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1. 发明授权

US07858717B2 Metallocene compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US07858717B2
公开(公告)日：2010-12-28
申请号：US12225200
申请日：2007-03-05
申请人： Luigi Resconi , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante , Gilberto Moscardi
发明人： Luigi Resconi , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante , Gilberto Moscardi
IPC分类号： C08F4/44
CPC分类号： C07F17/00 , C07F7/0838 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal selected from those belonging to group 3, 4, or to the lanthanide or actinide groups in the Periodic Table of the Elements; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a R, OR, OSO2CF3, OCOR, SR, NR2 or PR2 group; L is a divalent bridging group; R1 and R2, equal to each other, are C1-C40 hydrocarbon radical; R3 is hydrogen or a are C1-C40 hydrocarbon radical and W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥接金属茂化合物，其中：M是选自族3,4中的过渡金属的原子，或元素周期表中的镧系元素或锕系元素基团; X，相同或不同，为氢原子，卤素原子，R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团; L是二价桥基; R1和R2相同，为C1-C40烃基; R3是氢或a是C1-C40烃基，W是芳族5或6元环。

2. 发明授权

US07834205B2 Metallocene compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US07834205B2
公开(公告)日：2010-11-16
申请号：US12226095
申请日：2007-04-06
申请人： Luigi Resconi , Francesca Focante , Davide Balboni , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov
发明人： Luigi Resconi , Francesca Focante , Davide Balboni , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov
IPC分类号： C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C07F7/081 , C07F7/0812 , C08F4/65912 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/15 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F210/14 , C08F210/08
摘要： A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing heteroatoms; L is a divalent bridging group; R1 is a linear C1-C40 hydrocarbon radical optionally containing heteroatoms; T1 and T4 are a oxygen, sulfur atom or a C(R18)3 group; wherein R18, are hydrogen atoms or a C1-C40 hydrocarbon radical; T3 and T4 are C1-C40 hydrocarbon radicals; R4 is a hydrogen atom or a C1-C40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤原子或任选含有杂原子的烃基; L是二价桥基; R1是任选地含有杂原子的直链C 1 -C 40烃基; T1和T4是氧，硫原子或C（R18）3基团; 其中R18为氢原子或C1-C40烃基; T3和T4是C1-C40烃基; R4是氢原子或C1-C40烃基; W是芳族5或6元环。

3. 发明申请

US20090171047A1 Metallocene Compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US20090171047A1
公开(公告)日：2009-07-02
申请号：US12225200
申请日：2007-03-05
申请人： Luigi Resconi , Iiya E. Nifant'Ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante , Gilberto Moscardi
发明人： Luigi Resconi , Iiya E. Nifant'Ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante , Gilberto Moscardi
IPC分类号： C08F4/76 , C07F7/08
CPC分类号： C07F17/00 , C07F7/0838 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal selected from those belonging to group 3, 4, or to the lanthanide or actinide groups in the Periodic Table of the Elements; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a R, OR, OSO2CF3, OCOR, SR, NR2 or PR2 group; L is a divalent bridging group; R1 and R2, equal to each other, are C1-C40 hydrocarbon radical; R3 is hydrogen or a are C1-C40 hydrocarbon radical and W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥接金属茂化合物，其中：M是选自族3,4中的过渡金属的原子，或元素周期表中的镧系元素或锕系元素基团; X，相同或不同，为氢原子，卤素原子，R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团; L是二价桥基; R1和R2相同，为C1-C40烃基; R3是氢或a是C1-C40烃基，W是芳族5或6元环。

4. 发明申请

US20090221772A1 Metallocene Compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US20090221772A1
公开(公告)日：2009-09-03
申请号：US11886617
申请日：2006-03-15
申请人： Marco Sacco , Ilya E. Nifant'Ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante
发明人： Marco Sacco , Ilya E. Nifant'Ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante
IPC分类号： C08F4/64 , C07F7/00 , B01J31/12
CPC分类号： C07F7/0812 , C07D317/70 , C07F17/00 , C08F4/65912 , C08F210/06 , Y10S526/941 , Y10S526/943 , C08F2/001 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing hetematoms; L is a divalent bridging group; R1 is a linear C1C40 hydrocarbon radical optionally containing hetexoatonis; T1, T2, T3 and T4 are an oxygen or sulfur atom or a C(R18)2 group with the proviso that at least one group between T1 and T2 is an oxygen or a sulfur atom; wherein R18, are hydrogen atoms or a C1-C40 hydrocarbon radical; n is 1, 2 or 3; R4 is a hydrogen atom or a C1-C40 hydro carbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤素原子或任选含有蒸气的烃基; L是二价桥基; R1是任选含有hetexoatonis的线性C 1 -C 40烃基; T1，T2，T3和T4是氧或硫原子或C（R18）2基团，条件是T1和T2之间的至少一个基团是氧或硫原子; 其中R18为氢原子或C1-C40烃基; n为1,2或3; R4是氢原子或C1-C40氢碳基团; W是芳族5或6元环。

