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    • 7. 发明授权
    • Nonlinear optical devices
    • 非线性光学器件
    • US5119228A
    • 1992-06-02
    • US708575
    • 1991-05-31
    • Treliant Fang
    • Treliant Fang
    • C07D251/34C08G73/06G02F1/361
    • C08G73/0655C07D251/34G02F1/3612G02F1/3616Y10T428/31504
    • Optically nonlinear device elements such as directional couplers, switches, frequency stabilizers, optical parametric devices and modulators use as an optically nonlinear element a cross-linked triazine polymer containing a covalently bonded optically nonlinear dye moiety. A specific cross-linked triazine with this dye moiety may be made by cyclotrimerizing a p-(N,N-bis(4'-cyanatobenzyl)amino)-p'-(2,2-dicyanovinyl)azobenzene monomer. During polycyclotrimmerization or cure, the element is subjected to a poling voltage which aligns the dipoles of the dye moiety to give a large useful nonlinear susceptibility.
    • 诸如定向耦合器,开关,频率稳定器,光学参数装置和调制器之类的光学非线性器件元件用作含有共价键合的光学非线性染料部分的交联三嗪聚合物作为光学非线性元件。 具有该染料部分的具体的交联三嗪可以通过对p-(N,N-双(4'-氰基苄基)氨基)-p' - (2,2-二氰基乙烯基)偶氮苯单体进行环化三聚体来制备。 在多环多胺化或固化过程中,该元件经受极化电压,其使染料部分的偶极子对准以产生大的有用的非线性磁化率。