indenyl ligand substituted in any position with at least one aromatic or pseudoaromatic heterocyclic substituent that is bonded to the indenyl ring through a nitrogen or phosphorous ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl, heterocyclopentadienyl, indenyl, heteroindenyl, fluorenyl, or heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be E; Y is an optional bridging group; y is zero or one; X are, independently, univalent anionic ligands, and provided that when A is E, and y is one, and Y is bonded to the one position of each indenyl ligand, and per indenyl ligand there is only one aromatic heterocyclic or pseudoaromatic heterocyclic that is bonded to the indenyl ligand.
摘要翻译：本发明涉及由下式表示的化合物：其中M是3,4,5或6族过渡态，镧系元素或锕系金属原子; E是在任何位置被取代的茚基配体，其中至少一个芳族或假芳香杂环取代基通过氮或磷环杂原子与茚基环结合; A是取代或未取代的环戊二烯基，杂环戊二烯基，茚基，杂茚基，芴基或异芴基配体或其它单阴离子配体，或者A可以独立地为E; Y是可选的桥接基团; y为零或一; X独立地为单价阴离子配体，并且条件是当A为E且y为1时，并且Y键合到每个茚基配体的一个位置，并且每个茚基配体只有一个芳族杂环或假芳香族杂环，键合到茚基配体。

8. 发明授权

US07763562B2 Heteroatom bridged metallocene compounds for olefin polymerization 有权
标题翻译：异质桥接金属茂化合物用于烯烃聚合
公开(公告)号：US07763562B2
公开(公告)日：2010-07-27
申请号：US11302998
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/6392 , C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , B01J31/2295 , B01J2231/12 , B01J2531/48 , C08F4/65912 , C08F10/06 , C08F110/02 , C08F210/16 , C08F2420/06 , Y10S526/943 , C08F2500/03 , C08F210/14 , C08F2500/01 , C08F110/06 , C08F2500/20 , C08F210/06 , C08F10/00 , C08F4/65927
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）通过茚基环的4,5,6或7位与Y键合的取代或未取代的茚基配体，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

9. 发明授权

US07557171B2 Halogen substituted metallocene compounds for olefin polymerization 失效
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07557171B2
公开(公告)日：2009-07-07
申请号：US11300032
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/76 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi—bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp2 carbon atom at a bondable ring position of the ligand.
摘要翻译：包含过渡金属，与过渡金属键合的第一取代或未取代的茚基或芴基配体的金属茂化合物，与过渡金属键合的第二单离子配体和键合到茚基配体和所述第二单离子配体的二价桥连基团其中所述桥连基团连接到茚基配体的四，五，六或七位，或连接到芴基配体的一个，二个，三个，四个，五个，六个，七个或八个位置，并且其中至少一个第一和第二配体之一包括至少一个与配体的可键合环位置上的任何sp 2碳原子键合的卤素取代基。

10. 发明授权

US07538168B2 Halogen substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07538168B2
公开(公告)日：2009-05-26
申请号：US11300002
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/72 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/941 , Y10S526/943
摘要： A metallocene compound comprises a transition metal and at least one substituted monocyclic or polycyclic arene ligand bonded to the transition metal, wherein said arene ligand comprises at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of an aromatic five-membered ring of said arene ligand.
摘要翻译：金属茂化合物包含过渡金属和至少一个与过渡金属键合的取代的单环或多环芳族配体，其中所述芳族配体包括至少一个卤素取代基，其直接键合到芳族五元环的可键合环位上的sp2碳原子上，所述芳族配体的多元环。

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