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1. 发明授权

US06710153B2 Method for producing phosphonium phenolates 失效
标题翻译：苯酚酚盐生产方法
公开(公告)号：US06710153B2
公开(公告)日：2004-03-23
申请号：US10168166
申请日：2002-06-17
申请人： Lothar Bunzel , Uwe Hucks , Annett König , Silke Kratschmer
发明人： Lothar Bunzel , Uwe Hucks , Annett König , Silke Kratschmer
IPC分类号： C08G6400
CPC分类号： C08G64/30 , C07C37/00 , C07F9/54 , C07C39/04
摘要： A process for the production of phosphonium phenolates is disclosed. The process entails reacting a phosphonium halide and phenol in an aqueous alkaline solution. The phosphonium phenolate produced is separated from the synthesis mixture by crystallization
摘要翻译：公开了一种生产苯酚鏻的方法。该方法需要在碱性水溶液中使卤化鏻和苯酚反应。通过结晶将生产的苯酚鏻与合成混合物分离

2. 发明授权

US06307006B1 Method for producing branched polycarbonates 失效
标题翻译：支链聚碳酸酯的制备方法
公开(公告)号：US06307006B1
公开(公告)日：2001-10-23
申请号：US09445849
申请日：1999-12-14
申请人： Annett König , Lothar Bunzel , Uwe Hucks
发明人： Annett König , Lothar Bunzel , Uwe Hucks
IPC分类号： C08G6400
CPC分类号： C08G64/1616 , C08G64/30
摘要： A process of producing branched polycarbonates by melt transesterification from at least one diphenol, diaryl carbonate and a branching agent, and in the optional presence of a catalyst is disclosed. The process which is carried out at temperatures between 80 to 400° C. and at pressures between 1 and 0.01 mbar, entails using as branching agent at least one member selected from the group consisting of (i) a specifically structured aliphatic alcohol and (ii) the ether of (i) which is formed by self-condensation.
摘要翻译：公开了通过熔融酯交换从至少一种二酚，碳酸二芳酯和支化剂生产支化聚碳酸酯的方法，以及任选的催化剂存在下的方法。在80至400℃的温度和1至0.01毫巴的压力下进行的方法需要使用至少一种选自（i）特定结构的脂族醇和（ii））通过自缩合形成的（i）的醚。

3. 发明授权

US06476273B2 Method for producing phosphonium phenolates 有权
标题翻译：苯酚酚盐生产方法
公开(公告)号：US06476273B2
公开(公告)日：2002-11-05
申请号：US09446475
申请日：1999-12-21
申请人： Annett König , Lothar Bunzel , Uwe Hucks
发明人： Annett König , Lothar Bunzel , Uwe Hucks
IPC分类号： C07F954
CPC分类号： C07F9/54 , C07C37/00 , C07C39/04
摘要： A process for preparing phosphonium phenolate is disclosed. The process entails a reaction of phosphonium halide with phenol in an aqueous alkaline solution at a temperature of 0 to 55° C. The molar ratio of phenol to phosphonium halide is between 2:1 to 10:1 and the pH of the solution is 9.5 to 11. An optional embodiment entails carrying out the reaction in the further presence of alcohol.
摘要翻译：公开了一种制备酚酞的方法。该方法需要在0至55℃的温度下在碱性水溶液中将卤化鏻与酚反应。苯酚与卤化鏻的摩尔比为2:1至10:1，溶液的pH为9.5 任选的实施方案需要在醇的进一步存在下进行反应。

4. 发明授权

US06646101B2 Use of copolycarbonates 失效
公开(公告)号：US06646101B2
公开(公告)日：2003-11-11
申请号：US10291097
申请日：2002-11-08
申请人： Silke Kratschmer , Klaus Horn , Annett König , Rolf Wehrmann , Steffen Kühling
发明人： Silke Kratschmer , Klaus Horn , Annett König , Rolf Wehrmann , Steffen Kühling
IPC分类号： C08G6400
CPC分类号： C08L51/04 , C08G64/06 , C08L69/00 , Y10T428/31507 , C08L2666/14 , C08L51/00
摘要： The present invention provides the use of impact resistant, stress cracking resistant copolycarbonates with particularly good low temperature properties for applications in which particularly good low temperature properties are required, e.g., for automobile construction or external applications, and new copolycarbonates themselves.

5. 发明授权

US06586556B2 Use of copolycarbonates 失效
公开(公告)号：US06586556B2
公开(公告)日：2003-07-01
申请号：US09962168
申请日：2001-09-24
申请人： Silke Kratschmer , Klaus Horn , Annett König , Rolf Wehrmann , Steffen Kühling
发明人： Silke Kratschmer , Klaus Horn , Annett König , Rolf Wehrmann , Steffen Kühling
IPC分类号： C08G6402
CPC分类号： C08L51/04 , C08G64/06 , C08L69/00 , Y10T428/31507 , C08L2666/14 , C08L51/00
摘要： The present invention provides the use of impact resistant, stress cracking resistant copolycarbonates with particularly good low temperature properties for applications in which particularly good low temperature properties are required, e.g., for automobile construction or external applications, and new copolycarbonates themselves.

