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1. 发明申请

US20080194856A1 Silane-based Resins That Can Be Photochemically And/or Thermally Structured, Single-step Method for Their Production, Parent Compounds and Production Methods That Can Be Used for Said Resins 失效
标题翻译：可光化学和/或热结构的硅烷基树脂，它们生产的单步法，母体化合物和可用于所述树脂的生产方法
公开(公告)号：US20080194856A1
公开(公告)日：2008-08-14
申请号：US12029493
申请日：2008-02-12
申请人： Lothar Frohlich , Stephane Jacob , Michael Popall , Ruth Houbertz-Krauss
发明人： Lothar Frohlich , Stephane Jacob , Michael Popall , Ruth Houbertz-Krauss
IPC分类号： C07F7/02
CPC分类号： C08G77/14 , C08G77/20
摘要： A silane resin that can be structured photochemically and/or thermally is obtained by at least partial condensation of a mixture of a) at least one silane compound RaR2bSiX4-a-b wherein R is a group polymerizable photochemically and/or thermally via an organic group by radical or cationic polymerization; R2 is a straight-chain, branched, or cyclic C1-C12 alkyl group; X is identical or different and is a leaving group; a is 1 or 2; b is 0 or 1; a+b is not more than 2; and b) at least one silanediol R12Si(OH)2 wherein R1 is identical or different and is a straight-chain, branched, or cyclic C1-C12 alkyl group or a group polymerizable photochemically and/or thermally via an organic group by radical or cationic polymerization, provided the group does not contain aryl. The silane resins have dielectric properties useful in extremely high frequency applications.
摘要翻译：可通过光化学和/或热结构的硅烷树脂通过a）至少一种硅烷化合物R 2的混合物的至少部分缩合获得，其中R是通过自由基或阳离子聚合通过有机基团光化学和/或热可聚合的基团; R 2是直链，支链或环状C 1 -C 12烷基; X相同或不同，为离去组; a是1或2; b为0或1; a + b不大于2; 和b）至少一种硅烷二醇R 1 2 Si（OH）2 2其中R 1是相同或不同的并且是直链，支链或环状C 1 -C 12烷基或通过自由基或阳离子聚合通过有机基团光学和/或热可聚合的基团，条件是该基团不含芳基。硅烷树脂具有在极高频应用中有用的介电特性。

2. 发明授权

US07687654B2 Silane-based resins that can be photochemically and/or thermally structured, single-step method for their production, parent compounds and production methods that can be used for said resins 失效
标题翻译：可光化学和/或热结构的硅烷基树脂，其制备的单步法，可用于所述树脂的母体化合物和生产方法
公开(公告)号：US07687654B2
公开(公告)日：2010-03-30
申请号：US12029493
申请日：2008-02-12
申请人： Lothar Fröhlich , Stephane Jacob , Michael Popall , Ruth Houbertz-Krauss
发明人： Lothar Fröhlich , Stephane Jacob , Michael Popall , Ruth Houbertz-Krauss
IPC分类号： C07F7/08
CPC分类号： C08G77/14 , C08G77/20
摘要： A silane resin that can be structured photochemically and/or thermally is obtained by at least partial condensation of a mixture of a) at least one silane compound RaR2bSiX4-a-b wherein R is a group polymerizable photochemically and/or thermally via an organic group by radical or cationic polymerization; R2 is a straight-chain, branched, or cyclic C1-C12 alkyl group; X is identical or different and is a leaving group; a is 1 or 2; b is 0 or 1; a+b is not more than 2; and b) at least one silanediol R12Si(OH)2 wherein R1 is identical or different and is a straight-chain, branched, or cyclic C1-C12 alkyl group or a group polymerizable photochemically and/or thermally via an organic group by radical or cationic polymerization, provided the group does not contain aryl. The silane resins have dielectric properties useful in extremely high frequency applications.
摘要翻译：可通过光化学和/或热结构形成的硅烷树脂通过a）至少一种硅烷化合物RaR2bSiX4-ab的混合物的至少部分缩合获得，其中R是通过基团可光化学和/或热通过有机基团可聚合的基团或阳离子聚合; R2是直链，支链或环状的C 1 -C 12烷基; X相同或不同，为离去组; a是1或2; b为0或1; a + b不大于2; 和b）至少一种硅烷二醇R 12 Si（OH）2，其中R 1相同或不同，并且是直链，支链或环状的C 1 -C 12烷基或通过有机基团可光化和/或热自由基或/ 阳离子聚合，条件是该基团不含芳基。硅烷树脂具有在极高频应用中有用的介电特性。

