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    • 7. 发明授权
    • N,N'-bis(3,4-dicyanophenyl) alkanediamides
    • N,N {40-双(3,4-二氰基苯基)烷二胺
    • US4056560A
    • 1977-11-01
    • US707979
    • 1976-07-23
    • James R. GriffithJacques G. O'Rear
    • James R. GriffithJacques G. O'Rear
    • C08G73/06C07C121/78
    • C08G73/0672C08G73/06
    • N,N'-bis(3,4-dicyanophenyl) alkanediamides of the general formula: ##STR1## wherein R = (CH.sub.2).sub.n-2 and (CH.sub.2).sub.x CH(CH.sub.3)(CH.sub.sub.y ; n = 3 to 20; x = 1 to 8; and y = 1 to 8, prepared by reacting 4-aminophthalonitrile with a saturated aliphatic dicarboxylic acid halide. These dinitriles readily polymerize through heating by themselves or with a metal or with a salt to form polyphthalocyanine resins, of the infinite molecular weight type which are useful as coatings, laminates, adhesives, filament windings, and castings. The general formulas for these polyphthalocyanine resins are: ##STR2## wherein R = (CH.sub.2).sub.n-2 and (CH.sub.2).sub.x CH(CH.sub.3)(CH.sub.2).sub.y ; n = 3 to 20; x = 1 to 8; and y = 1 to 8.
    • N,N'-二(3,4-二氰基苯基)烷二胺,其通式如下:其中R =(CH 2)n-2和(CH 2)x CH(CH 3)(CH 2)y; n = 3〜20; x = 1〜8; 和y = 1-8,通过4-氨基邻苯二甲腈与饱和脂族二羧酸卤化物反应制备。 这些二腈通过自身或用金属或盐加热容易地聚合,形成无限分子量型的聚酞菁树脂,其可用作涂料,层压材料,粘合剂,丝线绕组和铸件。 这些聚酞菁树脂的通式为:其中R =(CH 2)n-2和(CH 2)x CH(CH 3)(CH 2)y; n = 3〜20; x = 1〜8; y = 1〜8。