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1. 发明授权

US08460427B2 Method for manufacturing metal nano particles having hollow structure 有权
标题翻译：具有中空结构的金属纳米颗粒的制造方法
公开(公告)号：US08460427B2
公开(公告)日：2013-06-11
申请号：US11873982
申请日：2007-10-17
申请人： Li-Duan Tsai , Kan-Lin Hsueh , Sung-Chun Chang , Man-Yin Lo , Yu-Min Peng , Chun-Chieh Huang , Ru-Shi Liu , Hao-Ming Chen , Hsin-Chieh Peng
发明人： Li-Duan Tsai , Kan-Lin Hsueh , Sung-Chun Chang , Man-Yin Lo , Yu-Min Peng , Chun-Chieh Huang , Ru-Shi Liu , Hao-Ming Chen , Hsin-Chieh Peng
IPC分类号： B22F9/16 , B22F9/18 , B22F9/24
CPC分类号： B22F9/24 , B22F2001/0029 , Y10T428/2982
摘要： A method for manufacturing metal nano particles having a hollow structure is provided. First, a suitable reducing agent is added into a first metal salt solution, and first metal ions are reduced to form first metal nano particles. Next, after the reducing agent is decomposed, a second metal salt solution with a higher reduction potential than that of the first metal is added. Then, the first metal particles are oxidized to form first metal ions when the second metal ions are reduced on the surface of the first metal by electrochemical oxidation reduction reaction, and thus, second metal nano particles having a hollow structure and a larger surface area are obtained. The method is simple and the metal nano particles with uniform particle size are obtained by this method.
摘要翻译：提供了一种制造具有中空结构的金属纳米颗粒的方法。首先，将合适的还原剂加入到第一金属盐溶液中，并且将第一金属离子还原形成第一金属纳米颗粒。接着，在还原剂分解后，添加比第一金属还原电位高的第二金属盐溶液。然后，当通过电化学氧化还原反应在第一金属的表面上还原第二金属离子时，第一金属颗粒被氧化以形成第一金属离子，因此具有中空结构和较大表面积的第二金属纳米颗粒是获得。该方法简单，通过该方法可以获得粒径均匀的金属纳米颗粒。

2. 发明申请

US20090035575A1 METHOD FOR MANUFACTURING METAL NANO PARTICLES HAVING HOLLOW STRUCTURE AND METAL NANO PARTICLES MANUFACTURED BY THE METHOD 有权
标题翻译：制备具有中空结构的金属纳米颗粒的方法和方法制备的金属纳米颗粒
公开(公告)号：US20090035575A1
公开(公告)日：2009-02-05
申请号：US11873982
申请日：2007-10-17
申请人： Li-Duan Tsai , Kan-Lin Hsueh , Sung-Chun Chang , Man-Yin Lo , Yu-Min Peng , Chun-Chieh Huang , Ru-Shi Liu , Hao Ming Chen , Hsin-Chieh Peng
发明人： Li-Duan Tsai , Kan-Lin Hsueh , Sung-Chun Chang , Man-Yin Lo , Yu-Min Peng , Chun-Chieh Huang , Ru-Shi Liu , Hao Ming Chen , Hsin-Chieh Peng
IPC分类号： B32B15/02 , B22F9/16
CPC分类号： B22F9/24 , B22F2001/0029 , Y10T428/2982
摘要： A method for manufacturing metal nano particles having a hollow structure is provided. First, a suitable reducing agent is added into a first metal salt solution, and first metal ions are reduced to form first metal nano particles. Next, after the reducing agent is decomposed, a second metal salt solution with a higher reduction potential than that of the first metal is added. Then, the first metal particles are oxidized to form first metal ions when the second metal ions are reduced on the surface of the first metal by electrochemical oxidation reduction reaction, and thus, second metal nano particles having a hollow structure and a larger surface area are obtained. The method is simple and the metal nano particles with uniform particle size are obtained by this method.
摘要翻译：提供了一种制造具有中空结构的金属纳米颗粒的方法。首先，将合适的还原剂加入到第一金属盐溶液中，并且将第一金属离子还原形成第一金属纳米颗粒。接着，在还原剂分解后，添加比第一金属还原电位高的第二金属盐溶液。然后，当通过电化学氧化还原反应在第一金属的表面上还原第二金属离子时，第一金属颗粒被氧化以形成第一金属离子，因此具有中空结构和较大表面积的第二金属纳米颗粒是获得。该方法简单，通过该方法可以获得粒径均匀的金属纳米颗粒。