3. 发明申请

US20080073642A1 Semi-Conductor Component, Component, Method for the Production Thereof and Use of Inorganic-Organic Hybrid Polymers for Producng Semi-Conductor Components 有权
标题翻译：半导体组件，组件，其制造方法和用于生产半导体组件的无机 - 有机混合聚合物的使用
公开(公告)号：US20080073642A1
公开(公告)日：2008-03-27
申请号：US11665740
申请日：2005-10-21
申请人： Ruth Houbertz-Krauss , Angelika Schmitt , Gerhard Domann , Michael Popall , Barbara Stadlober , Ursula Haas , Anja Haase
发明人： Ruth Houbertz-Krauss , Angelika Schmitt , Gerhard Domann , Michael Popall , Barbara Stadlober , Ursula Haas , Anja Haase
IPC分类号： H01L51/00 , H01L51/30
CPC分类号： H01L51/0097 , H01L51/0052 , H01L51/0096 , H01L51/0516 , H01L51/0541 , H01L51/0545 , Y02E10/549 , Y02P70/521
摘要： The invention relates to a semiconductor component having a metal-insulator structure (MIS) which contains as basic components a substrate, a layer made of an organic semiconductor material and a dielectric layer as insulator. The substrate and/or the dielectric layer made of an inorganic-organic hybrid polymer is chosen from these basic components. In addition, the invention relates to a method for the production of semiconductor components of this type and also to the use of inorganic-organic hybrid polymers for the production of semiconductor components.
摘要翻译：本发明涉及一种具有金属绝缘体结构（MIS）的半导体元件，该金属绝缘体结构（MIS）作为基底元件包含基底，由有机半导体材料制成的层和作为绝缘体的电介质层。由这些基本组分选择由无机 - 有机杂化聚合物制成的衬底和/或电介质层。此外，本发明涉及这种类型的半导体部件的制造方法，也涉及使用无机 - 有机杂化聚合物来制造半导体部件。

4. 发明申请

US20140051821A1 POLYMERIZABLE COMPOSITIONS, CURED PRODUCTS OBTAINED THEREWITH, AND USE OF THESE MATERIALS 有权
标题翻译：可聚合组合物，获得的固化产品，以及这些材料的使用
公开(公告)号：US20140051821A1
公开(公告)日：2014-02-20
申请号：US13980501
申请日：2011-01-21
申请人： Michael Popall , Ruth Houbertz-Krauss , Sebastien Cochet , Herbert Wolter , Kentaro Ohmori , Tetsuo Sato
发明人： Michael Popall , Ruth Houbertz-Krauss , Sebastien Cochet , Herbert Wolter , Kentaro Ohmori , Tetsuo Sato
IPC分类号： C08G77/20
CPC分类号： C08G77/80 , C08F2/24 , C08F230/08 , C08G77/20 , C08L43/04 , C08L83/04 , C09D183/04 , C08L2666/28
摘要： [Problem] To provide a polymerizable composition having an excellent transparency in near-infrared wavelength and excellent heat resistance, and a method for producing the same.[Means of Solving the Problem] A polymerizable composition includes: a reactive silicone compound obtained by polycondensing a diaryl silicic acid compound of Formula [1] below with a silane compound, selected under compounds of Formula [2] and Formula [2b] below in the presence of an acid or a base; and (b) a compound having at least one polymerizable group selected from the group consisting of alkenyl group and (meth)acryl group, wherein Ar1 and Ar2 are independently a phenyl group optionally substituted with a C1-C6 alkyl group, and X is a group which can undergo a hydrolytic condensation reaction, and wherein Ar3 is naphthyl or anthracyl substituted with at least one group having a polymerizable double bond, or wherein Ar3 is phenyl substituted with at least one group having a polymerizable double bond other than vinyl, or is phenyl substituted with at least two groups having a polymerizable double bond.
摘要翻译：本发明提供一种具有优异的近红外波长透明度和优异耐热性的聚合性组合物及其制造方法。解决问题的手段可聚合组合物包括：通过将下式[1]的二芳基硅酸化合物与下式在式[2]和式[2b]的化合物下选择的硅烷化合物缩聚得到的反应性硅氧烷化合物存在酸或碱; 和（b）具有至少一个选自烯基和（甲基）丙烯酰基的可聚合基团的化合物，其中Ar 1和Ar 2独立地是任选被C 1 -C 6烷基取代的苯基，X是可以进行水解缩合反应的基团，其中Ar 3是被至少一个具有可聚合双键的基团取代的萘基或蒽基，或其中Ar3是被至少一个具有除了乙烯基以外的可聚合双键的基团取代的苯基，或者被至少两个具有可聚合双键的基取代的苯基。