5. 发明申请

US20090275712A1 Metallocene Compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US20090275712A1
公开(公告)日：2009-11-05
申请号：US12226095
申请日：2007-04-06
申请人： Luigi Resconi , Francesca Focante , Davide Balboni , liya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov
发明人： Luigi Resconi , Francesca Focante , Davide Balboni , liya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov
IPC分类号： C08F4/76 , C07F17/00 , B01J31/12 , B01J31/14 , C08F2/00
CPC分类号： C07F17/00 , C07F7/081 , C07F7/0812 , C08F4/65912 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/15 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F210/14 , C08F210/08
摘要： A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing heteroatoms; L is a divalent bridging group; R1 is a linear C1-C40 hydrocarbon radical optionally containing heteroatoms; T1 and T4 are a oxygen, sulfur atom or a C(R18)3 group; wherein R18, are hydrogen atoms or a C1-C40 hydrocarbon radical; T3 and T4 are C1-C40 hydrocarbon radicals; R4 is a hydrogen atom or a C1-C40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤原子或任选含有杂原子的烃基; L是二价桥基; R1是任选地含有杂原子的直链C 1 -C 40烃基; T1和T4是氧，硫原子或C（R18）3基团; 其中R18为氢原子或C1-C40烃基; T3和T4是C1-C40烃基; R4是氢原子或C1-C40烃基; W是芳族5或6元环。

6. 发明申请

US20090062491A1 Metallocene Compounds 有权
标题翻译：茂金属化合物
公开(公告)号：US20090062491A1
公开(公告)日：2009-03-05
申请号：US11886646
申请日：2006-03-15
申请人： Ilya E. Nifant'ev , Pavel V. Ivchenko , Yoshikuni Okumura , Eleonora Ciaccia , Luigi Resconi
发明人： Ilya E. Nifant'ev , Pavel V. Ivchenko , Yoshikuni Okumura , Eleonora Ciaccia , Luigi Resconi
IPC分类号： C07F3/00 , C08F4/44 , C07F7/00 , C08F4/54
CPC分类号： C07F17/00
摘要： A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon-based group; R1 is a C1-C40 hydrocarbon radical; R2 and R3, form together a condensed 3-7 membered ring; R4 is a hydrogen atom or a C1-C40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥接茂金属化合物，其中：M是过渡金属的原子; X是氢原子，卤原子或烃基; R1是C1-C40烃基; R2和R3一起形成稠合的3-7元环; R4是氢原子或C1-C40烃基; W是芳族5或6元环。

7. 发明授权

US5968863A Process for the preparation of bridged metallocenes 失效
标题翻译：制备桥连金属茂的方法
公开(公告)号：US5968863A
公开(公告)日：1999-10-19
申请号：US599476
申请日：1996-01-23
申请人： Ilya E. Nifant'ev , Pavel V. Ivchenko , Luigi Resconi
发明人： Ilya E. Nifant'ev , Pavel V. Ivchenko , Luigi Resconi
IPC分类号： C07F7/10 , C07F7/00 , C07F7/28 , C07F17/00 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , C07F7/04 , C07F7/08 , C07F7/24
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65927
摘要： It is possible to prepare in high yield and purity the racemic and meso forms of bridged chiral metallocenes with a stereoselective method, by synthesizing the sylil-, germyl- or stannyl-substituted ligands. These compounds can be prepared in their racemic and meso forms, and then selectively transformed in the corresponding metallocenes.
摘要翻译：通过合成西尔基，甲锗烷基或者甲锡烷基取代的配体，可以通过立体选择性方法以高产率和纯度制备桥联手性金属茂的外消旋和内消旋形式。这些化合物可以以其外消旋和内消旋形式制备，然后在相应的金属茂中选择性地转化。

8. 发明授权

US06518386B1 Metallocene compounds, process for their preparation thereof, and their use in catalysts for the polymerization of olefins 有权
标题翻译：茂金属化合物，其制备方法及其在烯烃聚合催化剂中的应用
公开(公告)号：US06518386B1
公开(公告)日：2003-02-11
申请号：US09481047
申请日：2000-01-11
申请人： Luigi Resconi , Fabrizio Piemontesi , Ilya E. Nifant'ev , Pavel V. Ivchenko
发明人： Luigi Resconi , Fabrizio Piemontesi , Ilya E. Nifant'ev , Pavel V. Ivchenko
IPC分类号： C08F11006
CPC分类号： C08F10/06 , C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/61927 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F210/08
摘要： A class of metallocene compounds having two cyclopentadienyl rings bridged by an alkylidene group is disclosed. These metallocene compounds can be suitably used as catalyst components for the polymerization of olefins. In particular, by polymerising propylene in the presence of a catalyst based on these metallocene compounds, polymers having very high isotactic indexes, high molecular weights and narrow molecular weight distributions can be obtained in high yields.
摘要翻译：公开了一类具有由亚烷基桥连的环戊二烯基环的茂金属化合物。这些茂金属化合物可以适合用作烯烃聚合的催化剂组分。特别地，通过在基于这些茂金属化合物的催化剂的存在下聚合丙烯，可以高产率获得具有非常高的全同立构指数，高分子量和窄分子量分布的聚合物。