3. 发明授权

US09236616B2 Fuel cell electrode structure containing platinum alloy black layer, platinum alloy carbon support layer and substrate layer and fuel cell using the same 有权
标题翻译：包含铂合金黑层，铂合金碳载体层和基底层的燃料电池电极结构和使用其的燃料电池
公开(公告)号：US09236616B2
公开(公告)日：2016-01-12
申请号：US12651407
申请日：2009-12-31
申请人： Chiu-Ping Huang , Kan-Lin Hsueh , Li-Duan Tsai , Sung-Chun Chang , Fu-Chi Wu , Du-Yuan Yu
发明人： Chiu-Ping Huang , Kan-Lin Hsueh , Li-Duan Tsai , Sung-Chun Chang , Fu-Chi Wu , Du-Yuan Yu
IPC分类号： H01M4/92 , H01M8/10 , H01M4/86
CPC分类号： H01M4/921 , H01M4/8642 , H01M4/926 , H01M8/1004 , Y02E60/522
摘要： An electrode structure of a fuel cell for power generation comprises an anodic structure, a cathodic structure, and an ionic exchange membrane disposed between the anodic and cathodic structures. The anodic and cathodic structures respectively are formed by multi-layer structures, to reduce the fuel crossover from the anodic structure to the cathodic structure, to reduce the catalysts applied amount, and to increase an output electrical energy of the fuel cell. The multi-layer structure of the anodic structure comprises a thin platinum alloy black layer, a Pt alloy layer disposed on the carbon material, and a substrate.
摘要翻译：用于发电的燃料电池的电极结构包括阳极结构，阴极结构和设置在阳极和阴极结构之间的离子交换膜。阳极和阴极结构分别由多层结构形成，以减少从阳极结构到阴极结构的燃料交叉，减少催化剂的使用量，并增加燃料电池的输出电能。阳极结构的多层结构包括薄的铂合金黑层，设置在碳材料上的Pt合金层和基底。

4. 发明申请

US20070154780A1 Electrode structure 审中-公开
标题翻译：电极结构
公开(公告)号：US20070154780A1
公开(公告)日：2007-07-05
申请号：US11618154
申请日：2006-12-29
申请人： Chiu-Ping Huang , Kan-Lin Hsueh , Li-Duan Tsai , Sung-Chun Chang , Fu-Chi Wu , Du-Yuan Yu
发明人： Chiu-Ping Huang , Kan-Lin Hsueh , Li-Duan Tsai , Sung-Chun Chang , Fu-Chi Wu , Du-Yuan Yu
IPC分类号： H01M4/96 , H01M8/10 , H01M4/92
CPC分类号： H01M4/921 , H01M4/8642 , H01M4/926 , H01M8/1004 , Y02E60/522
摘要： An electrode structure of a fuel cell for power generation comprises an anodic structure, a cathodic structure, and an ionic exchange membrane disposed between the anodic and cathodic structures. The anodic and cathodic structures respectively are formed by multi-layer structures, to reduce the fuel crossover from the anodic structure to the cathodic structure, to reduce the catalysts applied amount, and to increase an output electrical energy of the fuel cell. The multi-layer structure of the anodic structure comprises a thin platinum alloy black layer, a Pt alloy layer disposed on the carbon material, and a substrate.
摘要翻译：用于发电的燃料电池的电极结构包括阳极结构，阴极结构和设置在阳极和阴极结构之间的离子交换膜。阳极和阴极结构分别由多层结构形成，以减少从阳极结构到阴极结构的燃料交叉，减少催化剂的使用量，并增加燃料电池的输出电能。阳极结构的多层结构包括薄的铂合金黑层，设置在碳材料上的Pt合金层和基底。