5. 发明授权

US09434818B2 Polymerizable compositions, cured products obtained therewith, and use of these materials 有权
标题翻译：可聚合组合物，由此获得的固化产物，以及这些材料的使用
公开(公告)号：US09434818B2
公开(公告)日：2016-09-06
申请号：US13980501
申请日：2011-01-21
申请人： Michael Popall , Ruth Houbertz-Krauss , Sebastien Cochet , Herbert Wolter , Kentaro Ohmori , Tetsuo Sato
发明人： Michael Popall , Ruth Houbertz-Krauss , Sebastien Cochet , Herbert Wolter , Kentaro Ohmori , Tetsuo Sato
IPC分类号： C08L83/04 , C08G77/20 , C08L43/04 , C08F2/24 , C08F230/08 , C09D183/04 , C08G77/00
CPC分类号： C08G77/80 , C08F2/24 , C08F230/08 , C08G77/20 , C08L43/04 , C08L83/04 , C09D183/04 , C08L2666/28
摘要： [Problem] To provide a polymerizable composition having an excellent transparency in near-infrared wavelength and excellent heat resistance, and a method for producing the same. [Means of Solving the Problem] A polymerizable composition includes: a reactive silicone compound obtained by polycondensing a diaryl silicic acid compound of Formula [1] below with a silane compound, selected under compounds of Formula [2] and Formula [2b] below in the presence of an acid or a base; and (b) a compound having at least one polymerizable group selected from the group consisting of alkenyl group and (meth)acryl group, wherein Ar1 and Ar2 are independently a phenyl group optionally substituted with a C1-C6 alkyl group, and X is a group which can undergo a hydrolytic condensation reaction, and wherein Ar3 is naphthyl or anthracyl substituted with at least one group having a polymerizable double bond, or wherein Ar3 is phenyl substituted with at least one group having a polymerizable double bond other than vinyl, or is phenyl substituted with at least two groups having a polymerizable double bond.
摘要翻译：本发明提供一种具有优异的近红外波长透明度和优异耐热性的聚合性组合物及其制造方法。解决问题的手段可聚合组合物包括：通过将下式[1]的二芳基硅酸化合物与下式在式[2]和式[2b]的化合物下选择的硅烷化合物缩聚得到的反应性硅氧烷化合物存在酸或碱; 和（b）具有至少一个选自烯基和（甲基）丙烯酰基的可聚合基团的化合物，其中Ar 1和Ar 2独立地是任选被C 1 -C 6烷基取代的苯基，X是可以进行水解缩合反应的基团，其中Ar 3是被至少一个具有可聚合双键的基团取代的萘基或蒽基，或其中Ar3是被至少一个具有除了乙烯基以外的可聚合双键的基团取代的苯基，或者被至少两个具有可聚合双键的基取代的苯基。

6. 发明授权

US08017937B2 Semi-conductor component, component, method for the production thereof and use of inorganic-organic hybrid polymers for producng semi-conductor components 有权
标题翻译：半导体部件，部件，其制造方法以及使用无机 - 有机杂化聚合物制造半导体部件
公开(公告)号：US08017937B2
公开(公告)日：2011-09-13
申请号：US11665740
申请日：2005-10-21
申请人： Ruth Houbertz-Krauss , Angelika Schmitt , Gerhard Domann , Michael Popall , Barbara Stadlober , Ursula Haas , Anja Haase
发明人： Ruth Houbertz-Krauss , Angelika Schmitt , Gerhard Domann , Michael Popall , Barbara Stadlober , Ursula Haas , Anja Haase
IPC分类号： H01L51/00
CPC分类号： H01L51/0097 , H01L51/0052 , H01L51/0096 , H01L51/0516 , H01L51/0541 , H01L51/0545 , Y02E10/549 , Y02P70/521
摘要： The invention relates to a semiconductor component having a metal-insulator structure (MIS) which contains as basic components a substrate, a layer made of an organic semiconductor material and a dielectric layer as insulator. The substrate and/or the dielectric layer made of an inorganic-organic hybrid polymer is chosen from these basic components. In addition, the invention relates to a method for the production of semiconductor components of this type and also to the use of inorganic-organic hybrid polymers for the production of semiconductor components.
摘要翻译：本发明涉及一种具有金属绝缘体结构（MIS）的半导体元件，该金属绝缘体结构（MIS）作为基底元件包含基底，由有机半导体材料制成的层和作为绝缘体的电介质层。由这些基本组分选择由无机 - 有机杂化聚合物制成的衬底和/或电介质层。此外，本发明涉及这种类型的半导体部件的制造方法，也涉及使用无机 - 有机杂化聚合物来制造半导体部件。