9. 发明授权

US06051728A Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins 失效
标题翻译：茂金属化合物，其制备方法及其在烯烃聚合催化剂中的应用
公开(公告)号：US06051728A
公开(公告)日：2000-04-18
申请号：US599483
申请日：1996-01-23
申请人： Luigi Resconi , Fabrizio Piemontesi , Ilya E. Nifant'ev , Pavel V. Ivchenko
发明人： Luigi Resconi , Fabrizio Piemontesi , Ilya E. Nifant'ev , Pavel V. Ivchenko
IPC分类号： C07F7/00 , C07F17/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C07F9/00 , C07F11/00
CPC分类号： C08F10/06 , C07F17/00 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A class of metallocene compounds having two substituted cyclopentadienyl rings bridged by an alkylidene group wherein the cyclopentadienyl groups can be indenyl groups. The metallocene compounds have the following structures: ##STR1## The metallocenes are characterized by three principal features: (i) the cyclopentadienyl groups are substituted at the 3-position with a substituent other than hydrogen, while R.sup.2 in the 2-position bears a hydrogen (formula (I)) or is part of a condensed benzene ring (formula (II)); (ii) the bridge is a substituted-methylene bridge, i.e. a methylene group bearing at least one substituent other than hydrogen (R.sup.6 is always different from hydrogen); and (iii) the cyclopentadienyl groups are identically substituted (page 2, line 23). These metallocene compounds can be suitably used as catalyst components for the polymerization of olefins. In particular, by polymerizing propylene in the presence of a catalyst based on these metallocene compounds, polymers having very high isotactic indexes, high molecular weights, and narrow molecular weight distributions can be obtained in high yields. A process for preparing the metallocenes from the corresponding organic ligands is also disclosed.
摘要翻译：一类具有由亚烷基桥连的取代环戊二烯基环的茂金属化合物，其中环戊二烯基可以是茚基。茂金属化合物具有以下结构：金属茂的特征在于三个主要特征：（i）环戊二烯基在3位被氢以外的取代基取代，而2-位的R2带有氢（式（式 I））或是稠合苯环的一部分（式（II））; （ii）桥是取代的亚甲基桥，即具有除氢之外的至少一个取代基的亚甲基（R6总是不同于氢）; 和（iii）环戊二烯基相同取代（第2页，第23行）。这些茂金属化合物可以适合用作烯烃聚合的催化剂组分。特别地，通过在基于这些茂金属化合物的催化剂的存在下聚合丙烯，可以高产率获得具有非常高的全同立构指数，高分子量和窄分子量分布的聚合物。还公开了从相应的有机配体制备金属茂的方法。

10. 发明授权

US06730754B2 Process for producing substantially amorphous propylene-based polymers 失效
标题翻译：生产基本无定形丙烯基聚合物的方法
公开(公告)号：US06730754B2
公开(公告)日：2004-05-04
申请号：US09936832
申请日：2001-09-18
申请人： Luigi Resconi , Simona Guidotti , Giovanni Baruzzi , Cristiano Grandini , Ilya E. Nifant'ev , Igor A. Kashulin , Pavel V. Ivchenko
发明人： Luigi Resconi , Simona Guidotti , Giovanni Baruzzi , Cristiano Grandini , Ilya E. Nifant'ev , Igor A. Kashulin , Pavel V. Ivchenko
IPC分类号： C08F444
CPC分类号： C07F7/0812 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F110/06 , Y10S526/943 , C08F4/6592 , C08F2500/17 , C08F2500/16
摘要： A process for producing substantially amorphous propylene (co)polymers, comprising contacting propylene optionally in the presence of one or more olefins under polymerization conditions with a catalyst system comprising: A) a half sandwich titanium complex wherein the cyclopentadienyl is substituted with one or two heterocyclic rings, according to formula (I): cf formula (I) in claim 1: wherein X is N or P; Z is C, Si or Ge; Y1 is an atom selected from the group consisting of NR7, O, PR7 or S; Y2 is selected from the group consisting of CR8 or Y1 and m is 0 or 1 and B) an activating cocatalyst. The above titanium complex and the ligand useful as intermediates in their synthesis are also described.
摘要翻译：一种制备基本无定形的丙烯（共）聚合物的方法，包括在聚合条件下任选地在一种或多种烯烃的存在下使丙烯与催化剂体系接触，所述催化剂体系包含：A）半夹心钛络合物，其中所述环戊二烯基被一个或两个杂环环，根据式（I）：权利要求1中的式（I）：其中X为N或P; Z是C，Si或Ge; Y 1是选自NR 7，O，PR 7或S的原子; Y 2选自CR 8或Y 1，m为0或1，B）活化助催化剂。还描述了上述钛络合物和在其合成中可用作中间体的配体。

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