5. 发明申请

US20100104924A1 ELECTRODE STRUCTURE 审中-公开
标题翻译：电极结构
公开(公告)号：US20100104924A1
公开(公告)日：2010-04-29
申请号：US12651407
申请日：2009-12-31
申请人： Chiu-Ping Huang , Kan-Lin Hsueh , Li-Duan Tsai , Sung-Chun Chang , Fu-Chi Wu , Du-Yuan Yu
发明人： Chiu-Ping Huang , Kan-Lin Hsueh , Li-Duan Tsai , Sung-Chun Chang , Fu-Chi Wu , Du-Yuan Yu
IPC分类号： H01M4/00
CPC分类号： H01M4/921 , H01M4/8642 , H01M4/926 , H01M8/1004 , Y02E60/522
摘要： An electrode structure of a fuel cell for power generation comprises an anodic structure, a cathodic structure, and an ionic exchange membrane disposed between the anodic and cathodic structures. The anodic and cathodic structures respectively are formed by multi-layer structures, to reduce the fuel crossover from the anodic structure to the cathodic structure, to reduce the catalysts applied amount, and to increase an output electrical energy of the fuel cell. The multi-layer structure of the anodic structure comprises a thin platinum alloy black layer, a Pt alloy layer disposed on the carbon material, and a substrate.
摘要翻译：用于发电的燃料电池的电极结构包括阳极结构，阴极结构和设置在阳极和阴极结构之间的离子交换膜。阳极和阴极结构分别由多层结构形成，以减少从阳极结构到阴极结构的燃料交叉，减少催化剂的使用量，并增加燃料电池的输出电能。阳极结构的多层结构包括薄的铂合金黑层，设置在碳材料上的Pt合金层和基底。

6. 发明申请

US20070048592A1 Composition, complex and method for enhancing catalysts utilization 审中-公开
标题翻译：组合物，复合物和提高催化剂利用的方法
公开(公告)号：US20070048592A1
公开(公告)日：2007-03-01
申请号：US11429108
申请日：2006-05-08
申请人： Fu-Chi Wu , Li-Duan Tsai , Kan-Lin Hsueh , Du-Yuan Yu , Chiou-Ping Huang , Sung-Chun Chang
发明人： Fu-Chi Wu , Li-Duan Tsai , Kan-Lin Hsueh , Du-Yuan Yu , Chiou-Ping Huang , Sung-Chun Chang
IPC分类号： H01M4/86 , H01M4/92 , H01M4/96 , H01M4/88 , B01J31/00 , B01J21/18
CPC分类号： H01M8/1004 , H01M4/8605 , H01M4/92 , H01M4/925 , H01M4/926
摘要： The present invention relates to a composition for enhancing the utilization of catalysts in fuel cell, comprising catalysts, proton-exchanged ionic polymers, and coupling agents. The coupling agents are bonded to the catalysts or catalyst carriers by a B1 functional group and bonded to the proton-exchanged ionic polymers by a B2 functional group. The present invention also relates to a method for enhancing the utilization of catalysts in fuel cell, comprising the steps of (a) utrasonicating catalysts; (b) adding coupling agents to bond to the catalysts; (c) adding a perfluoro polymer to form a catalyst-coupling agent-perfluoro polymer complex whereby developing stable dispersion; wherein the coupling agents in step (b) are bonded to the catalysts by a B1 functional group and bonded to a perfluoro polymer by a B2 functional group. The present invention also provides a complex for enhancing the utilization of catalysts in fuel cell, comprising catalysts, coupling agents, and proton-exchanged ionic polymers, wherein the coupling agents are bonded to the catalysts by a B1 functional group and bonded to the perfluoro polymer by a B2 functional group to form a complex.
摘要翻译：本发明涉及一种提高燃料电池中催化剂利用率的组合物，其中包括催化剂，质子交换离子聚合物和偶联剂。偶联剂通过B1官能团键合到催化剂或催化剂载体上，并通过B2官能团与质子交换的离子聚合物键合。本发明还涉及一种提高燃料电池中催化剂利用率的方法，包括以下步骤：（a）挥发催化剂; （b）加入偶联剂以结合到催化剂上; （c）加入全氟聚合物以形成催化剂偶联剂 - 全氟聚合物络合物，从而形成稳定的分散体; 其中步骤（b）中的偶联剂通过B1官能团与催化剂结合并通过B2官能团与全氟聚合物键合。本发明还提供了一种用于增强燃料电池中催化剂的利用的复合物，其包括催化剂，偶联剂和质子交换的离子聚合物，其中偶联剂通过B1官能团与催化剂结合并结合到全氟聚合物由B2官能团组成复合物。

