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    • 3. 发明申请
    • Electrochemical Sensors
    • 电化学传感器
    • US20080035481A1
    • 2008-02-14
    • US10591491
    • 2005-03-04
    • Sean McCormackRichard ComptonGregory WildgooseNathan Lawrence
    • Sean McCormackRichard ComptonGregory WildgooseNathan Lawrence
    • G01N27/26C01B31/02
    • C01B32/174B82Y15/00B82Y30/00B82Y40/00C01B32/05C01B32/20G01N27/308
    • An electrode for use in a electrochemical sensor comprises carbon modified with a chemically sensitive redox-active compound, excluding an electrode based on carbon having derivatised thereon two redox-active species wherein at least one of said species is selected from anthraquinone, phenanthrenequinone and N,N′-diphenyl-p-phenylenediamine (DPPD). The invention further provides a pH sensor comprising: a working electrode comprising carbon modified with a chemically sensitive redox active material; and a counter electrode, wherein the ratio of the surface area of the working electrode to the surface area of the counter electrode is from 1:10 to 10:1. Also provided is a pH sensor comprising: a working electrode comprising carbon modified with a chemically sensitive redox active material, and a counter electrode, wherein the area of the working electrode is from 500 μm2 to 0.1 m2. The uses of these electrodes and sensors are also described.
    • 用于电化学传感器的电极包括用化学敏感的氧化还原活性化合物改性的碳,不包括基于其上衍生有两种氧化还原活性物质的碳的电极,其中至少一种所述物质选自蒽醌,菲醌和N, N'-二苯基对苯二胺(DPPD)。 本发明还提供一种pH传感器,其包括:工作电极,其包含用化学敏感的氧化还原活性材料改性的碳; 和相对电极,其中工作电极的表面积与对电极的表面积之比为1:10至10:1。 还提供了一种pH传感器,包括:包含用化学敏感的氧化还原活性材料改性的碳的工作电极和对电极,其中工作电极的面积为500μm2〜0.1μm, SUP> 2 。 还描述了这些电极和传感器的用途。