7. 发明授权

US07348393B2 Silane-based resins that can be photochemically and/or thermally structured single-step method for their production, parent compounds and production methods that can be used for said resins 失效
标题翻译：可以光化学和/或热结构的硅烷基树脂，用于其生产的单步法，可以用于所述树脂的母体化合物和生产方法
公开(公告)号：US07348393B2
公开(公告)日：2008-03-25
申请号：US10491588
申请日：2002-10-04
申请人： Lothar Fröhlich , Stéphane Jacob , Michael Popall , Ruth Houbertz-Krauss
发明人： Lothar Fröhlich , Stéphane Jacob , Michael Popall , Ruth Houbertz-Krauss
IPC分类号： C08G77/20
CPC分类号： C08G77/14 , C08G77/20
摘要： A silane resin that can be structured photochemically and/or thermally is obtained by at least partial condensation of a mixture of a) at least one silane compound RaR2bSiX4-a-b wherein R is a group polymerizable photochemically and/or thermally via an organic rest by radical or cationic polymerization; R2 is a straight-chain, branched, or cyclic C1-C12 alkyl group; X is identical or different and is a leaving group; a is 1 or 2; b is 0 or 1; a+b is not more than 2; and b) at least one silanediol R12Si(OH)2 wherein R1 is identical or different and is a straight-chain, branched, or cyclic C1-C12 alkyl group or a group polymerizable photochemically and/or thermally via an organic rest by radical or cationic polymerization, provided the group does not contain aryl. The silane resins have dielectric properties useful in extremely high frequency applications.
摘要翻译：可通过光化学和/或热结构的硅烷树脂通过a）至少一种硅烷化合物R 2的混合物的至少部分缩合获得，其中R是通过自由基或阳离子聚合通过有机残基可光化学和/或热可聚合的基团; R 2是直链，支链或环状C 1 -C 12烷基; X相同或不同，为离去组; a是1或2; b为0或1; a + b不大于2; 和b）至少一种硅烷二醇R 1 2 Si（OH）2 2其中R 1是相同或不同的并且是直链，支链或环状C 1 -C 12烷基或通过自由基或阳离子聚合通过有机残基可光化和/或热可聚合的基团，条件是该基团不含芳基。硅烷树脂具有在极高频应用中有用的介电特性。

8. 发明申请

US20080069964A1 Transparent Coating Composition and Method for the Production Thereof and Correspondingly Transparent-Coated Substrates 审中-公开
标题翻译：透明涂料组合物及其生产方法和相应的透明涂层基材
公开(公告)号：US20080069964A1
公开(公告)日：2008-03-20
申请号：US11663726
申请日：2005-09-26
申请人： Pelagie Declerck , Birke Olsowski , Ruth Houbertz-Krauss , Michael Popall
发明人： Pelagie Declerck , Birke Olsowski , Ruth Houbertz-Krauss , Michael Popall
IPC分类号： B05D1/02 , B05D1/18 , C08G79/00
CPC分类号： G02B1/11 , C08G77/58 , C09D183/14 , G02B1/10
摘要： The invention relates to a method for the production of a transparent coating composition which is based essentially on a polycondensation reaction. The coating composition produced by this method is based on a completely through-condensed inorganic silicate network whilst the organic network is not yet formed. The invention also relates to a method for coating substrates with coating compositions of this type with formation of a coated substrate in which, in addition to the inorganic network, the organic network is also formed by the curing process. Coating compositions of this type and coated substrates are used widely in all optical fields of application.
摘要翻译：本发明涉及一种基本上基于缩聚反应的透明涂料组合物的制备方法。通过该方法制备的涂料组合物基于完全通过冷凝的无机硅酸盐网络，而有机网络尚未形成。本发明还涉及一种用这种涂层组合物涂覆基材的方法，其形成了涂覆的基材，其中除了无机网络之外，还通过固化方法形成有机网络。这种类型的涂层组合物和涂覆的基材广泛用于所有光学应用领域。