7. 发明授权

US08546046B2 Method for fabricating bi-polar plate of fuel cell and bi-polar plate of fuel cell 有权
标题翻译：燃料电池双极板和燃料电池双极板的制造方法
公开(公告)号：US08546046B2
公开(公告)日：2013-10-01
申请号：US12708192
申请日：2010-02-18
申请人： Wen-Lin Wang , Chun-Hsing Wu , Kan-Lin Hsueh , Huan-Ruei Shiu , Wen-Chen Chang , Fang-Hei Tsau , Lung-Yu Sung
发明人： Wen-Lin Wang , Chun-Hsing Wu , Kan-Lin Hsueh , Huan-Ruei Shiu , Wen-Chen Chang , Fang-Hei Tsau , Lung-Yu Sung
IPC分类号： H01M4/64
CPC分类号： H01M8/0245 , B32B7/12 , B32B9/007 , B32B9/041 , B32B15/18 , B32B2307/202 , B32B2457/18 , H01M8/0204 , H01M8/0206 , H01M8/0228 , Y02E60/50 , Y02P70/56 , Y10T156/10
摘要： A method for fabricating a bi-polar plate of a fuel cell and the bi-polar plate thereof are presented. A graphite film is formed first. Next, a polymeric material added with electrically conductive powder is coated on a surface of a metal substrate. The graphite film is disposed on the polymeric material and the polymeric material is hardened to form an adhesive layer, such that the graphite film is attached on the surface of the metal substrate.
摘要翻译：提出了一种制造燃料电池的双极板及其双极板的方法。首先形成石墨膜。接下来，在金属基板的表面上涂布添加导电粉末的聚合物材料。将石墨膜设置在聚合物材料上，聚合物材料硬化以形成粘合剂层，使得石墨膜附着在金属基材的表面上。

8. 发明申请

US20080166542A1 GAS DIFFUSION LAYER, MANUFACTURING APPARATUS AND MANUFACTURING METHOD THEREOF 有权
标题翻译：气体扩散层，制造装置及其制造方法
公开(公告)号：US20080166542A1
公开(公告)日：2008-07-10
申请号：US11954244
申请日：2007-12-12
申请人： Lung-Yu Sung , Kan-Lin Hsueh , Yi-Yie Yan , Shu-Mei He , Shi-Chern Yen
发明人： Lung-Yu Sung , Kan-Lin Hsueh , Yi-Yie Yan , Shu-Mei He , Shi-Chern Yen
IPC分类号： B32B3/00 , B05D1/32 , B05C9/14 , B05D1/36
CPC分类号： H01M8/04276 , H01M8/0234 , H01M8/0247 , Y02P70/56 , Y10T428/24322 , Y10T428/24331 , Y10T428/249978 , Y10T428/24998
摘要： A gas diffusion layer, a manufacturing apparatus and a manufacturing method thereof are provided. The gas diffusion layer having different hydrophilic/hydrophobic structure and channel therein can be manufactured quickly and easily by using a coating mask. The gas diffusion layer is used in various fuel cells to enhance the ability of water management and to solve the problem of flooding at the cathode, the problem of water deficit at the anode, and the problem of gas transfer. The gas diffusion layer includes a gas diffusion medium having a first property and a micro porous layer having a second property. The micro porous layer is formed on one surface of the gas diffusion medium. The micro porous layer has a plurality of channel layers penetrating the gas diffusion medium. One of the first property and the second property is hydrophilic, and the other is hydrophobic.
摘要翻译：提供气体扩散层，制造装置及其制造方法。通过使用涂布掩模，可以快速且容易地制造具有不同的亲水/疏水结构和通道的气体扩散层。气体扩散层用于各种燃料电池，以提高水的管理能力，解决阴极淹水的问题，阳极缺水问题和气体传输问题。气体扩散层包括具有第一特性的气体扩散介质和具有第二特性的微孔层。微孔层形成在气体扩散介质的一个表面上。微孔层具有穿透气体扩散介质的多个通道层。第一个属性和第二个属性之一是亲水的，另一个是疏水的。

