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1. 发明申请

US20110313095A1 SELF-CLEANING POLYMERS 失效
标题翻译：自清洁聚合物
公开(公告)号：US20110313095A1
公开(公告)日：2011-12-22
申请号：US13203356
申请日：2010-02-25
申请人： Leonie Felicitas Braun , Alexandra Seeber , Dirk Klingler
发明人： Leonie Felicitas Braun , Alexandra Seeber , Dirk Klingler
IPC分类号： C08L51/04
CPC分类号： C08L33/20 , B01J21/08 , B01J31/06 , B01J31/068 , B01J35/004 , B01J35/0086 , B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C08K3/10 , C08K3/105 , C08K3/11 , C08L9/02 , C08L9/06 , C08L35/04 , C09C1/3676 , C09C1/3692 , C08K3/0075
摘要： The present invention relates to a mixture, comprising at least one thermoplastic polymer as component (A) and at least one photocatalytically active particle, comprising a non-porous core comprising at least one metal oxide or semimetal oxide with a diameter of from 0.1 nm to 1 μm, and, at least to some extent surrounding the core, at least one porous outer layer comprising at least one further metal oxide or further semimetal oxide with an average layer thickness of from 0.1 to 10 nm, as component (B), to a process for the production of this mixture according to any of claims 1 to 5, via mixing of components (A) and (B), to the use of the mixture as photocatalytically active surface, to moldings, comprising this mixture, and to the use of this mixture for the production of moldings.
摘要翻译：本发明涉及一种混合物，其包含至少一种作为组分（A）的热塑性聚合物和至少一种光催化活性颗粒，所述至少一种光催化活性颗粒包含无孔芯，其包含至少一种直径为0.1nm至0.1nm的金属氧化物或半金属氧化物至少在一定程度上围绕所述芯，至少一个多孔外层包含至少一种另外的金属氧化物或另外的半平均层厚度为0.1-10nm的半金属氧化物，作为组分（B），至根据权利要求1至5中任一项所述的混合物的制备方法，通过将组分（A）和（B）混合，将所述混合物用作光催化活性表面，用于包含该混合物的模制品，以及使用这种混合物生产模制品。

2. 发明授权

US08748527B2 Self-cleaning polymers 失效
标题翻译：自清洁聚合物
公开(公告)号：US08748527B2
公开(公告)日：2014-06-10
申请号：US13203356
申请日：2010-02-25
申请人： Leonie Felicitas Braun , Alexandra Seeber , Dirk Klingler
发明人： Leonie Felicitas Braun , Alexandra Seeber , Dirk Klingler
IPC分类号： C09K9/00 , C09B67/00 , C08L33/20 , C08L9/02 , C08L9/06 , C08L35/04 , C08K3/00 , C08K3/10
CPC分类号： C08L33/20 , B01J21/08 , B01J31/06 , B01J31/068 , B01J35/004 , B01J35/0086 , B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C08K3/10 , C08K3/105 , C08K3/11 , C08L9/02 , C08L9/06 , C08L35/04 , C09C1/3676 , C09C1/3692 , C08K3/0075
摘要： The present invention relates to a mixture, comprising at least one thermoplastic polymer as component (A) and at least one photocatalytically active particle, comprising a non-porous core comprising at least one metal oxide or semimetal oxide with a diameter of from 0.1 nm to 1 μm, and, at least to some extent surrounding the core, at least one porous outer layer comprising at least one further metal oxide or further semimetal oxide with an average layer thickness of from 0.1 to 10 nm, as component (B), to a process for the production of this mixture according to any of claims 1 to 5, via mixing of components (A) and (B), to the use of the mixture as photocatalytically active surface, to moldings, comprising this mixture, and to the use of this mixture for the production of moldings.
摘要翻译：本发明涉及一种混合物，其包含至少一种作为组分（A）的热塑性聚合物和至少一种光催化活性颗粒，所述至少一种光催化活性颗粒包含无孔芯，其包含至少一种直径为0.1nm至0.1nm的金属氧化物或半金属氧化物至少在一定程度上围绕所述芯，至少一个多孔外层包含至少一种另外的金属氧化物或另外的半平均层厚度为0.1-10nm的半金属氧化物，作为组分（B），至根据权利要求1至5中任一项所述的混合物的制备方法，通过将组分（A）和（B）混合，将所述混合物用作光催化活性表面，制成包含该混合物的成型体，使用这种混合物生产模制品。