6. 发明授权

US06262219B1 Method for producing polycarbonate 失效
标题翻译：聚碳酸酯的制造方法
公开(公告)号：US06262219B1
公开(公告)日：2001-07-17
申请号：US09446852
申请日：1999-12-28
申请人： Annett König , Uwe Hucks , Claus-Ludolf Schultz , Günther Jeromin
发明人： Annett König , Uwe Hucks , Claus-Ludolf Schultz , Günther Jeromin
IPC分类号： C08G6430
CPC分类号： C08G64/307
摘要： The present invention relates to a transesterification method for producing solvent-free polycarbonate, using N-alkyl-substituted piperidines or N-alkyl-substituted morpholines comprising C2-C12 N-alkyl substituents, preferably C2-C8 N-alkyl substituents, most preferably C2-C5 N-alkyl substituents, as catalysts.
摘要翻译：本发明涉及使用N-烷基取代的哌啶或包含C 2 -C 12 N-烷基取代基的N-烷基取代的吗啉，优选C 2 -C 8 N-烷基取代基，最优选C 2 -C 5 N-烷基取代基，作为催化剂。

7. 发明授权

US06218502B1 Copolycarbonates with an indane bisphenol base 失效
标题翻译：具有茚满双酚基的共聚碳酸酯
公开(公告)号：US06218502B1
公开(公告)日：2001-04-17
申请号：US09463720
申请日：2000-02-28
申请人： Stefan Westernacher , Annett König , Jürgen Stebani , Friedrich-Karl Bruder , Wilfried Haese
发明人： Stefan Westernacher , Annett König , Jürgen Stebani , Friedrich-Karl Bruder , Wilfried Haese
IPC分类号： C08G6400
CPC分类号： G11B7/2534 , C08G64/06
摘要： A copolycarbonate having glass transition temperature not higher than 160° C. and a rheooptic constant not higher than 4 is disclosed. Containing structural units conforming to wherein the radicals R1 each independently denotes a C1-12-alkyl radical or a halogen atom and n is 0 to 3, the copolycarbonate is suitable for the preparation of lenses and optical mass storage means.
摘要翻译：公开了玻璃化转变温度不高于160℃，光热常数不高于4的共聚碳酸酯。包含符合其中R1基团的结构单元各自独立地表示C1-12烷基或卤素原子，n为0-3，共聚碳酸酯适用于制备透镜和光学储存装置

8. 发明授权

US06528612B1 Highly branched polycondensates 失效
标题翻译：高分支缩聚物
公开(公告)号：US06528612B1
公开(公告)日：2003-03-04
申请号：US09937190
申请日：2001-09-21
申请人： Axel Brenner , Annett König
发明人： Axel Brenner , Annett König
IPC分类号： C08G6300
CPC分类号： C08G83/005 , C08G63/20 , C08G64/14 , C08G69/26 , C08G69/44
摘要： A highly branched polycondensate is described. The polycondensate is prepared by polycondensating (a) monomers capable of polycondensation in the presence of (b) branching agents, wherein the branching agents are selected from polymers, oligomers consisting of 2 to 100 monomer units and dendritic polymers. The branching agents contain residues of monomers represented by the general formulas, A—R—Bx or Ax—R—B wherein A represents a —C(O)X group, X being hydroxyl, halogen, alkoxy or aralkoxy, each having 1 to 30 carbon atoms, B represents one of (i) an —OY group, Y being hydrogen, trialkyl silyl, alkyl or acyl, each having 1 to 30 carbon atoms, and (ii) an amino group, an ammonium halide or an alkyl carbamate having 1 to 8 carbon atoms, R is an organic aromatic, aliphatic-aromatic or aliphatic radical containing 1 to 25 carbon atoms, and x≧2. Also described are molded articles prepared from the highly branched polycondensate of the present invention.
摘要翻译：描述了高度支化的缩聚物。缩聚物（a）在（b）支化剂存在下缩聚（a）能够缩聚的单体，其中支化剂选自聚合物，由2至100个单体单元和树枝状聚合物组成的低聚物。支化剂含有由通式表示的单体的残基，其中A表示-C（O）X基，X为羟基，卤素，烷氧基或芳烷氧基，各自具有1至30个碳原子，B表示（i） -OY基，Y是氢，三烷基甲硅烷基，烷基或酰基，各自具有1至30个碳原子，和（ii）氨基，卤化铵或具有1至8个碳原子的氨基甲酸烷基酯，R是有机芳族，含有1至25个碳原子的脂族 - 芳族或脂族基团，x≥2。还描述了由本发明的高度支化缩聚物制备的模制品。

9. 发明授权

US06291630B1 Method for producing a liquid formulation of tetraphenylphosphonium phenolate 有权
标题翻译：苯酚四苯基膦液体制剂的制备方法
公开(公告)号：US06291630B1
公开(公告)日：2001-09-18
申请号：US09623635
申请日：2000-09-06
申请人： Annett König , Michael Prein
发明人： Annett König , Michael Prein
IPC分类号： C08G6400
CPC分类号： C08G64/307 , B01J31/0268 , B01J2231/14 , B01J2231/40 , B01J2231/49 , C07C39/235 , C07F9/5442
摘要： A catalyst formulation that is liquid at room temperature and that comprise tetraphenylphosphonium phenolate and phenol is disclosed. The catalyst formulation is suitable as a transesterification catalyst and most especially in the preparation of thermoplastic solvent-free polycarbonates.
摘要翻译：公开了一种在室温下为液体并且包含苯酚四苯基苯酚和苯酚的催化剂制剂。催化剂配方适合作为酯交换催化剂，最特别是在制备无溶剂的聚碳酸酯中。

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