9. 发明授权

US08263207B2 Gas diffusion layer, manufacturing apparatus and manufacturing method thereof 有权
标题翻译：气体扩散层，制造装置及其制造方法
公开(公告)号：US08263207B2
公开(公告)日：2012-09-11
申请号：US11954244
申请日：2007-12-12
申请人： Lung-Yu Sung , Kan-Lin Hsueh , Yi-Yie Yan , Shu-Mei He , Shi-Chern Yen
发明人： Lung-Yu Sung , Kan-Lin Hsueh , Yi-Yie Yan , Shu-Mei He , Shi-Chern Yen
IPC分类号： B32B3/24 , H01M8/04
CPC分类号： H01M8/04276 , H01M8/0234 , H01M8/0247 , Y02P70/56 , Y10T428/24322 , Y10T428/24331 , Y10T428/249978 , Y10T428/24998
摘要： A gas diffusion layer, a manufacturing apparatus and a manufacturing method thereof are provided. The gas diffusion layer having different hydrophilic/hydrophobic structure and channel therein can be manufactured quickly and easily by using a coating mask. The gas diffusion layer is used in various fuel cells to enhance the ability of water management and to solve the problem of flooding at the cathode, the problem of water deficit at the anode, and the problem of gas transfer. The gas diffusion layer includes a gas diffusion medium having a first property and a micro porous layer having a second property. The micro porous layer is formed on one surface of the gas diffusion medium. The micro porous layer has a plurality of channel layers penetrating the gas diffusion medium. One of the first property and the second property is hydrophilic, and the other is hydrophobic.
摘要翻译：提供气体扩散层，制造装置及其制造方法。通过使用涂布掩模，可以快速且容易地制造具有不同的亲水/疏水结构和通道的气体扩散层。气体扩散层用于各种燃料电池，以提高水的管理能力，解决阴极淹水的问题，阳极缺水问题和气体传输问题。气体扩散层包括具有第一特性的气体扩散介质和具有第二特性的微孔层。微孔层形成在气体扩散介质的一个表面上。微孔层具有穿透气体扩散介质的多个通道层。第一个属性和第二个属性之一是亲水的，另一个是疏水的。

10. 发明申请

US20110287183A1 MANUFACTURING METHOD OF GAS DIFFUSION LAYER 审中-公开
标题翻译：气体扩散层的制造方法
公开(公告)号：US20110287183A1
公开(公告)日：2011-11-24
申请号：US13183478
申请日：2011-07-15
申请人： Lung-Yu Sung , Kan-Lin Hsueh , Yi-Yie Yan , Shu-Mei He , Shi-Chern Yen
发明人： Lung-Yu Sung , Kan-Lin Hsueh , Yi-Yie Yan , Shu-Mei He , Shi-Chern Yen
IPC分类号： B05D5/00
CPC分类号： H01M8/04276 , H01M8/0234 , H01M8/0247 , Y02P70/56 , Y10T428/24322 , Y10T428/24331 , Y10T428/249978 , Y10T428/24998
摘要： A gas diffusion layer, a manufacturing apparatus and a manufacturing method thereof are provided. The gas diffusion layer having different hydrophilic/hydrophobic structure and channel therein can be manufactured quickly and easily by using a coating mask. The gas diffusion layer is used in various fuel cells to enhance the ability of water management and to solve the problem of flooding at the cathode, the problem of water deficit at the anode, and the problem of gas transfer. The gas diffusion layer includes a gas diffusion medium having a first property and a micro porous layer having a second property. The micro porous layer is formed on one surface of the gas diffusion medium. The micro porous layer has a plurality of channel layers penetrating the gas diffusion medium. One of the first property and the second property is hydrophilic, and the other is hydrophobic.
摘要翻译：提供气体扩散层，制造装置及其制造方法。通过使用涂布掩模，可以快速且容易地制造具有不同的亲水/疏水结构和通道的气体扩散层。气体扩散层用于各种燃料电池，以提高水的管理能力，解决阴极淹水的问题，阳极缺水问题和气体传输问题。气体扩散层包括具有第一特性的气体扩散介质和具有第二特性的微孔层。微孔层形成在气体扩散介质的一个表面上。微孔层具有穿透气体扩散介质的多个通道层。第一个属性和第二个属性之一是亲水的，另一个是疏水的。

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