3. 发明授权

US08501868B2 Thermoplastic molding compositions with improved optical properties 失效
标题翻译：具有改善光学性能的热塑性模塑组合物
公开(公告)号：US08501868B2
公开(公告)日：2013-08-06
申请号：US13072099
申请日：2011-03-25
申请人： Matthias Müller , Ludger Leber , Achim Datko , Leonie Felicitas Braun , Christian Lemaire , Piyada Charoensirisomboon , Michel Pepers
发明人： Matthias Müller , Ludger Leber , Achim Datko , Leonie Felicitas Braun , Christian Lemaire , Piyada Charoensirisomboon , Michel Pepers
IPC分类号： C08L33/12 , C08L51/06 , C08L25/12 , C08L33/20 , C08L51/04
CPC分类号： C08L33/12 , C08F285/00 , C08L25/00 , C08L51/003 , C08L51/04 , C08L2207/53 , C08L25/12 , C08F212/08
摘要： The present invention relates to thermoplastic molding compositions having a mixture of (a) from 10 to 50% by weight of a methyl methacrylate polymer as component (A), from 20 to 60% by weight of a copolymer as component (B), and from 20 to 70% by weight of a graft copolymer as component (C). Component (C) is obtainable from components (c1) a core, (c2) a first graft shell, and (c3) a second graft shell. The second graft shell (c3) is obtainable via polymerization of a C1-C8-alkyl ester of methacrylic acid as component (c31) and a further vinylaromatic monomer as component (c32). Graft copolymer (C) is produced via emulsion polymerization and is isolated from the reaction mixture by precipitation resulting from shear. Also disclosed are processes for producing the molding compositions, the use of the molding compositions, and moldings obtainable from the molding compositions.
摘要翻译：本发明涉及具有（a）10至50重量％的作为组分（A）的甲基丙烯酸甲酯聚合物，20至60重量％的作为组分（B）的共聚物的混合物的热塑性模塑组合物，以及 20〜70重量％的作为组分（C）的接枝共聚物。组分（C）可从组分（c1）芯，（c2）第一接枝壳和（c3）第二接枝壳获得。第二接枝壳（c3）可通过作为组分（c31）的甲基丙烯酸的C 1 -C 8烷基酯和作为组分（c32）的另外的乙烯基芳族单体的聚合获得。接枝共聚物（C）通过乳液聚合制备，并通过剪切产生的沉淀从反应混合物中分离。还公开了用于生产模塑组合物的方法，模塑组合物的使用以及可从成型组合物获得的模制品。

4. 发明申请

US20110237749A1 THERMOPLASTIC MOLDING COMPOSITIONS WITH IMPROVED OPTICAL PROPERTIES 失效
标题翻译：具有改进的光学性质的热塑性成型组合物
公开(公告)号：US20110237749A1
公开(公告)日：2011-09-29
申请号：US13072099
申请日：2011-03-25
申请人： Matthias Müller , Ludger Leber , Achim Datko , Leonie Felicitas Braun , Christian Lemaire , Piyada Charoensirisomboon , Michel Pepers
发明人： Matthias Müller , Ludger Leber , Achim Datko , Leonie Felicitas Braun , Christian Lemaire , Piyada Charoensirisomboon , Michel Pepers
IPC分类号： C08L51/06 , C08L33/12 , C08L33/20
CPC分类号： C08L33/12 , C08F285/00 , C08L25/00 , C08L51/003 , C08L51/04 , C08L2207/53 , C08L25/12 , C08F212/08
摘要： The present invention relates to thermoplastic molding compositions comprising a mixture of (a) from 10 to 50% by weight, based on the entirety of components (A), (B), and (C), of a methyl methacrylate polymer as component (A), and (b) from 20 to 60% by weight, based on the entirety of components (A), (B), and (C), of a copolymer as component (B), obtainable via polymerization of a vinylaromatic monomer and of a vinyl cyanide, and (c) from 20 to 70% by weight, based on the entirety of components (A), (B), and (C), of a graft copolymer as component (C), obtainable from (c1) from 50 to 70% by weight, based on (C), of a core as component (C1), obtainable via polymerization of a 1,3-diene and of a vinylaromatic monomer and an agglomeration polymer, and (c2) from 15 to 25% by weight, based on (C), of a first graft shell as component (C2), obtainable via polymerization of a vinylaromatic monomer, of a C1-C8-alkyl ester of methacrylic acid, and/or of a C1-C8-alkyl ester of acrylic acid, and a crosslinking monomer, and (c3) from 15 to 25% by weight, based on (C), of a second graft shell as component (C3), obtainable via polymerization of a C1-C8-alkyl ester of methacrylic acid as component (C31) and a further monomer as component (C32), where it is essential to the invention that component (C32) is a vinylaromatic monomer and the graft copolymer (C) is produced via emulsion polymerization and is isolated from the reaction mixture by precipitation resulting from shear, and also to processes for producing said molding compositions, to the use of these, and to the moldings obtainable therefrom.
摘要翻译：本发明涉及热塑性模塑组合物，其包含（a）10至50重量％，基于组分（A），（B）和（C）的组分（A），（B）和（C））的混合物，所述甲基丙烯酸甲酯聚合物作为组分 A），（b）20〜60重量％，作为成分（B）的共聚物的组分（A），（B）和（C）的全部，可通过乙烯基芳族单体和（c）20〜70重量％的组分（A），（B）和（C））作为组分（C）的接枝共聚物，可从（ c1）基于（C）50〜70重量％的作为组分（C1）的芯可通过1,3-二烯和乙烯基芳族单体和附聚聚合物的聚合获得，和（c2）从 15重量％至25重量％，基于（C），作为组分（C2）的第一接枝壳可通过乙烯基芳族单体聚合得到甲基丙烯酸的C 1 -C 8烷基酯和/或C 1 -C 8烷基酯丙烯酸的-C8-烷基酯，和a 交联单体和（c3）15至25重量％，基于（C），作为组分（C 3）的第二接枝壳可通过作为组分（C31）的甲基丙烯酸的C 1 -C 8烷基酯的聚合）和作为组分（C32）的另外的单体，其中本发明组分（C32）是乙烯基芳族单体并且通过乳液聚合制备接枝共聚物（C）是重要的，并且通过沉淀从反应混合物中分离剪切，以及用于生产所述模塑组合物的方法，使用它们以及由其获得的模制品。

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