9. 发明申请

US20130056910A1 DEVICE AND METHOD FOR PRODUCING THREE-DIMENSIONAL STRUCTURES 审中-公开
标题翻译：用于生产三维结构的装置和方法
公开(公告)号：US20130056910A1
公开(公告)日：2013-03-07
申请号：US13696966
申请日：2011-05-11
申请人： Ruth Houbertz-Krauss , Thomas Stichel , Soenke Steenhusen
发明人： Ruth Houbertz-Krauss , Thomas Stichel , Soenke Steenhusen
IPC分类号： B29C35/08
CPC分类号： B29C64/273 , B29C64/135 , B29C64/386 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00
摘要： The present invention relates to a device as well as a method for creating three-dimensional structures consisting of a material to be consolidated, in particular a material containing organopolysiloxane, by way of locally selective consolidation of the latter as a result of light-induced organic cross-linking. The device is characterized by a movable focusing optical system for the formation of one or a plurality of laser foci, wherein either the laser beam of a laser source can be introduced into the material to be consolidated through the material container and a movable carrier unit is arranged in said container or the focusing optical system is immersed into the material bath and the laser beams can be introduced into the material to be consolidated via a beam exit area of the focusing optical system. In the method, a focusing optical system that is movable in at least one plane is used for the formation of at least one laser focus, and a movable carrier unit is positioned in the material to be consolidated in one embodiment.
摘要翻译：本发明涉及一种装置以及由待固化的材料，特别是含有有机聚硅氧烷的材料构成的三维结构的方法，其通过局部选择性固结后者作为光诱导的有机物交联。该装置的特征在于用于形成一个或多个激光焦点的可移动聚焦光学系统，其中激光源的激光束可以通过材料容器被引入要被固结的材料中，并且可移动的载体单元是布置在所述容器中或聚焦光学系统被浸入材料浴中，并且可以通过聚焦光学系统的光束出射区域将激光束引入待固化的材料中。在该方法中，可以在至少一个平面中可移动的聚焦光学系统用于形成至少一个激光焦点，并且在一个实施例中可移动的载体单元被定位在待固结的材料中。

10. 发明授权

US09539763B2 Method for generating biocompatible three-dimensional objects or surfaces by laser irradiation, such objects, the use thereof and starting materials for the method 有权
标题翻译：通过激光照射产生生物相容的三维物体或表面的方法，这些物体，其用途和方法的原料
公开(公告)号：US09539763B2
公开(公告)日：2017-01-10
申请号：US13577731
申请日：2011-02-08
申请人： Ruth Houbertz-Krauss , Matthias Beyer , Joern Probst , Thomas Stichel
发明人： Ruth Houbertz-Krauss , Matthias Beyer , Joern Probst , Thomas Stichel
IPC分类号： B29C67/00 , C07H9/04
CPC分类号： B29C67/0066 , B29C64/135 , B33Y70/00 , C07H9/04
摘要： The present invention pertains to a process for producing three-dimensional, self-supporting and/or substrate-supported formed pieces or structures on surfaces by means of site-selective solidification of a liquid to pasty, organic or organically modified material within a bath consisting of this material by means of two- or multiphoton polymerization, whereby the material has at least one compound that has both an organic radical polymerizable via two-photon or multiphoton polymerization and a biocompatible, biodegradable or bioresorbable group, and/or wherein the bath material additionally contains groups or radicals, which are available for an inorganic crosslinking or which are already inorganically crosslinked, providing that both an organic radical polymerizable via two-photon or multiphoton polymerization and a biocompatible, biodegradable or bioresorbable group must be contained in the material. The formed pieces or surface structures according to the present invention are suitable as matrices for binding live cells, which can be multiplied after that or stimulated for the production of specific substances. They can be used, e.g., as an extracorporeal matrix or as an implant.
摘要翻译：本发明涉及一种通过在浴中的液体至糊状，有机或有机改性材料的选择性固化来在表面上生产三维，自支撑和/或基底支撑的成形片或结构的方法，该材料具有至少一种具有可通过双光子或多光子聚合的可自由基聚合的化合物和生物相容的可生物降解或生物可再吸收的基团的化合物，和/或其中所述浴材料另外包含可用于无机交联或已经无机交联的基团或基团，条件是材料中必须包含可通过双光子或多光子聚合反应的有机自由基和生物相容的，可生物降解的或生物可再吸收的基团。根据本发明的形成的片或表面结构适合作为结合活细胞的基质，其可以在之后倍增或刺激以产生特定物质。它们可以用作例如体外基质或植入物。

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